Patents Assigned to BASF
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Patent number: 5990269Abstract: The improved water-soluble photosensitive resin composition comprises a high-polymer compound represented by the general formula (I): ##STR1## (where X is Na, K or NH.sub.4) and a water-soluble polymer which is either polyvinylpyrrolidone or a copolymer of vinylpyrrolidone and vinylimidazole or both. The composition is applied to a substrate, exposed through a mask pattern and developed to form a photocured pattern and, thereafter, a light absorber is applied to the entire surface of the substrate and dried, followed by stripping away the photocured pattern and the overlying light absorber to form a black matrix pattern. The composition is suitable for use as a photoresist in the manufacture of black matrices as on color CRTs and capable of efficient formation of photocured patterns with high sensitivity by shorter times and lower intensities of exposure.Type: GrantFiled: November 21, 1997Date of Patent: November 23, 1999Assignees: BASF Aktiengesellschaft, Tokyo Ohka Kogyo Co., Ltd.Inventors: Karin Neubecker, Stefan Stien, Stephan Kothrade
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Patent number: 5990203Abstract: The present invention relates to a method for improving the compatibility of random vinyl substituted aromatic/C.sub.4 -C.sub.6 conjugated diolefin polymer/asphalt mixtures comprising adding a modifier to said random vinyl substituted aromatic/C.sub.4 -C.sub.6 conjugated diolefin polymer/asphalt mixture selected from the group consisting of:(a) polymers containing an epoxy functionality(b) polymers containing a carboxyl functionality(c) monomers, oligomers, and polymers containing an amine functionality;(d) monomers, oligomers, and polymers containing an ester functionality; or mixtures thereof.Type: GrantFiled: May 4, 1998Date of Patent: November 23, 1999Assignee: BASF CorporationInventors: John Tze-Chiang Cheng, Heinz Plaumann, Koichi Takamura, Arthur Barry Baughmann, Wai-chun Richard Liu
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Patent number: 5990320Abstract: Optically active diphosphine ligands of the formula I, ##STR1## where: R.sup.1 is hydrogen, C.sub.1 -C.sub.10 -acyl, C.sub.1 -C.sub.10 -alkyl, C.sub.2 -C.sub.10 -alkenyl, each of which may be linear or branched, aryl, arylalkyl, in which the ring systems may be substituted in each case, ##STR2## R.sup.2, R.sup.3 independently of one another are C.sub.1 -C.sub.10 -alkyl, which may be linear or branched, aryl, arylalkyl, in which the ring systems may be substituted in each case,R.sup.4, R.sup.5, R.sup.6 independently of one another are C.sub.1 -C.sub.10 -alkyl, which may be linear or branched, aryl, arylalkyl, in which the ring systems may be substituted in each case.Type: GrantFiled: June 16, 1998Date of Patent: November 23, 1999Assignee: BASF AktiengesellschaftInventors: Gunther Helmchen, Christoph Murmann
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Patent number: 5990236Abstract: Abstract of the disclosure: A process is described for the continuous preparation of an impact-resistant molding material by anionic polymerization of styrene or another aromatic vinyl compound or mixtures thereof in the presence of a solvent and a block rubber, wherein the polymerization is carried out in at least 2 reaction vessels that together form a reactor cascade, the monomer stream being subdivided among the reaction vessels present, the living polymer chain ends being terminated in a conventional manner and the solvent being removed.Type: GrantFiled: July 1, 1997Date of Patent: November 23, 1999Assignee: BASF AktiengesellschaftInventors: Konrad Knoll, Wolfgang Loth, Hermann Gausepohl
