Patents Assigned to BASF Corporation
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Patent number: 11498054Abstract: A metal trap for an FCC catalyst include pre-formed microspheres impregnated with an organic acid salt of a rare earth element.Type: GrantFiled: November 8, 2018Date of Patent: November 15, 2022Assignee: BASF CORPORATIONInventors: Gary M. Smith, Bilge Yilmaz
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Patent number: 11486288Abstract: The present disclosure is directed to a system for treating an exhaust gas stream from an engine, which includes a diesel oxidation catalyst (DOC) located downstream of the engine and adapted for oxidation of hydrocarbons and carbon monoxide, an injector adapted for the addition of a reductant to the exhaust gas stream located downstream of the DOC, a catalyzed soot filter (CSF) located downstream of the injector, and a selective catalytic reduction component adapted for the oxidation of nitrogen oxides located downstream of the CSF. The CSF is adapted for oxidizing hydrocarbons and includes a selective oxidation catalyst composition on a filter with high selectivity ratio for hydrocarbon oxidation:ammonia oxidation (e.g., at least 0.6).Type: GrantFiled: May 8, 2020Date of Patent: November 1, 2022Assignee: BASF CORPORATIONInventors: Kevin Hallstrom, David Youngren, Yuejin Li
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Patent number: 11478773Abstract: A coated substrate (2a, 2b) adapted for hydrocarbon adsorption having at least one surface, and a coating on the at least one surface, the coating comprising particulate carbon and a binder, wherein the particulate carbon has a BET surface area of at least about 1300 m2/g; and at least one of: (i) a butane affinity of greater than 60% at 5% butane; (ii) a butane affinity of greater than 35% at 0.5% butane; (iii) a micropore volume greater than about 0.2 ml/g and a mesopore volume greater than about 0.5 ml/g. A bleed emission scrubber (1) and an evaporative emission control canister system (30) comprising the coated substrate (2a, 2b) are provided. They can control evaporative hydrocarbon emissions and may provide low diurnal breathing loss (DBL) emissions even under a low purge condition.Type: GrantFiled: July 12, 2019Date of Patent: October 25, 2022Assignee: BASF CorporationInventors: Wolfgang Ruettinger, Laif R. Alden, Steven Wesley Chin, Akash Abraham, Chen Chen
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Patent number: 11477973Abstract: A pest control and/or detection system generally includes an electrically conductive bait matrix including at least one carrier material that is at least one of palatable, a phagostimulant and/or consumable and/or displaceable by pests, and a plurality of electrically conductive particles. The electrically conductive particles are substantially randomly interspersed throughout the at least one carrier material. The at least one carrier material includes a thermoplastic material and/or a resin.Type: GrantFiled: April 18, 2019Date of Patent: October 25, 2022Assignee: BASF CORPORATIONInventors: James H. Cink, Greggory K. Storey, Kyle K. Jordan, James W. Austin, Charles E. Evanhoe, Bart Ivy, Daniel W. Engels, Daniel Freeman, Kenneth Lauffenburger, Thomas Dills, Kenneth S. Brown, Cheryl Leichter
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Patent number: 11471862Abstract: A microspherical fluid catalytic cracking (FCC) catalyst includes Y zeolite and a gamma-alumina.Type: GrantFiled: May 16, 2018Date of Patent: October 18, 2022Assignee: BASF CORPORATIONInventors: Junmei Wei, Lucas Dorazio, Karl C. Kharas, David J. Camerota, David M. Stockwell
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Patent number: 11471863Abstract: Provided herein is a catalytic article including a catalytic coating disposed on a substrate, wherein the catalytic coating comprises a bottom coating on the substrate and a top coating layer on the bottom coating layer, one such coating layer containing a platinum group metal on a refractory metal oxide support and the other such coating layer containing a ceria-containing molecular sieve. Such catalytic articles are effective toward treating exhaust gas streams of internal combustion engines and exhibit outstanding resistance to sulfur.Type: GrantFiled: February 7, 2018Date of Patent: October 18, 2022Assignee: BASF CORPORATIONInventors: Shiang Sung, Markus Koegel, Bjoern Neumann, Patrick McCanty
