Abstract: Processes for the preparation of adherent polyvinylidene fluoride, hexafluoropropylene coatings on objects and for the direct production of open celled foams from a polymer latex without a need for any blowing agent.
Type:
Application
Filed:
April 29, 2002
Publication date:
April 24, 2003
Applicant:
ATOFINA Chemicals, Inc.
Inventors:
Ramin Amin-Sanayei, Lawrence K. Wempe, Kurt Arthur Wood, Stefano Finocchiaro, Delphine Tillier
Abstract: Process for the preparation of azine and of hydrazine by bringing ammonia, hydrogen peroxide and a reactant carrying a carbonyl group into contact with a working solution, comprising:
the treatment of an aqueous stream resulting from the circuit for the regeneration of the said working solution with an amount of acid such that the pH of the said stream is brought to a value of less than 6.4, then
the recycling of the said stream in the reactor for the synthesis of the azine.
Type:
Grant
Filed:
April 5, 2001
Date of Patent:
April 22, 2003
Assignee:
Atofina
Inventors:
Georges Brenguer, Rémi Jullin, Jean-Philippe Ricard
Abstract: To manufacture sulphurated products deriving from olefin(s) by sulphurization using sulphur and hydrogen sulphide, the reaction is carried out in the presence of a zeolite.
Abstract: The present invention relates to film consisting of a blend comprising (i) 70 to 98% by weight of a polymer (Z) chosen from (a) a poly-ethylene (C) obtained by metallocene catalysis, (b) a copolymer (A) of ethylene and of a monomer chosen from vinyl acetate, the vinyl acetate content being between 18 and 40% by weight and an alkyl (meth)acrylate and (c) a blend thereof, (ii) 2 to 30% by weight of high-density polyethylene. The present invention also relates to gloves made of the above films. These gloves are manufactured by thermal welding of the films.
Abstract: The invention concerns a method for preparing nitroxides, which consists in oxidising, in a two-phase medium, using an aliphatic peroxide, secondary amines with steric hindrance or having a —CH in the nitrogen atom &agr;.
Abstract: The invention concerns a method for making an organo-soluble (meth)acrylic resin composition which consists in: esterifying the COOH functions of a polymer comprising units derived from methacrylic acid, in a solvent medium, with Ti(OR)4, R representing one among ethyl, isopropyl, n-butyl, t-butyl, 2-ethylhexyl and t-amyl. The invention is characterised in that the esterification is carried out in the presence of at least a R′COOH monocarboxylic acid, R′ representing a linear, branched or cyclic C1-C18 alkyl radical; aryl; alkaryl; or aralkyl, by stopping esterification before a gel is formed, when the COOH resin and R′COOH functions have been added with a molar ratio Ti(OR)4/—COOH functions of the resin ranges between 1 and 3, and a molar ratio R′COOH/Ti(OR)4 ranges between 1 and 6.
Type:
Grant
Filed:
January 31, 2002
Date of Patent:
March 18, 2003
Assignee:
Atofina
Inventors:
Marie Humbert, Alain Riondel, Eric Jouandon, Andre Margaillan, Michel Camail, Jean-Louis Vernet
Abstract: A process is provided for preparing a catalyst support for polymerizing &agr;-olefins comprising the steps of: (i) reacting, in the presence of a first electron donor, a chlorine-containing organic compound and a prior mixture of an alkylmagnesien and an aluminoxane and/or aluminosiloxane and/or alkylaluminum and, optionally, a second electron donor; and (ii) activating a product from step (i) in suspension in an inert liquid by means of an activation electron donor, together with the support thus obtained, a catalyst for polymerizing &agr;-olefins, comprising this catalyst support and a group IV transition metal halide, and a process for polymerizing &agr;-olefins, particularly propylene, comprising contacting the &agr;-olefin with the catalyst.
Type:
Grant
Filed:
July 28, 2000
Date of Patent:
March 18, 2003
Assignee:
Atofina
Inventors:
Thierry Saudemont, Jean Malinge, Jean-Loup LaCombe, Daniel Cochard, Henri Violle
Abstract: The invention relates to a stripping composition which can be used in the construction field, especially for the stripping of external organic coatings, such as exterior waterproof coatings and thin films, and in the yachting field, for the stripping of antifouling coatings, characterized in that it comprises:
at least one dibasic ester,
at least one dipolar aprotic solvent,
at least one inorganic filler,
water,
at least one cellulose thickener,
at least one dispersing agent and activators.
Abstract: A radical (co)polymerization of ethylene is carried out under high pressure in the presence of at least one initiating free radical (Z•) and of at least one controlling stable free radical (SFR•) which comprises the indoline nitroxide backbone represented by the formula (I).
A is a hydrocarbonaceous chain forming an aromatic ring with the two carbon atoms to which it is attached, this ring being able to carry substituents or being able to carry one or more rings placed side by side, which rings are aromatic or aliphatic and optionally substituted, the carbon atoms forming the nitrogenous ring and in the alpha- and beta-position with respect to the nitrogen atom being able to carry hydrogen atoms or substituents.
