Patents Assigned to BASF
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Patent number: 5438099Abstract: Abstract of the disclosure: A particulate graft copolymer comprises 30 to 90% by weight of at least one elastomeric grafting base A having a weight average particle size of from 30 to 1,000 nm comprising, based on A, 85 to 99.8% by weight of at least one alkyl acrylate A11 having 1 to 8 carbon atoms in the alkyl radical, 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A12, and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or hydroxyalkyl methacrylate A13 or at least 50% by weight of one or more dienes A111, up to 50% by weight of one or more ethylenically unsaturated monomers A112, and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or hydroxyalkyl methacrylate A113 and10 to 70% by weight of a graft sheath B comprising, based on B, up to 99.9% by weight of at least one aromatic vinyl monomer B1, up to 99.9% by weight of at least one polar, copolymerizable, ethylenically unsaturated monomer B2, and 0.Type: GrantFiled: December 13, 1993Date of Patent: August 1, 1995Assignee: BASF AktiengesellschaftInventors: Wolfgang Fischer, Norbert Guentherberg
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Patent number: 5437695Abstract: Fuels and lubricants contain, as detergents, N-alkylcarboxamides prepared from olefins by the Ritter reaction.Type: GrantFiled: April 19, 1993Date of Patent: August 1, 1995Assignee: BASF AktiengesellschaftInventors: Juergen Mohr, Knut Oppenlaender, Hans J. Pander, Rolf Schneider, Juergen Thomas, Peter Schreyer
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Patent number: 5438140Abstract: Nickelized shaped articles are produced by electrodeposition of nickel from aqueous acidic baths containing as essential constituents one or more nickel salts, one or more inorganic acids and one or more brighteners, the brighteners used being cyclic ammonium compounds I ##STR1## where the nitrogen atom is part of a pyridine, quinoline or isoquinoline ring system which can additionally carry one or two C.sub.1 -C.sub.4 -alkyl substituents,R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.4 alkyl,A is a group of the formula --CO--O--R.sup.3, --CO--CH.sub.2 --CO--O--R.sup.3, --O--CO--R.sup.3 or --O--R.sup.3,whereR.sup.3 is C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.7 -C.sub.12 -phenylalkyl or phenyl which can be substituted by one or two C.sub.1 -C.sub.4 -alkyl radicals, C.sub.1 -C.sub.4 -alkoxy radicals, halogen atoms, hydroxyl groups, phenyl radicals or C.sub.1 -C.sub.4 alkoxycarbonyl groups, m is from 0 to 10, n is from 1 to 4, p is 0 or 1, and X.sup..crclbar.Type: GrantFiled: April 28, 1994Date of Patent: August 1, 1995Assignee: BASF AktiengesellschaftInventors: Alfred Oftring, Bernd Burkhart, Volker Schwendemann, Klaus Glaser
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Patent number: 5438070Abstract: Carboxanilides of the formula I where the substituents have the following meanings:R is substituted or unsubstituted alkyl, alkoxy, alkenyl, alkenyloxy, alkynyl, alkynyloxy, cycloalkyl, cycloalkenyl, cycloalkyloxy, cycloalkenyloxy or phenyl;A is one of the radicals A1 to A5 ##STR1## where R.sup.1 is hydrogen or alkyl;R.sup.2 is halogen or alkyl;R.sup.3 is alkyl or haloalkyl;n is 1 or 2,methods of manufacturing them, and agents containing them and their use for controlling harmful fungi.Type: GrantFiled: September 16, 1993Date of Patent: August 1, 1995Assignee: BASF AktiengesellschaftInventors: Karl Eicken, Hartmann Koenig, Eberhard Ammermann, Gisela Lorenz
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Patent number: 5436336Abstract: Isocyanurate- and/or uretidone-containing polyisocyanates having a reduced color index and improved shelf life are prepared by conventional catalytic oligomerization of aliphatic and/or cycloaliphatic diisocyanates and treatment of the oligomerization products with peroxycarboxylic acids.Type: GrantFiled: June 13, 1994Date of Patent: July 25, 1995Assignee: BASF AktiengesellschaftInventors: Bernd Bruchmann, Stefan Wolff, Konrad Stiefenhoefer
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Patent number: 5436049Abstract: A process for the manufacture of a stain resistant carpet by melt mixing a fiber forming synthetic polyamide with a compound, being capable to react with an amino group, to form a homogeneous polymer melt into fibers, tufting the fibers into a backing to form a carpet and treating the carpet with polymethacrylic acid, copolymers of polymethacrylic acid, a mixture of polymethacrylic acid and a sulfonated aromatic formaldehyde condensation product, and a reaction product of the polymerization or copolymerization of methacrylic acid in the presence of a sulfonated aromatic formaldehyde condensation product.Type: GrantFiled: December 21, 1993Date of Patent: July 25, 1995Assignee: BASF CorporationInventor: Harry Y. Hu
