Abstract: This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.
Type:
Application
Filed:
February 16, 2011
Publication date:
June 9, 2011
Applicant:
ALBEMARLE CORPORATION
Inventors:
John Y. Lee, Paul L. Wiggins, Judit Orgad
Abstract: Methods of processing four-legged slaughter animals for consumption as meat and/or meat product(s) are described. The methods comprise I) contacting exterior surfaces of the live animal at least once with a microbiocidal solution formed from mixing together at least (i) water and (ii) at least one N,N?-bromochloro-5,5-dialkylhydantoin, such contacting occurring at least once when the animal is en route to being slaughtered but before it is killed by exsanguination; or II) contacting the carcass of the animal, after exsanguination, with a microbiocidal solution formed from mixing together at least (i) water and (ii) at least one N,N?-bromochloro-5,5-dialkylhydantoin or III) contacting at least one raw meat product and/or at least one processed meat product derived from the carcass. The contacting can be done one or more times in each of I), II), and III). Considerable advantages, which are described, are realized when using such methods.
Abstract: The present invention relates to flame retarded polyurethane or polyisocyanurate foam formulations, flame retardant additives suitable for use therein, and flame retarded foams made therefrom.
Type:
Application
Filed:
August 6, 2008
Publication date:
June 2, 2011
Applicant:
Albemarle Corporation
Inventors:
Hoover B. Chew, Ravindra R. Joshi, Arthur G. Mack, Augusto C. Ibay
Abstract: This invention relates flame retardant compositions containing low molecular weight brominated anionic, chain transfer, vinyl aromatic polymers, hereinafter “ACTVAP”. The compositions can accommodate high bromine content while still exhibiting a low thermally labile bromine content. The compositions have glass transition temperatures, Tg, that are predictive of acceptable melt flows and heat distortion temperatures (HDT) in HIPS and ABS based formulations substrates. The compositions, are suitable flame retardant candidates for use in thermoplastic formulations, e.g. polystyrene and ABS formulations.
Type:
Application
Filed:
June 23, 2008
Publication date:
June 2, 2011
Applicant:
ALBEMARLE CORPORATION
Inventors:
William J. Layman, JR., Arthur G. Mack, Charles H. Kolich, Govindarajulu Kumar
Abstract: Described are multi-ring antioxidant products comprising at least one sulfur-bridged aromatic hydrocarbon compound substituted on at least one of its aromatic rings by at least one sterically hindered 3,5-dihydrocarbyl-4-hydroxybenzyl moiety. Such products have the formula: R—Sn—R[—S—R]m wherein each R is, independently, an aromatic hydrocarbon group having 6-12 carbon atoms, wherein m is 0-20, wherein n is 1-6 when m is 0, and when n is 1, m is 1-20; and wherein at least one of R, R1, and R2 is substituted by at least one such sterically hindered moiety. The preparation of such products and their use as antioxidants in compositions normally susceptible to oxidative degradation in oxygen or air, e.g., liquid fuel and lubricants, are also described.
Abstract: Process technology is described for producing a reaction-derived product mixture containing a high yield of octylated phenyl-alpha-naphthylamine by catalytic alkylation of phenyl-alpha-naphthylamine with diisobutylene. New reaction-derived product mixtures are produced. Also provided are novel reaction-derived octylated phenyl-alpha-naphthylamine reaction product mixtures from which catalyst residues and excess olefin components have been removed. These reaction product mixtures are effective as antioxidants for various oxygen-sensitive substrate materials such as oils and lubricants. Also described are new octylated phenyl-alpha-naphthylamine product mixtures and their use in forming clear, stable, liquid antioxidant compositions for addition to a wide variety of substrates.
