Patents Assigned to Atochem
  • Patent number: 4657751
    Abstract: The invention concerns the purification of impure aqueous hydrazine hydrate solutions by treating the hydrazine hydrate solution by means of a solid absorbent material consisting of microporous particles whose mean granulometry is smaller than 5 mm.
    Type: Grant
    Filed: February 7, 1985
    Date of Patent: April 14, 1987
    Assignee: ATOCHEM
    Inventors: Michel Alicot, Jacky Pierre
  • Patent number: 4654128
    Abstract: A process for the preparation of an organic trihalomethyl derivative comprising electrolytically reducing a compound of the formula:Cl.sub.x F.sub.3-x C--Brin which x is equal to 0, 1 or 2, in a reaction medium also containing an electrophilic substrate which is void of electrochemical activity at the reduction potential of said compound, and a support electrolyte in an aprotic solvent for a time and at a temperature sufficient to form the desired organic trihalomethyl derivative.
    Type: Grant
    Filed: May 16, 1986
    Date of Patent: March 31, 1987
    Assignee: Atochem
    Inventors: Francis Leroux, Michel Jaccaud
  • Patent number: 4650899
    Abstract: A liquid composition comprising a mixture of isomers of essentially diisocyanates having the diphenylmethane structure, the distribution by weight of isomers in the composition for each 100 parts by weight of the composition being:32 to 55% of the 4,4' isomer,30 to 45% of the 2,4' isomer,5 to 12% of the 3,4' isomer,4 to 10% of the 2,2' isomer, and2 to 5% of the 2,3' isomer;and the method of making the composition by first reacting a benzyl halide with benzene, followed by nitration, hydrogenation, and phosgenation.
    Type: Grant
    Filed: April 26, 1984
    Date of Patent: March 17, 1987
    Assignee: Atochem
    Inventors: Jacques Kervennal, Henri Mathais, Raymond Commandeur
  • Patent number: 4647391
    Abstract: Working fluid/solvent compositions for use in absorption heating and cooling equipment, which compositions comprise a chlorofluoroethane with a boiling point between -40.degree. and +50.degree. C. and at least one solvent with a boiling point above 100.degree. C., the solvent being at least one material having the formula:C.sub.m Cl.sub.2m+1 --(CF.sub.2 --CFCl).sub.n --Xwherein m is zero or one, n is an integer from one to four, and is at least two when m is zero, and X is hydrogen or chlorine, X being hydrogen only when m is one.
    Type: Grant
    Filed: December 23, 1985
    Date of Patent: March 3, 1987
    Assignee: Atochem
    Inventors: Rene Bertocchio, Andre Gagnieur, Henri Mathias
  • Patent number: 4647706
    Abstract: A process for producing 2,2,2-trifluoroethanol or 1,1,1,3,3,3-hexafluoroisopropanol which comprises hydrogenating a fluoro compound having the formula ##STR1## wherein R.sub.1 is hydrogen or CF.sub.3 and R.sub.2 is hydrogen or a straight- or branched-chain alkyl group, which can also be fluoro-substituted, in the liquid phase in the presence of a palladium-on-activated-carbon catalyst, and if desired a tertiary amine co-catalyst.
    Type: Grant
    Filed: July 16, 1985
    Date of Patent: March 3, 1987
    Assignee: Atochem
    Inventors: Bernard Cheminal, Henri Mathais, Marc Thomarat
  • Patent number: 4645786
    Abstract: Polycarbonate-based compositions the fire-resistance of which is improved with small but effective amounts of a urazole salt having the formula: ##STR1## wherein R and R' are the same or different and are hydrogen, an alkyl group having from one to six carbon atoms, phenyl, or halosubstituted phenyl, and M is an alkali metal, many of such fire-resistive polycarbonates being transparent, together with method for preparing such fire-resistive polycarbonates.
    Type: Grant
    Filed: August 9, 1985
    Date of Patent: February 24, 1987
    Assignee: Atochem
    Inventors: Joel Perthuis, Pierre Poisson
  • Patent number: 4643851
    Abstract: The invention relates to the preparation of trifluoroacetyl chloride by catalytic chlorination of trifluoroacetaldehyde with chlorine. Catalysis is performed in the vapor phase in a fixed bed or a fluidized bed reactor with an activated carbon catalyst. Optionally, hydrochloric acid and/or an inert diluent can be present with the reactant without affecting the results of this process.