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Patent number: 5436070Abstract: A magnetic dispersion comprising finely divided iron power or iron alloy powder having a BET value of more than 35 m.sup.2 /g dispersed in a polymeric binder and organic solvent, whose filterability is markedly improved, is obtained by using certain low molecular weight phosphoric esters of the general formula I or II ##STR1## combined with a dispersion-active compound which contains at least one polar group capable of adsorption on the magnetic pigment. The polar group of the dispersion-active compound can be an acid or alkaline or amphoteric group or a group capable of hydrogen bonding or polarization. The dispersion-active compound can be a polycondensate, a polyaddition product or a chain growth copolymer which can also be used in the magnetic dispersion combined with customary other polymeric binders.Type: GrantFiled: September 26, 1994Date of Patent: July 25, 1995Assignee: BASF Magnetics GmbHInventors: Wolf-Dieter Schroer, Attila Vass, Juergen Sauter, Juergen Schmidt, Guenther Kuntz
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Patent number: 5436306Abstract: Methine or azamethine dye polymers useful in nonlinear optics contain as characteristic monomer units radicals of the formulae I, II, III and IV ##STR1## where G is a divalent organic radical,Z is nitrogen or CH,R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.6 -alkyl or substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy,R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or C.sub.3 -C.sub.4 -alkenyl,R.sup.4 is hydrogen, deuterium, methyl, trideuterated methyl or chlorine,R.sup.5 is hydrogen or deuterium,Y.sup.1 and Y.sup.2 are each C.sub.2 -C.sub.10 -alkylene,E is oxygen, imino or C.sub.1 -C.sub.4 -alkylimino, andX is hydroxyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, phenoxy, amino or C.sub.1 -C.sub.4 -mono- or -dialkylamino, andthe ring A can be benzofused, and have an average molecular weight of from 1,000 to 100,000.Type: GrantFiled: June 29, 1994Date of Patent: July 25, 1995Assignee: BASF AktiengesellschaftInventors: Karl-Heinz Etzbach, Ruediger Sens, Heike Kilburg
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Patent number: 5436277Abstract: The invention provides a liquid polyisocyanate prepolymer composition which is a result of combining about 50 to 90 percent by weight of an isocyanate blend (a.) having 55 to 75 weight percent 4,4'-MDI, 17 to 27 weight percent 2,4'-MDI, 1 to 10 weight percent 3-ring MDI oligomer, and 1 to 15 weight percent n-ring MDI oligomer (n greater than 3); about 5 to 30 weight percent of a polyhydroxy containing polyol (b.) having a molecular weight of from 700 to about 6,000, and about 5 to 15 weight percent of a toluene diisocyanate (c.). The resulting isocyanate prepolymer composition has a free NCO content of from about 20 to 40 weight percent and particularly desirable flow characteristics. The invention further provides a method of making an isocyanate prepolymer composition, a process of making a polyurethane foam utilizing the isocyanate prepolymer composition of the invention, and polyurethane foams produced by the disclosed process.Type: GrantFiled: July 28, 1994Date of Patent: July 25, 1995Assignee: BASF CorporationInventors: Thirumurti Narayan, David J. Lovell, Carlos H. Lopez
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Patent number: 5436289Abstract: An aqueous polymer dispersion with a solids volume concentration of at least 50% by volume is obtainable by polymerizing monomers by the method of free radical aqueous emulsion polymerization with the addition of at least two starting polymer dispersions, of which one contains not only particularly finely divided but also coarsely divided polymer particles.Type: GrantFiled: March 31, 1994Date of Patent: July 25, 1995Assignee: BASF AktiengesellschaftInventors: Oral Aydin, Michael Portugall, Josef Neutzner, Walter Maechtle
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Patent number: 5436335Abstract: A process for the preparation of 2,6-dimethylmorpholine from N-(2-hydroxypropyl)-2,6-dimethylmorpholine, in which N-(2-hydroxypropyl)-2,6-dimethylmorpholine, in whicha) N-(2-hydroxypropyl)-2,6-dimethylmorpholine is caused to react in the presence of a catalyst containing an element listed in Groups Ib, IIb, and/or VIIIb of the Periodic Table at temperatures ranging from 150.degree. to 600.degree. C. and is then caused to react with water at temperatures ranging from 30.degree. to 300.degree. C. orb) N-(2-hydroxypropyl)-2,6-dimethylmorpholine is caused to react in the presence of an acid catalyst at temperatures ranging from 100.degree. to 400.degree. C. followed by acid hydrolysis with water at temperatures ranging from 30.degree. to 300.degree. C.Type: GrantFiled: September 16, 1994Date of Patent: July 25, 1995Assignee: BASF AktiengesellschaftInventors: Rolf Pinkos, Hans R. Merkle, Rolf Fischer
