Abstract: A molding material comprises styrene/butadiene block copolymers obtainable by anionic polymerization and from 0.01 to 1% by weight, based on the polymer, of .alpha.-tocopherol.
Type:
Grant
Filed:
August 14, 1997
Date of Patent:
March 2, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Norbert Niessner, Wolfgang Loth, Konrad Knoll, Norbert Guntherberg, Paul Naegele, Hubert Trauth, Jurgen Pohrt
Abstract: A process for preparing amines of the formula I ##STR1## where R.sup.1,R.sup.2,R.sup.3,R.sup.4,R.sup.5,R.sup.6 are hydrogen, C.sub.1 - to C.sub.20 -alkyl, C.sub.2 - to C.sub.20 -alkenyl, C.sub.2 - to C.sub.20 -alkynyl, C.sub.3 - to C.sub.20 -cycloalkyl, C.sub.4 - to C.sub.20 -alkyl-cycloalkyl, C.sub.4 - to C.sub.20 -cycloalkyl-alkyl, aryl, C.sub.7 - to C.sub.20 -alkylaryl or C.sub.7 - to C.sub.20 -aralkyl,R.sup.1 and R.sup.2 jointly are a saturated or unsaturated C.sub.3 - to C.sub.9 -alkylene divalent chain andR.sup.3 or R.sup.5 are C.sub.21 - to C.sub.200 -alkyl, C.sub.21 - to C.sub.200 -alkenyl or jointly are a C.sub.2 - to C.sub.12 -alkylene divalent chain,by reacting olefins of the formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the abovementioned meanings, with ammonia or primary or secondary amines of the formula III ##STR3## where R.sup.1 and R.sup.2 have the abovementioned meanings, at from 200.degree. to 350.degree. C.
Abstract: Carboxylic esters of the formula IR.sup.1 --CO--O--R.sup.2 I,whereR.sup.1 is an aliphatic, straight-chain or branched hydrocarbon radical having alkyl side chains and a number average molecular weight of from 250 to 5000 andR.sup.2 is a straight-chain or branched hydrocarbon radical of 1 to 30 carbon atoms or a radical of the formula II ##STR1## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6, independently of one another, are each hyrogen, branched or straight-chain alkyl, an aromatic radical or an araliphatic radical which may also contain heteroatoms,R.sup.7 and R.sup.8, independently of one another, are each branched or straight-chain alkyl or an aromatic or araliphatic radical which may also contain heteroatoms,X is O, S, NR.sup.9 or PR.sup.9, where R.sup.9 is an aliphatic or aromatic radical,n and m, independently of one another, are each from 2 to 20, andx is from 0 to 30,are used as fuel additives or lubricant additives, and fuel compositions or lubricant compositions contain these additives.
Type:
Grant
Filed:
August 12, 1996
Date of Patent:
March 2, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Arthur Hohn, Hans Funke, Knut Oppenlander, Wolfgang Gunther, Harald Schwahn
Abstract: The invention relates to a process for recycling diaphragms, in particular a process for recycling used asbestos-free diaphragms from alkali metal chloride electrolysis, the diaphragm material being comminuted, the diaphragm material being washed with a wash substrate and a reusable material being obtained.
Type:
Grant
Filed:
December 17, 1997
Date of Patent:
March 2, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Rudi Kroner, Bernd Leutner, Dieter Schlafer, Wolfgang Steiner, Holger Friedrich
Abstract: Thermoplastic molding materials compriseA) from 30 to 98% by weight of a graft polymer ofa.sub.K) from 30 to 90% by weight of an elastomeric graft core, obtainable by copolymerization ofa.sub.K /1) from 80 to 99.99% by weight of a C.sub.1 -C.sub.10 -alkyl ester of acrylic acid,a.sub.K /2) from 0.01 to 20% by weight of a crosslinking monomer anda.sub.K /3) from 0 to 40% by weight of one or more further monomers, anda.sub.S) from 10 to 70% by weight of a graft shell ofa.sub.S /1) from 50 to 100% by weight of a styrene compound of the general formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.8 -alkyl, and/or of a C.sub.1 -C.sub.8 -alkyl ester of acrylic acid or methacrylic acid, anda.sub.S /2) from 0 to 50% by weight of one or more further monomers,B) from 1 to 50% by weight of a thermoplastic polymer ofb.sub.1) from 50 to 100% by weight of styrene and/or .alpha.-methylstyrene,b.sub.2) from 0 to 50% by weight of acrylonitrile andb.sub.
