Abstract: The present invention relates to a process for the preparation of a zeolitic material SiO2 and X2O3 in its framework structure, wherein X stands for a trivalent element, wherein said process comprises interzeolitic conversion of a first zeolitic material comprising SiO2 and X2O3 in its framework structure, wherein the first zeolitic material has an FER-, TON-, MTT-, BEA-, MEL-, MWW-, MFS-, and/or MFI-type framework structure to a second zeolitic material comprising SiO2 and X2O3 in its framework structure, wherein the second zeolitic material obtained in (2) has a different type of framework structure than the first zeolitic material. Furthermore, the present invention relates to a zeolitic material per se as obtainable and/or obtained according to the inventive process and to its use, in particular as a molecular sieve, as an adsorbent, for ion-exchange, or as a catalyst and/or as a catalyst support.
Type:
Grant
Filed:
June 18, 2019
Date of Patent:
December 20, 2022
Assignee:
BASF Corporation
Inventors:
Andrei-Nicolae Parvulescu, Robert McGuire, Ulrich Mueller, Xiangju Meng, Feng-Shou Xiao, Toshiyuki Yokoi, Dirk De Vos, Bernd Marler, Hermann Gies, Ute Kolb, Weiping Zhang
Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.
Type:
Grant
Filed:
April 22, 2020
Date of Patent:
December 20, 2022
Assignee:
BASF Corporation
Inventors:
Ivor Bull, Wen-Mei Xue, Patrick Burk, R. Samuel Boorse, William M. Jaglowski, Gerald Stephen Koermer, Ahmad Moini, Joseph A. Patchett, Joseph C. Dettling, Matthew Tyler Caudle
Abstract: The present invention relates to a diesel oxidation catalyst comprising a substrate and a wash-coat comprising a first layer and a second layer, wherein the substrate has a substrate length, a front end and a rear end, the washcoat comprising the first layer comprising a first metal oxide and comprising a platinum group metal supported on a metal oxide support material; the second layer comprising a second metal oxide and comprising one or more of an oxidic compound of vanadium, an oxidic compound of tungsten and a zeolitic material comprising one or more of Fe and Cu; wherein the first layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on an intermediate layer which is disposed directly on the substrate over the entire length of the substrate, on x % of the length of the substrate from the front end of the substrate, and wherein the second layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on the i
Abstract: The present invention relates generally to the field of exhaust treatment systems for purifying exhaust gas discharged from a lean burn engine. The exhaust treatment system comprises a Diesel Oxidation Catalyst (DOC), a Catalyzed Soot Filter (CSF), a reductant injector, an AEI zeolite based Selective Catalyzed Reduction (SCR) catalyst and an Ammonia Oxidation Catalyst (AMOX) downstream to the AEI zeolite based SCR catalyst.
Type:
Grant
Filed:
October 24, 2019
Date of Patent:
November 29, 2022
Assignee:
BASF Corporation
Inventors:
Stefan Maurer, Jia Di Zhang, Yu Dai, Yu Fen Hao, Ming Ming Wei, Teng Shen
Abstract: A coated substrate (2a, 2b) adapted for hydrocarbon adsorption having at least one surface, and a coating on the at least one surface, the coating comprising particulate carbon and a binder, wherein the particulate carbon has a BET surface area of at least about 1300 m2/g; and at least one of: (i) a butane affinity of greater than 60% at 5% butane; (ii) a butane affinity of greater than 35% at 0.5% butane; (iii) a micropore volume greater than about 0.2 ml/g and a mesopore volume greater than about 0.5 ml/g. A bleed emission scrubber (1) and an evaporative emission control canister system (30) comprising the coated substrate (2a, 2b) are provided. They can control evaporative hydrocarbon emissions and may provide low diurnal breathing loss (DBL) emissions even under a low purge condition.
Type:
Grant
Filed:
July 12, 2019
Date of Patent:
October 25, 2022
Assignee:
BASF Corporation
Inventors:
Wolfgang Ruettinger, Laif R. Alden, Steven Wesley Chin, Akash Abraham, Chen Chen
Abstract: Described are exhaust gas treatment systems for treatment of a gasoline engine exhaust gas stream. The exhaust gas treatment systems comprise an ammonia generating catalyst and an ammonia selective catalytic reduction (SCR) catalyst downstream of the ammonia generating catalyst. The ammonia generating catalyst comprises a NOx storage component, a refractory metal oxide support, a platinum component, and a palladium component. The ammonia generating catalyst is substantially free of ceria. The platinum and palladium components are present in a platinum to palladium ratio of greater than about 1 to 1.
