Patents Assigned to BASF
  • Patent number: 6025317
    Abstract: Porous polymers which are in powder form and contain N-vinylimidazole units and which are obtainable by free-radical precipitation polymerization ofa) 5-100% by weight of at least one N-vinylimidazole of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and are H, C.sub.1 -C.sub.4 -alkyl, N-vinylaxazolidone, N-vinyltriazole, 4-vinylpyridine N-oxide or mixtures of said monomers,b) 0-95% by weight of other copolymerizable monoethylenically unsaturated monomers andc) 0-50% by weight of at least one monomer with at least two non-conjugated ethylenic double bonds in aqueous solution which contains 0.5-30% by weight of at least one electrolyte and, based on the monomers employed, 0.5-80% by weight of at least one surfactant, a process of the preparation thereof, and the use of the porous polymers.
    Type: Grant
    Filed: March 3, 1998
    Date of Patent: February 15, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Stein, Dieter Boeckh, Christian Schade, Gerhard Rossler
  • Patent number: 6025031
    Abstract: The present invention relates to a coating composition consisting of at least three components (I), (II) and (III), component (I) containing as binder (A) at least one acrylate copolymer (A1) which is dispersed or dissolved in organic, optionally water-dilutable solvent and/or one polyester resin (A2) which is dispersed or dissolved in organic, optionally water-dilutable solvent and/or one polyurethane resin (A3) which is dispersed or dissolved in organic, optionally water-dilutable solvent and/or optionally a further binder (A4),component (II) contains at least one nonblocked polyisocyanate as crosslinking agent, andcomponent (III) contains as constituent essential to the invention an aqueous dispersion, prepared in a single- or multistage method, of a hydrophilicized polymer resin HP based on a hydrophobic polymer resin HP' and also, if desired, contains components (A1) and/or (A2) and/or (A3) and/or (A4) in aqueous dispersion.
    Type: Grant
    Filed: December 11, 1998
    Date of Patent: February 15, 2000
    Assignee: BASF Coatings AG
    Inventors: Bernhard Lettmann, Heinz-Peter Rink, Bernd Mayer, Egbert Nienhaus, Sunitha Grandhee
  • Patent number: 6022979
    Abstract: A process for preparing pyrazoles of the formula I ##STR1## in which R.sup.1,R.sup.2,R.sup.3 independently of one another are C.sub.1 - to C.sub.20 -alkyl, C.sub.3 - to C.sub.8 -cycloalkyl, or C.sub.7 - to C.sub.20 -aralkyl or aryl, unsubstituted or substituted by C.sub.1 - to C.sub.4 -alkyl, halogen and/or nitro,R.sup.1,R.sup.3 are additionally independently of one another hydrogen,by reacting a carbonyl compound of the formula R.sup.1 --CH.sub.2 --CO--R.sup.2, in which R.sup.1 and R.sup.2 are as defined above in the presence of a strong base witha) formic esters of the formula H--COOR.sup.4, in which R.sup.4 is C.sub.1 - to C.sub.8 -alkyl at from (-20) to 70.degree. C. and a pressure of from 1 to 50 bar orb) carbon monoxide at from 0 to 100.degree. C. and a pressure of from 1.5 to 150 barand reacting the resulting intermediate, the hydrazines of the formula R.sup.3 --NH--NH.sub.2, in which R.sup.3 is as defined above, and an inorganic or organic acid at from 0 to 90.degree. C.
    Type: Grant
    Filed: July 13, 1999
    Date of Patent: February 8, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Barth, Norbert Rieber, Klaus Erhardt
  • Patent number: 6022918
    Abstract: The present invention relates to a wire enamel formulation comprising components which are known per se and an internal lubricant consisting of a polyethylene wax, preferably having a molecular mass of from 3000 to 6000 g/mol, and a wetting agent, preferably fatty alcohol ethoxylate.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: February 8, 2000
    Assignee: BASF Coatings AG
    Inventors: Klaus-Wilhelm Lienert, Irmgart Gebert, Helmut Lehmann, Michael W. Muller
  • Patent number: 6022915
    Abstract: The invention relates to thermoplastic molding compositions consisting ofA) 98-99.995% by weight, based on A+B, of at least one acrylonitrile-containing polymer, andB) 0.005-2% by weight, based on A+B, of .alpha.-tocopherol.The invention also relates to a method for reducing the formation of residual monomers on thermal stress and shearing of the thermoplastic molding compositions by adding .alpha.-tocopherol.
