Abstract: Hydroquinone diethers of the formula I ##STR1## where A.sup.1 and A.sup.2 are substituted or unsubstituted alkylene;R.sup.1 is hydrogen, halogen or alkyl;R.sup.2 is substituted or unsubstituted pyrazolyl or pyridyl;X is a substituted or unsubstituted 5-membered heteroaromatic radical, are prepared as described using the described intermediates, and are used as pesticides.
Type:
Grant
Filed:
October 8, 1991
Date of Patent:
June 22, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Christoph Nuebling, Hans Theobald, Wolfgang Krieg, Uwe Kardorff, Christoph Kuenast
Abstract: Organic sulfonic acids are liberated from aqueous solutions of their salts by a process in which the aqueous organosulfonate solution is subjected to electrodialysis with the aid of an electrodialysis cell which consists of diluate chambers DC, acid chambers AC and base chambers BC according to the sequence I(MB/AC/MA/DC/MK/BC).sub.n Iwhere MB is a bipolar ion exchange membrane, MA is an anion exchange membrane, MK is a cation exchange membrane and n is a number from 1 to 500.
Abstract: An aqueous laundry prewash stain remover composition has on a weight basis 0.1 to 20% of at least one chelating agent from the group of citric acid, tartaric acid, ethylene diamine tetracetic acid, isoserine diacetic acid and Beta-alanine diacetic acid; 0.1 to 40% of nonylphenol ethoxylate; 0.1 to 10% of propoxylated ethylenediamine known as N,N,N',N'-tetrakis (2-hydroxypropyl) ethylenediamine; 0.1 to 5% of alpha-olefin epoxide modified polyether thickener; with the remainder of the composition being water. The composition provides enhanced stain removal on both oil and water-borne stains on a variety of fabrics. These formulations are solvent free, freeze/thaw stable, and do not precipitate on standing at room temperature.
Abstract: E-oxime ethers of phenylglyoxylic esters of the formula I ##STR1## where X and Y are each halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or trifluoromethyl;m is an integer from 0 to 4;n is an integer from 0 to 3;are prepared.
Type:
Grant
Filed:
December 13, 1991
Date of Patent:
June 22, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Horst Wingert, Bernd Wolf, Remy Benoit, Hubert Sauter, Michael Hepp, Wassilios Grammenos, Thomas Kuekenhoehner
Abstract: Abrasives based on finely divided abrasive particles bonded to one another and/or to a support by means of a binder, where the binder is the solid component of an aqueous polymer dispersion which is obtainable by polymerizing unsaturated monomers which can be polymerized by means of free radicals, in the aqueous phase in the presence of a monosaccharide, oligosaccharide, polysaccharide, oxidatively, hydrolytically and/or enzymatically degraded polysaccharide, chemically modified monosaccharide, oligosaccharide or polysaccharide, or a mixture of the said compounds, by the process of free-radical aqueous emulsion polymerization.
Type:
Grant
Filed:
October 7, 1992
Date of Patent:
June 22, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Schwerzel, Kurt Wendel, Hermann Rockstroh
Abstract: An apparatus equilibrates component tensions in a multicomponent filamentary yarn which is advancing in a primary direction. The apparatus includes a series of yarn guides arranged so that the multicomponent filamentary yarn deviates both horizontally and vertically from the primary direction.
Type:
Grant
Filed:
March 16, 1992
Date of Patent:
June 22, 1993
Assignee:
BASF Corporation
Inventors:
Andrew M. Coons, III, Leonard C. Vickery, Jr.
Abstract: Compositions of the formula IMo.sub.12 P.sub.a V.sub.b X.sub.c.sup.1 X.sub.d.sup.2 X.sub.e.sup.3 Sb.sub.f Re.sub.g S.sub.h O.sub.n (I),whereX.sup.1 is potassium, rubidium and/or cesium,X.sup.2 is copper and/or silver,X.sup.3 is cerium, boron, zirconium, manganese and/or bismuth,a is from 0.5 to 3.0,b is from 0.01 to 3.0,c is from 0.2 to 3.0,d is from 0.01 to 2.0,e is from 0 to 2.0,f is from 0.01 to 2.0,g is from 0 to 1.0,h is from 0.001 to 0.5 andn is a number determined by the valency and content of the elements different from oxygen in I, are used as catalysts for preparing methacrylic acid by gas-phase oxidation of methacrolein.