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Patent number: 5989630Abstract: Disclosed are a polymer in the form of particles more than 1 .mu.m in size which contain more than one void, an aqueous dispersion comprising this polymer, processes for the preparation thereof and the use thereof.Type: GrantFiled: March 6, 1998Date of Patent: November 23, 1999Assignee: BASF AktiengesellschaftInventors: Bernhard Schlarb, Elmar Schwarzenbach, Walter Heckmann
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Patent number: 5990327Abstract: Use of aminotriarylmethanes of the formula ##STR1## where the ring A may be benzofused, andR.sup.1 and R.sup.2 are each substituted or unsubstituted C.sub.1 -C.sub.13 -alkyl or substituted or unsubstituted phenyl, or R.sup.1 and R.sup.2 are together with the nitrogen atom joining them together a heterocyclic radical, or else R.sup.1 is hydrogen,R.sup.3 and R.sup.4 are substituted or unsubstituted C.sub.1 -C.sub.20 -alkyl or else R.sup.3 is hydrogen, andX.sup.1 and X.sup.2 are each substituted or unsubstituted C.sub.1 -C.sub.13 -alkyl or a radical of the formula NR.sup.1 R.sup.2, or else one of X.sup.1 and X.sup.2 is hydrogen,for marking hydrocarbons, hydrocarbons comprising the abovementioned aminotriarylmethanes, a method for detecting the aminotriarylmethanes in hydrocarbons, and novel aminotriarylmethanes.Type: GrantFiled: November 30, 1995Date of Patent: November 23, 1999Assignee: BASF AktiengesellschaftInventors: Ulrike Schloesser, Karin Heidrun Beck
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Patent number: 5990219Abstract: To obtain a colored metallic paint with which a colored metallic paint film which has excellent features and with which a change in color is produced according to differences in the viewing angle can be formed using the usual cheap pigments without compounding special glitter materials. The present invention provides a paint composition which contains, per 100 parts by weight of a film forming binder (A), from 0.1 to 15 parts by weight of metallic powder (B), from 0.1 to 10 parts by weight of a first colored pigment (C) of primary particle size from 0.01 to 0.2 .mu.m which is selected from among the group comprising the phthalocyanine, perylene, indanthrone, azomethine, benzimidazolone, quinacridone, anthraquinone, diketopyrolopyrrole and dioxazine based pigments, and from 0.5 to 50 parts by weight of a second colored pigment (D) of primary particle size from 0.1 to 2 .mu.Type: GrantFiled: August 31, 1998Date of Patent: November 23, 1999Assignee: BASF Coatings AGInventors: Naoya Sakai, Eiji Fujimori, Shinichi Sakaniwa, Katsuaki Ishii
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Patent number: 5990358Abstract: A process for preparing formaldehyde by oxidative dehydrogenation of methanol comprises passing a gas mixture (i) comprisinga) from 0.1 to 50% by volume of methanol,b) from 0.1 to 30% by volume of oxygen,c) from 0 to 50% by volume of nitrogen oxide andd) from 0 to 60% by volume of water at from 150 to 800.degree. C. through a phosphorus-doped silver catalyst fixed bed (a) and applying from 0.01 to 100 ppm by weight of phosphorus, based on the phosphorus-doped silver catalyst fixed bed, in the form of a finely divided phosphorus compound having a melting point or decomposition temperature of more than 500.degree. C. (phosphorus compound P) to the phosphorus-doped silver catalyst fixed bed (a) per kg of methanol which is passed through in the form of the gas mixture (i) per cm.sup.2 of the cross-sectional area of the phosphorus-doped silver catalyst fixed bed (a).Type: GrantFiled: March 13, 1998Date of Patent: November 23, 1999Assignee: BASF AktiengesellschaftInventors: Bernhard Knuth, Rainer Diercks
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Patent number: 5990221Abstract: A process for preparing aqueous polymer dispersions by emulsion polymerization of free-radically polymerizable compounds (monomers) comprises adding, during the polymerization of the monomers, a miniemulsion which is an aqueous, surfactant-stabilized emulsion of monomers whose emulsified droplets have a size of from 10 to 500 nm and which comprises a compound (stabilizer) which is dissolved in the monomers of the droplets and whose solubility in the monomers is at least twice its solubility in water.Type: GrantFiled: July 8, 1997Date of Patent: November 23, 1999Assignee: BASF AktiengesellschaftInventors: Burkhardt Dames, Klemens Mathauer, Walter Machtle
