Patents Assigned to BASF
  • Patent number: 5681937
    Abstract: Reactive dyes of the formula ##STR1## where n is 1 or 2R.sup.1 is hydrogen or hydroxyl andD is the radical of a diazo or tetrazo component with, in each case, at least one anchor radical of the formula SO.sub.2 --Y where Y is vinyl or substituted ethyl,and the use thereof for dyeing or printing organic substrates having hydroxyl groups or nitrogen atoms are described.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: October 28, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Patsch, Heike Kilburg, Andrea Zamponi
  • Patent number: 5679158
    Abstract: A finish applicator mounting unit includes an apertured member having a plurality of apertures shaped to receive a corresponding plurality of finish applicator nozzles, and a locking mechanism that selectively obstructs the plurality of apertures such that when the corresponding plurality of finish applicator nozzles are received in the plurality of apertures, the finish applicator nozzles are selectively locked in the finish applicator mounting unit. The mounting unit preferably includes an alignment pin that ensures both proper alignment and proper insertion of the finish applicator nozzles. The finish applicator nozzles include a ceramic applicator head fictionally received in an elastic connector. A filament slot is configured to cooperate with the alignment pin to ensure the proper alignment and insertion of the nozzles. The nozzles operate more effectively and efficiently than conventional nozzles, and the mounting unit enables easy access to the nozzles for cleaning, repair and/or replacement.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: October 21, 1997
    Assignee: BASF Corporation
    Inventors: Carl R. Holzer, Jr., Walter L. Shaw, Bobby L. Tinsley, Gary Hanwell
  • Patent number: 5678400
    Abstract: A cabled yarn untwister untwists cabled yarn to obtain yarn components. The cabled yarn untwister includes an untwister frame that is rotated by a motorized drive unit (e.g., a hand-held electric drill). The untwister frame is preferably substantially T-shaped and includes a connector leg forming the base of the T-shape and a cross-wise extending yarn attatchment arm. The yarn components are attached to swivels disposed at opposing ends of the yarn attachment arm after which the untwister frame is rotated by the motorized drive unit while maintaining the cabled yarn under tension. Rotation of the untwister frame, in turn, causes the opposing ends of the yarn attachment arm to move in a generally circular orbital path and thereby untwist the individual yarn components of the cabled yarn.
    Type: Grant
    Filed: February 8, 1996
    Date of Patent: October 21, 1997
    Assignee: BASF Corporation
    Inventor: Joseph Mitchell Heard
  • Patent number: 5679868
    Abstract: A process for the preparation of glutaric dialdehyde by the reaction of alkoxy dihydropyrans of the general formula I ##STR1## in which R stands for C.sub.1 to C.sub.20 alkoxy, with water at temperatures ranging from 0.degree. to 150.degree. C. and pressures of from 0.01 to 50 bar in the presence of a which microporous, crystalline aluminum silicate catalyst, e.g. a beta-type zeolite or pentasil catalyst having a pore diameter greater than 5.4 .ANG..
    Type: Grant
    Filed: December 12, 1995
    Date of Patent: October 21, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinz-Josef Kneuper, Rainer Becker, Eugen Gehrer, Juergen Schossig, Andreas Henne
  • Patent number: 5679622
    Abstract: Pyridine-2,3-dicarboximides of the general formula I ##STR1## where R.sup.1 is hydrogen, alkoxy or unsubstituted or substituted alkyl, cycloalkyl, alkenyl or alkynyl and R.sup.2, R.sup.3 and R.sup.4 are identical or different and are each hydrogen, halogen, cyano, unsubstituted or substituted alkyl, benzyl, cycloalkyl, alkenyl, alkynyl, alkoxy, phenoxy or phenylthio, a 5-membered or 6-membered heterocyclic radical having one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, or unsubstituted or substituted phenyl, with the proviso thata) R.sup.2 is fluorine and R.sup.3 and R.sup.4 have the abovementioned general meanings orb) R.sup.3 is fluorine, chlorine, C.sub.1 -C.sub.3 -alkoxy, C.sub.2 -C.sub.5 -alkenyloxy, C.sub.2 -C.sub.5 -alkynyloxy, trifluoromethyl or cyano and R.sup.2 and R.sup.4 have the abovementioned general meanings orc) R.sup.4 is halogen or C.sub.1 -C.sub.3 -alkoxy, C.sub.2 -C.sub.5 -alkenyloxy or C.sub.2 -C.sub.5 -alkynyloxy and R.sup.2 and R.sup.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: October 21, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerhard Hamprecht, Eberhard Fuchs, Matthias Gerber, Helmut Walter, Karl-Otto Westphalen
  • Patent number: 5679869
    Abstract: A process for preparing aldehydes of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, aryl, C.sub.7 -C.sub.12 -alkylphenyl, C.sub.7 -C.sub.12 -phenylalkyl and R.sup.1 and R.sup.2 are joined together to form a 3-, 4-, 5-, 6- or 7-membered cycloaliphatic ring,R.sup.1 and R.sup.3 are each C.sub.1 -C.sub.4 -alkoxy, phenoxy, methylamino, dimethylamino or halogen, andR.sup.1 is additionally hydroxyl or aminocomprises reacting a carboxylic acid or ester of the general formula II ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each as defined above, andR.sup.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, aryl, C.sub.7 -C.sub.12 -alkylphenyl or C.sub.7 -C.sub.12 -phenylalkyl,with hydrogen in the gas phase at temperatures from 200.degree. to 450.degree. C. and pressures from 0.1 to 20 bar in the presence of a catalyst whose catalytically active mass comprises from 60 to 99.
