Abstract: Disclosed are zeolite catalysts having the CHA crystal structure with a low silica to alumina ratio, as well as articles and systems incorporating the catalysts and methods for their preparation and use. The catalysts can be used to reduce NOx from exhaust gas streams, particularly those emanating from gasoline or diesel engines.
Abstract: The present invention provides an oxidation catalyst composition suitable for at least partial conversion of gaseous hydrocarbon emissions, e.g., methane. The oxidation catalyst composition includes at least one platinum group metal (PGM) component supported onto a porous zirconia-containing material that provides an effect on hydrocarbon conversion activity. The porous zirconia-containing material is at least 90% by weight in the monoclinic phase. Furthermore, the PGM component can comprise at least one platinum group metal in the form of colloidally deposited nanoparticles. The oxidation catalyst composition can be used in the treatment of emissions from lean compressed natural gas engines.
Type:
Grant
Filed:
October 12, 2018
Date of Patent:
May 16, 2023
Assignee:
BASF CORPORATION
Inventors:
Xinyi Wei, Olga Gerlach, Emily Schulman, Andreas Sundermann, Stanley Roth, Limiao An
Abstract: The present disclosure generally provides a catalyst composition comprising a zeolite containing iron and/or copper with a reduced amount of extra-framework aluminum. The catalyst composition is useful to catalyze the reduction of nitrogen oxides in exhaust gas in the presence of a reductant.
Type:
Grant
Filed:
March 6, 2020
Date of Patent:
April 25, 2023
Assignee:
BASF Corporation
Inventors:
Ivan Petrovic, Subramanian Prasad, Joseph Palamara
Abstract: Provided are processes of removing lithium from an electrochemically active composition. The process of removing lithium from an electrochemically active composition may include providing an electrochemically active composition and combining the electrochemically active composition with a strong oxidizer optionally at a pH of 1.5 or greater for a lithium removal time. The electrochemically active composition may include Li, Ni, and O. The electrochemically active composition may optionally have an initial Li/M at % ratio of 0.8 to 1.3. According to some embodiments of the present disclosure, the lithium removal time may be such that a second Li/M at % ratio following the lithium removal time is 0.6 or less, thereby forming a delithiated electrochemically active composition.
Type:
Application
Filed:
March 9, 2020
Publication date:
April 13, 2023
Applicant:
BASF Corporation
Inventors:
William C. MAYS, Martin Lawrence PANCHULA, Dieter G. VON DEAK, Benjamin REICHMAN, Diana F. WONG
Abstract: The present disclosure relates to hydrocarbon emission control systems. More specifically, the present disclosure relates to substrates coated with hydrocarbon adsorptive coating compositions and evaporative emission control systems for controlling evaporative emissions of hydrocarbons from motor vehicle engines and fuel systems. The hydrocarbon adsorptive coating compositions include particulate carbon having a BET surface area of at least about 1300 m2/g, and at least one of (i) a butane affinity of greater than 60% at 5% butane; (ii) a butane affinity of greater than 35% at 0.5% butane; (iii) a micropore volume greater than about 0.2 mug and a mesopore volume greater than about 0.5 ml/g.
Type:
Grant
Filed:
August 7, 2019
Date of Patent:
April 11, 2023
Assignee:
BASF CORPORATION
Inventors:
Chen Chen, Wolfgang Ruettinger, Steven Chin, Laif R Alden, Akash Abraham
Abstract: This disclosure relates to devices and methods for coating various portions of catalyst support bodies, such as radially-zoned catalyst support bodies, such as those used in catalytic converters for treating exhaust gas streams of internal combustion engines.
Type:
Application
Filed:
January 22, 2021
Publication date:
March 9, 2023
Applicant:
BASF CORPORATION
Inventors:
Andreas R. Munding, Sandip D. Shah, Kai Schmitz, Yi Liu, Donald H. Reeder, Brian T. Jones, Eric George Klauber, James Dale Hoggard, Yogeshkumar Patel
Abstract: Disclosed herein are a catalyst composition, catalyst devices, and methods for removing formaldehyde, volatile organic compounds, and other pollutants from an air flow stream. The catalyst composition including manganese oxide, optionally one or more of alkali metals, alkaline earth metals, zinc, iron, binder, an inorganic oxide, or carbon.
