Abstract: 2-Ethylhexyl acrylate is manufactured according to a process for the direct esterification of acrylic acid with 2-ethylhexanol catalysed by sulphuric acid, the acrylic acid subjected to the esterification being stabilized by at least one stabilizing agent, the said esterification being followed by the neutralization by a base of the crude reaction mixture (B1) obtained, the resulting salts passing into the aqueous phase (A1) of the said mixture, the organic phase (O1) and the aqueous phase (A1) resulting from this neutralization being separated and the 2-ethylhexyl acrylate being recovered from the organic phase (O1). To suppress the emulsions which appear during the said neutralization, the stabilizer or stabilizers of acrylic acid is/are chosen with the exclusion of hydroquinone, in the absence of which the aqueous phase of the process is stabilized before and/or during the neutralization.
Abstract: The present invention relates to an initiation system composed of the reaction product of at least one cyclic siloxane and at least one organometalic compound of sufficient reactivity to open the siloxane ring.
Application of the present invention is to the preparation of homopolymers of (meth)acrylic, vinylaromatic or diene monomers, random or block copolymers of these monomers and, in particular, application to poly(methylmethacrylate) with a high content of isotactic triads.
Type:
Grant
Filed:
April 10, 1998
Date of Patent:
December 3, 2002
Assignee:
Atofina
Inventors:
Thomas Zundel, Philippe Teyssie, Robert Jerome, Christophe Navarro
Abstract: A method for preparing hydrazine hydrate comprising: (a) reacting ammonia, hydrogen peroxide and methyl ethyl ketone in a working solution to form an azine; (b) separating the working solution from a mixture comprising the azine, methyl ethyl ketone oxime and optionally the methyl ethyl ketone which had not reacted; (c) recycling the working solution to step (a) after an optional treatment; (d) hydrolyzing the azine to obtain hydrazine hydrate and regenerating the methyl ethyl ketone; (e) recycling to step (a) the methyl ethyl ketone. In step (d) the methyl ethyl ketone oxime is purged.
Abstract: The present invention relates to a lithium-ion battery element which is chosen from the separator and the electroactive layers and which results from the forming of a microcomposite powder comprising a fluoropolymer in the form of particles between 0.1 and 0.5 &mgr;m in size and fillers.
Abstract: An improved liquid phase process is provided for the fluorination of perchloroethylene to 1,1-dichloro-2,2,2-trifluoroethane in the presence of an antimony catalyst.
Type:
Grant
Filed:
March 28, 2002
Date of Patent:
November 12, 2002
Assignee:
Atofina Chemicals, Inc.
Inventors:
Maher Y. Elsheikh, Jonathan M. Tracy, John A. Wismer
Abstract: This process for the manufacture of norbornene from dicyclopentadiene (DCPD) and ethylene is characterized in that the DCPD is subjected to partial monomerization to CPD by preheating:
at a temperature of 140° C. to 240° C.; and
under a pressure of 20 to 300 bar abs., before reacting it with the ethylene;
with an ethylene/DCPD molar ratio of 1 to 20;
at a temperature of 200° C. to 320° C.;
under a pressure of 20 to 300 bar abs.; and
with a residence time of 1 to 10 minutes, under stable reaction conditions between the DCPD, the CPD and the ethylene.
Abstract: Polyester injection-moulded parts based on a polyester (A) and on a copolymer (B) of ethylene and of an unsaturated epoxy, such that weight % (B)×MFI (A+B)/MFI(A) is greater than 3 and in this expression:
MFI (A+B) denotes the melt flow index of the modified polyester, that is to say the blend of (A) and (B) and of any fillers;
MFI (A) denotes the melt flow index of the polyester (A) and of any fillers (without (B)); and
weight % (B) denotes the percentage by weight of (B) in the blend of (A) and (B) and of any fillers.
