Abstract: A process for the hydrogenation of an aromatic compound, in which at least one hydroxyl group is attached to an aromatic core, or an aromatic compound, in which at least one amino group is attached to an aromatic core, in the presence of a catalyst containing, as active metal, ruthenium and optionally one or more other Group IB, VIIB, or VIIIB metals, applied to a macroporous support.
Type:
Grant
Filed:
June 18, 1997
Date of Patent:
August 10, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Ruhl, Boris Breitscheidel, Jochem Henkelmann, Wolfgang Reif, Helmuth Menig, Sabine Weiguny
Abstract: An SiO.sub.2 -free, .alpha.Al.sub.2 O.sub.3 -containing catalyst support in the form of a hollow body in which at least part of the outer walls of the hollow body is open can be used to produce a catalyst for dehydrocyanation reactions.
Type:
Grant
Filed:
April 25, 1997
Date of Patent:
August 10, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Jacques Dupuis, Peter Trubenbach, Ekkehard Schwab, Michael Kroner
Abstract: In a process for producing polychrome ceramic shaped parts, at least two granulates formed from ceramic powder, binder and color-producing particles are shaped, subjected to binder removal and sintered. The granulates are formed from different color-producing particles and/or different concentrations of the same color-producing particles.
Abstract: Monomodal or polymodal catalyst supports or catalysts having a BET specific surface area of from 0.01 to 250 m.sup.2 /g and a monomodal or polymodal pore size distribution having a mean pore diameter of from 50 to 300,000 nm measured by the mercury pressure porosimetry method, whereina) from 10 to 95% of the pore volume is at from 0.2 to 100 times the mean pore diameter and/orb) from 10 to 80% of the pore volume is at from 0.8 to 100 times the mean pore diameter and/orc) from 50 to 95% of the pore volume is at from 0.2 to 1 times the mean pore diameter and/ord) from 50 to 80% of the pore volume is at from 0.8 to 1 times the mean pore diameter ande) the width at half height of the pore size distribution is less than 0.
Type:
Grant
Filed:
September 10, 1996
Date of Patent:
August 10, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Trubenbach, Alfred Hagemeyer, Gunter Lauth, Uwe Dingerdissen, Franz Josef Brocker, Klemens Flick
Abstract: In a process for the production of neopentyl glycol hydroxypivalate granules by depositing a neopentyl glycol hydroxypivalate melt on a chill surface, on which the melt solidifies, as a flat film, which, after solidification, is comminuted to give granules. The melt contains less than 3% by weight, based on the total amount of neopentyl glycol hydroxypivalate, of neopentyl glycol hydroxypivalate crystals.
Type:
Grant
Filed:
June 8, 1998
Date of Patent:
August 10, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Johann-Peter Melder, Dieter Baumann, Bernhard Maltry
Abstract: Provided are compositions and methods of improving a plant growth factor. The compositions and methods contain combinations of aminoethoxyvinylglycine and mepiquat chloride. The compositions provide an improvement in a plant growth factor, such as an increase in yield in cotton plant.
Type:
Grant
Filed:
December 20, 1996
Date of Patent:
August 10, 1999
Assignee:
BASF Corporation
Inventors:
Mary Callan, Warren E. Shafer, Candace L. Black-Schafer
Abstract: Monomodal or polymodal catalyst supports or catalysts having a BET specific surface area of from 0.01 to 250 m.sup.2 /g and a monomodal or polymodal pore size distribution having a mean pore diameter of from 50 to 300,000 nm measured by the mercury pressure porosimetry method, whereina) from 10 to 95% of the pore volume is at from 0.1 to 3 times the mean pore diameter and/orb) from 10 to 80% of the pore volume is at from 0.4 to 3 times the mean pore diameter and/orc) from 50 to 95% of the pore volume is at from 0.1 to 1 times the mean pore diameter and/ord) from 50 to 80% of the pore volume is at from 0.4 to 1 times the mean pore diameter ande) the width at half height of the pore size distribution is less than 0.
Type:
Grant
Filed:
September 10, 1996
Date of Patent:
August 10, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Trubenbach, Alfred Hagemeyer, Gunter Lauth, Uwe Dingerdissen, Franz Josef Brocker, Klemens Flick
Abstract: 2-?(2-Alkoxy-6-trifluoromethylpyrimidin-4-yl)oxymethylene!-phenylacetic acid derivatives of the formula I ##STR1## where the index and the substituents have the following meanings: U is CH or N;V is O or NH;R is alkyl;R.sup.1 is cyano, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or phenyl;n is 0 or an integer from 1 to 4,processes and intermediates for their preparation, and their use are described.
