Abstract: The present invention relates to water-blown integral skin polyurethane foam compositions, molded polyurethane articles, a process of preparing said articles, and an isocyanate composition for use therein. In particular, the invention relates to water-blown integral skin molded polyurethane articles having particularly advantageous physical properties, and compositions useful for producing such articles. In particular, the invention provides a polyurethane composition which has an isocyanate component (a) an isocyanate reactive component (b), a blowing agent comprising water (c), a polyether (d) selected from the group consisting of polytetrahydrofuran and polyethylene glycol having a number average molecular weight of from 200 to 2000 and optionally, one or more additives (e) from the group consisting of catalysts, chain extenders, oxo alcohols, and mixtures thereof.
Abstract: Monomeric styrene is recovered from plastics waste containing styrene polymers by thermal depolymerization by a process in which the waste is transported in liquid or solid form into a fluidized bed of a solid heat transfer agent and is cracked or depolymerized in an average residence time of less than 60 seconds and styrene is obtained from the gaseous crack products. Preferably, magnesium aluminum silicate is used as a heat transfer agent and C.sub.1 -C.sub.6 -hydrocarbons formed as byproducts in the depolymerization are used as operating gas for maintaining the fluidized bed and are circulated.
Abstract: A process for the preparation of recording materials for inkjet printers by applying aqueous coating compositions to one or both sides of a sheet of paper which has been treated with size, where the coating compositions contain from 20 to 200 g/l of starch and from 1 to 50 g/l of a copolymer which is obtainable by emulsion copolymerization of 100 parts by weight of a monomer mixture comprising(a) from 10 to 65 parts by weight of styrene, .alpha.-methylstyrene, acrylonitrile and/or methacrylonitrile,(b) from 30 to 85 parts by weight of acrylic and/or methacrylic esters of alcohols having 1 to 18 carbon atoms,(c) from 5 to 25 parts by weight of monomers containing tertiary and/or quaternary amino groups, and(d) from 0 to 20 parts by weight of other monoethylenically unsaturated monomersin an aqueous medium in the presence of from 12 to 300% by weight, based on the monomers, of at least one natural or synthetic protective colloid.
Type:
Grant
Filed:
May 8, 1996
Date of Patent:
September 30, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Arnold De Clercq, Lothar Hohr, Ulrich Riebeling
Abstract: An aqueous, multiphase, stable finished formulation for crop protection active compounds is described, containing in addition to watera) 10 to 700 g/l of one or more crop protection active compounds,b) 5 to 150 g/l of one or more dispersants,c) 50 to 500 g/l of one or more wetting agents,d) 0.5 to 5 g/l of one or more thickeners ande) if appropriate an organic solventand processes for preparation thereof are described.
Type:
Grant
Filed:
January 3, 1996
Date of Patent:
September 30, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
August Wigger, Hans-Michael Fricke, Uwe Kardorff, Adolf Parg, Reiner Kober
Abstract: The invention relates to a process for the production of polyurethane foams by reactinga) at least one organic polyisocyanate withb) at least one polyalkylene-polyol (b1) having a hydroxyl number of from 30 to 500, obtainable by alkoxylation of at least one initiator molecule from the group consisting of N,N'-bis(3-aminopropyl)ethylenediamine, tripropylenetetramine and tetrapropylenepentamine using at least one alkylene oxide, preferably ethylene oxide and/or 1,2-propylene oxide, or mixtures of the polyoxyalkylene polyols (b1) and other polyhydroxyl compounds having a functionality of from 2 to 8 and a hydroxyl number of from 15 to 500, andc) if desired, chain extenders and/or crosslinking agents, in the presence ofd) blowing agents and, if desired,e) catalysts andf) additives,and to the novel polyoxyalkylene-polyols (b1) which can be used for this purpose.
Type:
Grant
Filed:
October 16, 1995
Date of Patent:
September 30, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Horn, Ludwig Jung, Harald Larbig, Rolf Lebkucher, Gerhard Lehr
Abstract: A process for the recombinant production of proteins in yeast comprises transforming the yeast with an expression cassette which comprises the following structural elements encoded:L-A-P-GENwhereL is a leader sequence of an animal peptide neurohormone,A is an adaptor producing an alpha-helix structure,P is a processing signal andGEN is a structural gene for the required protein.
