Patents Assigned to BASF Coating AG
  • Patent number: 6201043
    Abstract: The invention relates to aqueous dispersions. They are obtainable by polymerizing an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monmers [sic] in an aqueous solution of an at least partially protonated epoxide-amine adduct. It is characterized in that the epoxide-amine adduct is for its part obtainable by reacting (A) a glycidyl ether of a polyphenol that contains on statistical average at least one epoxide group in the molecule, or a mixture of such glycidyl ethers, (B) a polygycidyl [sic] ether of a polyol that contains on statistical average more than 1.0 epoxide groups in the molecule, or a mixture of such polyglycidyl ethers, and (C) a compound that contains a primary amino group in the molecule, or a mixture of such compounds, to give the epoxide-amine adduct, components (A) and (B) being employed in a ratio of equivalents of from 1.0:0.5 to 1.0:8.0 and from 0.3 to 0.7 mol of component (C) being employed per equivalent of epoxide groups of (A) and (B).
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: March 13, 2001
    Assignee: BASF Coatings AG
    Inventors: Wolfgang Bremser, Frank Strickmann, Günther Ott, Karl-Heinz Grosse-Brinkhaus
  • Patent number: 6197179
    Abstract: The present invention relates to a novel process for coating objects by means of direct current, in which process an adjustable DC voltage is pulse-modulated with an adjustable AC voltage. The process is useful for electrochemical coating of objects with resinous coating material. Preferably, the pulse modulation of the DC voltage is limited to certain time intervals during the coating process and the pulse modulation is connected and disconnected with an adjustable duty ratio.
    Type: Grant
    Filed: September 17, 1997
    Date of Patent: March 6, 2001
    Assignee: BASF Coatings AG
    Inventors: Klaus Arlt, Karin Eckert, Margaret Stockbrink, Rolf Schulte, Harald Berlin, Gerd Nienhaus
  • Patent number: 6191210
    Abstract: The invention relates to water-dilutable binders which can be prepared by subjecting (A) from 20 to 90% by weight of a mixture of (a1) from 3 to 50% by weight of acrylic acid, methacrylic acid or of a mixture of acrylic acid and methacrylic acid, and (a2) from 50 to 97% by weight of an ethylenically unsaturated monomer or of a mixture of ethylenically unsaturated monomers to free-radical polymerization in the presence of (B) from 9.9 to 79.9% by weight of a halogen-free copolymer composed of (b1) from 1 to 99, preferably from 50 to 90% by weight, of propylene, (b2) from 1 to 99, preferably from 10 to 50% by weight, of at least one olefin which is copolymerizable with (b1) and contains per molecule from five to twenty, preferably from six to eight, carbon atoms, with the exception of isoprene, and (b3) from 0 to 50, preferably from 0 to 25% by weight, of ethylene and/or butylene, or of a mixture of such copolymers, and (C) from 0.
    Type: Grant
    Filed: June 23, 1998
    Date of Patent: February 20, 2001
    Assignee: BASF Coatings AG
    Inventors: Joachim Rösch, Harald Borgholte, Horst Hintze-Brüning
  • Patent number: 6187384
    Abstract: The invention relates to binders BM for one-component coating systems, comprising a polyurethane alkyd resin component (A) composed of: (a) from 5 to 50% by weight of a mixture of: (a1) from 90 to 30 parts by weight of an unsaturated C6 to C30 fatty acid containing at least two nonconjugated double bonds, and (a2) from 10 to 70 parts by weight of an is unsaturated C6 to C30 fatty acid containing at least two conjugated double bonds as esterified polymer side chains of the polyurethane alkyd resin component (A) and (b) from 95 to 50% by weight of polyurethane units as polymer main chains of the polyurethane alkyd resin component (A).