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Patent number: 5433769Abstract: Disclosed is a process for removing emissions, originated in the manufacturing industry, especially from polymerization operations and thermoplastic polymer processing operations which includes collecting the air, containing the emissions, directing the air, containing the emissions through a first heat exchanger thereby cooling the air, directing the air, exiting the first heat exchanger, through a second heat exchanger, thereby cooling the air, directing the air exiting the second heat exchanger to a liquid removal system and directing the air, exiting the liquid removal system through the first heat exchanger, thereby heating the air.Type: GrantFiled: November 29, 1993Date of Patent: July 18, 1995Assignee: BASF CorporationInventors: Beth O. Teague, David F. Mitchell, Joseph T. Flack, Dennis G. Shealy
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Patent number: 5433761Abstract: Disclosed is an apparatus for removing emissions, originated in the manufacturing industry, especially from polymerization operations and thermoplastic polymer processing operations which has a plurality of ducts, an entrance for collecting air, containing the emissions and an exit for exiting exhaust air, a first heat exchanger which has a hot side with an entrance and an exit and a cold side with an entrance and an exit, a second heat exchanger, which has a hot side with an entrance and an exit and a cold side, a liquid removal system, and a fan, whereby the first heat exchanger is connected with the entrance of the hot side to the entrance of the duct system and with the exit of the hot side to the entrance of the hot side of the second heat exchanger by a duct; the exit of the hot side of the second heat exchanger is connected to the entrance of the cool side of the first heat exchanger by a duct; the precipitator is connected to the exit of the cool side of the first heat exchanger by a duct and to the fType: GrantFiled: November 29, 1993Date of Patent: July 18, 1995Assignee: BASF CorporationInventors: Beth O. Teague, David F. Mitchell, Joseph T. Flack, Dennis G. Shealy
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Patent number: 5434273Abstract: The preparation of N-substituted 2-pyrrolidones (I) by the reaction of maleic acid, fumaric acid, or succinic acid or functional derivatives of these acids (compounds II) with a primary amine (III) or by the reaction of amides or imides derived from II and III under hydrogenating conditions in a synthesis stage followed by isolation, by distillation, of I and other volatile components from the resulting reaction mixture, in which the residues present following distillation are subjected to further hydrogenation treatment and the compound (I) thus formed is isolated by distillation.Type: GrantFiled: February 4, 1994Date of Patent: July 18, 1995Assignee: BASF AktiengesellschaftInventors: Hans-Juergen Weyer, Rolf Fischer
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Patent number: 5434290Abstract: Preparation of 5-cyanovalerates (I) by the carbonylation of a 1-cyanobutene with carbon monoxide and an alkanol (II) corresponding to the ester radical at an elevated temperature and under superatmospheric pressure in the presence of a cobalt catalyst as well as in the presence of an activating solvent, in which the activating solvent used is an effective amount of a carbonic diester, a carbamate, or a urea of the general formula IIIa, IIIb, or IIIcR--O--CO--O--R (IIIa)R.sub.2 N--CO--O--R (IIIb)R.sub.2 N--CO--NR.sub.2 (IIIc)or a mixture of these compounds (R's same or different, C.sub.1 -C.sub.6 alkyl, C.sub.5 -C.sub.7 cycloalkyl groups or together form 5-membered to 7-membered rings).The end products I serve as intermediates, chiefly for the preparation of .epsilon.-caprolactam.Type: GrantFiled: February 28, 1994Date of Patent: July 18, 1995Assignee: BASF AktiengesellschaftInventors: Stefan Stahl, Wolfgang Harder, Arthur Hoehn