Type:
Grant
Filed:
March 29, 1996
Date of Patent:
September 30, 1997
Assignees:
BASF Aktiengesellschaft, Rhein Biotech Gesellschaft
Abstract: Cathodic electrocoat compositions containing self-crosslinking polymers are described. The polymers of the invention are formed from an epoxide-functional prepolymer having polyepoxide and extender segments. Each extender segment has at least one pendant hydroxyalkyl carbamate group. The prepolymer is reacted with an amine compound having at least one blocked primary amine group and at least one epoxide-reactive group. The primary amine group is unblocked and the resultant polymer is dispersed in water with the aid of a neutralizing acid.
Abstract: Disclosed as a particular isocyanate prepolymer composition particularly suitable for use in polyurethane compositions having particular applicability for producing microcellular molded polyurethane articles particularly suitable for use as sealing devices. In particular, the isocyanate prepolymer composition is the result of reacting an isocyanate blend (a) having(i) 0 to 10 pbw 2,4'-diphenylmethane diisocyanate;(ii) 30 to 80 pbw 4,4'-diphenylmethane diisocyanate;(iii) 1 to 10 pbw of a mixture of uretonimine with from 10 to 70 parts by weight of a polyol (b) having a number average molecular weight of between 1000 and 10,000, and a hydroxyl number of between 10 to 75. The resulting isocyanate prepolymer (I) has a free NCO of less than 20 and a viscosity of from 200 to 1000 cPs.
Abstract: Cyclopentadineyl compounds of the formula II ##STR1## and formula III ##STR2## their preparation and their use as intermediates in the preparation of metallocene complexes of the formula I.
Type:
Grant
Filed:
March 22, 1996
Date of Patent:
September 23, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Franz Langhauser, Jurgen Kerth, Gunther Schweier, Hans-Herbert Brintzinger, Stefan Mansel
Abstract: N-Vinyl-containing glycoluril derivatives I ##STR1## where R.sup.1 and R.sup.2 independently of one another are each hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, phenyl, tolyl or C.sub.7 -C.sub.12 -phenylalkyl orR.sup.1 and R.sup.2 together form a tri-, tetra- or pentamethylene group,R.sup.3 to R.sup.6 are each C.sub.1 -C.sub.4 -alkyl,R.sup.7 is hydrogen, C.sub.1 -C.sub.8 -alkyl, cyano or a radical of the formula COOR.sup.9,R.sup.8 is cyano or a radical of the formula COOR.sup.9 andR.sup.9 is C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, phenyl, tolyl or C.sub.7 -C.sub.12 -phenylalkyl,are suitable as light stabilizers and stabilizers for organic material, in particular for plastics and coatings.
Type:
Grant
Filed:
August 7, 1995
Date of Patent:
September 23, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Alfred Krause, Alexander Aumueller, Eckhard Korona, Hubert Trauth
Abstract: The present invention relates to an aqueous two-component polyurethane coating composition comprisingA) a water-dilutable polyacrylate resin (A) having an OH number of from 40 to 200 mg of KOH/g, an acid number of from 20 to 100 mg of KOH/g and a glass transition temperature of from -40.degree. C. to +60.degree. C., andB) a polyisocyanate component as crosslinking agent,characterized in that the water-dilutable acrylate resin is obtainable by solution polymerization, in the presence of a polymerization initiator, of at least one monomer which is free of carboxyl groups, at least one monomer which contains hydroxyl groups, at least one vinyl ester of .alpha.-branched monocarboxylic acids having 5 to 18 carbon atoms per molecule and/or at least one reaction product of acrylic acid and/or methacrylic acid with the glycidyl ester of .alpha.
Abstract: Thioamides of the formula I ##STR1## where A, B, R' are hydrogen, cyano, alkyl, alkoxy or halogen,X is .dbd.CHCH.sub.3 or .dbd.N--OCH.sub.3,R.sup.1, R.sup.2 - are hydrogen or alkyl,Y is a group ##STR2## --O--CH.sub.2, --CH.sub.2 --O--, --S--CH.sub.2 --, --CH.sub.2 --S--, --CH.dbd.CH--, --C.tbd.C-- or --CH.sub.2 --O--N.dbd.C(R')-- andR is hydrogen, unsubstituted or substituted alkyl, unsubstituted or substituted cycloalkyl, unsubstituted or substituted aryl or unsubstituted or substituted hetaryl,and pesticides containing these compounds.
