Patents Assigned to BASF
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Patent number: 5276256Abstract: A molding composition containing, based on the total weight of the composition:A) at least 40% by weight of at least one halogen-free polycarbonate;B) 5-40% by weight of at least one halogen-free graft copolymer composed of;1) 40-80% by weight of an elastomer with a glass transition temperature below 0.degree. C., which elastomer is composed of, at least 50% by weight of a diene or of an at least C.sub.4 -alkyl acrylate, 1-40% by weight of a halogen-free phosphorus compound of the formula ##STR1## 2) 20-60% by weight of a shell composed of, 40-98% by weight of styrene, .alpha.-alkylstyrene, nuclear-substituted styrene and/or C.sub.1 -C.sub.8 -alkyl (meth)acrylate, and 2-60% by weight of (meth)acrylonitrile and/or maleic anhydride;C) 5-40% by weight of a halogen-free thermoplastic copolymer composed of, 50-95% by weight of styrene, .alpha.-alkylstyrene, nuclear-substituted styrene and/or C.sub.1 -C.sub.Type: GrantFiled: September 25, 1992Date of Patent: January 4, 1994Assignee: BASF AktiengesellschaftInventors: Norbert Niessner, Rainer Neumann, Karl Ruppmich, Friedrich Seitz, Doris Zeltner
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Patent number: 5276009Abstract: Dicarboximides of the general formulae Ia and Ib ##STR1## where X is oxygen or sulfur, R.sup.1 is hydrogen, cycloalkyl, alkyl, hydroxyl, alkoxy, cyanoalkyl, alkenyl, alkynyl, phenyl, naphthyl or a 5-membered or 6-membered heterocyclic structure, where the stated radicals may be substituted, andR.sup.2 and R.sup.3 are each nitro, cyano, halogen, amino, mono- or dialkylamino, alkylcarbonylamino, unsubstituted or halogen-substituted alkoxy or alkylthio, alkylsulfonyl, haloalkylsulfonyl, alkenyl, alkynyl, phenyl, phenoxy or phenylthio or one of the radicals R.sup.1, with the proviso that specific compounds named in the description are excluded.Processes for the preparation of the compounds Ia and Ib and herbicides containing them.Type: GrantFiled: July 19, 1991Date of Patent: January 4, 1994Assignee: BASF AktiengesellschaftInventors: Peter Muenster, Wolfgang Freund, Gerd Steiner, Helmut Walter, Karl-Otto Westphalen, Matthias Gerber
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Patent number: 5276148Abstract: Reactive dyes of the formula ##STR1## where n is 0 or 1,R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl,A is unsubstituted or substituted C.sub.2 -C.sub.8 -alkylene,Y is vinyl or a radical of the formula --CH.sub.2 --CH.sub.2 --Q, whereQ is a group which can be eliminated under alkaline reaction conditions,D.sup.1 is phenyl or naphthyl, where these radicals may be substituted,D.sup.2 is phenylene or naphthylene, where these radicals may be substituted, andZ is a reactive radical,with the proviso thata) n is zero when D.sup.1 is substituted by unsubstituted or substituted phenylazo or by unsubstituted or substituted naphthylazo andb) the reactive radical Z is not devised from the triazine series when n is zero and D.sup.1 is dihydroxysulfonylphenyl or trihydroxysulfonylnaphthyl,are used for dyeing and printing organic substrates containing hydroxyl groups or nitrogen atoms.Type: GrantFiled: May 22, 1992Date of Patent: January 4, 1994Assignee: BASF AktiengesellschaftInventors: Bernd Siegel, Manfred Patsch
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Patent number: 5276097Abstract: The present invention relates to coating agents containingA) one or more polymers containing carboxyl groups and having a number-average molecular weight of 500 to 8,000 and an acid number of 15 to 200 mg of KOH/g as the essential binder component andB) one or more compounds containing epoxide groups as crosslinking agents,wherein the compound B containing epoxide groups is a copolymer containing epoxide groups, has a number-average molecular weight M.sub.n of 300 to 5,000, preferably 500 to 3,500, and a heterogeneity (M.sub.w /M.sub.n), measured by gel permeation chromatography, of .ltoreq.3, preferably of .ltoreq.2, and has been prepared by continuous bulk polymerization at temperatures between 130.degree. and 350.degree. C. and pressures above 1 bar.The invention also relates to processes for the preparation of the coating agent and the use of the coating agents in automobile refinishing.Type: GrantFiled: January 24, 1992Date of Patent: January 4, 1994Assignees: BASF Lacke, Farben AktiengesellschaftInventors: Peter Hoffmann, Werner Alfons Jung, Elisabeth Kappes, Manfred Niessner