    Type: Grant
    Filed: May 1, 1998
    Date of Patent: February 13, 2001
    Assignee: BASF Coatings AG
    Inventors: Guido Wilke, Dittmar Grapatin, Heinz-Peter Rink
  • Patent number: 6180180
    Abstract: The present invention relates to an aqueous two-component polyurethane coating composition comprising a component (I) wich contains as binder (A1) at least one water-soluble or water-dispersible polyester resin (A1) which contains hydroxyl groups and acid groups which can be converted into the corresponding acid anion groups and has an OH number of from 30 to 250 mg of KOH/g and an acid number of from 5 to 150 mg of KOH/g, and (A2) at least one water-soluble or water-dispersible polyurethane resin (A2) which contains hydroxyl groups and acid groups which can be converted into the corresponding acid anion groups and has an OH number of from 20 to 200 mg of KOG/g and an acid number of from 5 to 150 mg of KOH/g, and (A3) at least one water-soluble or water-dispersible acrylate copolymer which contains hydroxyl groups and acid groups which can be converted into the corresponding acid anion groups, and/or an acrylated polyester and/or an acrylated polyurethane, which has an OH number of from 40 to 200 mg of KOG
    Type: Grant
    Filed: October 7, 1998
    Date of Patent: January 30, 2001
    Assignee: BASF Coatings AG
    Inventors: Horst Hintze-Br{umlaut over (u)}ning, Peter Rink, Egbert Nienhaus
  • Patent number: 6177144
    Abstract: The present invention relates to a radiation-curable binder BM consisting of a copolymer which is composed of: A) from 80 to 99% by weight of a hydroxyl-containing polyether acrylate and/or polyester acrylate A), which optionally contains a mono-, di- and/or polyamine AA) as adduct, and of B) from 1 to 20% by weight of benzophenonetetracarboxylic acid, its anhydrides and/or its esters. The invention additionally relates to processes for the preparation of the binder BM and to the use of the binders BM in radiation-curable coating compositions.
    Type: Grant
    Filed: January 14, 1999
    Date of Patent: January 23, 2001
    Assignee: BASF Coatings AG
    Inventors: Wolfgang Kranig, Rainer Blum
  • Patent number: 6177487
    Abstract: The invention relates to aqueous powder coating dispersions based on epoxy resins, consisting of a solid, pulverulent component I and an aqueous component II, component I being a powder coating comprising: A) at least one epoxy resin having an epoxide equivalent weight of from 300 to 5500 daltons, B) at least one di- and/or polycarboxylic acid as curing agent, comprising one or more organosilyl groups in the molecule, if desired in a mixture with other di- and/or polycarboxylic acids which contain no organosilyl group as substituent, and C) if desired, catalysts, fillers, auxiliaries and/or additives specific to powder coating, such as degassing agents, leveling agents, free-radical scavengers, antioxidants and/or UV absorbers, and component II being an aqueous dispersion comprising: D) at least one nonionic thickener and E) if desired, catalysts, auxiliaries, defoaming agents, dispersion auxiliaries, wetting agents, preferably carboxyl-containing dispersants, anti-oxidants, UV absorbers, free-radical s
    Type: Grant
    Filed: June 11, 1998
    Date of Patent: January 23, 2001
    Assignee: BASF Coatings AG
    Inventors: Ekkehard Sapper, Joachim Woltering
  • Patent number: 6174569
    Abstract: The invention relates to three-layer metal pipe coating compositions based on a powder primer, on a thermoplastic hard adhesive and on a polyolefin cladding. The powder primer contains epoxidized novolak resins, phenolic crosslinking agents and fillers based on crystalline silicic acid modifications. The invention likewise relates to a process for the exterior coating of metal pipes by a three-layer method, in which the powder primer described is applied to the metal pipe, a thermoplastic hard adhesive is applied to the powder primer, and subsequently a polyolefin cladding is applied.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: January 16, 2001
    Assignee: BASF Coatings AG
    Inventors: Werner Blömer, Udo Reiter, Josef Rademacher
  • Patent number: 6166150
    Abstract: A process for preparing binders for one-component paint systems has the following steps: (I) preparation of a polyurethane-alkyd resin component (A) composed of a mixture (a) of (a1) an unsaturated C.sub.6 -C.sub.30 fatty acid with at least two non-conjugated double bonds, and (a2) an unsaturated C.sub.6 -C.sub.
    Type: Grant
    Filed: May 25, 1999
    Date of Patent: December 26, 2000
    Assignee: BASF Coatings AG
    Inventors: Guido Wilke, Ulrich Poth, Rolf Seidemann, Vijay Kadambande
  • Patent number: 6165557
    Abstract: The invention relates to solvent-free coating compositions which can be cured with low emissions and comprise, as binders, saturated and/or unsaturated polyesters whose structural units include dihydrodicyclopentadiene units of the formula (I): ##STR1## and/or oligodihydrodicyclopentadiene units of the formula (II): ##STR2## where n=1 to 10, to processes for the production of coatings using the novel coating compositions, and to the use of the coating compositions for coating metal containers, especially cans.