Type:
Grant
Filed:
November 22, 1995
Date of Patent:
September 23, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Horst Wingert, Hubert Sauter, Herbert Bayer, Klaus Oberdorf, Gisela Lorenz, Eberhard Ammermann
Abstract: N-Vinyllactams of the general formula I ##STR1## where n is from 1 to 3, are prepared by a process which comprises reaction of a lactam of the general formula II ##STR2## where n is from 1 to 3, with from 10 to 90 percent by weight of an aqueous alkali metal hydroxide solution with distillation at from 50.degree. to 250.degree. C. and from 1 to 100 mbar and with a residence time of from 0.1 to 5 hours and subsequent reaction with acetylene at from 60.degree. to 250.degree. C. and from 1 to 100 bar.
Type:
Grant
Filed:
March 13, 1996
Date of Patent:
September 23, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Martin Schmidt-Radde, Marc Heider, Albrecht Dams, Harald Rust
Abstract: Use of herbicides of the auxin type for controlling broad-leaved weeds and grass weeds in transgenic crop plants which contain an ACC synthase antisense gene, ACC oxidase gene, ACC deaminase gene or combinations thereof is described.
Abstract: Aqueous polymer dispersions obtainable by polymerizing free-radically polymerizable unsaturated monomers in aqueous phase in the presence of a saccharide or of mixtures of saccharides by the method of free-radical aqueous emulsion polymerization are useful textile auxiliaries for the easy-care finishing of textile fabrics.
Abstract: A magneto-optical disk having at least one optically transparent, dimensionally stable substrate and at least one magneto-optical recording layer of a chromium-containing lanthanide/transition metal alloy, wherein the chromium concentration changes in the horizontal direction, and a process for the producton of the magneto-optical disks.
Abstract: The invention relates to a process for the production of a multicoat coating of the basecoat/clearcoat type using a water-dilutable basecoat composition. The process comprises a basecoat composition which contains 0.1 to 4.0% by weight, based on the binder solids, of xanthan gum and 5 to 80% by weight, based on the binder solids, of crosslinked polymeric microparticles prepared from polyester polyols and polyisocyanates.
Abstract: A generally cylindrical yarn package having multiple yarn ends is formed by converging the multiple yarn ends to form a substantially planar yarn end ribbon having the multiple yarn ends in a side-by-side untwisted contacting relationship with one another. The yarn end ribbon formed of the converged yarn ends is then wound about a continuously rotating yarn package core by reciprocally traversing the yarn end ribbon parallel to the longitudinal axis of the yarn package core while maintaining the side-by-side untwisted contacting relationship between the multiple yarn ends of the yarn end ribbon. In such a manner, a generally cylindrical yarn package is formed having multiple yarn ends which may later be separated into individual yarn ends for downstream processing by tangentially unwinding and separating the individual yarn ends from the yarn package. As a result, the present invention allows an increase in spinning capacity to be achieved (i.e.
Type:
Grant
Filed:
March 8, 1996
Date of Patent:
September 9, 1997
Assignee:
BASF Corporation
Inventors:
Theodore G. Karageorgiou, Gary W. Hanwell, David L. Caldwell, Jewell D. Purvis, Jerry M. Walker, Freddie L. Banks, Charles E. Eatmon, Otto M. Ilg, Eugene Carnes, James A. Hucks, James F. Coker, Carl R. Holzer, John E. Emery, II, David M. Pendley, Dennis W. Pomeroy, Richard Arnold, Billy K. Osborne, Philip T. Earley, John M. Temples, Larry D. Blackston, Thomas M. Toney
Abstract: A particular isocyanate prepolymer composition particularly suitable for use in polyurethane compositions having particular applicability for producing microcellular molded polyurethane articles and is particularly suitable for use in sealing devices. In particular, the isocyanate prepolymer composition is the result of reacting an isocyanate blend (a) having(i) 0 to 10 pbw 2,4'-diphenylmethane diisocyanate;(ii) 30 to 80 pbw 4,4'-diphenylmethane diisocyanate;(iii) 1 to 10 pbw of a mixture of uretoniminewith from 10 to 70 parts by weight of a polyol (b) having a number average molecular weight of between 1000 and 10,000, and a hydroxyl number of between 10 to 75. The resulting isocyanate prepolymer (I) has a free NCO of less than 20 and a viscosity of from 200 to 1000 cPs.