Abstract: The present disclosure is directed to an emission treatment system for NOx abatement in an exhaust stream of an ammonia-fueled engine, the emission treatment system including a selective catalytic reduction (SCR) catalyst disposed on a substrate in fluid communication with the exhaust stream, an oxidation catalyst disposed on a substrate positioned either upstream or downstream of the SCR catalyst and in fluid communication with the exhaust stream and the SCR catalyst, and optionally, one or more adsorption components disposed on a substrate positioned upstream and/or downstream of the SCR catalyst and in fluid communication with the exhaust stream and the SCR catalyst, the adsorption component chosen from low temperature NOx adsorbers (LT-NA), low temperature ammonia adsorbers (LT-AA), low temperature water vapor adsorbers (LT-WA), and combinations thereof. The disclosure further provides a related method of treatment of an exhaust gas.
Abstract: The present disclosure generally provides a catalyst composition comprising a zeolite containing iron and/or copper with a reduced amount of extra-framework aluminum. The catalyst composition is useful to catalyze the reduction of nitrogen oxides in exhaust gas in the presence of a reductant.
Type:
Grant
Filed:
March 6, 2020
Date of Patent:
October 11, 2022
Assignee:
BASF Corporation
Inventors:
Ivan Petrovic, Subramanian Prasad, Joseph Palamara
Abstract: Certain selective catalytic reduction (SCR) articles, systems and methods provide for high NOx conversion while at the same time low N2O formation. The articles, systems and methods are suitable for instance for the treatment of exhaust gas of diesel engines. Certain articles have zoned coatings containing copper-containing molecular sieves disposed thereon, where for example a concentration of catalytic copper in an upstream zone is lower than the concentration of catalytic copper in a downstream zone.
Type:
Grant
Filed:
August 4, 2017
Date of Patent:
September 20, 2022
Assignee:
BASF Corporation
Inventors:
Wen-Mei Xue, Jeff H. Yang, Stanley A. Roth, Kenneth E. Voss, Sandip D. Shah, Jaya L. Mohanan
Abstract: A cyclic metals deactivation system unit for the production of equilibrium catalyst materials including a cracker vessel configured for cracking and stripping a catalyst material; and a regenerator vessel in fluid communication with the cracker vessel, the regenerator vessel configured for regeneration and steam deactivation of the catalyst material.
Type:
Grant
Filed:
August 24, 2020
Date of Patent:
September 20, 2022
Assignee:
BASF Corporation
Inventors:
James C. Fu, Chandrashekhar Kelkar, Roman Matlin, Johannes Mang, Andreas Mueller
Abstract: The present disclosure is directed to a Low Temperature NOx-Absorber (LT-NA) catalyst composition which exhibits NOx adsorption in a broad temperature and space velocity range, and shifts NOx desorption to a desired temperature range. In particular, the LT-NA composition includes a large pore zeolite containing a palladium component and a small or medium pore zeolite containing a palladium component. Further provided is a catalyst article including the LT-NA catalyst composition, an emission treatment system for treating an exhaust gas including the catalyst article, and methods for reducing a NOx level in an exhaust gas stream using the catalyst article.
Type:
Grant
Filed:
May 29, 2019
Date of Patent:
August 16, 2022
Assignee:
BASF Corporation
Inventors:
Jia Cheng Liu, Evan Vincent Miu, Xiaoming Xu, Xinyi Wei, Stefan Maurer
Abstract: A four-way conversion catalyst for treating a gasoline engine exhaust gas has a porous wall flow filter substrate with an inlet end, outlet end, substrate axial length extending between the inlet and outlet end, and passages defined by porous internal walls of the substrate, the passages having inlet passages with an open inlet and closed outlet, and outlet passages having a closed inlet and open outlet. The internal wall pores have a three-way conversion catalytic in-wall coating with an oxygen storage compound and a platinum group metal supported on a refractory metal oxide. On at least a portion of the internal wall surface defining the interface between the internal walls and the passages, the catalyst has a porous on-wall coating from the internal wall surface to the passage. The coating has porous oxidic compound and platinum group metal content of 0 to 0.001 wt. %, of the total coating weight.