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Patent number: 5990339Abstract: The present invention relates to phenylacetic acid derivatives of the formula I ##STR1## where the substituents and the index have the following meanings: X is NOCH.sub.3, CHOCH.sub.3, CHCH.sub.3 and [sic] CHCH.sub.2 CH.sub.3 ;R.sup.1 is hydrogen and [sic] C.sub.1 -C.sub.4 -alkyl;R.sup.2 is cyano, nitro, trifluoromethyl, halogen, C.sub.1 -C.sub.4 -alkyl and [sic] C.sub.1 -C.sub.4 -alkoxy;m is 0, 1 or 2, it being possible for the R.sup.2 radicals to be different if m is 2;R.sup.3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, C.sub.1 -C.sub.1 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylamino or di-C.sub.1 -C.sub.4 -alkylamino;R.sup.4 is hydrogen, cyano, nitro, hydroxyl, amino, halogen,R.sup.5 is hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.10 -alkenyl, C.sub.2 -C.sub.10 -alkynyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.2 -C.sub.10 -alkenylcarbonyl, C.sub.3 -C.sub.Type: GrantFiled: June 16, 1998Date of Patent: November 23, 1999Assignee: BASF AktiengesellschaftInventors: Herbert Bayer, Hubert Sauter, Ruth Muller, Wassilios Grammenos, Albrecht Harreus, Reinhard Kirstgen, Franz Rohl, Eberhard Ammermann, Gisela Lorenz
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Patent number: 5989715Abstract: The present invention relates to a layer product consisting of thermoplastic polyurethane which is stabilized against ultraviolet radiation and is based on diisocyanates, diols as chain extenders, polytetrahydrofuran or linear polyesterdiols.Type: GrantFiled: January 20, 1998Date of Patent: November 23, 1999Assignee: BASF Coatings AGInventors: Leonidas Kiriazis, Frank Prissok, Karl-Heinz Dickerhof
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Patent number: 5986006Abstract: Homo- or copolymers A composed ofA.sub.1) 40-100% by weight of monomers of the general formula I ##STR1## A.sub.2) 0-60% by weight of monomers of the general formula II ##STR2## and A.sub.3) 0-10% by weight of further monomers capable of free radical polymerization,the percentages by weight of the monomers A.sub.1) to A.sub.3) summing to 100% andR.sup.1 and R.sup.4 being identical or different radicals and each being hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.2, R.sup.3, R.sup.5, R.sup.6 being identical or different radicals and each being hydrogen or C.sub.1 -C.sub.4 -alkyl,with the proviso that at least two radicals from the group consisting of R.sup.1, R.sup.2 and R.sup.3 and from the group consisting of R.sup.4, R.sup.5 and R.sup.6 are hydrogen, andR.sup.7 is alkyl, cycloalkyl, aryl or aralkyl,are used as branching agents for amino-containing thermoplastic polymers.Type: GrantFiled: January 29, 1998Date of Patent: November 16, 1999Assignee: BASF AktiengsellschaftInventors: Alexander Gluck, Walter Gotz, Gregor Ley
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Patent number: 5986027Abstract: Polymers are obtainable by polymerizing olefinically unsaturated monomers in the presence of a catalyst system which comprises as active constituentsa) a salt of a metal of group VIII B of the Periodic Table of the Elements,b) one or more compounds selected from the group consisting of protic acids and Lewis acids,c) a chelating compound of the formula (I)R.sup.1 R.sup.2 E.sup.1 --Z--E.sup.2 R.sup.3 R.sup.4 (I)where the substituents and indices have the following meanings:E.sup.1, E.sup.2 are each an element from group VA of the Periodic Table of the Elements,Z is a bridging structural unit comprising one, two or three substructural units of elements of groups IVA, VA and VIA of the Periodic Table of the Elements,R.sup.1 to R.sup.4 are substituents selected from the group consisting of C.sub.1 -C.sub.20 -organic and C.sub.3 -C.sub.30 -organosilicon radicals, where the radicals may contain one or more elements of groups IVA, VA, VIA and VIIA of the Periodic Table of the Elements.Type: GrantFiled: November 6, 1997Date of Patent: November 16, 1999Assignee: BASF AktiengesellschaftInventors: Ferdinand Lippert, Arthur Hohn, Eckard Schauss