    Type: Grant
    Filed: August 20, 1998
    Date of Patent: December 26, 2000
    Assignee: BASF Coatings AG
    Inventors: Rainer Blum, Uwe Meisenburg, Dietmar Chmielewski, Thomas Loerzer
  • Patent number: 6162506
    Abstract: The invention relates to an aqueous coating material. The aqueous coating material comprises 5-95% by weight (based on the overall binder content) of a binder component a) and 5-95% by weight (based on the overall binder content) of a binder component b). The binder component a) is obtainable by free-radical polymerization of an aqueous dispersion of a polyurethane resin with ethylenically unsaturated monomers and in the presence of a water-insoluble initiator. The binder component b) is obtainable by polymerizing ethylenically unsaturated monomers in an organic solvent or in a mixture of organic solvents and in the presence of a polyurethane resin and converting the resulting binder component b) into an aqueous dispersion.
    Type: Grant
    Filed: November 30, 1999
    Date of Patent: December 19, 2000
    Assignee: BASF Coatings AG
    Inventors: Bernhard Lettmann, Hermann Bruggemann, Michael Hartung
  • Patent number: 6159556
    Abstract: The present invention relates to an aqueous powder coating dispersion comprising a solid, pulverulent component A and an aqueous component B, in which component A. is a powder coating comprisinga) at least one epoxide-containing binder with a content of from 30 to 45%, preferably from 30 to 35%, of glycidyl-containing monomers and, if desired, with a content of aromatic vinyl compounds, preferably styrene,b) at least one crosslinking agent, preferably straight-chain aliphatic dicarboxylic acids and/or carboxy-functional polyesters, andc) if desired, catalysts, auxiliaries, typical powder coating additives, such as degassing agents, levelling agents, UV absorbers, free-radical scavengers and antioxidants,and component B.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: December 12, 2000
    Assignee: BASF Coatings AG
    Inventors: Dietmar Moller, Joachim Woltering
  • Patent number: 6156862
    Abstract: The invention relates to heat-hardenable paint composition which contains (A) vinyl based copolymer of hydroxyl group value from 20 to 200 mg KOH/g, being a copolymer of from 5 to 70 wt % hydroxyl group containing a particularly defined vinyl based monomer and from 95 to 30 wt % other vinyl based monomer (a-2), and (B), a particularly defined 1,3,5-triazine-2,4,6-triscarbamic acid ester, or an oligomer thereof, in which the mol ratio of hydroxyl groups originating from the aforementioned (A) component: NHCOOR groups originating from the aforementioned (B) component in the composition is from 1:3 to 3:1.
    Type: Grant
    Filed: February 3, 1999
    Date of Patent: December 5, 2000
    Assignee: BASF Coatings AG
    Inventors: Ingo Luer, Kishio Shibatoh, Akito Nukita
  • Patent number: 6146707
    Abstract: An aqueous coating composition which comprises as one binder component an aqueous polymer dispersion comprisingi) an acrylate polymer based on from 30 to 60% by weight of C.sub.1 -C.sub.8 -alkyl (meth)acrylate monomers, from 30 to 60% by weight of vinylaromatic monomers and from 0.5 to 10% by weight of (meth)acrylic acid,(ii) a nonassociative rheology stabilizer comprising an acrylate copolymer based on C.sub.1 -C.sub.6 -alkyl (meth)acrylate and (meth)acrylic acid, and(iii) as crosslinker, tris(alkoxycarbonylamino)-triazine or a mixture of tris(alkoxycarbonylamino)-triazines.
    Type: Grant
    Filed: September 27, 1999
    Date of Patent: November 14, 2000
    Assignee: BASF Coatings AG
    Inventors: Eckchard Sapper, Christian Schade, Kurt Wendel, Hubert Baumgart
  • Patent number: 6143367
    Abstract: The invention relates to a component system for a two-component coating composition comprising a hydroxy-functional binder or a mixture of hydroxy-functional binders, tris(alkoxycarbonylamino)triazine or a mixture of tris(alkoxycarbonylamino)triazines and free isocyanates or a mixture of free polyisocyanates. It is characterized in that a first component (I) is formed at least from the hydroxy-functional binder or the mixture of hydroxy-functional binders and in that a second component (II) is formed at least from the free isocyanates or the mixture of free polyisocyanates, where the tris(alkoxycarbonylamino)triazine or the mixture of tris(alkoxycarbonylamino)triazines is alternatively a constituent of the first component (I), the second component (II) or both components (I) and (II).
