Abstract: Promotion of paint adhesion and corrosion resistance on the surface of a non-ferrous metal such as aluminum by contact with an aqueous acidic solution containing an anionic polyacrylic/polyacrylamide copolymer, ammonium zirconium fluoride, nitric acid, and water.

Abstract: New and novel carboxylic acid hydrazides bearing a 2,2,6,6-tetra-alkyl-4-piperidine ring and new and novel polymeric compositions stabilized therewith are provided. The novel compounds which contain a light stabilizing group and a reactive hydrazide functionality in the same molecule are prepared by hydrazinolysis of the ester group of an intermediate carboxylic acid ester which contains the 2,2,6,6-tetralkylpiperidine moiety.

Abstract: Alkanedisulfonic acids, particularly methanedisulfonic acid (methionic acid), can be prepared by reacting the corresponding alkanesulfonic acid with chlorosulfonic acid. The reaction is carried out by heating the reactants with agitation, preferably under substantially anhydrous conditions in the presence of oxygen and at substantially atmospheric pressure. Particularly good yields are obtained using an activated carbon co-catalyst.

Abstract: Methods are provided for abrading dyed fabric to produce a stonewashed effect by tumbling the fabric with stones of a chemical composition that is soluble in wash or rinse liquid for the fabric, where the stones are of sufficient size and hardness to effect abrasion of the fabric without substantial mechanical disintegration of the stones and in a manner simulating the action of pumice stone. The chemical stonewashing composition may be a compacted powder, agglomerate, coagulate, or other integral mass or solid formed from an alkali or alkaline earth metal carbonate, bicarbonate, silicate, sulfate, borate, halide, hydroxide or hydrate or peroxyhydrate thereof, for example.

Abstract: What is described herein is a surface modified U.V. stabilized article which includes a resinous sheet whose sides are both exposed to the air. The surface region of one side of the sheet is substantially fully modified in situ with a stabilizing amount of an ultraviolet light stabilizer material, while the exposed surfaces are substantially free of residual stabilizer and solvent material, and the appearance and degree of surface perfection of the modified side are substantially the same as that of the unmodified side of the sheet.The U.V. stabilized resin article is made by a continuous process comprising immersing a resin body in a suitable liquid media, contacting the surface of the immersed body through the liquid with a solution of a ultraviolet light stabilizer in a suitable organic solvent, and displacing residual stabilizer and solvent from the modified surface in situ.

Abstract: This invention relates to heat and light stabilizer compositions for vinyl halide resin compositions comprising organotinthioalkanol compounds that are stabilized against gelation and precipitation, to methods of preparing the stabilizer compositions, and to stabilized vinyl halide resin compositions.

Abstract: A composition is disclosed for dissolving sulfur and preventing or removing sulfur plugs from sour gas and oil wells or other conduits through which sulfur bearing liquids flow which comprises a major proportion of a liquid or gaseous mercaptan, a minor proportion of a catalyst which is a substantially water-insoluble amine, and minor amount of an activator which is a compound of the formula ##STR1## where R is hydrogen, alkyl, aryl or alkaryl and the alkyl moieties have from 1 to 24 carbon atoms, and x and y are independent values between 0 and 24 provided that x or y is at least 1; a method is also disclosed wherein said composition in an effective amount is injected into a conduit to prevent or remove sulfur plugging, and the composition containing dissolved sulfur is optionally recovered.

Abstract: An ultrasonic nozzle includes an atomizing surface for producing an atomized liquid spray, a liquid-feed passageway for supplying process liquid to the atomizing surface, the passageway having a first-diameter section and a second fluidly connected smaller-diameter section, with a shoulder defined therebetween; an internal shut-off assembly for controlling the supply of process liquid to the atomizing surface, the shut-off assembly including a shut-off rod slidably positioned within the passageway and having a sealing end adapted to cooperate with the shoulder, an actuator piston connected with the opposite end of the shut-off rod and slidable within a cylinder bore which is in fluid communication with the passageway, and a valve actuator for slidably moving the piston and shut-off rod in the passageway between a first closed position and a second open position, by which operation the supply of liquid to the atomizing surface is controlled.

Abstract: A method for producing coatings on a heated substrate, preferably glass, comprises pretreating the substrate with a gaseous composition of water, air and a fluorine compound, and thereafter depositing a fluorine-doped tin-oxide coating on the substrate.