    Type: Grant
    Filed: May 12, 1998
    Date of Patent: February 8, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Anton Ticktin, Graham Edmund Mc Kee, Wolfgang Fischer, Binnur Gunesin, Norbert Guntherberg
  • Patent number: 6022938
    Abstract: Isocyanato compounds with capped, isocyanate-reactive groups are those of the formula I ##STR1## where R.sup.1 and R.sup.2 are hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.10 -aryl or C.sub.7 -C.sub.10 -aralkyl or together form C.sub.3 -C.sub.10 -alkanediyl,X and Y are --O--, --S-- or ##STR2## where R.sup.4 is hydrogen, C.sub.1 -C.sub.20 -alkyl which is uninterrupted or interrupted by oxygen atoms in ether function, or is C.sub.6 -C.sub.10 -aryl or C.sub.7 -C.sub.10 -aralkyl,R.sup.3 is C.sub.1 -C.sub.10 -alkanediyl which together with --X--CR.sup.1 R.sup.2 --Y-- forms a 4-7-membered ring,in which either one hydrogen in R.sup.3 or the radical R.sup.4 in ##STR3## is replaced by an allophanate group R.sup.Ia ##STR4## in which R.sup.5 is a divalent aliphatic, alicyclic, araliphatic or aromatic C.sub.2 -C.sub.20 hydrocarbon unit,R.sup.6 is a single bond or a divalent aliphatic, alicyclic, araliphatic or aromatic C.sub.1 -C.sub.20 hydrocarbon unit or a mono- or poly(C.sub.2 -C.sub.
    Type: Grant
    Filed: June 18, 1998
    Date of Patent: February 8, 2000
    Assignee: Basf Aktiengesellschaft
    Inventors: Bernd Bruchmann, Hans Renz, Gunter Mohrhardt
  • Patent number: 6022999
    Abstract: A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30 bya) imination of 3-cyano-3,5,5-trimethylcyclohexanone with ammonia in the presence of an imination catalyst at temperatures of from 20.degree. to 150.degree. C. and pressures of from 1.5 to 30 MPa to form 3-cyano-3,5,5-trimethylcyclo-hexanone imine followed byb) hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine in the presence of ammonia over a catalyst containing copper and/or a Group VIII metal at a temperature of from 80.degree. to 160.degree. C. and under a pressure of from 5 to 30 MPa,wherein the catalytic hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine is carried out in the presence of an acid used in an amount such as to give an acid number of from 0.1 to 2, based on 3-cyano-3,5,5-trimethylcyclohexanone used.
    Type: Grant
    Filed: December 9, 1998
    Date of Patent: February 8, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Guido Voit, Tom Witzel, Boris Breitscheidel, Hermann Luyken, Karl-Heinz Ross, Peter Wahl
  • Patent number: 6022831
    Abstract: The invention relates to the control of fireblight (Erwinia amylovora) in plants by application of acylcyclohexadiones to plants susceptible to fireblight to reduce or prevent the infestation and disease caused by Erwinia amylovora. Specific compounds suitable for use in practicing the invention include prohexadione calcium and trinexapac ethyl. Included in the invention are compounds from the formula: ##STR1## and compounds of the formula ##STR2## and the metal or ammonium salts thereof.
    Type: Grant
    Filed: July 14, 1998
    Date of Patent: February 8, 2000
    Assignee: BASF Corporation
    Inventor: Richard R. Evans
  • Patent number: 6022988
    Abstract: In a process for preparing 3-cyano-3,5,5-trimethylcyclohexanone by reacting isophorone with hydrogen cyanide at from 80 to 220.degree. C. in the presence of a catalyst, the reaction is carried out in the presence of the betaine 1,3-dimethylimidazolium-4-carboxylate.