Type:
Grant
Filed:
February 4, 2019
Date of Patent:
July 5, 2022
Assignee:
BASF Corporation
Inventors:
Thomas Schmitz, Attilio Siani, Stephan Siemund, Janosch Cravillon
Abstract: A microspherical fluid catalytic cracking (FCC) catalyst includes a zeolite and alumina comprising a strong Lewis site density of less than 70 ???ol/g.
Abstract: A catalyst material for abatement of exhaust gas emissions from a lean burn engine is provided, the catalyst material including a metal-exchanged SAPO-34 material, and an oxide layer at least partially covering an outside surface of the SAPO-34 material, wherein the oxide layer is not substantially blocking the pores of the SAPO-34 material.
Abstract: Zoned diesel oxidation catalysts containing a higher precious metal loading in the inlet zone that the outlet zone and an equal or shorter length inlet zone are described. Emission treatment systems and methods of remediating nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons using zoned diesel oxidation catalysts are also described.
Type:
Grant
Filed:
June 1, 2018
Date of Patent:
May 31, 2022
Assignee:
BASF Corporation
Inventors:
Kenneth E. Voss, Kevin A. Hallstrom, Sanath V. Kumar, Susanne Stiebels, Marius Vaarkamp
Abstract: Certain selective catalytic reduction (SCR) articles, systems and methods provide for high NOx conversion while at the same time low N2O formation. The articles, systems and methods are suitable for instance for the treatment of exhaust gas of diesel engines. Certain articles have zoned coatings disposed thereon, for example, a zoned coating comprising an upstream zone comprising a coating layer comprising a steam-activated iron-containing molecular sieve and a downstream zone comprising a coating layer comprising a high copper-containing molecular sieve.
Type:
Grant
Filed:
August 4, 2017
Date of Patent:
May 31, 2022
Assignee:
BASF Corporation
Inventors:
Jeff H. Yang, Wen-Mei Xue, Stanley A. Roth, Kenneth E. Voss, Qi Fu, Subramanian Prasad, Barbara K. Slawski, Jaya L. Mohanan, Sandip D. Shah
Abstract: Certain catalytic articles, systems or methods provide for excellent NOx conversion and are especially suitable for low temperature NOx conversion. The articles, systems and methods are suitable for instance for the treatment of exhaust gas of diesel engines. Certain articles or systems contain an upstream SCR composition and a downstream LNT composition. The substrate(s) may advantageously be electrically heated.
Abstract: A bottoms cracking catalyst composition, comprising: about 30 to about 60 wt % alumina; greater than 0 to about 10 wt % of a dopant, measured as the oxide; about 2 to about 20 wt % reactive silica; about 3 to about 20 wt % of a component comprising peptizable boehmite, colloidal silica, aluminum chlorohydrol, or a combination of any two or more thereof; and about 10 to about 50 wt % of kaolin.
Type:
Grant
Filed:
December 10, 2018
Date of Patent:
May 17, 2022
Assignee:
BASF Corporation
Inventors:
David M. Stockwell, Junmei Wei, Xingtao Gao, David H. Harris
Abstract: An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat layer comprising a Pt component and a Pd component, and a second washcoat layer including a refractory metal oxide support containing manganese, a zeolite, and a platinum component is described.
Type:
Grant
Filed:
May 13, 2019
Date of Patent:
April 26, 2022
Assignee:
BASF Corporation
Inventors:
Shiang Sung, Stanley A Roth, Claudia Zabel, Susanne Stiebels, Andreas Sundermann, Olga Gerlach
Abstract: A catalyst for gasoline engine exhaust gas after-treatment, comprising Pt and optionally at least one other platinum group metal on a hydrothermal stable support material which is coated onto a gasoline particulate filter. The catalyst oxidizes particulate matter trapped in the gasoline particulate filter under low temperature and abates NOx, CO and HC. Also a process for preparing the catalyst is disclosed, and a method for after-treatment of gasoline engine exhaust gas using the catalyst is disclosed.
Type:
Grant
Filed:
February 22, 2019
Date of Patent:
April 19, 2022
Assignee:
BASF Corporation
Inventors:
Yun Fei Qi, Jun Cong Jiang, Shau Lin Chen, Weiyong Tang, Yu Lin Qiu, Liang Fang Lv, Yan Zhu Lei