Patents Assigned to BASF
  • Patent number: 5342898
    Abstract: A particulate graft polymer comprisingA: from 30 to 80% by weight of one or more elastomeric polymers A having a mean particle size of from 30 to 1000 run, comprising, based on A,A1: from 85 to 99.8% by weight of one or more alkyl acrylates A1 having from 1 to 8 carbon atoms in the alkyl radical,A2: from 0.1 to 5% by weight of one or more polyfunctional, crosslinking monomers A2, andA3: from 0.1 to 10% by weight of one or more monomers A3 containing one or more acid groups, orA11: up to 100% by weight of a diene A11,A12: up to 50% by weight of one or more vinyl-aromatic monomers A12,A13: up to 10% by weight of one or more monomers A13 containing one or more acid groups, as the graft base, andB: from 20 to 70% by weight of a shell B grafted onto the elastomeric polymer A and comprising, based on B,B1: from 50 to 89.9% by weight of one or more vinylaromatic monomers B1,B2: from 10 to 49.9% by weight of one or more polar, copolymerizable, ethylenically unsaturated monomers B2, andB3: from 0.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: August 30, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Friedrich Seitz, Karl Ruppmich, Norbert Guentherberg, Norbert Niessner
  • Patent number: 5342928
    Abstract: Azo dyes useful for dyeing or printing textile fibers or fabrics and containing novel aminobenzo heterocycles as diazo component have the formula ##STR1## where X is nitrogen or a radical of the formula CR.sup.6, where R.sup.6 is hydrogen, C.sub.1 -C.sub.4 -alkoxycarbonyl or C.sub.1 -C.sub.6 -alkanoyl,R.sup.1 and R.sup.2 are substituted or unsubstituted C.sub.1 -C.sub.10 -alkyl or substituted or unsubstituted C.sub.3 -C.sub.4 -alkenyl or additionally in the case of R.sup.1 hydrogen,R.sup.3 is hydrogen or C.sub.1 -C.sub.4 -alkoxy,R.sup.4 is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxy, substituted or unsubstituted C.sub.1 -C.sub.8 -alkanoylamino, C.sub.1 -C.sub.4 -alkylsulfonylamino, C.sub.3 -C.sub.4 -alkenoylamino or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxycarbonylamino, andR.sup.5 is hydrogen, nitro, halogen, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio or cyano.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: August 30, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Roetsch, Helmut Hagen, Helmut Reichelt, Clemens Grund
  • Patent number: 5342488
    Abstract: A process for the separation of 1,4-butanediol from mixtures obtained by the catalytic hydrogenation of maleates, fumarates, and/or succinates, which also contain tetrahydrofuran, water, C.sub.1 -C.sub.4 alcohols, succinic diesters, hydroxybutyrates, alkylhydroxyalkyl succinates, gamma-butyrolactone and butyrates, in addition to 1,4-butanediol, comprising the following steps:a) separating, in a first column having an actual number of plates of from 20 to 70 and operated at a top pressure of from 50 to 1100 mbar and preferably from 50 to 500 mbar and a top temperature of from 40.degree. to 120.degree. C., alcohol, water and tetrahydrofuran, as overhead product,b) feeding the bottom product of the first column into a second column having an actual number of plates of from 30 to 90 and withdrawing the overhead product consisting of alcohol and butyrate and obtained at a top pressure of from 45 to 250 mbar and a top temperature of from 45.degree. to 120.degree. C.
    Type: Grant
    Filed: February 17, 1993
    Date of Patent: August 30, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Juergen Gosch, Harald Rust, Rolf Fischer, Claus Hechler, Rolf Pinkos
  • Patent number: 5342561
    Abstract: A process for thermoplastic processing and sintering an unplastifiable polymer comprises dispersing the unplastifiable polymer in powder form in a melt of a polyacetal or a mixture of polyacetals, cooling the resulting mixture, granulating it, forwarding the granules to a thermoplastic processing stage, injection or extrusion molding, exposing the molding to an atmosphere which contains an acidic gas, thereby de-polymerizing the polyacetal, enveloping the remaining porous molding on all sides in a gas/liquid-impermeable film, heating in an autoclave, and isostatically sintering the molding with pressure from all sides to form the finished article.