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Patent number: 5276165Abstract: A process for the preparation of N-substituted lactams of the formula I ##STR1## where Z is C.sub.2 - to C.sub.10 -alkylene, C.sub.7 - to C.sub.12 -aralkylene, phenylene or naphthylene, andR.sup.1 is C.sub.1 - to C.sub.20 -alkyl, C.sub.6 - to C.sub.10 -aryl or C.sub.7 - to C.sub.12 -aralkyl,by hydrogenating a compound of the formula II ##STR2## where W is C.sub.2 - to C.sub.10 -alkylene, C.sub.2 - to C.sub.10 -alkenylene, C.sub.7 - to C.sub.12 -aralkylene, phenylene or naphthylene, andX and Y together form an oxa or imido bridge of the formula ##STR3## or alternatively are identical or different and are hydroxyl, C.sub.1 - to C.sub.20 -alkoxy, C.sub.6 - to C.sub.10 -aryloxy or C.sub.7 - to C.sub.12 -aralkoxy, and, if X and Y are different, Y, in addition to the abovementioned meanings, may also be hydrogen,at superatmospheric pressure and at elevated temperature in the presence of a catalyst and in the presence of an amine, which comprises using a secondary and/or tertiary amine of the formula IIINH.sub.n R.Type: GrantFiled: November 25, 1992Date of Patent: January 4, 1994Assignee: BASF AktiengesellschaftInventors: Hans-Juergen Weyer, Rolf Fischer
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Patent number: 5276069Abstract: Synthetic resins are obtainable by chemically bonding one or more compounds of the general formula I ##STR1## where R.sup.1 is --OH, --NH.sub.2, ##STR2## --NHR.sup.3 or ##STR3## R.sup.2 is --H, --CH.sub.3 or --C.sub.2 H.sub.5, R.sup.3 is --C.sub.m H.sub.2m+1, where m is from 1 to 6, R.sup.4 is --H or --CH.sub.3 and n is from 1 to 12, via the oxygen or nitrogen atom of R.sup.1 to one or more polymers A which consist ofa) from 50 to 100% by weight of one or more esters of acrylic or methacrylic acid with monohydric alcohols of 1 to 18 carbon atoms or a mixture of these esters (monomers a) andb) from 0 to 50% by weight of other copolymerizable monomers (monomers b) in polymerized form,in amounts such that the synthetic resin contains from 0.01 to 1 mole of double bonds per kg of polymer A.After exposure to ultraviolet light or to electrons, these synthetic resins are suitable as contact adhesives.Type: GrantFiled: May 3, 1991Date of Patent: January 4, 1994Assignee: BASF AktiengesellschaftInventors: Gerd Rehmer, Gerhard Auchter, Helmut Jaeger
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Patent number: 5276130Abstract: According to the present invention, a .beta.-dicarbonyl functionality, an .alpha.,.beta.-unsaturation functionality, or a vinylogous amide functionality is incorporated into an aminoplast resin or an aminoplast resin precursor.Type: GrantFiled: October 30, 1991Date of Patent: January 4, 1994Assignee: BASF CorporationInventors: Christopher J. Bradford, Adriana E. Ticu, Richard E. De Schepper
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Patent number: 5276160Abstract: Abstract of the Disclosure: 3-Carbamoylisoxazole-4-carboxylic esters of the formula I ##STR1## where R.sup.1 is hydrogen, alkyl, cycloalkyl, phenyl or a 5- to 6-membered heterocyclic radical, it being possible for the organic radicals to carry substituents which are inert under the reaction conditions;R.sup.2 is alkyl, cycloalkyl, benzyl or C.sub.1 -C.sub.3 -alkenyl;R.sup.3 is hydrogen, alkyl or cycloalkyl andR.sup.4 is an aliphatic or cycloaliphatic radical or unsubstituted or substituted phenyl, or R.sup.4 together with R.sup.3 is a 4- to 7-membered alkylene chain which can be interrupted by oxygen, sulfur or N-methyl, are prepared by selective amidation of an isoxazole-3,4-dicarboxylic diester of the formula II ##STR2## where R.sup.2 has the meanings of R.sup.2 and is identical to or different from R.sup.2.Type: GrantFiled: March 23, 1993Date of Patent: January 4, 1994Assignee: BASF AktiengesellschaftInventors: Volker Maywald, Thomas Kuekenhoehner, Gerhard Hamprecht
