Patents Assigned to Anic S.p.A.
  • Patent number: 4833260
    Abstract: A process for the epoxidation of olefinic compounds, consisting of reacting said compounds with hydrogen peroxide either introduced as such or produced by substances capable of generating it under the reaction conditions, in the presence of synthetic zeolites containing titanium atoms, of general formula:xTiO.sub.2.(1-x)SiO.sub.2,where x lies between 0.0001 and 0.04, and possibly in the presence of one or more solvents, operating at a temperature of between 0.degree. and 150.degree. C., and at a pressure of between 1 and 100 ata.
    Type: Grant
    Filed: January 11, 1988
    Date of Patent: May 23, 1989
    Assignee: Anic S.p.A.
    Inventors: Carlo Neri, Bartolomeo Anfossi, Antonio Esposito, Franco Buonomo
  • Patent number: 4623705
    Abstract: The application relates to a process for synthesizing carbonic allyl esters from polyhydric alcohols, which are reacted with diallyl carbonate in the presence of a basic catalyst, which can be chosen from sodium hydroxide, sodium carbonate, sodium alcoholate, organic bases or basic ion exchange resins.The final products obtained differ according to the ratio of the components of the starting mixture. Thus, in the case of diols with a diallyl carbonate/diol ratio greater than or equal to 10, the resultant product is constituted by the bis allyl carbonate of the diol together with a quantity of less than or equal to 10% of oligomers represented mainly by dimers. If the ratio is less than 10, the percentage of oligomers rises until, in the case of an approximately stoichiometric ratio, it reaches a value close to 70% of the reaction product.
    Type: Grant
    Filed: January 24, 1985
    Date of Patent: November 18, 1986
    Assignee: Anic S.p.A.
    Inventors: Ugo Romano, Giuseppe Iori
  • Patent number: 4614815
    Abstract: Process for preparing diesterdiamides, consisting of reacting a diester with a diamine under wet conditions in the presence of suitable solvents and catalysts, to give the diester diamide, together with an ester salt derivative as impurity. The reaction product is then filtered to give a diesterdiamide cake and a mother solution of the reagents which also contains the solvent, the catalyst and the ester salt product. The cake is washed with a solvent of the ester salt, which also dissolves the reagents and catalysts. The mother solution and wash solution are then distilled, the two fractions obtained being recycled to the synthesis and to the wash.
    Type: Grant
    Filed: June 7, 1982
    Date of Patent: September 30, 1986
    Assignee: Anic S.p.A.
    Inventors: Franco Cognigni, Armando Mariano
  • Patent number: 4544725
    Abstract: A composition based on aliphatic polycarbonates containing urethan groups and acrylic or metacrylic end groups, to be cross-linked in the presence of radicalic initiators for their functionalization with acrylic or metacrylic groups of a mixture composed of diols, polyols and their oligomeric derivatives terminated by OH groups and containing in their molecule carbonate groups and urethan groups.
    Type: Grant
    Filed: April 14, 1983
    Date of Patent: October 1, 1985
    Assignee: Anic S.p.A.
    Inventors: Aldo Priola, Ugo Romano, Fiorenzo Renzi
  • Patent number: 4544450
    Abstract: An electrochemical process is disclosed for the synthesis of organic compounds, said process having the unique characteristic that the element evolved at the anode is exploited by having it reacting with the product of electrolysis obtained at the cathode by the presence of an appropriate catalyst. The catalyst may be associated in the most convenient manner to the anode, or it can be the anode itself. The process opens the way to a number of synthesis reaction which may be carried out electrolytically instead of the conventional ways.
    Type: Grant
    Filed: June 30, 1983
    Date of Patent: October 1, 1985
    Assignee: Anic S.p.A.
    Inventors: Ermanno Oberrauch, Lennard Eberson
  • Patent number: 4524092
    Abstract: There is disclosed the coating of a metallic substrate with a cross-linked polymeric film by contacting the substrate with an aqueous composition containing:at least an acrylic or metacrylic compound which can be defined by the general formula: ##STR1## wherein: R is a straight-line or branched aliphatic hydrocarbon radical, either saturated or unsaturated containing from 2 to 10 carbon atoms, or a cycloaliphatic or an aromatic group;R.sub.1 and R.sub.
    Type: Grant
    Filed: September 7, 1983
    Date of Patent: June 18, 1985
    Assignee: Anic S.p.A.