Type:
Grant
Filed:
October 25, 1996
Date of Patent:
March 2, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Norbert Guntherberg, Martin Weber, Freddy Gruber, Gerhard Lindenschmidt
Abstract: Prints are produced by the offset heatset process using a printing ink based on mineral oil and additionally using an agent for increasing the abrasion resistance of the prints, where the agent for increasing the abrasion resistance is an oxidized olefin polymer which has a melt viscosity of from 100 to 15,000 mm.sup.2 /s, measured in accordance with DGF M-III 8 (75), and an acid number of from 5 to 50 mg of KOH/g of polymer, measured in accordance with DGF M-IV 2 (57).
Type:
Grant
Filed:
July 31, 1996
Date of Patent:
March 2, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Stefan Weiss, Michael Wolfgang Muller, Klaus Boehlke, Wilhelm Weber
Abstract: A process for preparing substituted imidazoles of the formula I ##STR1## R.sup.1, R.sup.2 and R.sup.3 are identical or different and are each hydrogen, halogen, NO.sub.2, CN or a C.sub.1 -C.sub.20 -hydrocarbon radical which is unsubstituted or substituted by one or more halogens or R.sup.1 and R.sup.2 together are members of a 3- to 20-membered hydrocarbon ring which is unsubstituted or substituted by one or more halogens and/or C.sub.1 -C.sub.8 -alkyl groups and which may contain 1, 2 or 3 heteroatoms from the group consisting of nitrogen, oxygen and sulfur, andR.sup.4 is a C.sub.1 -C.sub.20 -hydrocarbon radical which is unsubstituted or substituted by one or more halogens,comprises using an aqueous phase of the imidazoles of the formula II ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are as defined above with compounds of the formula IIIR.sup.4 --O--R.sup.5 IIIwhereR.sup.4 is as defined above andR.sup.5 is hydrogen or R.sup.4, it being possible in the latter case for the two R.sup.
Type:
Grant
Filed:
August 19, 1997
Date of Patent:
March 2, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Gisela Hieber, Klaus Ebel, Jurgen Schroder, Toni Dockner, Carsten Groning, Bernd Ruge
Abstract: A process for increasing the amount of isolatable products in a by-product stream generated in the production of 1,6 hexanediol includes combining the by-product stream with water to form a combination of the water and the by-product stream; and reacting the combination at a temperature between about 250.degree. C. to about 400.degree. C. at a pressure from about 1,000 psig to about 3,000 psig to form one or more reaction products.
Abstract: A method for increasing the shelf life of liquid hydroxy- and alkoxyalkyl ketones by adding from 0.0001 to 1% by weight of a base is described.
Type:
Grant
Filed:
September 18, 1996
Date of Patent:
February 23, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Karl-Heinz Ross, Ludwig Wambach, Harro Wache
Abstract: A process for preparing .gamma.,.delta.-unsaturated ketones bya) reacting vinylcarbinols or propargyl alcohols with alkyl acetoacetates or diketene andb) thermally rearranging the resulting acetoacetates in the presence or absence of an aluminum catalyst to .gamma.,.delta.-unsaturated ketones (Carroll reaction),wherein step a) and/or step b) is carried out in a cyclic carbonate of the formula I or a .gamma.-lactone of the formula II ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are H, or lower alkyl and R.sup.4 is H, lower alkyl, phenyl or methoxymethyl, as solvent.
Abstract: In a process for hydrogenating an aromatic compound in which at least one hydroxyl group is bonded to an aromatic ring or an aromatic compound in which at least one amino group is bonded to an aromatic ring, in the presence of a catalyst comprising as catalytically active component at least one metal of transition group I, VII or VIII of the Periodic Table applied to a support, the catalyst is obtainable bya) dissolving the catalytically active component or a precursor compound thereof in a solvent,b) admixing the solution thus obtained with an organic polymer which is able to bind at least ten times its own weight of water, giving a swollen polymer,c) subsequently mixing the swollen polymer with a catalyst support material andd) shaping, drying and calcining the composition obtained in this way.
Type:
Grant
Filed:
December 9, 1997
Date of Patent:
February 23, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Boris Breitscheidel, Thomas Ruhl, Klemens Flick, Jochem Henkelmann, Andreas Henne, Rolf Lebkucher
Abstract: A process for the coproduction of 6-aminocapronitrile (ACN) and hexamethylenediamine (HMD) by treatment of adiponitrile (ADN) with hydrogen in the presence of a nickel-containing catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent comprises, after the conversion based on ADN and/or the selectivity based on ACN has or have dropped below a defined value(a) interrupting the treatment of ADN with hydrogen by stopping the feed of ADN and of the solvent, if used,(b) treating the catalyst at from 150.degree. to 400.degree. C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and(c) then continuing the hydrogenation of ADN with the treated catalyst of stage (b).
