Abstract: Pyridine-N-oxide-substituted salicylaldehyde and salicylic acid derivatives of the general formula I ##STR1## where R is a formyl group, a CO.sub.2 H group or a radical which can be hydrolyzed to CO.sub.2 H and the other substituents have the following meanings:R.sup.2 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio;X is nitrogen or CR.sup.13, R.sup.13 being hydrogen or halogen or together with R.sup.3 forming a 3- to 4-membered alkylene or alkenylene chain in which at least one methylene group is replaced by oxygen;R.sup.3 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio, or R.sup.3 is linked with R.sup.13 as indicated above to give a 5- or 6-membered ring;Y is oxygen or sulfur;R.sup.14 -R.sup.
Type:
Grant
Filed:
November 1, 1994
Date of Patent:
May 6, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Joachim Rheinheimer, Uwe J. Vogelbacher, Ernst Baumann, Matthias Gerber, Karl-Otto Westphalen, Helmut Walter
Abstract: A single tube catalyst loading device is provided which consists of a transport belt system, electric motor, and catalyst loading hopper. Using this equipment, it is possible to control the drop rate of catalyst pellets without incurring mechanical damage or breakage of the catalyst. By raising or lowering the hopper section above the transport belt, it is possible to increase or decrease the drop rate of catalyst. Drop rate is the critical parameter in controlling catalyst density within the tubes of an ethylene oxide reactor.
Abstract: Preparation of bluish luster pigments by treating titania-coated silicatic platelets with a reducing gas mixture, which comprises treating titania-coated silicatic platelets whose titania coating has a geometric layer thickness of from 10 to 60 nm at from 800.degree. to 900.degree. C. with a gas mixture comprising a vaporized organic compound and ammonia, and also bluish luster pigments based on silicatic platelets comprising a reduced titania coating with a geometric layer thickness of from 10 to 60 nm and CIELAB color coordinates -2.ltoreq.a*.ltoreq.2 and b*.ltoreq.-20 (measuring angle 20.degree., standard illuminant D65).
Type:
Grant
Filed:
March 26, 1996
Date of Patent:
April 29, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Helmut Schmidt, Werner Ostertag, Hermann Bidlingmaier, Norbert Mronga, Juan A. G. Gomez, Claus Kaliba, Raimund Schmid, Raymond Ellinghoven
Abstract: Polyalkylpiperidine-containing acetic acid and 3-aminoacrylic acid derivatives I ##STR1## where R.sup.1 is hydrogen, C.sub.1 - to C.sub.6 -alkyl, formyl, C.sub.2 - to C.sub.6 -alkanoyl, C.sub.1 - to C.sub.12 -alkoxy, C.sub.5 - to C.sub.6 -cycloalkoxy, cyanomethyl, hydroxymethyl, 2-hydroxyethyl or a radical of the formula --CR.sup.3 =CH--CO--OR.sup.4, whereR.sup.3 is hydrogen, C.sub.1 -to C.sub.6 -alkyl or a radical of the formula --CO--OR.sup.4 andR.sup.4 is C.sub.1 - to C.sub.20 -alkyl, C.sub.5 - to C.sub.8 -cycloalkyl, C.sub.7 - to C.sub.18 -aralkyl, phenyl, tolyl or a radical of the formula --(CH.sub.2 CH.sub.2 O).sub.n H or --[CH(CH.sub.3)CH.sub.2 O].sub.n H, where n is a number from 1 to 30,X is O, NH or NR.sup.6, whereR.sup.6 is C.sub.1 - to C.sub.12 -alkyl, andY is hydrogen or a group of the formula =CH--NHR.sup.7 or =CH--NR.sup.6 R.sup.7, whereR.sup.7 is phenyl which can be substituted by one to three C.sub.1 - to C.sub.12 -alkyl, C.sub.1 - to C.sub.
Type:
Grant
Filed:
October 7, 1994
Date of Patent:
April 29, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Martin Holderbaum, Alexander Aumueller, Hubert Trauth
Abstract: The present invention relates to water-blown integral skin polyurethane foam compositions, molded polyurethane articles, a process of preparing said articles, and an isocyanate composition for use therein. In particular, the invention relates to water-blown integral skin molded polyurethane articles having particularly advantageous physical properties, and compositions useful for producing such articles.In particular, the invention provides a polyurethane composition which has an isocyanate component (a) an isocyanate reactive component (b), a blowing agent comprising water (c), a polyether (d) selected from the group consisting of polytetrahydrofuran and polyethylene glycol having a number average molecular weight of from 200 to 2000 and optionally, one or more additives (e) from the group consisting of catalysts, chain extenders, oxo alcohols, and mixtures thereof.