    Type: Grant
    Filed: September 15, 1983
    Date of Patent: February 17, 1987
    Assignee: Atochem
    Inventors: Bernard Cheminal, Henri Mathais, Marc Thomarat
  • Patent number: 4642386
    Abstract: A process for preparing pure fluoral hydrate or hexafluoroacetone hydrate which comprises reacting a hemiacetal with the formula ##STR1## wherein R is hydrogen or CF.sub.3, with water in a distillation column, removing respectively the methanol or ethanol produced at the head of the column, and recovering at the bottom of the column the pure hydrate so produced.
    Type: Grant
    Filed: July 16, 1985
    Date of Patent: February 10, 1987
    Assignee: Atochem
    Inventors: Bernard Cheminal, Henri Mathais, Marc Thomarat
  • Patent number: 4639430
    Abstract: A catalyst support consisting essentially of a mixture of silica and magnesium chloride, said support having a porous structure and containing less than 100 micromoles of hydroxyl groups per gram of support; the process of making such support by heating such mixture at a temperature below about 720.degree. C. in the presence of a dehydrating agent, and catalysts consisting essentially of such support and at least one active component.
    Type: Grant
    Filed: May 22, 1986
    Date of Patent: January 27, 1987
    Assignee: Atochem
    Inventors: Veronique Pasquet, Roger Spitz
  • Patent number: 4636368
    Abstract: A stabilized acidic aqueous composition comprising hydrogen peroxide, metallic ions, and 3-amino-1,2,4-triazine, said triazine being present in an amount sufficient to improve the stability of said composition against decomposition of said peroxide and the methods of utilizing such composition to treat metallic surfaces and to precipitate hydrated uranium peroxide from a solution containing uranium dissolved therein.
    Type: Grant
    Filed: April 17, 1985
    Date of Patent: January 13, 1987
    Assignee: Atochem
    Inventor: Christian Pralus
  • Patent number: 4633004
    Abstract: Fluorosilanes containing at least one partially or totally fluorinated chain and at least one silicon chain linked with a thioether bridge, the fluorosilanes being prepared by radical addition of a silicon thiol to a fluorinated olefin, and the fluorosilanes being useful intermediates for the preparation of fluorinated silicones such as fluorinated silicone elastomers.
    Type: Grant
    Filed: November 12, 1985
    Date of Patent: December 30, 1986
    Assignee: Atochem
    Inventors: Bernard Boutevin, Yves Pietrasanta
  • Patent number: 4628103
    Abstract: A process for preparing 3-amino-1,2,4-triazole by reacting hydrazine hydrate, cyanamide and formic acid to form aminoguanidine formate and cyclizing the formate, wherein hydrazine hydrate and formic acid are simultaneously added to the cyanamide at 0.degree. to 10.degree. C. and a pH of 6 to 7, maintaining the mixture at 60.degree. to 100.degree. C. and a pH of 7 to 8 to form aminoguanidine formate, evaporating the aminoguanidine formate solution at 30.degree. to 60.degree. C. to a solids content of 100 to 700 g/L, filtering and washing the formate to a dicyandiamide content below 0.25%, and heating the formate at 110.degree. to 200.degree. C. to obtain the aminotriazole.
    Type: Grant
    Filed: June 19, 1985
    Date of Patent: December 9, 1986
    Assignee: Atochem
    Inventor: Michel Alicot
  • Patent number: 4622104
    Abstract: A process for the separation of ethylene glycol from glycolated water obtained from the bottom of an ethylene oxide desorption column in a process for the manufacture of ethylene oxide by catalytic oxidation of ethylene by oxygen in the vapor phase, comprising feeding said glycolated water directly from the bottom of said ethylene oxide desorption column into the top of a separation column having therebelow up to 12 theoretical plates and adding sufficient indirect heat to said glycolated water to form two streams; a first gaseous stream consisting essentially of steam which is removed from the top of said separation column and introduced into said ethylene oxide desorption column to serve therein as the desorption fluid, and a second aqueous stream containing from about 40% to 90% by weight of ethylene glycol which is removed from the bottom of said separation column.
    Type: Grant
    Filed: July 16, 1984
    Date of Patent: November 11, 1986
    Assignee: Atochem
    Inventors: Henri Neel, Francis Delannoy
  • Patent number: 4620050
    Abstract: Process for the manufacture of high purity ethylene by the decomposition in the gaseous phase of certain aliphatic carboxylic acid esters, at a temperature between about 150.degree. and 300.degree. C. in the presence of a zeolite having a pore diameter above about 0.6 nm as the catalyst.