    Inventors: Sebastiano Cesca, Aldo Priola, Fiorenzo Renzi
  • Patent number: 4524187
    Abstract: Isobutylene copolymers, cross-linkable under ambient humidity conditions, characterized by the presence of pendant functions containing a silyl radical, are prepared by a process comprising the preliminary formation of new copolymers of isobutylene with a triene containing a system of two conjugate double bonds in position 1,3 and at least one other double bond of vinyl type, followed by the silylation of the polymers thus produced by means of a silicon derivative chosen from those of formula (I) or (II): ##STR1##
    Type: Grant
    Filed: December 9, 1982
    Date of Patent: June 18, 1985
    Assignees: Anic S.p.A., Dow Corning Corporation
    Inventors: Alberto Greco, Guglielmo Bertolini, Omero Zavattini
  • Patent number: 4517355
    Abstract: A flameproof linear polyester is described containing, copolymerized in the molecule, a phosphorus compound of formula: ##STR1## where R is a hydrogen atom, an alkyl group with 1 to 4 carbon atoms or a hydroxyalkyl group, and R' is a hydrogen atom, a hydroxyalkyl group or the group --(CH.sub.2 CH.sub.2 O).sub.n H, where n varies from 1 to 4. Said linear polyester is prepared by firstly forming a low molecular weight precondensate from a dicarboxylic aromatic acid (or a relative lower alkyl diester) and an alkylene glycol, and then polycondensing in the presence of said phosphorus compound, in such a quantity as to obtain a content of phosphorus (expressed as the metal) in the linear polyester of between 0.4 and 0.8% by weight. The linear polyester thus obtained can be formed into articles such as fibres, film, sheets and other articles which, besides being flameproof, possess improved dyeing characteristics.
    Type: Grant
    Filed: April 20, 1983
    Date of Patent: May 14, 1985
    Assignee: Anic S.p.A.
    Inventors: Giorgio Mercati, Armando Mariano, Fulvio Pertot, Antonio Glionna, Mario Ferri
  • Patent number: 4502881
    Abstract: The description relates to heterocyclic compounds having weed-killing activity and defined by the following general formula: ##STR1## where R is a straight-chain or branched alkyl group with 1 to 6 carbon atoms or the phenyl group, R.sub.1 is a straight-chain or branched alkyl group with 1 to 10 carbon atoms (substituted if required by halide, or phenyl group), an alkenyl group, an alkynyl group, a cycloalkyl group, or the phenyl group.
    Type: Grant
    Filed: March 27, 1984
    Date of Patent: March 5, 1985
    Assignee: ANIC S.p.A.
    Inventors: Renato Francese, Roberta Fruttero, Vittorio Messori, Anna Peluffo
  • Patent number: 4497739
    Abstract: A process for the synthesis of thiocarbamic acid esters by reacting amine compounds having a general formula ##STR1## wherein A is an arylene radical, simple or substituted by halogens hydrocarbon radicals, alkoxy groups, or can be an alkylene radical having from 1 to 15 carbon atoms, straight-line or branched, simple or substituted, whereas X can be hydrogen --NH.sub.2 or can be an H.sub.2 --N--Z group in which the bivalent function Z derives from alkyl, aryl, cycloaryl, alkaryl, aralkyl radicals which can be, in their turn, simple or substituted, R and R' equal or different can be hydrogen or alkyl, aryl, alkaryl radicals and otherwise, with carbon monoxide, in the presence of a catalyst composed of a metallic selenide. The thiocarbamic acid esters are known compounds that find applications as medicaments for plants and as intermediates for organic synthesis.
    Type: Grant
    Filed: February 3, 1983
    Date of Patent: February 5, 1985
    Assignee: Anic S.p.A.
    Inventors: Villiam Giroldini, Carlo Neri
  • Patent number: 4495371
    Abstract: A process for isomerizing styrene or homologues to .beta.-phenylaldehydes, consisting of conducting the isomerization reaction in the presence of a catalyst constituted by synthetic zeolites containing titanium, of formulaxTiO.sub.2.(1-x)SiO.sub.2where x lies between 0.0001 and 0.04, and optionally in the presence of one or more solvents, operating at a temperature of between 30.degree. and 100.degree. C.
    Type: Grant
    Filed: July 14, 1983
    Date of Patent: January 22, 1985
    Assignee: ANIC S.p.A.
    Inventors: Carlo Neri, Franco Buonomo
  • Patent number: 4487952
    Abstract: Process for the preparation of esters of carbamic acids by carbonylation of aromatic nitrocompounds, with carbon monoxide, in the presence of alcohols and of catalyst consisting of metallic selenides.
    Type: Grant
    Filed: February 3, 1983
    Date of Patent: December 11, 1984
    Assignee: Anic S.p.A.
    Inventor: Villiam Giroldini
  • Patent number: 4481342
    Abstract: Method for the copolymerization of ethylene with C.sub.4 -C.sub.8 alpha-olefins by means of a suspension method in an organic liquid, at a temperature of from 50.degree. C. to 70.degree. C.