Type:
Grant
Filed:
May 6, 1997
Date of Patent:
August 10, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Reinhard Kirstgen, Klaus Oberdorf, Franz Schutz, Hans Theobald, Volker Harries
Abstract: There are described compounds of the general formula I ##STR1## in which the index and the substituents have the following meanings: n is 0, 1, 2, 3 or 4;R is nitro, cyano, halogen,unsubstituted or substituted alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy orin the event that n is greater than 1 additionally an unsubstituted or substituted bridge which is bonded to two adjacent ring atoms;R.sup.1, R.sup.2 are alkyl;R.sup.3 is a substituted pyrazole ?sic! or triazole ?sic! radical of the formulae A.1 to A.3 ##STR2## where the bond marked .circle-solid. is the bond to the oxygen, processes for their preparation, and their use.
Type:
Grant
Filed:
November 20, 1997
Date of Patent:
August 10, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernd Muller, Reinhard Kirstgen, Hartmann Konig, Michael Rack, Klaus Oberdorf, Franz Rohl, Hubert Sauter, Gisela Lorenz, Eberhard Ammermann, Siegfried Strathmann, Volker Harries
Abstract: Biodegradable polymers comprising a polyether ester P1 obtained by reactinga first mixture of20-95 mol% of adipic acid or ester-forming derivatives thereof or mixtures thereof,5-80 mol% of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and0-5 mol% of a compound containing sulfonate groups,and a second mixture of15-99.8 mol% of a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,85-0.2 mol% of a dihydroxy compound IHO--?(CH.sub.2).sub.n --O!.sub.m --H(n=2, 3 or 4, m=2-250)with0-5 mol%, based on the first mixture, of a compound D having at least three groups capable of ester formation,and a bisoxazoline C1, their preparation and their use in the manufacture of biodegradable molding materials.
Type:
Grant
Filed:
August 14, 1997
Date of Patent:
August 10, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Volker Warzelhan, Gunter Pipper, Ursula Seeliger, Peter Bauer, Dieter Bernhard Beimborn, Motonori Yamamoto
Abstract: A compound of the formula I ##STR1## where R.sup.1 is i-propyl, i-butyl or t-butyl,R.sup.2 is alkyl with 6-14 carbon atoms, ##STR2## with R.sup.3 =H or C.sub.1 -C.sub.4 -alkyl and m, n=0 or 1.
Abstract: A process for preparing block copolymers containing at least one block A, constructed from units of styrene or its technical equivalents (a), and at least one block C, constructed from units of a cyclic lactone (c), by anionic polymerization comprises reacting the living chain end remaining following the construction of block A with a diarylethylene, especially 1,1-diphenylethylene, under anionic polymerization conditions before reaction with the monomer (c), and preferably attaching in a conventional manner to the living end of block A a further block B, constructed from units of a diene, and also at least one further monomer unit (a) before the reaction with the diarylethylene. The block copolymer is useful for producing shaped articles, films or fibers or as a compatibilizer in polymer blends.
Type:
Grant
Filed:
July 3, 1997
Date of Patent:
August 3, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Axel Gottschalk, Raimund Stadler, Karsten Jung, Susanne Brinkmann, Vittoria Balsamo-Hernandez
Abstract: A process for preparing metal-free phthalocyanine by reductive cyclization of phthalonitrile in the presence of an aliphatic alcohol, of a redox catalyst and of an inorganic base comprises effecting the cyclization in the presence of one or more phthalocyanine derivatives selected from the group consisting of phthalocyanine-sulfonic acids and -carboxylic acids and their alkali metal, ammonium and alkylarnozium salts, the amino-substituted and aminomethylated phthalocyanines and their reaction products with alkylating agents, sulfonic acids, sulfonyl chlorides and carbonyl chlorides, the imidomethylene- and amidomethylene-substituted phthalocyanines, the alkyl-, aryl- and cyano-substituted phthalocyanines, the hydroxyl- and alkoxy-substituted phthalocyanines and their reaction products with tetraalkyl- and tetraalkoxy-silanes and the halogenated phthalocyanines.
