Patents Assigned to BASF
  • Patent number: 5324843
    Abstract: 3-(3,4,5,6-tetrahydrophthalimido)cinnamic esters I ##STR1## (R.sup.1 =H, halogen; R.sup.2, R.sup.3 =halogen; R.sup.4 =C-organic radical, R.sup.5 =H, CH.sub.3) are prepared by reducing 3-nitrocinnamic esters II ##STR2## with hydrogen in the presence of a catalyst and condensing the resulting 3-aminocinnamic esters III ##STR3## with a 3,4,5,6-tetrahydrophthalic anhydride IV ##STR4## and are valuable active ingredients in crop protection.
    Type: Grant
    Filed: April 29, 1993
    Date of Patent: June 28, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Lothar Rueb, Karl Eicken, Bernd Schaefer, Gernot Reissenweber, Peter Schaefer
  • Patent number: 5324404
    Abstract: In order to increase the stone chip resistance of automobile finishes aqueous electrocoating paints are used which are produced by the use of a pigment paste which contains as grinding resin an at least partially protonated epoxide-amine adduct which is obtainable by reacting(A) a glycidyl ether of a polyphenol which contains on statistical average at least one epoxide group in the molecule, or a mixture of such glycidyl ethers,(B) a polyglycidyl ether of a polyol which contains on statistical average more than 1.0 epoxide groups in the molecule, or a mixture of such polyglycidyl ethers, and(C) a compound which contains a primary amino group in the molecule or a mixture of such compoundswith each other in such a stoichiometric ratio that an epoxide-amine adduct is obtained in which on statistical average at least 2.
    Type: Grant
    Filed: July 28, 1992
    Date of Patent: June 28, 1994
    Assignee: BASF Lacke + Farben Aktiengesellschaft
    Inventors: Gunther Ott, Ulrich Heimann, Udo Reiter, David J. Santure, Thomas Brucken, Walter Jouck
  • Patent number: 5324754
    Abstract: The invention pertains to polyol compositions containing a lithium salt of an aliphatic or cycloaliphatic, saturated or unsaturated carboxylic acid having 2 to 7 carbon atoms and to flexible polyurethane foams having an open cell structure produced thereby.
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: June 28, 1994
    Assignee: BASF Corporation
    Inventors: Valeri L. Valoppi, Donald L. Christman
  • Patent number: 5324697
    Abstract: A novel Phillips catalyst for the homopolymerization of ethylene and the copolymerization of ethylene with .alpha.-olefins contains as catalytically active components a specific chromium catalyst on an aluminum phosphate support and cocatalysts of the formula I to IV, ##STR1## where M is lithium, sodium and potassium,M.sup.1 is magnesium and zinc,M.sup.2 is boron and aluminum,R is C.sub.1 -C.sub.10 -alkyl and C.sub.6 -C.sub.20 -aryl,R.sup.1 is R and C.sub.1 -C.sub.10 -alkoxy and C.sub.6 -C.sub.20 -aryloxy,X is chlorine, bromine and iodine,n is 0, 1 and 2The chromium catalyst on an aluminum phosphate support can be obtained by applying chromium compounds to a finely divided aluminum phosphate with a P:A1 molar ratio near to or equal to 1 and a pore volume of >1 cm.sup.3 /g and activating the resulting intermediate at elevated temperatures in an oxidizing atmosphere. The novel Phillips catalyst has an exceptionally long duration of activity and its productivity can be increased further by adding hydrogen.
    Type: Grant
    Filed: June 26, 1992
    Date of Patent: June 28, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Joachim Mueller, Rainer Konrad, Guenther Schweier, Siegfried Weber, Roland Saive, Peter Koelle
  • Patent number: 5324354
    Abstract: Pigment formulations contain a) a finely divided pigment, b) at least one colorant which has at least one external basic group, c) at least one acidic and/or neutral phosphoric ester and d) if required, further assistants conventionally used in such formulations. The formulations are used for pigmenting printing inks and lakes.The printing inks, pastes and lakes produced using the formulations have substantially better flow behavior than the inks and lakes obtained using prior art pigments.