    Type: Grant
    Filed: May 27, 1992
    Date of Patent: August 30, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Josef Sterzel, Marion Meyer
  • Patent number: 5340886
    Abstract: A process for preparing melt spun polymeric fiber made from polymerized amide monomers includes the steps of pigmenting the polymer, incorporating within the polymer sufficient SO.sub.3 H groups or salts thereof to give the polymer a sulphur content of between about 10 and about 160 equivalents per 10.sup.6 grams polymer and thereafter chemically blocking with a chemical blocking agent a portion of amino end groups present in the sulphonated polymer.
    Type: Grant
    Filed: June 2, 1993
    Date of Patent: August 23, 1994
    Assignee: BASF Corporation
    Inventors: Matthew B. Hoyt, Andrew M. Coons, III, David N. Dickson
  • Patent number: 5340642
    Abstract: In a sheetlike composite comprising a polyolefin matrix and natural fiber mats as reinforcement the natural fibers have a basis weight of more than 10 dtex. Sisal fibers are preferred. The composites are used in particular in automotive construction.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: August 23, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Horst Baumgartl, Alois Schlarb, Ludwig Wahl, Peter Ittemann, Karl-Ludwig Brentrup
  • Patent number: 5340208
    Abstract: A refrigerator cabinet is provided with a plastic liner, the inside wall of the refrigerator, which is resistant to chemical degradation by fluorocarbons. Freon and Freon substitutes used as blowing agents for foaming the insulation contained between an outer metal cabinet and on the inside wall of the refrigerator can cause blistering, cracking, and sometimes dissolution of materials used to form the plastic liner which is the inside wall of the refrigerator. There is provided a plastic liner which is resistant to those blowing agents and particularly to those blowing agents which are partially halogenated and tend to be more aggressive than Freon. The plastic liner wall maintains impact strength and toughness after exposure to fluorohydrocarbons conventionally employed in refrigerator units for in situ polyurethane foam production.
    Type: Grant
    Filed: June 16, 1993
    Date of Patent: August 23, 1994
    Assignee: BASF Corporation
    Inventors: Steven M. Hauck, Jeffrey P. Viola
  • Patent number: 5340859
    Abstract: An aqueous polymer dispersion with a solids volume concentration of at least 50% by volume is obtainable by polymerizing monomers by the method of free radical aqueous emulsion polymerization with the addition of at least two starting polymer dispersions, of which one contains not only particularly finely divided but also coarsely divided polymer particles.
    Type: Grant
    Filed: April 26, 1993
    Date of Patent: August 23, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Oral Aydin, Michael Portugall, Josef Neutzner, Walter Maechtle
  • Patent number: 5340858
    Abstract: Final aqueous polymer dispersions are obtainable by polymerizing radical polymerizable monomers with the addition of an aqueous dispersion of a starting polymer by the method of free radical aqueous emulsion polymerization.
    Type: Grant
    Filed: April 22, 1993
    Date of Patent: August 23, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerhard Bauer, Oral Aydin, Josef Neutzner
  • Patent number: 5340916
    Abstract: The present invention relates to a process for the preparation of a hard foam containing urethane groups or urethane and isocyanurate groups by the polyisocyanate polyaddition process, by reactinga) a polyoxypropylene- or polyoxyethylene-polyoxypropylene-polyol containing secondary hydroxyl groups, having a functionality of from 3.5 to 4.3, a hydroxyl number of from 350 to 650 and a viscosity of from 500 to 2,500 mPa.multidot.s at 23.degree. C.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: August 23, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Rolf Henn, Werner Hinz, Ludwig Schuster, Klaus Vorspohl
  • Patent number: 5338888
    Abstract: An improved process for preparing E,Z-butenedial bis(dialkyl acetals) by reacting the corresponding 2,5-dialkoxy-2,5-dihydrofurans with the corresponding lower alkanols in the presence of an acid at elevated temperature entails carrying out the reaction in the presence of approximately equimolar amounts of a trialkyl orthoformate and in the presence of catalytic amounts of a strong mineral acid or of a strong organic acid.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: August 16, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Paust, Wolfgang Krause
  • Patent number: 5338749
    Abstract: Compounds of formula I ##STR1## and compounds of formula Ia ##STR2## where the substituents are as defined in the specification.