Type:
Grant
Filed:
June 29, 2000
Date of Patent:
November 5, 2002
Assignee:
Atofina
Inventors:
Patrice Perret, Jacques Komornicki, Yoshiyuki Miyaki
Abstract: For the anionic polymerization of lactams: (a) (i) a catalyst capable of creating a lactamate and (ii) a regulator chosen from amides of formula R1-NH—CO—R2, in which R1 can be substituted by an R3-CO—NH— or R3-0— radical and in which R1, R2 and R3 denote an aryl, alkyl or cycloalkyl radical, are dissolved in the molten lactam, (a1) the solution from stage (a) is cooled, optionally to the solid state in a form which can be divided, (a2) the product from stage (a1) is optionally reheated to a temperature below the polymerization temperature of the lactam, (a3) optionally, the product from stage (a1) is reheated and is maintained at a temperature between the melting temperature of the lactam and 15° C. above, and (b) the produce from any one of stages (a1), (a2) or (a3) is introduced into a mixing device or mold and is then heated to a temperature sufficient to obtain the bulk polymerization of the lactam.
Type:
Application
Filed:
September 24, 2001
Publication date:
October 31, 2002
Applicant:
ATOFINA
Inventors:
Nicola Hoogen, Andreas Wollny, Heike Faulhammer, Rolf Muelhaupt
Abstract: A conduit for transporting non-volatile liquids is provided in which the conduit's internal surfaces have a surface energy lower than that of the non-volatile liquid.
Type:
Grant
Filed:
June 13, 2000
Date of Patent:
October 29, 2002
Assignee:
Atofina Chemicals, Inc.
Inventors:
Sivakumar Gopalnarayanan, Scott R. Gaboury
Abstract: To manufacture sulphurated products derived from olefin(s) by sulphurization using sulphur and hydrogen sulphide, the reaction is carried out in the presence of a solid acid catalyst and of a solid basic catalyst.
Type:
Grant
Filed:
April 25, 2001
Date of Patent:
October 29, 2002
Assignee:
Atofina
Inventors:
Piet Luyendijk, Jean-Francois Devaux, Bernard Monguillon
Abstract: These compounds are represented by the formulae (Ia) and (Ib). To prepare them, in a first stage, p-xylylene dichloride is reacted with a compound (II) to produce a compound (III) and, in a second stage, the compound (III) thus obtained is reacted with a compound of formula (IVa) or (IVb), resulting in an aqueous solution of the compound (Ia) or (Ib) respectively, the water of which is removed, if appropriate.
Abstract: A thermoforming multilayer film comprising successively: at least one layer chosen from layers A1 and A2, an optional layer B1, a layer B2, a layer B3, and an optional layer B4. A1 comprises a fluoropolymer A111 or a polymer A112 consisting essentially of alkyl(methyl)acrylate units or a blend of the two, layer A2 consists of ink, layer B1 comprises a fluoropolymer B111 or a polymer B112 consisting essentially of alkyl(meth)acrylate units or a blend of the two, layer B2 is based on a polyamide, layer B3 consists of polyolefin functionalized with unsaturated carboxylic anhydride and layer B4 comprises polyolefin. A process for producing the multilayer film comprising co-extrusion is described.
Type:
Application
Filed:
January 22, 2002
Publication date:
October 17, 2002
Applicant:
ATOFINA
Inventors:
David Silagy, Frank Bertoux, Phillipe Bussi, Anthony Bonnet
Abstract: The invention relates to a thermoplastic composition comprising: a matrix-forming thermoplastic polymer (M), rigid nodules obtained by radical polymerization, and optionally an impact modifier (S). It also relates to a process comprising, in a first stage, forming a homogeneous solution of precursor of the nodules in the thermoplastic (M) in the molten state, in a second stage, introducing the initiator while remaining at a temperature below which the initiator becomes active, and, in a third stage, heating to a temperature sufficient to cause crosslinking of the precursor and to form rigid nodules while kneading the composition, the impact modifier being introduced during the first or the second stage.
Abstract: Antinoise and flame-resistant barriers formed by supports and by sheets fixed thereon, characterized by the fact that the sheets consist of a methylmethacrylate copolymer and acrylic acid comprised between 1 and 20% by weight.
Type:
Grant
Filed:
March 10, 1998
Date of Patent:
October 8, 2002
Assignee:
Atofina
Inventors:
Alberto Luca Stasi, Fabio Giberti, Cristiano De Marco