Type:
Grant
Filed:
February 3, 2020
Date of Patent:
February 21, 2023
Assignee:
BASF Corporation
Inventors:
David Weinberger, Wolfgang Ruettinger, Pascaline Tran, Laif Alden, Ting Gu, Feng Zhao, Anju Shi, Nils Lawrenz, Lukas Wengeler
Abstract: A pest monitoring system generally includes a circuit, wherein the circuit is initially in a first impedance state that is configured to change to a second impedance state due to pest activity, wherein the second impedance state is lower than the first impedance state.
Type:
Grant
Filed:
September 13, 2019
Date of Patent:
February 7, 2023
Assignee:
BASF CORPORATION
Inventors:
James W. Austin, Cheryl Ann Leichter, Greggory Keith Storey, Kenneth Scott Brown, Gregory Kent Thompson, Thomas S. Rancour, II, Timothy Robert Sloper
Abstract: The present disclosure is directed to a system for treating an exhaust gas stream from an engine, which includes a diesel oxidation catalyst (DOC) located downstream of the engine and adapted for oxidation of hydrocarbons and carbon monoxide, an injector adapted for the addition of a reductant to the exhaust gas stream located downstream of the DOC, a catalyzed soot filter (CSF) located downstream of the injector, and a selective catalytic reduction component adapted for the oxidation of nitrogen oxides located downstream of the CSF. The CSF is adapted for oxidizing hydrocarbons and includes a selective oxidation catalyst composition on a filter with high selectivity ratio for hydrocarbon oxidation:ammonia oxidation (e.g., at least 0.6).
Type:
Application
Filed:
September 26, 2022
Publication date:
January 26, 2023
Applicant:
BASF CORPORATION
Inventors:
Kevin Hallstrom, David Youngren, Yuejin Li
Abstract: The present disclosure generally relates to emission control catalyst articles comprising a platinum group metal (PGM) enriched zone, methods of making such emission control catalyst articles, and methods of using such emission control catalyst articles.
Abstract: Example embodiments provide systems and methods for simulating a disease outbreak using a relatively simple formula based on a limited number of input parameters. In particular, disease severity is computed based on a relationship between leaf wetness duration and average temperature during a wetness period. The resulting model is a physical, deterministic model that accepts hourly weather data as input and outputs the most significant severity event of disease infection during a specified (e.g., one-day) period. This information can then be used to guide the application of various treatments when they can be most effective (e.g., when predicted disease severity is at its worst).
Abstract: The present invention relates to a selective catalytic reduction catalyst for the treatment of an exhaust gas of a diesel engine comprising: a flow-through substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the flow through substrate extending therethrough; a coating disposed on the surface of the internal walls of the substrate, wherein the coating comprises a non-zeolitic oxidic material comprising manganese and one or more of the metals of the groups 4 to 11 and 13 of the periodic table, and further comprises one or more of a vanadium oxide and a zeolitic material comprising one or more of copper and iron.
Type:
Grant
Filed:
April 23, 2019
Date of Patent:
January 10, 2023
Assignee:
BASF Corporation
Inventors:
Marcus Hilgendorff, Karifala Dumbuya, Matthias Peter, Andreas Sundermann
Abstract: The present disclosure is directed to an emission treatment system for NOx abatement in an exhaust stream of a lean burn engine. The emission treatment system includes a lean NOx trap (LNT) in fluid communication with and downstream from the lean burn engine and a low-temperature NOx adsorber (LT-NA) in fluid communication with and downstream of the LNT. Further provided is a method for abating NOx in an exhaust stream from a lean burn engine utilizing the disclosed system.
Abstract: Emissions treatment systems of combustion engines are provided, which comprise a platinum-containing catalyst that is degreened during production, which is before exposure to operating conditions of a vehicle having a diesel engine. The platinum-containing catalyst, in the form of a platinum component on a high surface area refractory metal oxide support, exhibits a vibration frequency of about 2085 to about 2105 cm?1 as measured by CO-DRIFTS. Such catalytic material is essentially-free of platinum oxide species found at greater than about 2110 cm?1 as measured by CO-DRIFTS. Such catalysts can provide excellent and consistent conversion of nitrogen oxide (NO) to nitrogen dioxide (NO2).