Type:
Grant
Filed:
December 16, 1997
Date of Patent:
August 3, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Andrea Birgit Schutze, Frank Scherhag, Ingo Klopp, Anette Hartmann
Abstract: A process for preparing keto-functional polyethylene waxes having a molecular weight of from 150 to 1000 g/mol by telomerization of ethylene with aldehydes at from 500 to 5000 bar and from 100 to 280.degree. C., wherein ethylene and aldehyde are employed in a molar ration of from 5:1 to 50:1.
Abstract: The present invention provides a process for making articles of manufacture, as well as the articles themselves, comprising thermoplastic nylon materials and thermoplastic polyurethane blends capable of adhering to the thermoplastic nylon materials, wherein the thermoplastic polyurethane blends comprise:a) 3 to 200 parts of a terpolymer of styrene/.alpha.-methylstyrene/acrylonitrile/C.sub.1 -C.sub.6 alkyl acrylate with a glass transition temperature (Tg) below 0.degree. C.;b) 100 parts of a thermoplastic polyurethane produced from a diisocyanate, a C.sub.2 -C.sub.10 diol, and a polyether and/or polyester-based polyol; andc) 0 to 50 parts of various additives including lubricants, pigments, stabilizers, etc. The articles of manufacture may be configured as power tool housings, luggage handles, gear shifts, automotive pedals, etc.
Type:
Grant
Filed:
December 19, 1997
Date of Patent:
August 3, 1999
Assignee:
BASF Corporation
Inventors:
Roger Jyh-Chiarng R. Huarng, James M. Hurley
Abstract: Multicomponent fibers and methods of producing the same are provided such that an inter-domain boundary layer is interposed between distinct domains formed of incompatible polymers so as to minimize (if not eliminate entirely) separation of the domains at their interfacial boundary. The polymer forming the inter-domain boundary layer therefore is provided so as to be compatible with the otherwise incompatible polymers forming each of the domains between which it is interposed.
Type:
Grant
Filed:
January 7, 1998
Date of Patent:
August 3, 1999
Assignee:
BASF Corporation
Inventors:
Diane R. Kent, Matthew B. Hoyt, Charles F. Helms, Jr.
Abstract: Thrombin inhibitors of the formula ##STR1## where R.sup.1, A, B and D have the meaning indicated in the description, and intermediates for the preparation thereof are described.The compounds I are suitable for controlling diseases.
Type:
Grant
Filed:
July 30, 1997
Date of Patent:
August 3, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Werner Seitz, Helmut Mack, Thomas Zierke, Hans-Joachim Bohm, Hans Wolfgang Hoffken, Stefan Koser, Thomas Pfeiffer, Wilfried Hornberger
Abstract: Arylaminomethylenecamphor derivatives of the formula (1) ##STR1## where the C.dbd.C double bond is in the Z or E configuration, and the variables have the following meanings:R.sup.1 H, CH.sub.3,R.sup.2 H, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.3 -C.sub.8 -cycloalkenyl, aryl or substituted aryl,R.sup.3 H, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, aryl, substituted aryl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.8 -acyl,Ar aryl, substituted aryl, hetaryl or substituted hetaryl,are used as sunscreen agents, especially in cosmetic and pharmaceutical formulations.
Type:
Grant
Filed:
January 13, 1998
Date of Patent:
August 3, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Drogemuller, Volker Bomm, Volker Schehlmann, Horst Westenfelder
Abstract: Carboxylic acid derivatives ##STR1## where R-R.sup.6, X, Y and Z have the meanings stated in the description, and the preparation thereof, are described. The novel compounds are suitable for controlling diseases.
Type:
Grant
Filed:
March 27, 1997
Date of Patent:
August 3, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Hartmut Riechers, Dagmar Klinge, Wilhelm Amberg, Andreas Kling, Stefan Muller, Ernst Baumann, Joachim Rheinheimer, Uwe Josef Vogelbacher, Wolfgang Wernet, Liliane Unger, Manfred Raschack
Abstract: The present invention relates to N-substituted derivatives of glutamic acid of pharmaceutical interest, to pharmaceutical compositions which include compounds of the invention and pharmaceutically acceptable carriers, to methods of their preparation, and to their use in purification of interleukin-1.beta. converting enzyme (ICE).