Abstract: Anilines of the formula ##STR1## where rings A and B may each be benzofused,X is a bridge member,R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, halogen, hydroxysulfonyl, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 is hydrogen, amino, C.sub.1 -C.sub.4 -alkanoylamino or nitro, andY is vinyl or a radical of the formula C.sub.2 H.sub.4 --Q, where Q is a group detachable under alkaline reaction conditions.
Abstract: Telecheles are prepared by reacting, preferably, polyfunctional, living polymers obtained by anionic polymerization with a functionalizing agent by a process in which the reaction is carried out while stirring with a stirrer having knife-like blades as stirring elements, the latter being inclined relative to their plane of movement and passing over essentially the complete space occupied by the reaction mixture.
Abstract: Condensation products obtainable by condensation of a mixture comprising unsubstituted melamine, substituted melamine and hydroxyphenyl compounds with formaldehyde or formaldehyde donor compounds are dyed in the form of fibers, yarns, threads, wovens, knits or nonwovens in an aqueous liquor with one or more dyes of the class of the azo, anthraquinone, coumarin, methine, azamethine, quinophthalone or nitro dyes.
Abstract: In a process for producing rigid foams based on isocyanate, the blowing agent used is a mixture of at least one low-boiling hydrocarbon having from 3 to 7 carbon atoms, low molecular weight monohydric alcohols containing primary or secondary hydroxyl groups and having from 1 to 4 carbon atoms, and, if desired, the carbon dioxide formed from water and isocyanate. The rigid foams can be used as insulation material.
Type:
Grant
Filed:
July 10, 1996
Date of Patent:
April 29, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Holger Seifert, Renate Hempel, Gottfried Knorr, Udo Rotermund
Abstract: Luster pigments based on multiply coated plateletlike metallic substrates comprisingA) a first layer consisting essentially of silicon oxide, aluminum oxide and/or aluminum oxide hydrate,B) a second layer consisting essentially of metal and/or nonselectively absorbing metal oxide, andC) if desired, a third layer consisting essentially of colorless or selectively absorbing metal oxide.
Abstract: An aqueous polymer dispersion with a solids volume concentration of at least 50% by volume is obtainable by polymerizing monomers by the method of free radical aqueous emulsion polymerization with the addition of at least one fine and at least one coarse aqueous starting polymer dispersion.
Type:
Grant
Filed:
March 29, 1995
Date of Patent:
April 29, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Oral Aydin, Michael Portugall, Josef Neutzner, Walter Maechtle
Abstract: A process for the preparation of a supported catalyst for the polymerization of .alpha.-olefins, in which(1) a silicon dioxide-containing support gel is prepared by(1.1) introducing a sodium water glass or potassium water glass solution into a swirling stream of an aqueous mineral acid longitudinally and tangentially to the stream, spraying the resultant silica hydrosol in drop form into a gaseous medium and allowing it to solidify to form a hydrogel, and freeing the resultant hydrogel from salts by washing without prior ageing,(1.2) drying the hydrogel resulting from (1.1) to form the support gel,(2) the support gel (1) is charged with chromium trioxide or a chromium compound which can be converted into chromium trioxide under the conditions of process step (3), giving a chromium-containing support gel, and(3) the chromium-containing support gel (2) is heated at from 400.degree. to 1100.degree. C.
Type:
Grant
Filed:
May 24, 1995
Date of Patent:
April 29, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans-Joachim Mueller, Godofredo Follmer, Rainer Konrad, Roland Saive, Martin Lux, Hans-Helmut Goertz, Guido Funk
Abstract: Packaging materials are produced by a process which comprises coating substrates suitable for packaging with an aqueous solution or emulsion which contains a copolymer A) composed ofa) from 10 to 100% by weight of an ethylenically unsaturated C.sub.3 -C.sub.5 -carboxylic acid or C.sub.3 -C.sub.5 -di-carboxylic acid or anhydrides or half-esters of the dicarboxylic acids,b) from 0 to 50% by weight of an ethylenically unsaturated compound having at least one sulfo or sulfonate group andc) from 0 to 70% by weight of further monomers,and a polyester B) and, if required, then applying further top coats.