    Type: Grant
    Filed: May 26, 1983
    Date of Patent: November 6, 1984
    Assignee: Anic S.p.A.
    Inventors: Renzo Invernizzi, Ferdinando Ligorati
  • Patent number: 4480135
    Abstract: A process for oxidizing primary and/or secondary alcohols to the corresponding aldehyde and/or ketone derivatives, consisting of reacting said alcohols with an aqueous solution of hydrogen peroxide in the presence of synthetic zeolites containing titanium atoms, of general formula:xTiO.sub.2.(1-x)SiO.sub.2,where x lies between 0.0001 and 0.04, and possibly in the presence of one or more solvents, operating at a temperature of between 20.degree. and 100.degree. C.
    Type: Grant
    Filed: July 14, 1983
    Date of Patent: October 30, 1984
    Assignee: Anic S.p.A.
    Inventors: Antonio Esposito, Carlo Neri, Franco Buonomo
  • Patent number: 4476327
    Abstract: A process for the synthesis of glycol monomethylethers consisting of reacting an olefin compound, methanol and hydrogen peroxide in aqueous solution in the presence of synthetic zeolites containing titanium atoms, of general formula:xTiO.sub.2.(1-x)SiO.sub.2,where x lies between 0.0001 and 0.04.
    Type: Grant
    Filed: July 14, 1983
    Date of Patent: October 9, 1984
    Assignee: Anic S.p.A.
    Inventors: Carlo Neri, Franco Buonomo, Bartolomeo Anfossi
  • Patent number: 4473688
    Abstract: A high-toughness thermoplastic polyamide composition resistant to impact even at low temperature, formed from polyamides of type 6 or 66 in mixture with alternating elastomer copolyesteramides in a quantity of between 3 and 10% and preferably between 5 and 7% by weight.
    Type: Grant
    Filed: February 22, 1983
    Date of Patent: September 25, 1984
    Assignee: ANIC S.p.A.
    Inventors: Alessandro Zappa, Nicola Di Donato
  • Patent number: 4469897
    Abstract: A method for preparing monoalkylethers of hydroquinone and of substituted hydroquinones of general formula ##STR1## in which R is an alkyl group and R.sub.1 is hydrogen or an alkyl group, wherein a hydroquinone compound of general formula ##STR2## is reacted with an alcohol or formula R-OH in the presence of transition metal salts, either in the presence or in the absence of air or oxygen.
    Type: Grant
    Filed: October 21, 1981
    Date of Patent: September 4, 1984
    Assignee: Anic S.p.A.
    Inventors: Franco Rivetti, Ugo Romano, Nicola Di Muzio
  • Patent number: 4468522
    Abstract: Process for the preparation of (omega-carbalkoxy-nor.alkyl) dialkylamines having a linear alkyl chain, comprising the steps of amination of allyl compounds in which at least an allyl carbon atom is a part of a cyclopropane ring which contains one or two carboxyl or carbalkoxy groups on the carbon atom which is adjacent to the allyl carbon, or is a part of a lactone ring, in the presence of catalysts consisting of triarylphosphine complexes of palladium, or trialkyl phosphite complexes of nickel, and the subsequent hydrogenation of the unsaturated amine thus obtained. By so doing, interesting linear amines are obtained, which contain carboxyl units or carbalkoxy units, said amines being useful as additives for the industry of synthetic fibres (viscosity stabilizers for polycaprolactam).
    Type: Grant
    Filed: April 6, 1982
    Date of Patent: August 28, 1984
    Assignee: Anic S.p.A.
    Inventors: Gian Paolo Chiusoli, Mirco Costa, Luciano Pallini, Giuliana Terenghi
  • Patent number: 4464321
    Abstract: Hollow chitosan fibres for use in ultrafiltration processes are described, and which can be plasticized by the addition of glycerin such that they contain this latter in a quantity variable between 0.5 and 5% by weight with respect to the polymer. Said fibres are prepared by the wet spinning of acid chitosan solutions, using an alkali solution as the external fibre coagulant and a gaseous phase containing a basic gaseous component as the internal fibre coagulant.
    Type: Grant
    Filed: October 7, 1982
    Date of Patent: August 7, 1984
    Assignee: Anic S.p.A.
    Inventors: Francesco Pittalis, Francesco Bartoli, Guido Giovannoni
  • Patent number: 4463099
    Abstract: New immunofluorescence reagents prepared by reacting together a protein, a cross-linking agent and a dye, which are of general formula ##STR1## and which fluoresce between 600 and 900 nm.
    Type: Grant
    Filed: September 16, 1982
    Date of Patent: July 31, 1984
    Assignee: Anic S.p.A.
    Inventors: Vittorio Baroncelli, Claudio Colapicchioni, Ivo Giannini, Filippo Porcelli