Abstract: The present invention relates to a polyurethane-modified polyacrylate which is obtainableI. by polymerization with the additiona1) of an essentially carboxyl-free acrylate or of a mixture of acrylates,a2) of an ethylenically unsaturated monomer which carries at least one hydroxyl group per molecule and is essentially carboxyl-free or of a mixture of such monomers, anda3) of an essentially carboxyl-free, ethylenically unsaturated monomer which is different from (a1) and (a2), or of a mixture of such monomers,to give a polyurethane solution which contains no copoly-merizable double bonds,II. by subsequent further polymerization and additionb1) of at least one ethylenically unsaturated monomer which carries one carboxyl group per molecule, or of a mixture of such monomers, andb2) of an essentially carboxyl-free, ethylenically unsaturated monomer, or of a mixture of such monomers,after the monomers added in step I have been almost completely reacted, andIII.
Type:
Grant
Filed:
September 16, 1997
Date of Patent:
December 14, 1999
Assignee:
BASF Coating AG
Inventors:
Stephan Schwarte, Egon Wegner, Gerhard Reusmann, Cornelia Petri-Huber
Abstract: A process for preparing 1,2-butylene oxide by catalytic hydrogenation of vinyloxirane over a heterogeneous catalyst comprises using a catalyst comprising an element of subgroup I, VII or VIII of the periodic table, or mixtures of a plurality of these elements, in the presence or absence of one or more promoter elements, these elements and promoters having been applied by means of a vacuum vapor deposition technique to a support of metal foil or metal wire fabric.
Type:
Grant
Filed:
March 23, 1998
Date of Patent:
December 14, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Christoph Sigwart, Franz Josef Brocker, Rolf Fischer, Peter Lingelbach
Abstract: Aqueous solutions of N-methylol compounds of carboxamides, urethanes, ureas and aminotriazines or of N-methylol ethers of these compounds that are suitable for finishing cellulose-containing textile materials are prepared by reaction of compounds having one or more N--H groups in aqueous solution with formaldehyde and, in the case of N-methylol ethers, with an alcohol by adding boron trifluoride, a boron trifluoride addition compound or tetrafluoroboric acid or a salt thereof to the aqueous solutions during or immediately after the reaction.
Type:
Grant
Filed:
April 5, 1990
Date of Patent:
December 14, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Attila Bereck, Klaus Flory, Matthias Kummer
Abstract: A process for producing solid combination tablets which have at least two phases comprises molding a melt of a polymeric binder with or without at least one active ingredient, there being at least one solid product, which may contain an active ingredient incorporated into the still plastic composition during the molding step.
Type:
Grant
Filed:
March 10, 1998
Date of Patent:
December 14, 1999
Assignee:
Basf Aktiengesellschaft
Inventors:
Jurgen Zeidler, Joerg Rosenberg, Jorg Breitenbach, Andreas Kleinke, Werner Maier
Abstract: Cosmetic compositions contain a polymer with the repeating structural unit (I) ##STR1## where the radicals have the meanings stated in the description.
Type:
Grant
Filed:
August 22, 1997
Date of Patent:
December 14, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Harald Keller, Karin Sperling-Vietmeier, Horst Westenfelder
Abstract: The invention relates to a process for the preparation of a two-coat finish on a substrate surface, in which process a basecoat is employed which contains as binder a polymer which can be obtained by subjecting an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monomers to free-radical polymerization in an aqueous dispersion of a polyurethane resin which has a number-average molecular weight of from 1000 to 30,000 and contains on average from 0.05 to 1.1 polymerizable double bonds per molecule, and in the presence of a water-insoluble initiator or of a mixture of water-insoluble initiators, the weight ratio of the polyurethane resin to the ethylenically unsaturated monomer or to the mixture of ethylenically unsaturated monomers being between 1:10 and 10:1.