    Type: Grant
    Filed: July 27, 1999
    Date of Patent: November 7, 2000
    Assignee: BASF Coatings AG
    Inventors: Fritz Bartol, Hubert Baumgart, Ulrike Rockrath
  • Patent number: 6136449
    Abstract: To form paint films of outstanding acid resistance, finished appearance, water resistance, adhesion and bending resistance by coating a base finishing coat and top finishing coat wet-on-wet.A method for forming a paint film by a method for forming a thermosetting paint film in which a solvent-based thermosetting base finishing coat is painted onto the surface of an object to be painted, a thermosetting top finishing coat is painted on top of this wet-on-wet, and the paint films are hardened at the same time, in which the aforementioned top finishing coat which contains as a primary resin a copolymer which is a copolymer of a vinyl monomer which has a ring structure and other vinyl monomers in which the proportion of vinyl monomer having a ring structure in the total quantity of monomers is 20-50 wt %, and the proportion of other vinyl monomer(s) is 80-50 wt %, and which has a glass transition temperature of 0-60.degree. C., a solubility parameter of 9.0-11.
    Type: Grant
    Filed: July 21, 1998
    Date of Patent: October 24, 2000
    Assignee: BASF Coatings AG
    Inventors: Kazuyoshi Furuuchi, Souichi Mori
  • Patent number: 6132864
    Abstract: The present invention relates to films coated with two or more coats, whereinA the surface of a plastic film having a thickness of from 10 to 500 .mu.m is coated if desired with a filler composition,B the surface of the plastic film, or the filler coat, is overcoated with at least one pigmented paint coat,C the pigmented paint coat is coated if desired with a transparent plastic film.
    Type: Grant
    Filed: March 10, 1998
    Date of Patent: October 17, 2000
    Assignee: BASF Coatings AG
    Inventors: Leonidas Kiriazis, Egon Wegner
  • Patent number: 6129989
    Abstract: A process is claimed for producing a multilayer coating on a substrate surface, in which(A) an aqueous coating composition comprising as film-forming agent an aqueous polymer dispersion is applied as basecoat composition to a substrate surface coated with a customary primer surfacer,(B) a suitable transparent topcoat composition is applied to the basecoat thus obtained, and(C) the basecoat is baked together with the topcoat,wherein the basecoat composition comprises an aqueous polymer dispersion comprising(i) an acrylate polymer based on from 30 to 60% by weight of C.sub.1 -C.sub.8 -alkyl (meth)acrylate monomers, from 30 to 60% by weight of vinyl-aromatic monomers and from 0.5 to 10% by weight of (meth)acrylic acid, and(ii) a thickener, which does not have an associative action, comprising an acrylate copolymer based on (C.sub.1 -C.sub.6)-alkyl (meth)acrylate and (meth)acrylic acid.
    Type: Grant
    Filed: July 21, 1998
    Date of Patent: October 10, 2000
    Assignee: BASF Coatings AG
    Inventor: Gotz-Ekkehard Sapper
  • Patent number: 6130308
    Abstract: The invention relates to coating compositions for the production of coatings which are resistant to condensed water and comprise binders based on a polyurethane resin PUR which comprises alpha, omega-polymethacrylatediols (A) as structural units. The alpha, omega-polymethacrylatediols (A) preferably consist of the monomer units methyl methacrylate, ethyl methacrylate, propyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, tert-butyl methacrylate, n-pentyl methacrylate, amyl methacrylate, n-hexyl methacrylate, n-octyl methacrylate, 2-ethylhexyl methacrylate, n-decyl methacrylate, cyclopentyl methacrylate, cyclohexyl methacrylate, 4-tert-butylcyclohexyl methacrylate, cyclooctyl methacrylate, phenyl methacrylate or isobornyl methacrylate or mixtures thereof.
    Type: Grant
    Filed: August 20, 1998
    Date of Patent: October 10, 2000
    Assignee: BASF Coating AG
    Inventors: Heinz-Peter Rink, Bernd Mayer, Egbert Nienhaus
  • Patent number: 6127479
    Abstract: Provided are paint films with outstanding paint film performance traits such as water resistance and chemical resistance, etc., and outstanding finished appearance. The water-based paints are easy to apply and have outstanding storage stability. The invention further provides an acrylic graft copolymer obtained by reacting a acrylic copolymer (a) of acid number 35 to 120 mg KOH/g, hydroxyl group number 50 to 150 mg KOH/g, glass transition temperature -20 to +50.degree. C. and number average molecular weight 4500 to 9000, and a monomer combination (b) comprising an unsaturated monomer (b1) containing a glycidyl group and an unsaturated monomer (b2) containing a hydroxyl group to give an acid number of .ltoreq.15 mg KOH/g and a hydroxyl group number of 50 to 150 mg KOH/g.
    Type: Grant
    Filed: February 20, 1997
    Date of Patent: October 3, 2000
    Assignee: BASF Coatings AG
    Inventors: Yoshiaki Matsukura, Atsuhiro Sakai, Hitoshi Taniguchi, Yoshiaki Kawamura