Abstract: The invention addresses the problem of improving the adhesion between silver surfaces and resin materials, such as epoxy resins and mold materials, used in the production of electronic devices. The invention provides a method for improving the adhesion between a silver surface and a resin material comprising a step of electrolytically treating the silver surface with a solution containing a hydroxide selected from alkali metal hydroxides, alkaline earth metal hydroxides, ammonium hydroxides and mixtures thereof, wherein the silver surface is the cathode.
Type:
Grant
Filed:
September 10, 2009
Date of Patent:
September 2, 2014
Assignee:
Atotech Deutschland GmbH
Inventors:
Christian Wunderlich, Robert Rüther, Jürgen Barthelmes, Sia-Wing Kok, Nadine Menzel
Abstract: The invention relates to an electroless aqueous copper plating solution, comprising a source of copper ions, a source of glyoxylic acid as reducing agent, and at least one polyamino disuccinic acid or at least one polyamino monosuccinic acid, or a mixture of at least one polyamino disuccinic acid and at least one polyamino monosuccinic acid as complexing agent, as well as to a method for electroless copper plating utilizing said solution and the use of the solution for the plating of substrates.
Abstract: The present invention concerns an aqueous plating bath composition for electroless deposition of palladium and/or palladium alloys and a method which utilises such aqueous plating bath compositions. The aqueous plating bath comprises a source of palladium ions, a reducing agent, a nitrogenated complexing agent which is free of phosphorous and at least one organic stabilising agent comprising 1 to 5 phosphonate residues. The aqueous plating bath and the method are particularly useful if the aqueous plating bath comprises copper ions.
Abstract: An autocatalytic tin plating bath containing Sn2+ ions, Ti3+ ions as reducing agent, an organic complexing agent and phenanthroline or a derivative thereof as stabilizing agent is disclosed. The plating bath is suitable for manufacture of printed circuit boards, IC substrates and metallization of semiconductor wafers.
Abstract: Disclosed is an electroplating method for filling cavities, through holes, blind holes, or micro blind holes of a work piece with metals. According to said method, the work piece containing cavities, through holes, blind holes, or micro blind holes is brought in contact with a metal deposition electrolyte, and a voltage is applied between the work piece and at least one anode such that a current flow is fed to the work piece. The invention method is characterized in that the electrolyte encompasses a redox system.
Type:
Grant
Filed:
March 30, 2007
Date of Patent:
July 22, 2014
Assignee:
Atotech Deutschland GmbH
Inventors:
Bert Reents, Bernd Roelfs, Tafadzwa Magaya, Markus Youkhanis, René Wenzel, Soungsoo Kim
Abstract: An agent for the production of anti-corrosion layers on metal surfaces is produced by producing an aqueous solution, which contains at least oxo-cations and halogen complex anions, and forming nanoparticles in the solution in situ by physical and/or chemical treatment of the solution. The oxo-cations are selected from MnO3+, VO3+, VO2+, WO22+, MoO22+, TiO2+, ZrO2+ and mixtures thereof, and the halogen complex anions have the structure MXab?, wherein M is selected from B, Ti, Zr, Si, Al, X is selected from F, Cl, Br, I, a is an integer of between 3 and 6 and b is an integer of between 1 and 4. The nanoparticles have a mean particle diameter of <500 nm.
Type:
Grant
Filed:
March 20, 2008
Date of Patent:
July 1, 2014
Assignee:
Atotech Deutschland GmbH
Inventors:
Hermann Donsbach, Udo Hofmann, Joerg Unger
Abstract: A silicon solar cell includes a first silicon layer with an emitter layer which has a thickness in a range of 50 nanometers to few hundreds nanometers. The emitter layer has at least one region which is porosified by chemical or electrochemical etching, wherein at least one part of the porosified region is embodied as metal silicide layer. A second silicon layer is disposed underneath the emitter layer, with the metal silicide extending from a top side of the emitter layer in a direction to the second silicon layer. At least one metal layer is applied on the metal silicide layer.
Abstract: Disclosed is a composition for and applying said method for micro etching of copper or copper alloys during manufacture of printed circuit boards. Said composition comprises a copper salt, a source of halide ions, a buffer system and a benzothiazole compound as an etch refiner. The inventive composition and method is especially useful for manufacture of printed circuit boards having structural features of ?100 ?m.
Type:
Grant
Filed:
May 26, 2010
Date of Patent:
June 24, 2014
Assignee:
Atotech Deutschland GmbH
Inventors:
Dirk Tews, Christian Sparing, Martin Thoms
Abstract: The present invention relates to an aqueous plating bath composition for depositing a nickel phosphorous alloy having a phosphorous content in the range of 5 to 12 wt. %. The plating bath comprises a sulfur-containing organic stabilizing agent.
Type:
Application
Filed:
July 4, 2012
Publication date:
June 5, 2014
Applicant:
ATOTECH DEUTSCHLAND GMBH
Inventors:
Boris Alexander JANSSEN, Holger BERA, Sebastian WEISSBROD, Britta SCHAFSTELLER
Abstract: The present invention relates to a method for increasing the adhesion of organic resist materials on copper or copper alloy surfaces. The copper or copper alloy surface is contacted with an aqueous adhesion promoting solution comprising at least one organic acid, a peroxide compound and optionally one or more substances selected from the group consisting of urea, derivatives thereof and water-soluble polymers.