Type:
Application
Filed:
July 21, 2009
Publication date:
May 26, 2011
Applicant:
ALBEMARLE CORPORATION
Inventors:
Steven G. Karseboom, Hassan Y. Elnagar, Vincent J. Gatto, William E. Moehle
Abstract: This invention provides stabilized biodiesels comprising (1) biodiesel, such as fatty acid methyl ester (FAME), (2) mono- or bis-hindered phenolic derived from 2,6-di-tert-butylphenol, and (3) N,N?-di-substituted para-phenylene diamine. Also methods of stabilizing biodiesel are provided involving adding (2) and (3) to (1).
Type:
Application
Filed:
July 30, 2008
Publication date:
May 26, 2011
Applicant:
Albemarle Corporation
Inventors:
Emily R. Schneller, William E. Moehle, Gangkai Zhao
Abstract: Methods are provided for removing impurities from compositions comprising alkyl bromide. Such methods comprise combining such composition with at least one nonvolatile epoxide during distillation to purify the alkyl bromide. Ultra pure alkyl bromide compositions are also provided.
Type:
Application
Filed:
August 28, 2008
Publication date:
May 12, 2011
Applicant:
Albemarle Corporation
Inventors:
William B. Harrod, Dru J. Manuel, Keith G. Anderson, Aaron C. Williams, Kimberly A. Maxwell
Abstract: The present invention relates to the use of quaternary ammonium compounds in the remediation of microbial growth such as mold, funguses, and mildew.
Type:
Grant
Filed:
November 5, 2007
Date of Patent:
April 26, 2011
Assignee:
Albemarle Corporation
Inventors:
Joe D. Sauer, George W. Cook, Jr., Christopher S. Knight
Abstract: Compositions useful for activating catalysts for olefin polymerization are-provided. The compositions are derived from at least: a) compound derived from at least (i) carrier having at least one pair of hydrogen bonded hydroxyl groups, (ii) organoaluminum compound, and (iii) Lewis base, such that each of a majority of aluminum atoms in the organoaluminum compound forms chemical bonds with at least two oxygen atoms from the at least one pair of hydrogen bonded hydroxyl groups; and b) Bronsted acid, wherein the molar ratio of the Bronsted acid to the organoaluminum compound is less than or equal to about 2:1.
Type:
Grant
Filed:
December 4, 2007
Date of Patent:
April 19, 2011
Assignee:
Albemarle Corporation
Inventors:
Lubin Luo, Katherine Wu, Steven P. Diefenbach
Abstract: Methods of processing four-legged slaughter animals for consumption as meat and/or meat product(s) are described. The methods comprise I) contacting exterior surfaces of the live animal at least once with a microbiocidal solution formed from mixing together at least (i) water and (ii) at least one N,N?-bromochloro-5,5-dialkylhydantoin, such contacting occurring at least once when the animal is en route to being slaughtered but before it is killed by exsanguination; or II) contacting the carcass of the animal, after exsanguination, with a microbiocidal solution formed from mixing together at least (i) water and (ii) at least one N,N?-bromochloro-5,5-dialkylhydantoin or III) contacting at least one raw meat product and/or at least one processed meat product derived from the carcass. The contacting can be done one or more times in each of I), II), and III). Considerable advantages, which are described, are realized when using such methods.
Abstract: Methods of processing four-legged slaughter animals for consumption as meat and/or meat product(s) are described. The methods comprise: I) contacting exterior surfaces of the live animal at least once with a microbiocidal solution formed from mixing together at least (i) water and (ii) at least one 1,3-dibromo-5,5-dialkylhydantoin, such contacting occurring at least once when the animal is en route to being slaughtered but before it is killed by exsanguination; or II) contacting the carcass of the animal, after exsanguination, with a microbiocidal solution formed from mixing together at least (i) water and (ii) at least one 1,3-dibromo-5,5-dialkylhydantoin or III) contacting at least one raw meat product and/or at least one processed meat product derived from the carcass. The contacting can be done one or more times in each of I), II), and III). Considerable advantages, which are described, are realized when using such methods.