Type:
Grant
Filed:
January 23, 2001
Date of Patent:
March 11, 2003
Assignee:
Atofina
Inventors:
Eric Minaux, Lucedio Greci, Michael Buback, Paul Tordo, Thierry Senninger, Pierluigi Stipa, Patricia Carloni, Elisabetta Damiani, Giampaolo Tommasi
Abstract: A gas phase process for the preparation of 245fa is provided, wherein 1233zd is contacted with HF in the presence of a supported antimony catalyst.
Abstract: A structure comprising at least one layer of a polymer (A) comprising:
the units (A1)
and the units (A2)
wherein the A2/(A1+A2) molar ratio is between 0 and 30% is a barrier against oxygen permeation under high relative humidity, making the structure useful for packaging and hollow bodies, such as pipes, bottles and containers.
Abstract: The present invention relates to a coextrusion binder comprising:
5 to 35 parts of a polymer (A) which itself consists of a blend of 80 to 20 parts of a metallocene polyethylene (A1) of relative density between 0.865 and 0.915 and of 20 to 80 parts of a non-metallocene LLDPE polyethylene (A2), the blend of (A1) and (A2) being cografted by an unsaturated carboxylic acid;
95 to 65 parts of a polyethylene (B) chosen from ethylene homopolymers or copolymers and elastomers; the blend of (A) and (B) being such that:
the content of grafted unsaturated carboxylic acid is between 30 and 100 000 ppm,
the MFI or melt flow index (ASTM D 1238 standard: 190° C./2.16 kg) is between 0.1 and 10 g/10 min.
The present invention also relates to a multilayer structure.
Type:
Grant
Filed:
March 26, 2001
Date of Patent:
March 4, 2003
Assignee:
Atofina
Inventors:
Patrice Robert, Christophe Le Roy, Jerome Pascal
Abstract: The present invention relates to copolymers containing polyamide blocks and polyether blocks based on ethoxylated primary amines, these copolymers having a melting point of between 80° C. and 135° C. and an MFI (melt flow index) of between 5 and 80 g/10 min (2.16 kg-150° C.).
The invention also relates to adhesives of the HMA (or hot melt adhesive) type consisting of the above copolymers containing polyamide blocks and polyether blocks.
Abstract: A cathode comprising an electrically conductive substrate made of titanium, nickel, tantalum, zirconium, niobium, iron or alloys thereof, coated with an intermediate layer of oxides of titanium and of a precious metal, and with an outer layer comprising metal oxides of titanium, zirconium and a precious metal, can be used for the electrolysis of solutions, in particular for the electrolysis of aqueous solutions of alkali metal chlorides.
Abstract: The present invention relates to an antistatic composition having improved impact strength behaviour, comprising, per 100 parts by weight:
95 to 80 parts of (A)+(C),
5 to 20 parts of (B),
(A) being an acrylic polymer,
(B) being a copolymer containing polyamide blocks and polyether blocks essentially comprising ethylene oxide —(C2H4—O)— units,
(C) being a polymer chosen from acrylic impact modifiers, low-mass copolymers (C1) of styrene and of an unsaturated carboxylic anhydride, copolymers (C2) of ethylene and of an unsaturated carboxylic anhydride, copolymers (C3) of ethylene and of an unsaturated epoxide, or mixtures thereof.
Abstract: The invention relates to an improvement to conveyors comprising moving elements which slide over fixed elements such that at least one moving element made of a polyamide-based blend (A) slides over a fixed element made of polyacetal and/or such that at least one moving element made of polyacetal slides over a fixed element made of a polyamide-based blend (A).
Type:
Grant
Filed:
December 1, 2000
Date of Patent:
February 25, 2003
Assignee:
Atofina
Inventors:
Patrick Alex, Christian Capion Knudsen, Niels Peter Rosenkrands
Abstract: The invention relates to an article containing at least three layers, which is intended to adhere to a polymer incompatible with polyvinylidine fluoride (PVDF). The article comprises at least one layer of PVDF, at least one layer of PVDF rendered opaque to UV and visible radiation, and a composition for adhesion of the PVDF to an incompatible thermoplastic. The three-layer complex may be obtained by coextrusion. The three-layer complex is generally intended to form, with a PVDF-incompatible thermoplastic material, a novel 4-layer integral complex, either by coextrusion or by hot-pressing.
Abstract: A structure made of a fluoropolymer layer and directly attached to one of its sides a tie layer based on a polyamide which results from the condensation of at least one diacid and at least one diamine of the following formula (1): 1
Type:
Application
Filed:
June 19, 2002
Publication date:
February 20, 2003
Applicant:
ATOFINA
Inventors:
Philippe Bussi, Christophe Lacroix, David Silagy