    Type: Grant
    Filed: August 11, 1999
    Date of Patent: February 8, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Jakob Fischer, Wolfgang Siegel, Volker Bomm, Martin Fischer, Klaus Mundinger
  • Patent number: 6022935
    Abstract: Polymers of C.sub.2 -C.sub.12 -alk-1-enes are prepared at from -50 to 300.degree. C. and from 0.5 to 3000 bar in the presence of a catalyst system by a process in which the catalyst system used is one which containsA) an inorganic or organic carrier,B) a metallocene complex,C) a compound forming metallocenium ions andD) if required, a metal compound of the general formula IM.sup.1 (R.sup.1).sub.r (R.sup.2).sub.s (R.sup.3).sub.t IwhereM.sup.1 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table,R.sup.1 is hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,R.sup.2 and R.sup.3 are each hydrogen, halogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.
    Type: Grant
    Filed: April 18, 1997
    Date of Patent: February 8, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: David Fischer, Helmut Frank, Martin Lux, Roland Hingmann, Gunther Schweier
  • Patent number: 6022957
    Abstract: Azothiophene disperse dyes of Formula (1) ##STR1## in which R, R.sup.1, R.sup.2 and R.sup.3 each independently is alkyl or alkenyl and mixtures thereof with other dyes are useful for dyeing synthetic textile material or a fiber blend thereof such as secondary cellulose acetate, cellulose triacetate, polyamide, polyacrylonitrile and aromatic polyester.
    Type: Grant
    Filed: April 17, 1998
    Date of Patent: February 8, 2000
    Assignee: BASF Aktiengesellschaft
    Inventor: Alan T. Leaver
  • Patent number: 6020108
    Abstract: Photopolymeric letterpress printing plates which are to be developed with water or water/alcohol mixtures after imagewise exposure and have, arranged one on top of the other on a dimensionally stable substrate, a layer (A) which may be bonded to the dimensionally stable substrate by an adhesion-promoting layer and is crosslinkable by actinic radiation, a layer (B) which is sensitive to IR radiation and, if required, a parting layer arranged between layer (A) and layer (B), and a peelable protective film applied to the layer (B), are produced by a process in which the layer (A) contains a mixture of at least one polymeric binder which is soluble or dispersible in water or water/alcohol mixtures, copolymerizable ethylenically unsaturated organic compounds which are compatible with the polymeric binder and a photoinitiator, the layer (B) sensitive to IR radiation has an optical density.gtoreq.2.
    Type: Grant
    Filed: September 26, 1996
    Date of Patent: February 1, 2000
    Assignee: BASF Lacke + Farben Aktiengesellschaft
    Inventors: Friedrich Goffing, Thomas Loerzer, Hartmut Sandig, Markus Tonnessen
  • Patent number: 6020441
    Abstract: Polymers containing ethylenically unsaturated double bonds are hydroformylated by reacting aqueous dispersions of the polymers with hydrogen and carbon monoxide in the presence of suitable hydroformylation catalysts.Also provided are the polymer dispersions obtainable by this process and the hydroformylated polymers themselves.
    Type: Grant
    Filed: May 12, 1997
    Date of Patent: February 1, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Edgar Zeller, Hartmann F. Leube, Bernhard Schlarb, Heinz-Josef Kneuper, Michael Roper
  • Patent number: 6020106
    Abstract: Transparent molded articles having a high-contrast laser inscription thereon are produced from a polymer mixture consisting ofA) from 40 to 99% by weight of a polymer of an alkyl ester of (meth)acrylic acid,B) from 1 to 50% by weight of a copolymer of styrene and acrylonitrile having an acrylonitrile content of from 8 to 30% by weight,C) from 0 to 50% by weight of rubber particles, andD) from 0 to 20% by weight of additives and processing auxiliaries, by preparing a transparent molded article from the polymer mixture, and exposing the transparent molded article to laser radiation.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: February 1, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Graham Edmund Mc Kee, Martin Welz, Andreas Deckers, Daniel Wagner, Paul Otto Damm, Hans-Josef Oslowski
  • Patent number: 6020003
    Abstract: The present invention relates to a method for making spray-dried tablettable powders with high edible oil loadings based on non-hydrolyzed gelatin. Said edible oils can be vitamin, flavor and fragrance oils.