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Patent number: 5986013Abstract: Polymers which contain N-substituted formamide structural units, obtainable by catalytic reaction of nitrile-containing polymers in the presence of hydrogen, carbon monoxide and/or carbon monoxide-releasing compounds, are described.Type: GrantFiled: December 28, 1998Date of Patent: November 16, 1999Assignee: BASF AktiengesellschaftInventors: Klaus Ebel, Hans-Joachim Hahnle
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Patent number: 5985786Abstract: A phosphorus-doped silver catalyst fixed bed is obtainable byI. arranging silver crystals obtained by electrolytic deposition of silver from an aqueous silver salt solution to form a starting silver catalyst fixed bed,II. producing an activated silver catalyst fixed bed from the starting silver catalyst fixed bed by passing through the latter, at from 150 to 800.degree. C., a gas mixture comprising methanol and oxygen (gas mixture M), andIII. bringing the activated silver catalyst fixed bed into contact with from 1 to 20,000 ppm by weight of phosphorus, based on the silver, in the form of a finely divided phosphorus compound having a melting point or decomposition temperature of more than 500.degree. C. (phosphorus compound P).Type: GrantFiled: August 5, 1998Date of Patent: November 16, 1999Assignee: BASF AktiengesellschaftInventors: Rainer Diercks, Bernhard Knuth, Albrecht Aicher
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Patent number: 5986099Abstract: Quaterrylenetetracarboxylic diimides I ##STR1## where R is hydrogen;C.sub.1 -C.sub.30 -alkyl whose carbon chain may be interrupted by one or e of --O--, --S--, --NR.sup.1 --, --CO-- and/or --SO.sub.2 -- and which may be monosubstituted or polysubstituted by cyano, C.sub.1 -C.sub.6 -alkoxy or a 5-, 6- or 7-membered heterocyclic radical which is attached via a nitrogen atom and which may contain further heteroatoms and may be aromatic, whereR.sup.1 is hydrogen or C.sub.1 -C.sub.6 -alkyl;C.sub.5 -C.sub.8 -cycloalkyl whose carbon skeleton may be interrupted by one or more of --O--, --S-- and/or --NR.sup.1 --;aryl or hetaryl, which may each be monosubstituted or poly-substituted by C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.6 -alkoxy, cyano, --CONHR.sup.2, --NHCOR.sup.2 and/or aryl- or hetaryl-azo, which may each be substituted by C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.6 -alkoxy or cyano, whereR.sup.2 is hydrogen; C.sub.1 -C.sub.18 -alkyl; aryl or hetaryl, which may each be substituted by C.sub.1 -C.sub.Type: GrantFiled: July 21, 1997Date of Patent: November 16, 1999Assignees: BASF Aktiengesellschaft, Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V. BerlinInventors: Klaus Mullen, Heribert Quante, Arno Bohm
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Patent number: 5985919Abstract: (Het)aryloxy-, -thio- and -aminocrotonates of the formula I ##STR1## where the substituents have the following meanings: U is oxygen, sulfur or amino;V is oxygen, sulfur, amino or alkylamino;X, Y and Z independently of one another are .dbd.N-- or .dbd.CR.sup.3 --;R.sup.1 and R.sup.2 independently of one another are alkyl;R.sup.3 is hydrogen, cyano, nitro, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio and haloalkylthio; andR.sup.4 is an organic radical which is bonded to the skeleton directly or via an oxy, mercapto, amino, carboxyl or carbonylamino group,process for their preparation, and their use.Type: GrantFiled: October 30, 1997Date of Patent: November 16, 1999Assignee: BASF AktiengesellschaftInventors: Thomas Grote, Reinhard Kirstgen, Bernd Muller, Hubert Sauter, Albrecht Harreus, Hartmann Konig, Eberhard Ammermann, Gisela Lorenz, Siegfried Strathmann, Franz Rohl