Type:
Grant
Filed:
May 16, 1996
Date of Patent:
December 14, 1999
Assignee:
BASF Lacke + Farben Aktiengesellschaft
Inventors:
Bernd Lettmann, Gerhard Reusmann, Egon Wegner
Abstract: This invention relates to a plastics processing equipment cleaning compound comprising a hard outer shell made from a thermoplastic resin and a soft inner core containing a substituted pyrrolidone.
Type:
Grant
Filed:
March 3, 1998
Date of Patent:
December 14, 1999
Assignee:
BASF Corporation
Inventors:
William C. Walsh, Tom A. Hazenstab, Mark W. Waldrop
Abstract: A process for preparing carboxylic acid derivatives of the formula I ##STR1## where X is OR.sup.2 or NH.sub.2,R.sup.1 is C.sub.1 -C.sub.20 -alkyl, C.sub.l -C.sub.20 -hydroxyalkyl, C.sub.3 -C.sub.12 -cycloalkyl, C.sub.4 -C.sub.12 -alkylcycloalkyl, C.sub.4 -C.sub.12 -cycloalkylalkyl, C.sub.5 -C.sub.20 -alkylcycloalkylalkyl, aryl, C.sub.7 -C.sub.20 -aralkyl, C.sub.7 -C.sub.20 -alkylaryl, a heteroaliphatic or heteroaromatic ring with 5 to 8 carbon atoms andR.sup.2 is C.sub.1 -C.sub.20 -alkyl,from carbonitriles of the formula IIR.sup.1 --C.tbd.N (II),where R.sup.1 has the abovementioned meanings, and alcohols of the formula IIIR.sup.2 --OH (III),where R.sup.2 has the abovementioned meanings, at from 50 to 300.degree. C. under from 0.1 to 350 bar in the presence of a heterogeneous catalyst, wherein the reaction is carried out in liquid phase.
Abstract: The use of modified polyaspartic acids which are obtainable by polycondensation of aspartic acid in the presence of, in each case based on the aspartic acid employed,(a) 2.5 to 25 mol % of amines with at least 6 carbon atoms(b) at least 2% by weight of phosphoric acid, phosphorous acid, hypophosphorous acid, polyphosphoric acids, phosphorus pentoxide, phosphonic acids or mixtures of said acids,at temperatures of at least 120.degree. C. and subsequent hydrolysis with bases to give modified polyaspartic acids with a phosphorus content of from 0.5 to 10% by weight, as additive to detergents, and detergents which contain the modified polyaspartic acids in amounts of from 0.1 to 20% by weight.
Type:
Grant
Filed:
March 4, 1998
Date of Patent:
December 14, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Richard Baur, Werner Bertleff, Hans-Ulrich Jager, Angelika Funhoff, Matthias Kroner, Gunnar Schornick
Abstract: Aqueous alkyldiketene dispersions comprising an alkyldiketene, cationic starch having an amylopectic content of at least 95% by weight and as anionic dispersants(a) from 0.05 to 1.0% by weight of ligninsulfonic acid, condensates of naphthalenesulfonic acid and formaldehyde, sulfonated polystyrene, salts and mixtures of said polymers and (b) from 0.05 to 1.5% by weight of sulfuric monoesters of alcohols having at least 10 carbon atoms, phosphoric monoesters or diesters of alcohols having at least 10 carbon atoms, sulfuric monoesters of alkoxylated alcohols having at least 10 carbon atoms, phosphoric monoesters or diesters of alkoxylated alcohols having at least 10 carbon atoms, C.sub.12 -C.sub.30 -alkylsulfonic acids, salts and mixtures of said compoundscan be used as body size in the manufacture of paper, paperboard and cardboard and for making cellulose fibers hydrophobic.