    Type: Grant
    Filed: February 23, 1998
    Date of Patent: February 1, 2000
    Assignee: BASF Corporation
    Inventors: Friedemann Stroh, David Bower, Frederick Chaundy, Jeffrey Finnan, Thomas Soblesky
  • Patent number: 6020451
    Abstract: Thus, there is provided according to the present invention polyol compositions comprising(A) a polytetramethylene ether glycol, and(B) a difunctional active hydrogen compound-initiated polyoxyalkylene polyether polyol having a degree of unsaturation of not greater than 0.04 milliequivalents per gram of said polyether polyol.
    Type: Grant
    Filed: July 30, 1997
    Date of Patent: February 1, 2000
    Assignee: BASF Corporation
    Inventors: Thomas L. Fishback, Curtis J. Reichel, Thomas B. Lee
  • Patent number: 6020501
    Abstract: The disclosure is a process for preparing a phthalide of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently of the others hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy, by hydrogenation of a phthalic anhydride of the general formula II ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each as defined above, with the aid of a hydrogenation catalyst, which comprises performing the hydrogenation with the aid of a nickel catalyst doped with metals of subgroup 1, subgroup 6 and/or subgroup 7 of the Periodic Table.
    Type: Grant
    Filed: January 7, 1999
    Date of Patent: February 1, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Klemens Massonne, Rainer Becker, Wolfgang Reif, Joachim Wulff-Doring
  • Patent number: 6017479
    Abstract: Multicomponent fibers and methods and apparatus for producing the same are provided such that an inter-domain boundary layer is interposed between distinct domains formed of incompatible polymers so as to minimize (if not eliminate entirely) separation of the domains at their interfacial boundary. The inter-domain boundary layer is formed of a heterogeneous mixture of the polymers forming the respective adjacent domains between which the boundary layer is interposed. The inter-boundary layer will most preferably include rivulets or fingers of each polymer forming the adjacent domains which interlock with one another in a randomly tortuous manner. These different polymer rivulets thereby effectively increase the surface area and mechanical interlocking at the interfacial boundary between the fiber domains thereby increasing the adhesion therebetween.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: January 25, 2000
    Assignee: BASF Corporation
    Inventors: Charles F. Helms, Jr., Diane R. Kent, Matthew B. Hoyt, James R. Bristow, Phillip E. Wilson
  • Patent number: 6017505
    Abstract: Preparation of inorganic aerogels based on oxides of the metals magnesium, aluminum, silicon, tin, lanthanum, titanium, zirconium, chromium and/or thorium by producing a hydrogel in a sol/gel process, replacing the water in the hydrogel by an organic solvent, and drying the solvent-moist gel, takes place by conducting the drying step by exposing the solvent-moist gel to an ambient temperature which is above the boiling temperature of the solvent and at a pressure which is below the supercritical pressure of the solvent in such a way that the solvent within the gel is heated up very rapidly and evaporates.
    Type: Grant
    Filed: April 14, 1998
    Date of Patent: January 25, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Ziegler, Thomas Gerber
  • Patent number: 6018074
    Abstract: A process for the preparation of polyalcohols comprises the stages:(a) Reaction of an alkanal or ketone with formaldehyde in aqueous solution in the presence of a tertiary amine, to form a formates containing polyalcohol product mixture,(b) removal of water, excess tertiary amine, excess formaldehyde(c) heating of remaining mixture from (b) with removal of further formaldehyde and tertiary amine with formation of the formates of the polyalcohol,(d) transfer of tertiary amine removed from stage (b) and/or from stage (c), to synthesis stage (a) and/or to the subsequent transesterification stage (e),(e) transesterification of the resulting formates of the polyalcohol from stage (c) with an alcohol of the formula ROH in the presence of a transesterification catalyst to give polyalcohols and formates of the formula ##STR1## where R is a hydrocarbon radical, preferably alkyl of 1-6, particularly preferably 1-2, carbon atoms, and(f) isolation of the polyalcohols.
    Type: Grant
    Filed: October 5, 1998
    Date of Patent: January 25, 2000
    Assignee: BASF Aktiengesellshcaft
    Inventors: Detlef Kratz, Achim Stammer, Tom Witzel, Martin Brudermuller