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Patent number: 5985100Abstract: Butanol and dibutyl ether are separated from a mixture containing water, dibutyl ether and n-butanol, 2-butanol and/or isobutanol by a process in whicha) the mixture is introduced into a first distillation column, essentially butanol is separated off at the bottom of this distillation column and the mixture taken off at the top of the distillation columnb) is introduced into a second distillation column and essentially dibutyl ether is separated off at the bottom of this second distillation column and the mixture formed at the top of the second distillation column is removed,c) the second distillation column being operated at a higher pressure than the first distillation column and at least one of the two mixtures taken off via the top of the distillation columns being subjected to phase separation, only the organic phase separated off being fed to the second distillation column in the case of phase separation downstream of the first distillation column, and separation into an aqueous and an organic phase alsType: GrantFiled: February 17, 1998Date of Patent: November 16, 1999Assignee: BASF AktiengesellschaftInventors: Maik Aron, Harald Rust
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Patent number: 5985837Abstract: Compounds of the present invention include cell growth inhibitors which are peptides of Formula IA--B--D--E--F--G (I)and acid salts thereof, wherein A, D, and E are .alpha.-amino acid residues, B is an .alpha.-amino acid residue or an .alpha.-hydroxy acid residue, F is an aminobenzoic acid residue or an aminocycloalkanecarboxylic acid residue, and G is a monovalent radical, such as, for example, a hydrogen atom, an amino group, an alkyl group, an alkylene alkyl ether, an alkylene alkyl thioether, an alkylene aldehyde, an alkylene amide, a .beta.-hydroxylamino group, a hydrazido group, an alkoxy group, a thioalkoxy group, an aminoxy group, an oximato group, an alkylene aryl group, an alkylene ester, an alkylene sulfoxide or an alkylene sulfone. Another aspect of the present invention includes pharmaceutical compositions comprising a compound of Formula I and a pharmaceutically acceptable carrier.Type: GrantFiled: July 8, 1998Date of Patent: November 16, 1999Assignee: BASF AktiengesellschaftInventors: Kurt Ritter, Bernd Janssen, Andreas Haupt, Andreas Kling, Teresa Barlozzari, Wilhelm Amberg
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Patent number: 5985985Abstract: Polyurethanes I obtained by reacting1) an isocyanate II as defined in the specification with2) a compound V which is suitable as chain extender, obtained bya) reacting a polyhydric alcohol VI withb1) a compound VII, which includes an epoxy function and, in addition, an alcohol-reactive functional group, to form a compound VIII, and reacting a compound VIII with an .alpha.,.beta.-olefinically unsaturated carboxylic acid IX to give a compound X orb2) an .alpha.,.beta.-olefinically unsaturated carboxylic acid IX, to give a compound X andc) reacting a compound X with an amine XI having at least one primary amino which is reactive toward the .alpha.,.beta. multiple bond of IX,the sum of the number of isocyanato-reactive aminos and hydroxyls of the compound V being greater than the number of isocyanate groups of the compound II. The polyurethanes are useful as binders or binder components for pigment0free or pigment-containing coatings.Type: GrantFiled: June 26, 1997Date of Patent: November 16, 1999Assignee: BASF AktiengesellschaftInventors: Franz Weingart, Uwe Burkhardt, Stephan Bauer, Wolfgang Reich, Albert Kohl