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Patent number: 5433752Abstract: Products useful for fatliquoring and filling leather and fur skins are obtained on reactingA) homo- or copolymers based on monoethylenically unsaturated dicarboxylic anhydrides and obtainable by free-radically initiated polymerization ofa) from 30 to 100 mol % of one or more monoethylenically unsaturated dicarboxylic anhydrides of from 4 to 10 carbon atoms,b) from 0 to 70 mol % of one or more aromatic vinyl compounds of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, methyl or ethyl and k is 1 or 2,(c) from 0 to 70 mol % of one or more vinyl esters of C.sub.1 - to C.sub.8 -carboxylic acids,(d) from 0 to 50 mol % of one or more C.sub.2 - to C.sub.6 -olefins, and(e) from 0 to 30 mol % of one or more monoethylenically unsaturated C.sub.3 - to C.sub.5 -carboxylic acids,which mixture of monomers (a) to (e) may additionally contain up to 10% by weight of further copolymerizable monomers, withB) amines of the general formula R.sub.4 R.sub.5 NH, where R.sup.4 is hydrogen, C.sub.Type: GrantFiled: August 26, 1994Date of Patent: July 18, 1995Assignee: BASF AktiengesellschaftInventors: Hermann Birkhofer, Peter Danisch, Walter Denzinger, Heinrich Hartmann, Norbert Greif, Knut Oppenlaender
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Patent number: 5434291Abstract: A process for the preparation of aminopropionitriles of the general formula I ##STR1## in which R denotes hydrogen or methyl, wherein ammonia is caused to react with an acrylonitrile of the general formula II ##STR2## In which the substituent has the aforementioned meanings, in a molar ratio of from 1:1 to 500:1 over a heterogenic catalyst at temperatures ranging from 40.degree. to 180.degree. C. and pressures ranging from 10 to 350 bar.Type: GrantFiled: June 1, 1994Date of Patent: July 18, 1995Assignee: BASF AktiengsellschaftInventors: Tom Witzel, Rudolf Kummer, Franz Merger, Guido Voit, Martin Brudermueller, Claus-Ulrich Priester, Wolfgang Harder
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Patent number: 5434231Abstract: Azo dye polymers useful in nonlinear optics contain as characteristic monomer units radicals of the formulae I, II, III and IV ##STR1## where D is the radical of a heterocyclic diazo component,R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.6 -alkyl or substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, and R.sup.2 may also be C.sub.1 -C.sub.4 -alkanoylamino,R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or C.sub.3 -C.sub.4 -alkenyl,R.sup.4 is hydrogen, deuterium, methyl, trideuterated methyl or chlorine,R.sup.5 is hydrogen or deuterium,Y.sup.1 and Y.sup.2 are each substituted or unsubstituted C.sub.2 -C.sub.10 -alkylene,W is oxygen, imino or C.sub.1 -C.sub.4 -alkylimino, andX is hydroxyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, phenoxy, amino or mono- or di(C.sub.1 -C.sub.4 -alkyl)amino,and have an average molecular weight of from 1,000 to 100,000.Type: GrantFiled: June 24, 1993Date of Patent: July 18, 1995Assignee: BASF AktiengesellschaftInventors: Matthias Wiesenfeldt, Sabine Gruettner-Merten, Ruediger Sens, Karl-Heinz Etzbach, Heike Kilburg
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Patent number: 5434218Abstract: Rubber-modified, impact-resistant molding materials contain, based on the sum of A, B1 and B2,A: from 70 to 98% by weight of a polymer matrix A formed by free radical polymerization of a mixture of from 60 to 90% by weight of styrene and from 10 to 40% by weight of acrylonitrile,B1: from 1 to 29% by weight of a particulate, first graft copolymer B1 which is distributed in the matrix A and consists of a grafting base of polybutadiene and grafts of a copolymer of styrene and acrylonitrile having a mean particle size of about 100-500 nm, andB2: from 1 to 29% by weight of a particulate, second graft copolymer B2 distributed in the matrix A and consisting of a grafting base of polybutadiene and grafts of a copolymer of styrene and acrylonitrile having a mean particle size of from 600 to 10,000 nm, as obtained if both graft copolymers have been prepared by solution and/or mass polymerization and have been incorporated in the polymer matrix in a conventional manner.Type: GrantFiled: April 11, 1994Date of Patent: July 18, 1995Assignee: BASF AktiengesellschaftInventors: Ehrenfried Baumgartner, Juergen Hofmann, Rudolf H. Jung, Rainer Moors, Hansjoerg Schaech
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Patent number: 5434202Abstract: N-(.beta.-carbonyl- and .beta.-cyanovinyl)-2,2,6,6-tetramethylpiperidine derivatives of the formula I ##STR1## where R.sup.1 is COOR.sup.3, COR.sup.4, CONR.sup.4 R.sup.5 or CN,R.sup.2 has the meanings of R.sup.1 or is C.sub.1 -C.sub.12 -alkyl or hydrogen,R.sup.3 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.5 -alkenyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,R.sup.4 and R.sup.5 are each hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,n is 1-4,X and A for each individual n have been defined in the specification.Type: GrantFiled: June 3, 1994Date of Patent: July 18, 1995Assignee: BASF AktiengesellschaftInventors: Alfred Krause, Alexander Aumueller, Hubert Trauth