Type:
Grant
Filed:
April 22, 1996
Date of Patent:
February 23, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Werner Schnurr, Guido Voit, Klemens Flick, Rolf-Hartmuth Fischer
Abstract: An improved process for the preparation of caprolactam by heating 6-aminocapronitrile in the presence of a heterogenous catalyst and water under superatmospheric pressure without rapid deactivation of the catalysts used. The process further includes the addition of a low or high boiling alcohol in the heating phase, after which the products are obtained by distillation. The process further includes a method of working up the top and bottom products of the reactors to achieve higher yields.
Abstract: Polymer powders which are redispersible in an aqueous medium are prepared by drying an aqueous polymer dispersion whose polymer particles dispersed in the aqueous medium have a positive or a negative electric surface charge, with the addition of a water-soluble polyelectrolyte as a drying assistant, the electric charge of the polyion being opposite to the electric surface charge of the disperse polymer particles.
Type:
Grant
Filed:
October 23, 1996
Date of Patent:
February 23, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Joachim Pakusch, Reinhold Dieing, Jurgen Tropsch
Abstract: Amines of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 : are each hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl,R.sub.1 and R.sup.2 together are a saturated or unsaturated C.sub.3 -C.sub.9 -alkylene chain andR.sup.3 or R.sup.5 is C.sub.21 -C.sub.200 -alkyl or C.sub.21 -C.sub.200 -alkenyl or R.sup.3 and R.sup.5 together are a C.sub.2 -C.sub.12 -alkylene chain,are prepared by reacting an olefin of the general formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the abovementioned meanings, with ammonia or a primary or secondary amine of the general formula III ##STR3## where R.sup.1 and R.sup.2 have the abovementioned meanings, at from 200.degree.0 to 350.degree. C.
Type:
Grant
Filed:
February 12, 1998
Date of Patent:
February 23, 1999
Assignee:
BASF Aktiengesellschaft
Inventors:
Karsten Eller, Rudolf Kummer, Matthias Dernbach, Hans-Jurgen Lutzel
Abstract: A polyisocyanate prepolymer composition which comprises the reaction product of a) diphenylmethane diisocyanate composition and b) an active hydrogen containing compound having a number average molecular weight of at least about 2000 wherein the reaction is carried out in the presence of a diluent capable of maintaining the average viscosity of the resulting prepolymer below about 500 cps at 25.degree. C. The prepolymer may be reacted with a resin composition to prepare soft elastomers.
Abstract: A process for preparing enantiomerically pure cis-1-amino-2-hydroxyindane, which comprisesa) converting racemic trans-1-aminoindan-2-ol with acids or acid derivatives of the general formula RCOX by conventional methods into amides of type A ##STR1## b) adding seed crystals of one enantiomer to a super-saturated solution or melt of the racemic amide A,c) isolating the crystals which have separated out, and again supersaturating the remaining mother liquor or melt after dissolving racemic amide A, and adding seed crystals of the other enantiomer, leading to selective crystallization of the latter,d) converting the resulting enantiomerically pure trans amide by conventional methods into the enantiomerically pure cis-1-amino-2-hydroxyindane.
Abstract: The present invention relates to a process for the preparation of a multicoat refinish, in which process a metallic basecoat is applied by spraying to the pretreated old finish and dried and then a clearcoat is applied to the basecoat and the clearcoat is dried together with the basecoat. The process is characterized in that the aqueous basecoat composition is applied such thata) in a first spray pass the aqueous basecoat composition is applied to the pretreated area of the old finish until a boundary is reached,b) the area of the old finish coated in step (a) is then coated in a second spray pass with the aqueous basecoat composition,c) steps (a) and (b) of the process are repeated in the region of the old finish which adjoins the previously coated region of the old finish, again until a boundary is reached, andd) process step (c) is carried out until the entire component to be coated is provided with a basecoat.
Abstract: Curable coating compositions are described comprising(a) a polymer resin comprising active hydrogen-containing functional groups,(b) a curing agent having groups that are reactive with said functional groups on (a), and(c) a compound comprising at least one carbamate group that is the reaction product of:(1) a hydroxyl group that is the result of a ring-opening reaction between an epoxy group and an organic acid group, and(2) cyanic acid or a compound comprising a carbamate group.
Abstract: The present invention relates to a coating composition containing a combination of ultraviolet light absorbing compounds, one or more of which is bound to a polymer, and a method for reducing degradation of coating compositions due to ultraviolet light exposure.
Type:
Grant
Filed:
December 18, 1996
Date of Patent:
February 16, 1999
Assignee:
BASF Corporation
Inventors:
Patricia K. Oberg, Donald L. St. Aubin, John E. Boisseau, Walter H. Ohrbom