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Patent number: 11473471Abstract: Described are exhaust gas treatment systems for treatment of a gasoline engine exhaust gas stream. The exhaust gas treatment systems comprise an ammonia generating catalyst and an ammonia selective catalytic reduction (SCR) catalyst downstream of the ammonia generating catalyst. The ammonia generating catalyst comprises a NOx storage component, a refractory metal oxide support, a platinum component, and a palladium component. The ammonia generating catalyst is substantially free of ceria. The platinum and palladium components are present in a platinum to palladium ratio of greater than about 1 to 1.Type: GrantFiled: June 10, 2016Date of Patent: October 18, 2022Assignee: BASF CorporationInventors: Wen-Mei Xue, John K. Hochmuth
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Publication number: 20220323905Abstract: The present disclosure is directed to an emission treatment system for NOx abatement in an exhaust stream of an ammonia-fueled engine, the emission treatment system including a selective catalytic reduction (SCR) catalyst disposed on a substrate in fluid communication with the exhaust stream, an oxidation catalyst disposed on a substrate positioned either upstream or downstream of the SCR catalyst and in fluid communication with the exhaust stream and the SCR catalyst, and optionally, one or more adsorption components disposed on a substrate positioned upstream and/or downstream of the SCR catalyst and in fluid communication with the exhaust stream and the SCR catalyst, the adsorption component chosen from low temperature NOx adsorbers (LT-NA), low temperature ammonia adsorbers (LT-AA), low temperature water vapor adsorbers (LT-WA), and combinations thereof. The disclosure further provides a related method of treatment of an exhaust gas.Type: ApplicationFiled: June 17, 2022Publication date: October 13, 2022Applicant: BASF CorporationInventors: Shiang SUNG, Pushkaraj R. PATWARDHAN
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Patent number: 11465134Abstract: The present disclosure generally provides a catalyst composition comprising a zeolite containing iron and/or copper with a reduced amount of extra-framework aluminum. The catalyst composition is useful to catalyze the reduction of nitrogen oxides in exhaust gas in the presence of a reductant.Type: GrantFiled: March 6, 2020Date of Patent: October 11, 2022Assignee: BASF CorporationInventors: Ivan Petrovic, Subramanian Prasad, Joseph Palamara
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Patent number: 11446624Abstract: A cyclic metals deactivation system unit for the production of equilibrium catalyst materials including a cracker vessel configured for cracking and stripping a catalyst material; and a regenerator vessel in fluid communication with the cracker vessel, the regenerator vessel configured for regeneration and steam deactivation of the catalyst material.Type: GrantFiled: August 24, 2020Date of Patent: September 20, 2022Assignee: BASF CorporationInventors: James C. Fu, Chandrashekhar Kelkar, Roman Matlin, Johannes Mang, Andreas Mueller
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Patent number: 11448110Abstract: Certain selective catalytic reduction (SCR) articles, systems and methods provide for high NOx conversion while at the same time low N2O formation. The articles, systems and methods are suitable for instance for the treatment of exhaust gas of diesel engines. Certain articles have zoned coatings containing copper-containing molecular sieves disposed thereon, where for example a concentration of catalytic copper in an upstream zone is lower than the concentration of catalytic copper in a downstream zone.Type: GrantFiled: August 4, 2017Date of Patent: September 20, 2022Assignee: BASF CorporationInventors: Wen-Mei Xue, Jeff H. Yang, Stanley A. Roth, Kenneth E. Voss, Sandip D. Shah, Jaya L. Mohanan