Type:
Grant
Filed:
February 14, 2020
Date of Patent:
December 27, 2022
Assignee:
BASF CORPORATION
Inventors:
Xinyi Wei, Stanley A. Roth, Haiyang Zhu
Abstract: The present invention relates to a process for the preparation of a zeolitic material SiO2 and X2O3 in its framework structure, wherein X stands for a trivalent element, wherein said process comprises interzeolitic conversion of a first zeolitic material comprising SiO2 and X2O3 in its framework structure, wherein the first zeolitic material has an FER-, TON-, MTT-, BEA-, MEL-, MWW-, MFS-, and/or MFI-type framework structure to a second zeolitic material comprising SiO2 and X2O3 in its framework structure, wherein the second zeolitic material obtained in (2) has a different type of framework structure than the first zeolitic material. Furthermore, the present invention relates to a zeolitic material per se as obtainable and/or obtained according to the inventive process and to its use, in particular as a molecular sieve, as an adsorbent, for ion-exchange, or as a catalyst and/or as a catalyst support.
Type:
Grant
Filed:
June 18, 2019
Date of Patent:
December 20, 2022
Assignee:
BASF Corporation
Inventors:
Andrei-Nicolae Parvulescu, Robert McGuire, Ulrich Mueller, Xiangju Meng, Feng-Shou Xiao, Toshiyuki Yokoi, Dirk De Vos, Bernd Marler, Hermann Gies, Ute Kolb, Weiping Zhang
Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.
Type:
Grant
Filed:
April 22, 2020
Date of Patent:
December 20, 2022
Assignee:
BASF Corporation
Inventors:
Ivor Bull, Wen-Mei Xue, Patrick Burk, R. Samuel Boorse, William M. Jaglowski, Gerald Stephen Koermer, Ahmad Moini, Joseph A. Patchett, Joseph C. Dettling, Matthew Tyler Caudle
Abstract: The present invention relates to a diesel oxidation catalyst comprising a substrate and a wash-coat comprising a first layer and a second layer, wherein the substrate has a substrate length, a front end and a rear end, the washcoat comprising the first layer comprising a first metal oxide and comprising a platinum group metal supported on a metal oxide support material; the second layer comprising a second metal oxide and comprising one or more of an oxidic compound of vanadium, an oxidic compound of tungsten and a zeolitic material comprising one or more of Fe and Cu; wherein the first layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on an intermediate layer which is disposed directly on the substrate over the entire length of the substrate, on x % of the length of the substrate from the front end of the substrate, and wherein the second layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on the i
Abstract: The present invention relates generally to the field of exhaust treatment systems for purifying exhaust gas discharged from a lean burn engine. The exhaust treatment system comprises a Diesel Oxidation Catalyst (DOC), a Catalyzed Soot Filter (CSF), a reductant injector, an AEI zeolite based Selective Catalyzed Reduction (SCR) catalyst and an Ammonia Oxidation Catalyst (AMOX) downstream to the AEI zeolite based SCR catalyst.
Type:
Grant
Filed:
October 24, 2019
Date of Patent:
November 29, 2022
Assignee:
BASF Corporation
Inventors:
Stefan Maurer, Jia Di Zhang, Yu Dai, Yu Fen Hao, Ming Ming Wei, Teng Shen
Abstract: A process for the preparation of amino alcohols includes condensing a compound of Formula (II), a stereoisomer, a tautomer, or a salt thereof with a compound of Formula (IIIa) or Formula (IIIb), a stereoisomer, a tautomer, or a salt thereof to form a condensation product; hydroxylating or acyloxylating the condensation product in the presence of an oxidant to obtain a hydroxylation or acyloxylation product; and subjecting the hydroxylation or acyloxylation product to one or more subsequent reactions comprising a hydrolysis reaction, alcohol deprotection, an amino lysis reaction, or a combination of two or more thereof to obtain an amino alcohol of Formula (I).
Type:
Grant
Filed:
July 2, 2019
Date of Patent:
November 29, 2022
Assignees:
BASF SE, BASF CORPORATION, THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Inventors:
Martin Ernst, Stephan Zuend, Bo Su, Ala Bunescu, John F. Hartwig