Type:
Grant
Filed:
August 12, 1992
Date of Patent:
June 22, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Karl-Heinz Boehning, Gerd Duembgen, Ulrich Hammon, Richard Krabetz, Franz Merger, Matthias Schwarzmann, Fritz Thiessen, Herbert Vogel
Abstract: Aqueous synthetic resin dispersions are obtainable by copolymerizingA) from 70 to 97.5 parts by weight of a monomer mixture containinga) from 40 to 75% by weight of butadiene (monomer I),b) from 25 to 60% by weight of acrylonitrile (monomer II),c) from 0 to 25% by weight of styrene (monomer III),d) from 0 to 10% by weight of one or more amides of .alpha.,.beta.-monoethylenically unsaturated monocarboxylic acids of 3 to 5 carbon atoms (monomers IV) ande) from 0 to 10% by weight of other copolymerizable monomers (monomers V) andB) from 2.5 to 30 parts by weight of one or more copolymerizable monovinyl compounds (monomers VI) in aqueous emulsion at from 30.degree. to 70.degree. C. by a method in which not less than 50% by weight of the monomer mixture A is prepolymerized to a conversion of not less than 80%, and the polymerization is then continued with the addition of the remaining monomers A and the monomers B.These dispersions are suitable as binders for protective coats on leather.
Type:
Grant
Filed:
June 20, 1991
Date of Patent:
June 22, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Martin Meister, Guenter Eckert, Juergen Schmidt-Thuemmes, Albrecht Zosel
Abstract: Pigment dispersion resins for use in cathodic electrocoat paint systems are the reaction products of (A) the reaction product of an aromatic diglycidyl ether and a bis-aryl alcohol or aromatic diol; (B) a primary amine which includes a diamine, an amino alcohol, an aminopolyalkoxy alcohol, a fatty amine, or any mixture thereof; and (C) a monoepoxide. In one embodiment, the fatty amine is provided in an effective amount to eliminate the necessity of the inclusion of the monoepoxide.
Type:
Grant
Filed:
May 27, 1992
Date of Patent:
June 22, 1993
Assignee:
BASF Corporation
Inventors:
John A. Gilbert, Gunther Ott, David J. Santure
Abstract: A high-sensitivity surface wave gas sensor in which the interaction of a surface wave field with a solid film suitable for adsorbing the gas to be determined causes a change in the frequency of an oscillating circuit containing a surface wave delay line as a function of the type and concentration of the gas entails the delay line provided for adsorption of the gas being completely coated with the solid film, and the dimensions of the delay lines being such that the length of the surface wave transformer is greater than that of the delay line.
Type:
Grant
Filed:
September 24, 1991
Date of Patent:
June 22, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Harald Fuchs, Wolfgang Schrepp, Michael Rapp, Siegfried Hunklinger, Manfred von Schickfus
Abstract: Polymethine dyes suitable for use in an optical recording medium have the formula ##STR1## where p is 0 or 1,Z is nitrogen, oxygen, sulfur, isopropylidene, cyclohexylidene or the radical --CH.dbd.CH--,Q is a radical of the formula ##STR2## where R.sup.2 is hydrogen, chlorine, bromine or C.sub.1 -C.sub.6 -alkyl, L is C.sub.1 -C.sub.12 -alkylene, or a single bondR.sup.1 is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.20 -alkyl, substituted or unsubstituted C.sub.5 -C.sub.7 -cycloalkyl or substituted or unsubstituted phenyl,X.sup..crclbar. is an anion, and the rings A may each be substituted or benzofused.