    Type: Grant
    Filed: August 5, 1991
    Date of Patent: June 28, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Jesse, Juan A. Gonzalez Gomez, Gustav Bock, Paul Guenthert
  • Patent number: 5324493
    Abstract: Aluminophosphates and silicoaluminophosphates having the AEL structure are prepared under hydrothermal crystallization conditions by a process in which 1,2-bis-( 4-pyridyl)-ethane is used for the crystallization.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: June 28, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulrich Mueller, Wolfgang Hoelderich, Guenter Lauth
  • Patent number: 5322897
    Abstract: The invention relates to copolymers containing hydroxyl groups having a hydroxyl value of 50 to 200 mg of KOH/g and an average molecular weight (number average) of 1500 to 6000, which can be prepared by free-radical solution polymerization at temperatures of 130.degree. to 200.degree. C. of 5 to 25% by weight of vinyl ester monomers, 10 to 50% by weight of vinylaromatic monomers, 10 to 50% by weight of hydroxyalkyl ester monomers and, if desired, other monomers, in which the vinyl ester is initially used and the remaining monomers are added over a monomer addition period which is the same for all monomers as follows:i) The amount of the acrylate monomer added per unit time remains constant.
    Type: Grant
    Filed: December 19, 1990
    Date of Patent: June 21, 1994
    Assignees: BASF Lacke, Farben Aktiengesellschaft
    Inventors: Werner A. Jung, Udo Vorbeck
  • Patent number: 5322883
    Abstract: Disclosed is a thermoplastic polyester with reduced flammability obtained by:(a) condensating an aromatic dicarboxylic acid and an alkylene glycol in a mole ratio of from 1:1.1-1.5 at a temperature of from 180.degree. to 240.degree. C. in the presence of a catalyst;(b) adding a polyalkylene glycol phosphate ester;(c) polycondensating at a temperature of from 265.degree. to 280.degree. C. under a pressure decreasing from 760 torr to less than 2 torr until an intrinsic viscosity of about 0.5 to about 0.7 is reached.
    Type: Grant
    Filed: September 24, 1992
    Date of Patent: June 21, 1994
    Assignee: BASF Corporation
    Inventors: Atish Adyha, Thomas F. Corbin, Robert L. Lilly
  • Patent number: 5322915
    Abstract: A condensation polymer, obtainable by condensation of a mixture containing, as chief components,(A) from 90 to 99.9% molar of a mixture substantially consisting of(a) from 30 to 99% molar of melamine and(b) from 1 to 70% molar of a substituted melamine of the general formula I ##STR1## in which X, X', and X" are selected from the group consisting of --NH.sub.2, --NHR, and --NRR', and only one or two of X, X', and X" denote(s) --NH.sub.2, and R and R' are selected from the group consisting of hydroxy-C.sub.2 -C.sub.10 -alkyl, hydroxy-C.sub.2 -C.sub.4 -alkyl-(oxa-C.sub.2 -C.sub.4 -alkyl).sub.n, where n is an integer from 1 to 5, and amino-C.sub.2 -C.sub.12 -alkyl, or mixtures of melamines I, and(B) from 0.1 to 10% molar, based on (A) and (B), of unsubstituted phenols or phenols substituted by radicals selected from the group consisting of C.sub.1 -C.sub.9 -alkyl and hydroxy, or of C.sub.1 -C.sub.
    Type: Grant
    Filed: July 8, 1992
    Date of Patent: June 21, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Weiser, Wolfgang Reuther, Rolf Fikentscher, Wolfgang Fath, Heinz Berbner, Hans D. Zettler, Heinz Voelker
  • Patent number: 5322863
    Abstract: The invention relates to a coating compound which comprises a binder solution containinga) 30 to 70% by weight of a binder,b) 2 to 30% by weight of a crosslinking agent,c) if appropriate, 1 to 7% by weight of neutralization agent,d) 20 to 60% by weight of solvent.