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Patent number: 5276007Abstract: Substituted sulfonylureas of the general formula I ##STR1## where n and m are each 0 or 1, andR.sup.1 is hydrogen, alkyl, alkenyl or alkynyl;R.sup.2 is halogen or trifluoromethyl when m is 0, or, when m is 1, alkyl, alkenyl or alkynyl and, when X is 0 or S and m is 1, is trifluoromethyl or chlorodifluoromethyl;X is 0, S or N--R.sup.4, where R.sup.4 is hydrogen or alkyl;R.sup.3 is hydrogen, halogen, alkyl, haloalkyl or alkoxy;A is haloalkyl, halogen or ##STR2## where Z is oxygen or alkylimino N--R.sup.6 ;R.sup.5 is hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, alkenyl or alkynyl;R.sup.6 is hydrogen, alkyl, or together with R.sup.5 is a C.sub.4 -C.sub.6 -alkylene chain, where one methylene may be replaced by an oxygen atom or a C.sub.1 -C.sub.4 -alkylimino group, andR.sup.7 is hydrogen or halogen,and environmentally tolerated salts thereof, processes and intermediates for the manufacture of compounds I, and their use as herbicides and bioregulators.Type: GrantFiled: February 19, 1991Date of Patent: January 4, 1994Assignee: BASF AktiengesellschaftInventors: Gerhard Hamprecht, Horst Mayer, Karl-Otto Westphalen, Bruno Wuerzer, Matthias Gerber, Klaus Grossmann, Wilhelm Rademacher
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Patent number: 5274011Abstract: Cationic resins are obtainable by reaction ofA) a carboxyl-containing copolymer containing as comonomersa) 35-100 mol % of butadiene,b) 0-45 mol % of acrylonitrile, andc) 0-20 mol % of further comonomers, which has an average molecular weight of 500-50,000 and carries on average from 1.5 to 4 carboxyl groups per molecule, andB) a condensation product ofd) a polybasic aliphatic C.sub.10 -C.sub.100 -carboxylic acid, ande) an amine which is polyfunctional in respect of primary and secondary amino groups,the amount of e) having been determined in such a way that, arithmetically, there are from 1.05 to 4 amino groups for every carboxyl group of d),with the proviso that the amount of B) is chosen in such a way that there are from 1.05 to 4 mol of amino groups per mole of the carboxyl groups present in A).Type: GrantFiled: October 22, 1992Date of Patent: December 28, 1993Assignee: BASF Lacke+Farben AktiengesellschaftInventors: Dieter Faul, Gerhard Hoffmann, Klaus Huemke, Ulrich Heimann
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Patent number: 5274164Abstract: A process for the preparation of aromatic aryl chloroformates of the general formula I ##STR1## in which Ar denotes an aryl radical optionally mono- to penta-substituted by C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.3 -C.sub.8 -alkyl-cycloalkyl, C.sub.1 -C.sub.20 -haloalkyl, C.sub.1 -C.sub.20 -alkoxy, C.sub.1 -C.sub.20 -alkylthio, halo, cyano, C.sub.2 -C.sub.20 -alkylcarbonyloxy, C.sub.3 -C.sub.20 -carboalkoxy, formyl, C.sub.2 -C.sub.20 -dialkylamino, aryl, aryloxy, arylthio, aroyl, C.sub.7 -C.sub.20 -aralkyl, C.sub.7 -C.sub.20 -aralkoxy, arylsulfonyl and/or C.sub.7 -C.sub.20 -aralkylthio and/or optionally mono- or di-substituted by chloroformyl and/or nitro, from phosgene and phenols of the general formula IIAr--OH (II),in which Ar has the meanings stated above and optionally carries one or two hydroxy groups, wherein the reaction is carried out at a temperature of from 60.degree. to 180.degree. C.Type: GrantFiled: November 13, 1992Date of Patent: December 28, 1993Assignee: BASF AktiengesellschaftInventors: Thomas Wettling, Jochem Henkelmann, Irene Troetsch-Schaller, Hermann Koehler