    Type: Grant
    Filed: September 3, 1985
    Date of Patent: October 28, 1986
    Assignee: ATOCHEM
    Inventors: Jean-Marie Cognion, Pierre Durual
  • Patent number: 4619663
    Abstract: A stabilizing composition for and a process for the bleaching of cellulose-containing fibers or fabrics in a bleaching bath containing an oxidizing agent without any degradation thereof due to the presence of iron or ferrous metals, comprising adding to said bath a stabilizing composition consisting essentially of:______________________________________ A metal chelating agent 1-2 g/l of bath Sodium metasilicate 0-8 g/l of bath pentahydrate Sodium tetraborate 5-10 g/l of bath decahydrate A soluble alkaline phosphate 10-15 g/l of bath (calculated in weight of anhydrous product) A non-ionic wetting agent 1-2 g/l of bath ______________________________________
    Type: Grant
    Filed: April 25, 1984
    Date of Patent: October 28, 1986
    Assignee: Atochem
    Inventor: Gerard Tatin
  • Patent number: 4617341
    Abstract: A sizing agent for the paper industry comprising a cationic oligourethane latex; said urethane having the formula: ##STR1## in which R.sub.2 is an alkylene radical containing a C.sub.2 -C.sub.6 radical or a polyoxyalkylenic radical of a degree of polycondensation of 1 to 4,R.sub.3 is an alkyl radical containing at least 7 carbon atoms, andR.sub.4 and X represent the remainder of the quaternizing agent R.sub.4 Xwith(a) R.sub.1 representing ##STR2## R.sub.5 being an aliphatic radical containing C.sub.4 as a maximum and n varying from 1 to 3; or(b) R.sub.1 representing ##STR3## R.sub.5 being ##STR4## in which R.sub.2, R.sub.3, R.sub.4 and X having the preceding definitions and n varying from 2 to 6; and the method of making the oligourethane latex.
    Type: Grant
    Filed: May 20, 1985
    Date of Patent: October 14, 1986
    Assignee: Atochem
    Inventors: Antoine Laine, Claude Senez
  • Patent number: 4617354
    Abstract: Adhesive compositions with thermoreversible crosslinking resulting from the reaction of a divinyl ether having the formula CH.sub.2 .dbd.CH--O--R--O--CH.dbd.CH.sub.2, R being aliphatic, aromatic or cycloaliphatic, with a copolymer resulting from the copolymerization of an olefin with an ethylenically unsaturated monocarboxylic acid and, optionally, an ester of an ethylenically unsaturated monocarboxylic acid, the proportion being 0.1 to 5 percent by weight of the divinyl ether to 99.9 to 95 percent by weight of the copolymer.
    Type: Grant
    Filed: January 24, 1985
    Date of Patent: October 14, 1986
    Assignee: Atochem
    Inventors: Daniel Augustin, Christian Leriche, Pierre Poisson
  • Patent number: 4614678
    Abstract: Composite material comprising a flexible sheath covering a roving of fibers impregnated to the core with a finely powdered thermoplastic, the melting point of which thermoplastic is equal to or greater than that of the sheathing material, together with process and apparatus for producing same by using an extrusion coating technique, the coating die being mounted on a leakproof powder fluidization tank via a blowing chamber thermally insulated from the tank.
    Type: Grant
    Filed: June 25, 1984
    Date of Patent: September 30, 1986
    Assignee: Atochem
    Inventor: Roland A. Ganga
  • Patent number: 4611833
    Abstract: Pipelines internally coated with heat sensitive materials to protect the pipe from corrosion and/or abrasion, the edges of the pipe sections and the interiors of the pipe sections being coated with stainless metal alloy for a distance from one-half to three pipe diameters from the edge of the pipe, the interior of the pipe being coated with the heat sensitive material except for a reserved zone of the interior measuring from one to two diameters from the edge of the section and the heat sensitive material covering about 20 millimeters of the stainless alloy coating, the pipes being joined by a first weld of the stainless alloy and an outer weld of the pipe metal, together with methods for the preparation of such pipelines.
    Type: Grant
    Filed: May 10, 1985
    Date of Patent: September 16, 1986
    Assignee: Atochem
    Inventor: Pierre L. Lescaut
  • Patent number: 4612133
    Abstract: Compositions for use as fluids in absorption heat pumps, which compositions comprise a chlorofluoro-hydrocarbon heat exchange fluid, an amide or glycol-ether solvent vehicle, and at least one metal salt of an alkylarylsulfonate which stabilizes the fluid against decomposition, together with use of the compositions in absorption heat pumps.
    Type: Grant
    Filed: July 3, 1985
    Date of Patent: September 16, 1986
    Assignees: Atochem, Gaz de France
    Inventors: Rene Bertocchio, Bernard Genest, Henri Mathais