    Type: Grant
    Filed: August 7, 1992
    Date of Patent: June 21, 1994
    Assignee: BASF Lacke + Farben Aktiengesellschaft
    Inventors: Hans-Jurgen Figge, Holger Dartmann
  • Patent number: 5322715
    Abstract: A process utilizing a pigmented aqueous basecoat composition which contains as the film-forming material a water-thinnable emulsion polymer. The water-thinnable emulsion polymer is prepared in a two-stage emulsion polymerization. In the first stage a polymer is prepared having a glass transition temperature (T.sub.G1) of +30.degree. to +110.degree. C. In the second stage a mixture of monomers is polymerized in the presence of the polymer prepared in the first stage, which mixture, polymerized on its own, would give a polymer with a glass transition temperature (T.sub.G2) of -60.degree. to +20.degree. C. The hydroxyl value of the emulsion polymer is between 2 and 100.
    Type: Grant
    Filed: July 28, 1992
    Date of Patent: June 21, 1994
    Assignee: BASF Lacke+Farber Aktiengesellschaft
    Inventors: Walter Jouck, Bernd Mayer, Stefan C. Wieditz
  • Patent number: 5322560
    Abstract: The invention is a slightly water-soluble, time release corrosion inhibitor compound for treating aluminum flake pigment. The corrosion inhibitor is the reaction product of a water-soluble metal salt including metals selected from the group consisting of yttrium and rare earth metals and an anionic metal salt including transition metal oxo-complexes and soluble salts of silicon and mixtures thereof. The corrosion inhibitor is useful for preventing hydrogen gassing of aluminum pigment particles. The compound is particularly useful for preventing gassing of bare and chromated aluminum pigment particles in aqueous compositions and in water-borne coating compositions having a basic pH. The pigment particles used in combination with the corrosion inhibitors of the present invention experience significantly less hydrogen gassing in a high pH aqueous environment and in water-borne coating compositions having high pH, than aluminum flake pigment particles and coatings without the corrosion inhibitor.
    Type: Grant
    Filed: August 31, 1993
    Date of Patent: June 21, 1994
    Assignee: BASF Corporation
    Inventors: Jeffrey S. DePue, Clint W. Carpenter, Lynne G. Bemer
  • Patent number: 5320771
    Abstract: The present invention provides an antifreeze/coolant additive comprising polymeric polycarboxylates which reduces the corrosion rate of heat rejecting aluminum, and is effective at relatively low concentrations.
    Type: Grant
    Filed: July 23, 1991
    Date of Patent: June 14, 1994
    Assignee: BASF Corp.
    Inventors: David E. Turcotte, John J. Conville, James T. Lyon, Stanley T. Hirozawa, Shrikant V. DeSai
  • Patent number: 5321189
    Abstract: A process for propene oligomerization catalyzed by transition metal complexes in liquid phase to give propene oligomers with a high content of terminal double bonds, comprises oligomerizing propene in the presence of a catalyst of the formula ICp.sub.2 MX.sub.2 Iwhere Cp is an unsubstituted cyclopentadienyl unit and/or a mono-C.sub.1 -C.sub.4 -alkylcyclopentadienyl unit, M is zirconium or hafnium and the ligands X are each hydride and/or halide and/or methyl, and in the presence of an aluminoxane cocatalyst, and where the ratio of the amounts of the catalyst I and the aluminoxane cocatalyst is such that the M/Al atomic ratio is from 1:250 to 1:1000, employing a temperature of from 50.degree. to 110.degree. C. and a pressure of from 30 to 100 bar.
    Type: Grant
    Filed: February 25, 1993
    Date of Patent: June 14, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Joachim Mueller, Bernd L. Marczinke, Juergen Kerth, Rainer Konrad, Guenther Schweier, Max Strohmeyer, Bernhard Rieger
  • Patent number: 5320647
    Abstract: Fluent dye preparations useful for dyeing leather or wool containa) at least 15% of the weight of the dye preparation of one or more polyazo dyes in salt form which have one or more hydroxysulfonyl and/or carboxyl groups and may be present in the form of a 1:1 or 1:2 metal complex,b) from 2 to 15% of the weight of the dye preparation of a surfactant, andc) water.