    Type: Grant
    Filed: December 5, 1995
    Date of Patent: October 21, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Werner Schnurr, Rolf Fischer, Joachim Wulff-Doring, Michael Hesse
  • Patent number: 5679855
    Abstract: A process for preparing benzophenone imines of the general formula I ##STR1## where R.sup.1 to R.sup.6 are hydrogen, C.sub.1 -to C.sub.4 -alkoxy, C.sub.1 -to C.sub.2 -alkylamine or C.sub.2 -to C.sub.4 -dialkylamine, by reacting benzophenones of the general formula II ##STR2## where R.sup.1 to R.sup.6 have the abovementioned meanings, in liquid ammonia in the presence of oxides of the elements boron, aluminum, gallium, indium, silicon, germanium, tin, lead, phosphorus, arsenic, antimony, bismuth, scandium, yttrium, titanium, zirconium, vanadium, niobium, tantalum or mixtures thereof at from 50.degree. to 150.degree. C. and from 50 to 350 bar is described.
    Type: Grant
    Filed: November 21, 1995
    Date of Patent: October 21, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Guido Voit, Martin Holderbaum, Tom Witzel, Alexander Aumuller
  • Patent number: 5679863
    Abstract: The preparation of .alpha.-carbonylphosphine oxides by oxidizing an .alpha.-hydroxyalkyl phosphine oxide with an organic hydroperoxide or of an organic peroxy acid in the presence of a compound of a Group IV to Group VIII metal in the periodic table, and novel .alpha.-hydroxybenzyl phosphine oxides. .alpha.-Carbonylphosphine oxides are used as photoinitiators for polymerizable compositions.
    Type: Grant
    Filed: October 16, 1995
    Date of Patent: October 21, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Fischer, Eckhard Hickmann, Rudolf Kropp, Jochen Schroeder, Beate Trentmann
  • Patent number: 5679804
    Abstract: Phosphonic esters I ##STR1## (A is an aromatic radical or an .alpha., .beta.-olefinically unsaturated group and R.sup.1 is C.sub.1 -C.sub.4 -alkyl or phenyl) are prepared by subjecting a phosphite II ##STR2## to a rearrangement reaction in the presence of a catalytic amount of a halide ion-donating compound to give I. The compounds I are used as intermediates for organic syntheses, in particular for the synthesis of polyenes.
    Type: Grant
    Filed: July 27, 1995
    Date of Patent: October 21, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Ditrich, Wolfgang Krause
  • Patent number: 5677452
    Abstract: The manufacture of 5-dichloroacetyl-3,3,6-trimethyl-9-oxo-1,5-diazabicyclo?4.3.0!-nonane I by the reaction of 3,3,6-trimethyl-9-oxo-1,5-diaza-bicyclo?4.3.0!nonane II with dichloroacetyl chloride in the presence of a solvent and a base, whereina) this reaction is carried out in a two-phase system comprising a virtually water-insoluble organic solvent and water, and sodium or potassium hydroxide acting as the base is metered in at a rate corresponding to the rate of consumption of the dichloroacetyl chloride such that the aqueous phase exhibits a pH of from 7 to 9, andb) the resulting product is separated.