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Patent number: 5273676Abstract: Copolymers useful in amounts of from 0.1 to 15% by weight as grayness inhibiting and primary detergency boosting additives in pulverulent liquid detergents have K values of from 10 to 80 (determined by Fikentscher in dimethylformamide at 25.degree. C. with a polymer concentration of 2% by weight) and are obtainable by copolymerizing monomer mixtures of(a) from 10 to 60% by weight of water-soluble monomers obtainable from (A) water-soluble polyalkylene glycols or (B) water-soluble alkoxylated C.sub.1 -C.sub.25 -alcohols, for example by esterification with C.sub.3 -C.sub.6 -carboxylic acids, by vinylation with acetylene or by allylation with alkenyl ethers, or by reaction with ammonia to give the corresponding end group aminated compounds (A) or (B) and by reaction with monoethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids to form the amides, and(b) from 40 to 90% by weight of vinyl esters of saturated monocarboxylic acids and/or alkyl esters of monoethylenically unsaturated C.sub.3 -C.sub.Type: GrantFiled: October 24, 1991Date of Patent: December 28, 1993Assignee: BASF AktiengesellschaftInventors: Dieter Boeckh, Hans-Peter Seelmann-Eggebert, Heinrich Hartmann, Alexander Kud, Wolfgang Trieselt
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Patent number: 5273577Abstract: An essentially monoclinic bismuth vanadate of the formula Bi[V.sub.1-x P.sub.x)O.sub.4 ] where x is from 0 to 0.1 has a chroma of .gtoreq.85, a lightness of .gtoreq.80, a hue angle of from 89 to 95 and a photochromism with a .DELTA.E value of .ltoreq.2 under the CIELAB system.Type: GrantFiled: December 30, 1992Date of Patent: December 28, 1993Assignee: BASF AktiengesellschaftInventors: Egon Liedek, Helmut Knittel, Hans-Ulrich Reisacher, Norbert Mronga, Harald Ochmann, Henning Wienand
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Patent number: 5271885Abstract: A method of producing inside linings with a skin of polyurethane material and a polyurethane support reinforced with fiberglass pour-behind foamed together in a mold. The method operates in such a fashion that the support is first produced separately from a fiberglass mat, cut to size with exact contours and dimensions relative to the finished inside lining, and saturated with polyurethane material to form a support with a protruding edge section consisting only of the polyurethane material. The polyurethane skin is inserted into a lower mold with an edge that protrudes in the separation plane of the lower mold. The separately produced polyurethane support is then inserted into the upper mold with the edge section, made only of polyurethane material, lying in the separation plane. The support and the skin are pour-behind foamed by filling the polyurethane material into the open mold.Type: GrantFiled: March 3, 1992Date of Patent: December 21, 1993Assignee: BASF AktiengesellschaftInventors: Ernst Denker, Gerhard Reisinger
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Patent number: 5272187Abstract: A water-dilutable coating comprising a binder obtained from an epoxide resin-modified polyester possessing free carboxyl groups prepared from the reaction of:A) a polyester polymerized from:a.sub.1) a polycarboxylic acid containing at least three carboxyl groups and/ora.sub.2) a polyol containing at least one carboxyl group anda.sub.3) a polycarboxylic acid containing two carboxyl groups anda.sub.4) a polyol, wherein the polyester contains (cyclo)aliphatic elements having at least six carbon atoms;B) from 0.3-1.5 equivalents per polyester molecule of a bisphenol epoxide resin or a reaction product thereof containing at least one epoxide group per molecule with a carboxylic acid; andC) a crosslinking agent.Type: GrantFiled: October 21, 1992Date of Patent: December 21, 1993Assignee: BASF Lacke & Farben AGInventors: Lutz-Werner Gross, Ulrich Poth, Dieter Hille, Klaus Weidemeier