    Type: Grant
    Filed: November 6, 1992
    Date of Patent: August 16, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Heiner Wuest, Bernd Janssen, William V. Murray, Michael P. Wachter, Stanley Bell
  • Patent number: 5338434
    Abstract: The invention relates to aqueous electrocoating paints which contain 2 to 10% by weight of an anticorrosive pigment based on zinc silicate in combination with 1 to 15% by weight of a very fine quartz powder or cristobalite powder coated with epoxysilane or aminosilane, the percentages by weight being based on the total solids content of the electrocoating paint and the anticorrosive pigment being preparable by fusing together 35 to 65% by weight of ZnO, 15 to 35% by weight of SiO.sub.2 and 0 to 20% by weight of B.sub.2 O.sub.3 and/or 0 to 20% by weight of WO.sub.3 and/or 0 to 20% by weight of MoO.sub.3 and/or 0 to 20% by weight of SnO.sub.2, the components being fused together using at least one of the cited oxides besides ZnO and SiO.sub.2 in such a manner that the percentages by weight always total 100.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: August 16, 1994
    Assignee: BASF Lacke & Farben Aktiengesellschaft
    Inventors: Dieter Ruhl, Klaus Arlt, Ulrich Heilmann, Ulrich Heimann, Udo Hoffmann
  • Patent number: 5338819
    Abstract: Solid isocyanate-terminated prepolymer powders useful in preparation of films, coatings, and one-component adhesives are prepared by reacting a low molecular weight di- or polyisocyanate with a glycol mixture in a solvent in which the isocyanate is soluble but the reaction product is not.
    Type: Grant
    Filed: November 29, 1991
    Date of Patent: August 16, 1994
    Assignee: BASF Corporation
    Inventors: Thirumurti Narayan, Anthony W. Tantillo, John R. Stoll
  • Patent number: 5338848
    Abstract: Indolizinetrimethine dyes useful for laser-optical recording media have the formula ##STR1## where the variables are defined as follows: R.sup.1 is C.sub.1 -C.sub.22 -alkyl which may be substituted by halogen, hydroxyl, C.sub.1 -C.sub.6 -alkoxy, benzyloxy, C.sub.1 -C.sub.6 -alkanoyl, C.sub.1 -C.sub.6 -alkoxycarbonyl or phenyl, C.sub.3 -C.sub.7 -cycloalkyl, which may be substituted by halogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy, or phenyl which may be substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, carboxyl, C.sub.1 -C.sub.6 -alkoxycarbonyl or hydroxysulfonyl,R.sup.2 has one of the meanings of R.sup.1, except than the carbon chain of C.sub.1 -C.sub.22 -alkyl may be interrupted by from one to five oxygen atoms in ether function,R.sup.3 is hydrogen, halogen or C.sub.1 -C.sub.6 -alkyl,Z is --O-- or --NH--, andAn.sup..crclbar. is one equivalent of an acid anion.
    Type: Grant
    Filed: July 20, 1993
    Date of Patent: August 16, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Acker, Bernhard Albert, Michael Schmitt
  • Patent number: 5338639
    Abstract: Electrostatic toners contain a polymeric binder and, as a charge stabilizer, a compound of the formula ##STR1## where Z is C.sub.1 -C.sub.20 -alkyl which is unsubstituted or substituted by phenyl or Z is C.sub.5 -C.sub.7 -cycloalkyl or unsubstituted or substituted phenyl, X and Y are each cyano or a radical of the formula --CO--OR.sup.1, --CO--NR.sup.1 R.sup.2 or --C--R.sup.3, where R.sup.2 is C.sub.1 -C.sub.20 -alkyl which is unsubstituted or substituted by phenyl or R.sup.1 is C.sub.5 -C.sub.7 -cycloalkyl, R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl and R.sup.3 is C.sub.1 -C.sub.20 -alkyl which is unsubstituted or substituted by phenyl or R.sup.3 is C.sub.5 -C.sub.7 -cycloalkyl or unsubstituted or substituted phenyl, or X and Y together form a radical of the formula --CO--L--CO-- or --CO--CH.dbd.C(CH.sub.3)--O--CO--, where L is C.sub.2 -C.sub.4 -alkylene, and cat.sup..sym. is one equivalent of a cation.