Type:
Grant
Filed:
September 5, 1995
Date of Patent:
April 29, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Erich Penzel, Hermann Seyffer, Eberhard Beckmann, Norbert Sendhoff
Abstract: Copolymers which are obtainable by free radical copolymerization of a mixture of(a) from 20 to 95% by weight of 1-vinylpyrrolidone, a 1-vinylimidazole or a mixture of 1-vinylpyrrolidone and/or 1-vinylimidazoles which may contain up to 20% by weight of other monoethylenically unsaturated monomers and(b) from 5 to 80% by weight of water-insoluble polymers which contain at least one ethylenically unsaturated double bond and/or one mercapto group in the molecule, processes for the preparation of the copolymers by copolymerization of the compounds of groups (a) and (b) in the abovementioned amounts in water, an alcohol, an ester or a ketone in the presence of free radical initiators, and the use of the copolymers thus obtainable and of copolymers of from 20 to 95% by weight of 1-vinylpyrrolidone or a mixture of 1-vinylpyrrolidone with up to 20% by weight of other monoethylenically unsaturated monomers andfrom 10 to 80% by weight of styrene as additives for detergents for inhibiting the dye transfer during the wash
Type:
Grant
Filed:
June 21, 1995
Date of Patent:
April 22, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Christian Schade, Juergen Detering, Wolfgang Trieselt
Abstract: Thiazolemethine dyes of the formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.8 -alkyl with or without substitution, C.sub.3 -C.sub.4 -alkenyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or tolyl, or are together with the nitrogen atom joining them together a heterocyclic radical,R.sup.3 is hydrogen, halogen, C.sub.1 -C.sub.8 -alkyl, substituted or unsubstituted phenyl, substituted or unsubstituted benzyl, cyclohexyl, thienyl, hydroxyl or C.sub.1 -C.sub.8 -monoalkylamino, andQ is the radical of an acidic-CH compound,are useful in nonlinear optics.
Type:
Grant
Filed:
June 28, 1995
Date of Patent:
April 22, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Stefan Beckmann, Karl-Heinz Etzbach, R udiger Sens
Abstract: A dispersion or solution of a free radical polymer, polycondensate or polyadduct, which consist of from 0.001 to 20% by weight of aldehyde groups --CHO or keto groups --CO--, contains, as a crosslinking agent, a compound having at least two H.sub.2 N--O---groups or oxime ether groups derived therefrom.
Type:
Grant
Filed:
December 13, 1994
Date of Patent:
April 22, 1997
Assignee:
Basf Aktiengesellschaft
Inventors:
Gerhard Bauer, Oral Aydin, Kaspar Bott, Horst Neuhauser, Gregor Ley, Albrecht Zosel, Jochen Wild, Albrecht Harreus, Eckehardt Wistuba
Abstract: Disclosed is a fiber-forming polymer blend, comprising:a) a polyamide;b) a miscible amorphous polymer; andc) an immiscible amorphous polymer.
Abstract: This invention relates to 1-amino-3-phenoxy-propane-derivatives of formula 1: ##STR1## (in which A, B, R, R.sup.x, X and Z are defined as in the specification described) and methods for their preparation.These compounds may be used as modulators of multidrug resistance in cancer chemotherapy and for circumvention of resistance in the treatment of malaria.
Type:
Grant
Filed:
June 6, 1995
Date of Patent:
April 22, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernd Janssen, Andreas Kling, Stefan Mueller, Kurt Ritter, Rainer Schlecker, Gerhard Keilhauer, Cynthia Romerdahl, Ulrich Traugott
Abstract: Acyl chlorides are prepared by reacting a carboxylic acid or its anhydride with carbonyl chloride in the presence of a carboxamide of the formula I ##STR1## where R.sup.1 is a radical of the formula ##STR2## R.sup.2 and R.sup.3 are each alkyl of 1 to 9 carbon atoms, R.sup.4 and R.sup.5 are each hydrogen or alkyl of 1 to 9 carbon atoms and the two radicals R.sup.1 and R.sup.2 may furthermore be a hydrocarbon radical which completes the moiety ##STR3## to form a heterocyclic structure, and the stated alkyl and hydrocarbon radicals may furthermore contain substituents which are inert under the reaction conditions.
Type:
Grant
Filed:
July 11, 1995
Date of Patent:
April 22, 1997
Assignee:
BASF Aktiengesellschaft
Inventors:
Martin Decker, Wolfgang Franzischka, Rudolf Irnich, deceased, Manfred Sauerwald