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Patent number: 11439992Abstract: The present disclosure relates to processes for formation of a molecular sieve, particularly a metal-promoted molecular sieve, and more particularly an Iron(III) exchanged zeolite. Preferably, the zeolite is of the chabazite form or similar structure. The processes can include combining a zeolite with Iron(III) cations in an aqueous medium. The process can be carried out at a pH of less than about 7, and a buffering material can be used with the aqueous medium. The processes beneficially result in Iron exchange that can approach 100% along with removal of cations (such as sodium, NH4, and H) from the zeolite. An Iron(III)-exchanged zeolite prepared according to the disclosed processes can include about 2,000 ppm or less of cation and about 1% by weight or greater of Iron(III). The disclosure also provides catalysts (e.g., SCR catalysts) and exhaust treatment systems including the Iron(III)-exchanged zeolite.Type: GrantFiled: June 11, 2020Date of Patent: September 13, 2022Assignee: BASF CORPORATIONInventors: Qi Fu, Barbara Slawski, Peter Pfab
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Publication number: 20220280924Abstract: The present disclosure provides a method of forming a selective catalytic reduction (SCR) catalyst, the method including receiving a first iron-promoted zeolite having a first iron content, and treating the iron-promoted zeolite with additional iron in an ion exchange step to form a second iron-promoted zeolite with a second iron content, the second iron content being higher than the first iron content. A selective catalytic reduction (SCR) catalyst composition including an ironpromoted zeolite having at least about 6 weight percent iron, based on total weight of the ironpromoted zeolite, wherein the iron content of the zeolite was added to the zeolite in at least two separate steps is also provided herein.Type: ApplicationFiled: August 12, 2020Publication date: September 8, 2022Applicant: BASF CORPORATIONInventors: Jeff H. Yang, Stanley A. Roth, Robin M. Huff
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Publication number: 20220258141Abstract: The present disclosure provides catalyst compositions capable of reducing nitrogen oxide (NOx) emissions in engine exhaust, catalyst articles coated with such compositions, and processes for preparing such catalyst compositions and articles. The catalyst compositions include metal ion-exchanged zeolites useful for selective catalytic reduction (SCR) of NOx. Further provided is an exhaust gas treatment system including such catalytic articles, and methods for reducing NOx in an exhaust gas stream using such catalytic articles.Type: ApplicationFiled: May 6, 2020Publication date: August 18, 2022Applicant: BASF CORPORATIONInventors: Yi Liu, Brian T. Jones, Donald H. Reeder, Eric George Klauber, Oliver Seel, Torsten Neubauer, Saeed Alerasool, James Dale Hoggard, John Robert White, Claudia Zabel
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Publication number: 20220258137Abstract: A catalyst article is provided including a substrate including a plurality of passageways, and further including a first and a second oxidation region including a first and a second subset of said plurality of passageways. A first catalyst composition is coating at least a portion of each passageway of the first oxidation region and positioned as a sole PGM-containing catalyst layer, or a zoned portion thereof, or as a top PGM-containing catalyst layer, or a zoned portion thereof, in the first oxidation region. A second catalyst composition is coating at least a portion of each passageway of the second oxidation region and positioned as a sole PGM-containing catalyst layer, or a zoned portion thereof, or as a top PGM-containing catalyst layer, or a zoned portion thereof, in the second oxidation region. The Pt:Pd weight ratio is greater in the first catalyst composition than in the second catalyst composition.Type: ApplicationFiled: July 9, 2020Publication date: August 18, 2022Applicant: BASF CORPORATIONInventors: Weiyong Tang, Sandip D. Shah, Andreas R. Munding, Fabien A. Rioult, Ramesh Murlidhar Kakwani
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Patent number: 11413607Abstract: The present disclosure is directed to a Low Temperature NOx-Absorber (LT-NA) catalyst composition which exhibits NOx adsorption in a broad temperature and space velocity range, and shifts NOx desorption to a desired temperature range. In particular, the LT-NA composition includes a large pore zeolite containing a palladium component and a small or medium pore zeolite containing a palladium component. Further provided is a catalyst article including the LT-NA catalyst composition, an emission treatment system for treating an exhaust gas including the catalyst article, and methods for reducing a NOx level in an exhaust gas stream using the catalyst article.Type: GrantFiled: May 29, 2019Date of Patent: August 16, 2022Assignee: BASF CorporationInventors: Jia Cheng Liu, Evan Vincent Miu, Xiaoming Xu, Xinyi Wei, Stefan Maurer