    Type: Grant
    Filed: July 20, 1993
    Date of Patent: August 16, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Gunter-Rudolf Schroeder, Udo Mayer
  • Patent number: 5338805
    Abstract: Copolymers are obtainable by (1) copolymerization of a monomer mixture of(A) from 1 to 99% by weight of at least one monomer of the general formula ICH.sub.2 .dbd.C(E)CH.sub.2 --O--CH.sub.2 C(F).dbd.CH.sub.2 Iwhere E and F are selected from the group consisting of --COOR.sup.1, --COR.sup.1, --CONR.sup.2 R.sup.3 and --CN, and R.sup.1 is H, C.sub.1 -C.sub.18 -alkyl, unsubstituted or substituted C.sub.3 -C.sub.8 -cycloalkyl or C.sub.3 -C.sub.8 -cycloalkyl- C.sub.1 -C.sub.5 -alkyl, hydroxy-C.sub.1 -C.sub.5 -alkyl, amino-C.sub.1 -C.sub.5 -alkyl, N-C.sub.1 -C.sub.4 -alkylamino-C.sub.1 -C.sub.5 -alkyl, N, N-di-C.sub.1 -C.sub.4 -alkylamino-C.sub.1 -C.sub.5 -alkyl, unsubstituted or substituted C.sub.6 -C.sub.18 -aryl or C.sub.6 -C.sub.18 -aryl-C.sub.1 -C.sub.4 -alkyl, andR.sup.2 and R.sup.3 are each H, C.sub.1 -C.sub.18 -alkyl, unsubstituted or substituted C.sub.3 -C.sub.8 -cycloalkyl or C.sub.3 -C.sub.8 -cycloalkyl-C.sub.1 -C.sub.5 -alkyl, unsubstituted or substituted C.sub.6 -C.sub.18 -aryl or C.sub.6 -C.sub.
    Type: Grant
    Filed: March 16, 1993
    Date of Patent: August 16, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Siegmund Besecke, Andreas Deckers, Harald Lauke
  • Patent number: 5338820
    Abstract: The invention relates to water blown integral skin polyurethane foams made with a particular isocyanate quasi-prepolymer and resin side ingredients to yield a foam having good overall mechanical roperties. The isocyanate quasi-prepolymer component of the present invention comprises from 0.5 weight percent to 30.0 weight percent or less uretonimine-carbodiimide-modified diphenylmethane diisocyanate, from 50 weight percent to 80 weight percent 4,4'-diphenylmethane diisocyanate and reacted with from 15 weight percent to 40 weight percent of a polyether polyol containing predominately secondary hydroxy groups and having an average molecular weight from about 2,000 to 10,000, an average functionality from 1.5 to about 3.2, and a hydroxyl number from about 20 to 60. The resin side component comprises a high molecular weight polyether polyol with an average functionality from 1.5 to about 3.2, water as a blow agent, and optionally an mono- or di-functional alcohol composition having from 8 to about 30 carbon atoms.
    Type: Grant
    Filed: February 4, 1994
    Date of Patent: August 16, 1994
    Assignee: BASF Corporation
    Inventors: Richard P. Harrison, Michael Scarpati, Thirumurti Narayan, Blair J. Zagata
  • Patent number: 5336753
    Abstract: The present invention relates to a polycondensation and/or addition product containing carboxyl groups and amino groups. This can be obtained by reactinga) polycarboxylic acids or anhydrides thereof, if appropriate together with monocarboxylic acids,b) polyols, if appropriate together with monools, and, if appropriatec) further modifying components, and, if appropriate,d) a component which is capable of reacting with the reaction product from a), b) and, if appropriate, c), with the proviso that the final product contains tertiary amino groups which originate from components a) and/or b) and/or d), and the reaction product from a), b), if appropriate c) and if appropriate d) has an acid number from 5 to 200, preferably 10 to 130, and an amine number from 3 to 150, preferably 10 to 100.
    Type: Grant
    Filed: January 8, 1993
    Date of Patent: August 9, 1994
    Assignee: BASF Lacke + Farben AG
    Inventors: Werner A. Jung, Udo Vorbeck, Arno Schmitz, Wilhelm Heise, Lutz-Werner Gross
  • Patent number: 5336566
    Abstract: Compounds are described having the formula: ##STR1## Z represents a cyanuric ring nucleus or the residue of a polyol, L.sub.1, L.sub.2, and L.sub.3 each independently represents a divalent linking group or a covalent bond, andR.sub.1, R.sub.2, and R.sub.3 each independently represents H, alkyl, cycloalkyl, or aryl.These compounds are useful as crosslinking agents for curable compositions such as coating compositions.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: August 9, 1994
    Assignee: BASF Corporation
    Inventor: John W. Rehfuss