Abstract: Novel thiadiazole compounds of the formula[Z--S--Q--S].sub.x Mwhere: Q is a bivalent thiadiazole ring; Z is a succinate group; M is hydrogen, a metal ion selected from the Periodic Table Groups IA, IIA, IIIA, IB, IIB, IIIB, IVB, VB, and VIB, a (MoO.sub.2).sup.+2 radical, or an amine salt; and X is a whole number equal to the valence of M are used as lubricant additives for providing antiwear and antioxidant properties to lubricant compositions.

Abstract: Phenolic N-(amido)imides are provided which are useful as antioxidant stabilizers for organic materials, including a large variety of synthetic polymers, typically subject to thermooxidative degradation. The antioxidant effectiveness of the phenolic N-(amido)imide stabilizers is enhanced by the deactivating potential of the amido-imide moiety towards metals or metal ions that frequently contaminate polymer compositions and serve to catalyze thermal degradation.

Abstract: N-(2,2,6,6,-tetraalkyl-4-piperidinyl)amide-hydrazides of dicarboxylic acids contain a light stabilizing group, a heat stabilizing group, and a reactive hydrazide functionality in the same molecule. The reactive stabilizers are prepared by reacting 4-amino-2,2,6,6-tetraalkylpiperidines with diesters (or mono ester acid chlorides) of dicarboxylic acids or dialkyl itaconates followed by hydrazinolysis of the ester group of the intermediate mono esteramide. The compounds are useful for introducing permanent heat and light stability to coreactive polymers or copolymers. They are also useful in the stabilization of inert polymeric systems against the degradative effects of heat and light when merely mixed with, rather than reacted with, the polymers for which stabilization is sought.

Abstract: The present invention comprises a stabilized halogen containing polymer, preferably poly(vinyl halide), and more preferably poly(vinyl chloride) composition. A preferred polymer composition is a rigid halogenated polymer such as rigid poly(vinyl chloride). The composition contains at least one metal salt selected from the group consisting of at least one carboxylic acid or derivative thereof having at least two carboxyl groups, at least one carboxyl group and at least one hydroxyl group, at least one carboxyl group and at least one mercaptan, and an aromatic carboxylic acid having at least one carboxyl group. The metal salt is most preferably disodium adipate.

Abstract: Partial or total separation of a mixture of 1,1,1,3,4-pentafluorobutane and 1,1-dichloro-1-fluoroethane by liquid-liquid extraction with methanol based solvent mixtures, such as methanol with ethanolamine or ethylene glycol.

Abstract: Partial or total separation of a mixture of 1,1,1,3,3-pentafluorobutane and 1,1-dichloro-1-fluoroethane by liquid-liquid extraction with solvents containing ethylene glycol, 2-butene-1,4-diol, ethanolamine, propylene glycol, or mixtures thereof, preferably ethylene glycol.

Abstract: Polymer bound stabilizer compounds are provided in which two or more different classes of stabilizers are chemically bound to anhydride containing polymers or copolymers. Polymeric stabilizers are prepared by the reaction of primary amino or hydrazido substituted stabilizers (i.e., antioxidants, light stabilizers, etc.) with some or all of the anhydride groups of the polymer or copolymer to form pendant stabilizer substituted imide or amic acid groups. The polymer bound stabilizers are not lost from the polymer system by volatilization, migration or extraction, even at high temperatures. The polymer bound stabilizer compounds may be used as concentrates to stabilize other polymer systems.

Abstract: A floor finish remover composition containing a solvent, water, and an organosilicon complex formed from a silicate such as sodium metasilicate and a linear, 6-10 carbon, organic compound such as sodium n-octane sulfonate.

Abstract: A composition comprises a thermoplastic or polymeric resin; an organic peroxide; and an organic sulfide antioxidant represented by Formula I, II or III: ##STR1## wherein m, n, r, R.sup.1, R.sup.2, R.sup.3, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are as set forth in the Summary of the Invention.

Abstract: Ultraviolet light stabilizers are chemically bound to anhydride containing polymers or copolymers. Polymeric stabilizers are prepared by the reaction of primary amino or hydrazido-substituted UV absorbers with some or all of the anhydride groups of the polymer or copolymer to form pendant stabilizer substituted imide or amic acid groups. The polymer bound stabilizers are not lost from the polymer system by volatilization, migration, or extraction, even at high temperature. The polymeric stabilizers of this invention may be used as they are or as concentrates to stabilize other polymer systems.

Abstract: Increased efficiency coagulation and washing of latex particles is achieved by coagulating the latex to form particle flocks by application of a combination of mechanical and thermal energy, with up to about 85% of the applied energy being thermal energy. The flocks are thereafter washed by passage in counter-current relationship with wash water. The invention is particularly useful in the coagulation of fluorocarbon latices generated by polymerization, particularly emulsion polymerization.