Abstract: A composition useful for activating catalysts for olefin polymerization Is provided. The composition is derived from at least: carrier; treated organoaluminoxy compound: and ionic compound having at feast one active proton.
Type:
Grant
Filed:
July 2, 2007
Date of Patent:
March 8, 2011
Assignee:
Albemarle Corporation
Inventors:
Zhike Wang, Lubin Luo, Steven P. Diefenbach
Abstract: A composition useful for activating catalysts for olefin polymerization is provided. The composition is derived from at least: carrier; organoaluminoxy compound; N,N-dimethylaniline and pentaflurophenol in amounts such that them are at least two equivalents of pentafluorophenol per equivalent of the N,N-dimethylaniline.
Type:
Grant
Filed:
July 2, 2007
Date of Patent:
March 1, 2011
Assignee:
Albemarle Corporation
Inventors:
Lubin Luo, Zhike Wang, Steven P. Diefenbach
Abstract: Methods are provided for reducing emission of mercury from a gas stream by treating the gas with carbonaceous mercury sorbent particles to reduce the mercury content of the gas; collecting the carbonaceous mercury sorbent particles on collection plates of a hot-side ESP; periodically rapping the collection plates to release a substantial portion of the collected carbonaceous mercury sorbent particles into hoppers; and periodically emptying the hoppers, wherein such rapping and emptying are done at rates such that less than 70% of mercury adsorbed onto the mercury sorbent desorbs from the collected mercury sorbent into the gas stream.
Abstract: Processes are provided for combining nonsubstituted hydrazine (N2H4), a strong acid, alcohol, and tetraalkoxypropane to produce N-alkylpyrazole.
Abstract: Poultry carcasses are contacted with water treated with one or more specified dihalodialkylhydantoin biocides in a processing operation downstream from a scalding tank. The aqueous effluent from that downstream operation or from any location further downstream is recycled to the scalding tank. Surprisingly, the bromine residues from the dihalodialkylhydantoin biocides are much more thermally unstable than, for example, the commonly used microbiocide, sodium hypochlorite. Thus, the effluent from the scalding tank has its active bromine content significantly reduced before it is sent to a water purification facility wherein microbial action is used to reduce the BOD of the waste water before its release to the environment. Thus, injury to this desired microbial action is reduced. In addition, the recycle reduces water consumption in the overall poultry processing operation.
Abstract: Methods are provided for reducing or eliminating bacteria such as Salmonella in eggs for human consumption through the use of at least one N,N-dihalo-5,5-dialkylhydantoin in which each of the alkyl groups independently comprises from 1 to about 6 carbon atoms.
Type:
Application
Filed:
March 25, 2009
Publication date:
January 27, 2011
Applicant:
Albemarle Corporation
Inventors:
George W. Cook, JR., Christopher J. Nalepa, Joe D. Sauer
Abstract: This invention provides a process for reducing the amount of soluble halide in a solution comprising a liquid organic medium, at least one viscosity reducing agent, at least one dihydrocarbylmagnesium compound, and an initial amount of soluble halide. The process comprises mixing at least one alkali metal with the solution at a mole ratio of alkali metal to magnesium of less than about 1:2.5, thereby forming precipitated soluble halides. Also provided by this invention is a process for reducing the amount of soluble halide in a slurry comprising a liquid organic medium, at least one viscosity reducing agent, at least one dihydrocarbylmagnesium compound, solids from the formation of said dihydrocarbylmagnesium compound, and an initial amount of soluble halide. This process comprises mixing at least one alkali metal with the slurry at a mole ratio of alkali metal to magnesium of less than about 1:1.25, thereby forming precipitated soluble halides.
Type:
Grant
Filed:
November 12, 2004
Date of Patent:
January 18, 2011
Assignee:
Albemarle Corporation
Inventors:
Milind M. Pradhan, Chi Hung Cheng, Rajeev S. Mathur, Richard A. Holub, Donald W. Imhoff