    Type: Grant
    Filed: August 14, 1992
    Date of Patent: June 14, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Georg Henning, Georg Zeidler, Ortwin Schaffer
  • Patent number: 5320673
    Abstract: A compound is described that is useful as a dispersant for inorganic pigments and metallic flake pigments in waterborne coatings. The compound comprises a polymeric backbone having a pigment-interactive substituent and a stabilizing substituent.The pigment-interactive substituent has at least one functionality selected from the group consisting of ##STR1## wherein A.sub.1, A.sub.2, A.sub.3, and A.sub.4 are as defined herein. The stabilizing substituent includes the structure ##STR2## wherein D.sub.1, D.sub.2, R.sub.1, R.sub.2, R.sub.3, m, and n are as defined herein.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: June 14, 1994
    Assignee: BASF Lacke+Farben Aktiengesellschaft
    Inventor: Clint W. Carpenter
  • Patent number: 5321093
    Abstract: A process for preparing bifunctional living polymers which are able to forth bifunctional telechelic polymers or block copolymers with at least 3 blocks of conjugated dienes and/or vinylaromatics with molecular weights of from 1,500 to 500,000, by bifunctional initiators whose anionic centers are aliphatic carbon atoms which are substituted by lithium and an aliphatic hydrocarbon radical as well as by either 2 aryl radicals or by one aryl radical and one hydrogen radical, where one of the aryl radicals can also be part of the two anionic centers, in a first stage being reacted in the presence of not more than 2.5 moles of an aliphatic ether or a tertiary amine per mole of lithium and not less than 2 mol/l of a conjugated diene at from -40.degree. to +35.degree. C. with not less than two moles of diene, resulting in the formation of low molecular weight diene oligomers which in turn act as bifunctional initiators, and using the latter in a second reaction stage in a conventional manner at above 40.degree. C.
    Type: Grant
    Filed: September 24, 1991
    Date of Patent: June 14, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Bronstert, Konrad Knoll, Erich Haedicke
  • Patent number: 5320833
    Abstract: Arylpolyenecarboxylic acids and their derivatives of the formula I ##STR1## where Ar is phenyl, biphenylyl or naphthyl, each of which can be substituted by one to three C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, hydroxyl or phenoxy groups, or amino groups which can be mono- or di-substituted by C.sub.1 -C.sub.4 -alkyl groups, or one methylenedioxy group, it being possible for the substituents to be identical or different,R.sup.1 is hydrogen, an alkali metal or ammonium cation, C.sub.1 -C.sub.20 -alkyl or C.sub.2 -C.sub.20 -alkenyl,R.sup.2 is C.sub.1 -C.sub.8 -alkyl,R.sup.3 to R.sup.7 are each hydrogen or C.sub.1 -C.sub.4 -alkyl, andn is 0 or 1are used as sunscreen agents in cosmetic preparations.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: June 14, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Gabriele Deckers, Rainer Becker, Bernd Wenderoth, Norbert Goetz, Karin Sperling-Vietmeier
  • Patent number: 5319044
    Abstract: A branched polymer containing silyl groups, a process for the preparation thereof, coating agents based on the polymer, and the use thereof.The invention relates to polymers containing silyl groups, the silyl groups being introduced into the polymer through ethylenically unsaturated monomers of the general formula ##STR1## wherein R.sup.1 =alkyl, aryl, acyl or aralkyl having 1 to 10 carbon atoms,R.sup.2 =an organic radical having a polymerizable double bond,X=a hydrolyzable group, andn=1, 2 or 3.The polymers can be obtained by copolymerization ofa) 0.1 to 40% by weight of the silane monomers (a),b) 5 to 30% by weight, preferably 8 to 25% by weight, of monomers containing at least 2 polymerizable, ethylenically unsaturated double bonds, andc) 30 to 90% by weight of ethylenically unsaturated monomers without groups containing active hydrogen.The invention also relates to moisture-hardening coating agents based on the polymers containing silyl groups.
    Type: Grant
    Filed: March 13, 1992
    Date of Patent: June 7, 1994
    Assignee: BASF Lacke + Farben AG
    Inventors: Werner A. Jung, Arno Schmitz
  • Patent number: D348262
    Type: Grant
    Filed: July 10, 1991
    Date of Patent: June 28, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Schoettle, Joachim Eberhard, Kurt Schmidts, Bozidar Pavelka