    Type: Grant
    Filed: October 24, 1996
    Date of Patent: October 14, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Gernot Reissenweber, Winfried Richarz, Knut Koob
  • Patent number: 5677384
    Abstract: Grafted polyamidoamines and grafted polyethyleneimines obtainable by free-radically initiated polymerization of(a) 1-vinylpyrrolidone, 1-vinyltriazole, 1-vinylimidazoles, mixtures of said monomers or mixtures of at least one of said monomers with up to 20% by weight of other monoethylenically unsaturated monomers in the presence of(b) water-soluble or -dispersible polyamidoamines, polyethyleneimines or mixtures thereof in a weight ratio of (a):(b) from 5:95 to 95:5, are useful as dye transfer inhibitors in surfactant-based detergents when included therein in an amount from 0.05 to 10% by weight.
    Type: Grant
    Filed: September 7, 1995
    Date of Patent: October 14, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Detering, Christian Schade, Knut Oppenlaender, Michael Zirnstein, Guenter Scherr, Wolfgang Trieselt, Volker Schwendemann
  • Patent number: 5677347
    Abstract: Ortho-substituted phenylacetamides I ##STR1## (R.sup.1 =H, alkyl, cycloalkyl, alkenyl, alkynyl, phenylalkynyl, alkoxyalkyl, alkoxycarbonyl, phenyl, phenylalkyl, phenylalkenyl or phenoxyalkyl, 5- or 6-membered heterocycle with 1-3 hetero atoms to which a benzene ring or a 5- or 6-membered heterocycle can be fused; R.sup.2 and R.sup.3 =H, CN, halogen, alkyl, alkoxy; R.sub.4 and R.sup.5 =H, alkyl and R.sup.4 or R.sup.5 =alkoxy; Y=O, S, SO, SO.sub.2, N.dbd.N, O--CO, CO--O, CO--O--CH.sub.2, alkylene or haloalkylene, alkenylene, alkynylene, oxy- alkylene, thio-alkylene, alkyleneoxy, carbonylalkylene or alkylenecarbonyl, W=alkoxyimino, alkoxymethylene or alkylthiomethylene), excepting compounds where R.sup.1 is hydrogen, phenyl or 2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropyl, R.sup.2 to R.sup.5 are each hydrogen, Y is carbonyloxymethylene and W is methoxymethylene or methylthiomethylene,are suitable as fungicides and for controlling pests.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: October 14, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Siegbert Brand, Eberhard Ammermann, Gisela Lorenz, Hubert Sauter, Klaus Oberdorf, Uwe Kardorff, Christoph Kuenast
  • Patent number: 5677261
    Abstract: A catalyst which consists of a carrier and a catalytically active oxide material applied to the surface of the carrier is prepared by a process in which the carrier is first moistened with, as an adhesive liquid, an aqueous solution of an organic substance boiling at above 100.degree. C. at atmospheric pressure and a layer of active oxide material is then bonded to the surface of the moistened carrier by bringing it into contact with dry, finely divided active oxide material and the adhesive liquid is then removed from the moistened carrier coated with active oxide material.
    Type: Grant
    Filed: November 24, 1995
    Date of Patent: October 14, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Andreas Tenten, Peter Weidlich, Gerd Linden
  • Patent number: 5677359
    Abstract: There is now provided a polyisocyanate based rigid closed cell foam made by reacting an organic isocyanate with a polyol composition in the presence of a blowing agent, where the polyol composition contains at least:a) an aromatic amine initiated polyoxyalkylene polyether polyol having an hydroxyl number of 200 meq polyol/g KOH or more;b) an aliphatic amine initiated polyoxyalkylene polyether polyol having an hydroxyl number of 200 meq polyol/g KOH or more; andc) an aromatic polyester polyol having an hydroxyl number of 200 meq. polyol/g KOH or more.The blowing agent is selected from the group consisting of cyclopentane, HFC's, HCFC's, and mixtures thereof in an amount of 5.0 weight percent or more based on the weight of the polyol composition. Preferably, the blowing agent is soluble in the polyol composition without sacrificing, and advantageously improving, the thermal insulation and dimensional stability of the resulting polyurethane foam.
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: October 14, 1997
    Assignee: BASF Corporation
    Inventors: Walter R. White, III, James A. Mullins, Thomas B. Lee, Keith McLellan, Ronald J. Wierzbicki
  • Patent number: 5677263
    Abstract: 5-Tetrahydropyranone cyclohexenone oxime ethers I ##STR1## where R.sup.1 =C.sub.1 -C.sub.6 -alkylR.sup.2 =phenyl which can have attached to it 1-3 substituents; C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.4 -alkenyl or C.sub.3 -C.sub.4 -alkynyl, each of which can be substituted by halogen, C.sub.1 -C.sub.3 -alkyl, unsubstituted or substituted phenyl or unsubstituted or substituted phenoxy;and their agriculturally useful salts and esters.