Type:
Application
Filed:
June 29, 2012
Publication date:
May 22, 2014
Applicant:
ATOTECH DEUTSCHLAND GMBH
Inventors:
Thomas Huelsmann, Arno Clicque, Dirk Tews, Mirko Kloppisch, Andry Liong
Abstract: The invention relates to an aqueous acidic bath for electrolytic deposition of copper, comprising, at least one source of copper ions, at least one acid, at least one brightener compound, and at least one leveler for copper-deposition, wherein at least one leveler is a ruthenium compound, and to a process for the electrolytic deposition of copper, in particular for filling a blind micro Vertical Interconnect Access (VIA), through hole VIA, trench and similar structures on printed circuit boards, chip carriers and semiconductor wafers.
Abstract: A pyrophosphate-containing bath for the cyanide-free deposition of copper alloys on substrate surfaces, comprising a reaction product of a secondary monoamine with a diglycidyl ether, is described. The electrolyte bath is suitable for the galvanic deposition of glossy white, even and uniform copper-tin alloy coatings.
Type:
Application
Filed:
December 9, 2013
Publication date:
May 8, 2014
Applicant:
ATOTECH DEUTSCHLAND GMBH
Inventors:
Philip Hartmann, Klaus-Dieter Schulz, Lars Kohlmann, Heiko Brunner
Abstract: Method for producing a plastic layer having a layer thickness of less than 200 ?m on an upper side of a substrate includes the following steps: applying plastic powder to the substrate upper side by means of a powder scattering device, then cleaning the substrate underside, then melting the applied plastic powder in a furnace, as a result of which the plastic layer is formed on the substrate, and cooling the substrate, wherein the substrate is transported continuously from method step to method step.
Type:
Grant
Filed:
February 19, 2010
Date of Patent:
May 6, 2014
Assignee:
Atotech Deutschland GmbH
Inventors:
Alex Bruderer, Jurgen Herbert, Max Hunziker, Michel Probst
Abstract: To achieve high efficiency in regeneration of waste fluid from metal plating electrolytes for example, a device and a method for recovering a recovering material from a recovering fluid containing the recovering material are provided.
Abstract: The present invention discloses a method for electroless plating of a metal or metal alloy onto a metal or a metal alloy structure comprising a metal such as molybdenum or titanium and alloys containing such metals. The method comprises the steps of activation, treatment in an aqueous solution comprising at least one nitrogen-containing compound or a hydroxy carboxylic acid and electroless plating of a metal or metal alloy.
Type:
Application
Filed:
April 17, 2012
Publication date:
April 24, 2014
Applicant:
Atotech Deutschland GmbH
Inventors:
Frank Brüning, Birgit Beck, Bexy Dosse, Johannes Etzkorn
Abstract: The present invention concerns thin diffusion barriers in metal and metal alloy layer sequences of contact area/barrier layer/first bonding layer type for metal wire bonding applications. The diffusion barrier is selected from Co-M-P. Co-M-B and Co-M-B—P alloys wherein M is selected from Mn, Zr, Re, Mo, Ta and W having a thickness in the range 0.03 to 0.3 ?m. The first bonding layer is selected from palladium and palladium alloys.
Type:
Application
Filed:
May 9, 2012
Publication date:
April 24, 2014
Applicant:
ATOTECH DEUTSCHLAND GMBH
Inventors:
Albrecht Uhlig, Josef Gaida, Christof Suchentrunk
Abstract: A method for copper plating in a plating bath wherein the substrate is brought into contact with a leveller additive comprising a heterocyclic core having a thiol group and an amino group attached to said heterocyclic core by a spacer is disclosed. Said method is particularly suitable for filling recessed structures in the manufacture of printed circuit boards, IC substrates and semiconducting substrates.
Abstract: An aqueous, acid bath for the electrolytic deposition of copper contains at least one copper ion source, at least one acid ion source, at least one brightener compound, and at least one leveler compound, and generates a very uniform copper deposit in particular in blind micro vias (BMVs) and trenches. The leveler compound is selected from among synthetically produced non-functionalized peptides, synthetically produced functionalized peptides, and synthetically produced functionalized amino acids.
Type:
Grant
Filed:
April 27, 2009
Date of Patent:
March 25, 2014
Assignee:
Atotech Deutschland GmbH
Inventors:
Heiko Brunner, Bernd Roelfs, Dirk Rohde, Thomas Pliet
Abstract: The invention concerns a solution for pretreating copper surfaces, and a method for pre-treating copper surfaces allowing the formation of a tight bond to plastic substrates. The solution comprises: a) hydrogen peroxide, b) at least one acid, and c) at least one nitrogen-containing, five-membered, heterocyclic compound, and d) additionally at least one nitrogen containing, adhesion-promoting compound, said compound comprising, or consisting of, lactams, non-quaternary fatty amines, amides and polyamides, connected at one or more of its nitrogen atoms with at least one residue of formula (I).
Type:
Application
Filed:
October 24, 2011
Publication date:
March 20, 2014
Applicant:
ATOTECH DEUTSCHLAND GMBH
Inventors:
Christian Sparing, Thomas Huelsmann, Arno Clicque, Patrick Brooks, Adrian Zee, Heiko Brunner
Abstract: A device and a method for chemically or electrolytically treating work pieces (1) are proposed in an effort to avoid irregular contours of finest conductive structures, pads and lands as well as bridges (shorts) on the one side or breaks on printed circuit boards on the other side. The device comprises processing tanks (2) for the treating of work pieces and a conveyor system for the transport thereof. The conveyor system comprises at least one transport carriage (18), at least one holding element (14, 25) and at least one connection means (12, 13, 35) between the transport carriage(s) and the holding element(s). The processing tanks adjoined with a clean room zone (3). The work pieces are conveyed through the clean room zone using the conveyor system.