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Patent number: 5270352Abstract: Compounds useful for improving the dispersibility of micaceous particulates in aqueous-based coating compositions comprise urethanes or ureas which are the reaction products of silylalkyl or silylaryl isocyanates with alcohols, amines, polyether alcohols or amine-terminated polyethers. The compounds may also be the reaction products of silylalkyl- or silylarylamines with half-blocked diisocyanates which are themselves the reaction products of a diisocyanate with an alcohol, amine, polyether alcohol or amine-terminated polyether.Micaceous particulates which have been surface modified by reaction with these compounds, as well as coating compositions comprising such surface-modified micaceous particulates, and coated substrates are also disclosed.Type: GrantFiled: November 15, 1991Date of Patent: December 14, 1993Assignee: BASF CorporationInventors: Clint W. Carpenter, Thomas G. Savino, Alan L. Steinmetz
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Patent number: 5270399Abstract: The present invention is directed to a pigment dispersant for use in coating compositions. The dispersant is the reaction product of a functionalized copolymer, a polyalkylene glycol monalkyl compound to impart water soluble character to the copolymer, and a urea-containing pigment interactive substituent that enhances pigment dispersion in solution.Type: GrantFiled: September 22, 1992Date of Patent: December 14, 1993Assignee: BASF CorporationInventors: Zenon P. Czornij, Thomas G. Savino
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Patent number: 5270325Abstract: p-hydroxy phenone derivatives of the formula I ##STR1## where X is ##STR2## where R.sup.1 =F, Cl, Br or trifluoromethyl or a heteroaryl of the structure ##STR3## with R.sup.2 =C.sub.1 -C.sub.4 -alkyl,Y is a bridging member of the formula --CH.dbd.CH--, --CH.sub.2 CH.sub.2 -- or --CH.sub.2 --,n is one of the numbers 2, 3 or 4 andZ is an amino group of the formula --NR.sup.2 R.sup.3 or N-pyrrolidyl or N-piperidyl, where R.sup.2 and R.sup.3 are, independently of one another, C.sub.1 -C.sub.4 -alkyl, as well as the physiologically tolerated salts thereof, are used for preparing drugs.Type: GrantFiled: April 19, 1993Date of Patent: December 14, 1993Assignee: BASF AktiengesellschaftInventors: Wilfried Lubisch, Gerda von Philipsborn
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Patent number: 5270376Abstract: A process is provided for the preparation of an aqueous polymer dispersion which entails incorporating one or more divalent metals of magnesium, calcium or zinc in the form of an oxide, hydroxide, carbonate or bicarbonate, or in the form of a mixture of these basic salts into an aqueous starting dispersion containing a polymer A as the dispersed phase, an effective amount of an emulsifier and water as the remainder, at a temperature below the boiling point of pure water and above the glass transition point of the polymer A, wherein polymer A consists essentially of monomers, a) which are one or more .alpha., .beta.-monoethylenically unstaturated mono- or di-carboxylic acids containing from 3 to 5 carbon atoms, an anhydride o these acids or a mixture thereof; and monomers b) being one or more other copolymerizable monomers.Type: GrantFiled: August 17, 1992Date of Patent: December 14, 1993Assignee: BASF AktiengesellschaftInventors: Franz Matejcek, Maximilian Angel, Rudolf Schuhmacher
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Patent number: 5270383Abstract: Aqueous polyurethane dispersions are prepared by reacting (a) dihydroxy compounds having a molecular weight of from 500 to 5,000, (b) diisocyanates and, if required, (c) chain extenders having at least two hydrogen atoms which are reactive toward isocyanate groups and a molecular weight of less than 300 in the melt or in the presence of a water-miscible, inert organic solvent (S) which boils below 100.degree. C. to give a prepolymer having terminal isocyanate groups, then reacting the prepolymer with (d) salts of aliphatic aminocarboxylic or aminosulfonic acids or tertiary ammonium salts and dispersing the resulting polyurethane in water, by a process in which, before the polyurethane obtained is dispersed in water, from 5 to 60 parts by weight, based on 100 parts by weight of the polyurethane, of a polymer (p) [sic]which is dissolved in a solvent (S') boiling below 100.degree. C.Type: GrantFiled: December 14, 1992Date of Patent: December 14, 1993Assignee: BASF AktiengesellschaftInventors: Herbert Fisch, Lothar Maempel