Type:
Grant
Filed:
May 4, 1998
Date of Patent:
December 14, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Roland Ettl, Wolfgang Reuther, Primoz Lorencak, Johann Bonn
Abstract: The present invention relates to a coating composition comprising(A) at least one hydroxyl-containing polyacrylate resin,(B) at least one isocyanate crosslinking agent and, if desired,(C) at least one hydroxyl-containing polyester-modified polyacrylate resin,wherein the polyacrylate resin (A) is obtainable by polymerizing(a1) at least one essentially carboxyl-free (meth)acrylic ester,(a2) at least one copolymerizable, hydroxyl-containing monomer which is different from (a3)(a3) at least one reaction product of acrylic acid and/or methacrylic acid with the glycidyl ester of an .alpha.-branched monocarboxylic acid having 5 to 18 carbon atoms per molecule,(a4) if desired, an [sic] at least one carboxyl-containing monomer,(a5) at least one polysiloxane macromonomer having a number-average molecular weight of from 1000 to 40,000 and on average from 0.5 to 2.5 ethylenically unsaturated double bonds per molecule or having on average from 0.5 to 2.
Type:
Grant
Filed:
February 4, 1998
Date of Patent:
December 14, 1999
Assignee:
BASF Coatings AG
Inventors:
Michael Brunnemann, Harald Borgholte, Peter Hoffmann, Olaf Hallmann, Bernhard Rubbert
Abstract: Compounds of formula I ##STR1## including pharmaceutically acceptable salts thereof in which R.sub.1 represents hydrogen, 2-phenyl-1,3-dioxan-5-yl, a C.sub.1-6 alkyl group, a C.sub.3-8 cycloalkyl group, a C.sub.5-7 cycloalkenyl group or an (optionally substituted phenyl)C.sub.1-6 alkyl group wherein the alkyl, cycloalkyl and cycloalkenyl groups are optionally substituted by one or more groups of formula OR.sub.A in which R.sub.A represents H or a C.sub.1-6 alkyl group provided that a group of formula OR.sub.A is not located on the carbon attached to nitrogen;R.sub.2 represents hydrogen, a C.sub.1-6 alkyl group, a C.sub.3-8 cycloalkyl group, halo, hydroxy, an (optionally substituted phenyl)C.sub.1-6 alkyl group, optionally substituted phenyl or R.sub.4 ; andR.sub.3 represents a group of formula (a) ##STR2## in which the phenyl ring is additionally optionally substituted and A represents NH, O, NHSO.sub.2, SO.sub.2 NH, a C.sub.1-4 alkylene chain, NHCO, NHCO.sub.2, CONH, NHCONH, CO.sub.2 or S(O).sub.
Type:
Grant
Filed:
March 17, 1998
Date of Patent:
December 14, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
David J. Calderwood, David N. Johnston, Paul Rafferty, Helen L. Twigger, Rainer Munschauer, Lee Arnold
Abstract: Allyl alcohols are isomerized in aqueous solution in the presence of protonic acids, with the pH of the reaction mixture being adjusted to the range from 2 to 5 with an acid concentration below 0.16 mol per liter of the reaction mixture or with a buffer which comprises the protonic acid.
Type:
Grant
Filed:
February 24, 1998
Date of Patent:
December 7, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Matthias Kiefer, Wolfgang Siegel, Jorg Therre, Melanie Pahl, Werner Aquila, Ulrich Schafer-Luderssen, Udo Rheude
Abstract: Thus, there is provided according to the present invention polyol compositions comprising(A) a polytetramethylene ether glycol, and(B) a difunctional active hydrogen compound-initiated polyoxyalkylene polyether polyol having a degree of unsaturation of not greater than 0.04 milliequivalents per gram of said polyether polyol.