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Publication number: 20220241761Abstract: The present disclosure is directed to an emission treatment system for oxidation of hydrocarbons and carbon monoxide and for NOx abatement in an exhaust stream of a lean burn engine, the emission treatment system including a low-temperature NOx adsorber (LT-NA) that includes a molecular sieve impregnated with at least one PGM component positioned in fluid communication with the exhaust stream; and an oxidation catalyst that includes a refractory metal oxide support containing manganese impregnated with platinum positioned in fluid communication with the exhaust stream, each of the LT-NA and the oxidation catalyst being disposed on a substrate. The invention provides a catalyst article combining an oxidation catalyst with a LT-NA and a related method of treatment of an exhaust gas.Type: ApplicationFiled: May 20, 2020Publication date: August 4, 2022Applicant: BASF CORPORATIONInventors: Jeffrey B. Hoke, Gerd Grubert, Alfred Punke
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Patent number: 11389786Abstract: Disclosed herein is a chromium oxide catalyst composition having reduced levels of chromium (VI), methods of making a chromium oxide catalyst composition and system, and illustrative uses of the chromium oxide catalyst composition and system. The catalyst disclosed may be a gel and may comprise chromium (III) oxide and chromium (VI) oxide at an amount of about 10,000 ppm or less based on total chromium oxide contents in the chromium oxide catalyst composition.Type: GrantFiled: May 22, 2017Date of Patent: July 19, 2022Assignee: BASF CORPORATIONInventors: Weiqing Joe Zou, David James Brockway, Peter Pfab, Matthias Georg Schwab
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Patent number: 11388903Abstract: The present invention relates to a composition comprising a) recombinant exosporium-producing Bacillus cells that express a fusion protein comprising: (i) at least one plant growth stimulating protein or peptide and (ii) a targeting sequence that localizes the fusion protein to the exosporium of the Bacillus cells; and b) at least one further biological control agent selected from particular microorganisms disclosed herein and/or a mutant of a specific strain of a microorganism disclosed herein having all identifying characteristics of the respective strain, and/or at least one metabolite produced by the respective strain, and/or at least one metabolite produced by the respective strain that exhibits activity against insects, mites, nematodes and/or phytopathogens in a synergistically effective amount. Furthermore, the present invention relates to the use of this composition as well as a method for enhancing plant growth, promoting plant health, and/or reducing overall damage of plants and plant parts.Type: GrantFiled: April 24, 2020Date of Patent: July 19, 2022Assignee: BASF CORPORATIONInventors: Damian Curtis, Brian Thompson
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Publication number: 20220212162Abstract: The present disclosure is directed to Low Temperature NOx-Absorber (LT-NA) catalyst compositions, catalyst articles, and an emission treatment system for treating an exhaust gas, each including the LT-NA catalyst compositions. Further provided are methods for reducing a NOx level in an exhaust gas stream using the catalyst article. In particular, the LT-NA compositions include a zeolite containing a first metal component including palladium and a second metal component which is an alkaline earth metal component, an oxide of an alkaline earth metal component, a rare earth metal component, an oxide of a rare earth metal component, or a combination thereof. The LT-NA compositions exhibit increased low temperature NOx adsorption capacity and enhanced hydrothermal stability.Type: ApplicationFiled: May 7, 2020Publication date: July 7, 2022Applicant: BASF CORPORATIONInventors: Xinyi Wei, Xiaoming Xu, Evan Vincent Miu