    Type: Grant
    Filed: February 15, 1996
    Date of Patent: October 14, 1997
    Assignee: Basf Aktiengesellschaft
    Inventors: Joachim Rheinheimer, Ulf Misslitz, Uwe Kardorff, Karl-Otto Westphalen, Helmut Walter
  • Patent number: 5675002
    Abstract: Purification of hydrophobic solids by forming granules in the presence of water comprises treating the solids, if desired more than once, with one or more different two-phase systems comprisingA) a phase which wets the solids and effects granule formation and which consists essentially of one or more water-immiscible or partially water-miscible organic liquids, andB) a phase which takes up the impurities and which consists essentially ofB1) water, one or more water-miscible organic liquids and if desired an inorganic acid or an inorganic base, orB2) water and an inorganic acidin the heat and subsequently separating the resulting granules from the aqueous phase.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: October 7, 1997
    Assignee: BASF Aktiengesellschaft
    Inventor: Karl Schmeidl
  • Patent number: 5674973
    Abstract: A process for the continuous production of polyamides from a mixture of at least one lactam and water and, if required, other monomer units and/or conventional additives and fillers under polyamide-forming conditions, where the mixture of the starting materials is heated in liquid phase in a first reaction zone until a conversion of at least 70% is reached, and undergoes adiabatic decompression and further polymerization in another reaction zone, wherein, in the first reaction zone, 0.5-7% by weight of water are employed, the temperature is increased to the range from 220.degree. to 310.degree. C., and polymerization is carried out until a conversion of at least 85% is reached and, in the second reaction zone, after the decompression further polymerization is carried out in the range from 215.degree. to 300.degree. C. without heat input.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: October 7, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Gunter Pipper, Andreas Kleinke, Peter Hildenbrand
  • Patent number: 5674436
    Abstract: Hydrogen peroxide complexes in powder form are prepared by spray drying aqueous or alcoholic solutions.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: October 7, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Jorg Breitenbach, Axel Sanner
  • Patent number: 5674812
    Abstract: 5-(Sulfo-/carbamoylmethyl)cyclohexenone oxime ethers I ##STR1## where R.sup.1 =C.sub.1 -C.sub.6 -alkyl;R.sup.2 =H, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.3 -alkoxy-C.sub.1 -C.sub.3 -alkyl, C.sub.3 -C.sub.6 -cycloalkyl;R.sup.3 =C.sub.1 -C.sub.4 -alkylsulfonyl or C.sub.1 -C.sub.4 -alkylcarbonyl;Alk=a C.sub.2 -C.sub.4 -alkylene, C.sub.3 -C.sub.4 -alkenylene, C.sub.3 -C.sub.4 -alkynylene or C.sub.2 -C.sub.3 -alkyleneoxy chain, it being possible for each chain if desired to carry a C.sub.1 -C.sub.3 -alkyl group;X.sup.1, X.sup.2 and X.sup.3 =H, halogen, C.sub.1 -C.sub.4 -haloalkyl,and their salts and esters are described.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: October 7, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulf Misslitz, Helmut Walter, Karl-Otto Westphalen, Matthias Gerber
  • Patent number: 5672721
    Abstract: A process for the preparation of low-solvent alkyl diketenes of the general formula: ##STR1## in which R.sup.1 denotes C.sub.10 -C.sub.30 alkyl or C.sub.10 -C.sub.30 alkenyl andR.sup.2 denotes hydrogen or C.sub.1 -C.sub.8 alkyl, by causing carboxylic chlorides of the formula II ##STR2## in which R.sup.1 and R.sup.2 have the aforementioned meanings, to react with tertiary amines of the formula III ##STR3## in which R.sup.3, R.sup.4, R.sup.5 denote C.sub.1 -C.sub.12 alkyl or C.sub.3 -C.sub.12 cycloalkyl andR.sup.3 and R.sup.4 together denote a C.sub.2 -C.sub.11 alkylene dichain optionally interrupted by oxygen or nitrogen,in a substantially water-immiscible, inert solvent, wherein distillation is carried out at temperatures ranging from 80.degree. to 130.degree. C. and pressures ranging from 10 to 500 mbar and subsequently with the addition of water or steam.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: September 30, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Roland Ettl, Wolfgang Kasel, Matthias Fankhanel, Wolfgang Reuther