Type:
Grant
Filed:
July 10, 1996
Date of Patent:
December 7, 1999
Assignee:
BASF Corporation
Inventors:
Thomas L. Fishback, Curtis J. Reichel, Thomas B. Lee
Abstract: The production of open-celled porous inorganic sintered products comprises the stepsa) introducing a flowable mixture comprising an aqueous polymer dispersion, sinterable inorganic powder and dispersant into a precipitation bath in which the polymer precipitates or coagulates to form a non-flowable product comprising polymer, inorganic powder and dispersant,b) removing the product from the precipitation bath and drying the product,c) heating the product to remove polymer and dispersant and sintering the product.The porous open-celled sintered products comprising sintered inorganic powder have a pore volume of from 50 to 95%, a surface area of from 0.1 to 50 m.sup.2 /g and an at least bimodal pore size distribution having maxima in the ranges from 0.02 to 5 .mu.m and from 20 to 500 .mu.m.
Abstract: Biphenylamides of the general formula I ##STR1## and their salts (A= ##STR2## R.sup.1 =F; R.sup.2 =H, halogen, alkyl, CF.sub.3, alkoxy, alkylthio; R.sup.3 =Cl, CF.sub.3 ; R.sup.4 =H, CH.sub.3 ; R.sup.5 =Cl, CH.sub.3, CHF.sub.2, CF.sub.3 ;R.sup.6 =CH.sub.3, CHF.sub.2, CF.sub.3), and compositions comprising I, the preparation of I and of the compositions, and of the use of both of them for controlling harmful fungi.
Type:
Grant
Filed:
February 17, 1998
Date of Patent:
December 7, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Karl Eicken, Harald Rang, Albrecht Harreus, Norbert Gotz, Eberhard Ammermann, Gisela Lorenz, Siegfried Strathmann
Abstract: A method of printing paper by gravure printing, wherein the paper used is coated with a paper-coating slip containing a binding agent having a butadiene content of at least 74 wt %, based on the binding agent.
Type:
Grant
Filed:
December 22, 1997
Date of Patent:
December 7, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Hartmann F. Leube, Dirk Lawrenz, Wolfgang Garber
Abstract: There are described compounds of the general formula I ##STR1## where the index and the substituents have the following meanings: R is cyano, halogen, alkyl or alkoxy;n is 0, 1 or 2, it being possible for the substituents R to differ from each other if n is 2;Het is a 5-membered heteroaromatic ring having three nitrogen atoms or two nitrogen atoms and one oxygen or sulfur atom and having attached to it an unsubstituted or substituted 6-membered aromatic or heteroaromatic ring;processes for their preparation, and their use.
Abstract: Individual differently colored or colorable feed filament ends are withdrawn from respective creel-mounted packages and passed through a separation guide. The separation guide serves to "normalize" the filament end-to-end positions and tensions. That is, the separation guide will cause the individual feed ends to be in specific predetermined positions relative to the other feed ends regardless of the position of the package on the creel. In addition, the separation guide will effectively cause a short length of each feed end to be parallel to, and separated by a substantially uniform distance from, corresponding lengths of the other feed ends. This parallel alignment of individual end lengths and the substantially uniform filament end-to-end positioning thereby imparts substantially uniform tensions on the feed ends while substantially maintaining their respective positions in the combined yarn product relative to one another.
Type:
Grant
Filed:
October 22, 1997
Date of Patent:
December 7, 1999
Assignee:
BASF Coporation
Inventors:
Willis M. King, Melvin R. Thompson, Andrew M. Coons, III, Myles W. Sterling, Leroy Boseman, Donald E. Wright
Abstract: Use of compounds from the class of the phthalocyanines, naphthalocyanines, nickel dithiolene complexes, aminium compounds of aromatic amines, methine dyes or azulenesquaric acid dyes which have their absorption maximum in the range from 600 to 1,200 nm and/or a fluorescence maximum in the range from 620 to 1,200 nm, as markers for liquids, a process for detecting markers in liquids, and a detector suitable for this purpose.
Type:
Grant
Filed:
July 17, 1998
Date of Patent:
December 7, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernhard Albert, Juergen Kipper, Christos Vamvakaris, Karin Heidrun Beck, Gerhard Wagenblast