Type:
Grant
Filed:
May 20, 1991
Date of Patent:
June 22, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Acker, Bernhard Albert, Sibylle Brosius, Klaus D. Schomann, Harald Kuppelmaier
Abstract: One or more indoaniline dyes are transferred from a transfer to a sheet of plastic-coated paper by diffusion or sublimation with the aid of an energy source, said indoaniline dyes having the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each independently of the others hydrogen, methyl, fluorine or chlorine,X is fluorine or chlorine, andK is an aromatic radical.
Abstract: A refrigerator cabinet is provided with a plastic liner, the inside wall of the refrigerator, which is resistant to chemical degradation by fluorocarbons. Freon and Freon substitutes used as blowing agents for foaming the insulation contained between the outer metal cabinet and the inside wall of the refrigerator can cause blistering, cracking, and sometimes dissolution of materials used to form the plastic liner, which is the inside wall of the refrigerator. There is now provided a plastic liner which is resistant to those blowing agents and particularly to those blowing agents which are partially halogenated and tend to be more aggressive than Freon. The plastic liner wall maintains impact strength and toughness after exposure to fluorohydrocarbons conventionally employed in refrigerator units for in situ polyurethane foam production.
Abstract: A process for the preparation of 1-(4-tetrahydropyranyl)- or 1-(4-tetrahydrothiopyranyl)prop-1-en-3-ones of the general formula I ##STR1## where R.sup.1 is hydrogen, C.sub.1 - to C.sub.10 -alkyl, C.sub.1 - to C.sub.10 -alkoxy or aryloxy,R.sup.2 is hydrogen, C.sub.1 - to C.sub.4 -alkyl, or aryl which is unsubstituted or substituted by C.sub.1 - to C.sub.4 -alkyl and/or halogen, andX is oxygen or sulfur,by reacting 1-aminoprop-1-en-3-ones of the general formula II ##STR2## where R.sup.1 and R.sup.2 are as defined above, andR.sup.3 and R.sup.4, independently of one another, are hydrogen, C.sub.1 - to C.sub.4 -alkyl, aryl or together are a C.sub.2 - to C.sub.7 -alkylene chain,with a 4-tetrahydropyranyl- or 4-tetrahydrothiopyranylmagnesium halide of the general formula III ##STR3## where X is as defined above and Y is halogen, at from -20.degree. to 100.degree. C.,and novel 1-(4-tetrahydropyranyl)- or 1-(4-tetrahydrothiopyranyl)prop-1-en-3-ones are described.
Abstract: A flame retardant molding composition contains a halogen-free polycarbonate at least one halogen-free graft copolymer assembled from copolymerized units of an elastomer and certain ethylenically unsaturated monomers which include 1-50% by weight of an organic phosphorus compound of the formula (I) ##STR1## a halogen-free thermoplastic copolymer comprising styrene, .alpha.-alkylstyrene, nuclear-substituted styrene and/or C.sub.1 -C.sub.8 -alkyl (meth)acrylate, and (meth)acrylonitrile and/or maleic anhydride, as well as 1-46% by weight of a halogen-free phosphorus compound of the formula (I): Optionally a monophosphate additive and up to 5% by weight of a polytetrafluoroethylene with a median particle size of from 0.05 to 20 .mu.m may be added.
Type:
Grant
Filed:
September 25, 1992
Date of Patent:
June 15, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Norbert Niessner, Rainer Neumann, Karl Ruppmich, Friedrich Seitz, Doris Zeltner
Abstract: Novel sulfonium salts useful as photoinitiators for cationic polymerization and for producing relief patterns and relief images have the general formula (I) ##STR1## where A.sup..crclbar. is a non-nucleophilic counterion,x is 1, 2 or 3,R is a hydrocarbon radicalR' is arylene or substituted arylene, andR" is ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each alkyl or monohalogenated or polyhalogenated alkyl orR.sup.1 and R.sup.2 are each hydrogen or alkyl, and R.sup.3 is phenyl, alkenyl or cycloalkenyl, orR.sup.1 is hydrogen, and R.sup.2 and R.sup.3 form ethylenically unsaturated ring, orR.sup.1 and R.sup.2 are each hydrogen, alkyl, cycloalkyl or aryl, and R.sup.3 is alkoxy orR.sup.1 is hydrogen or alkyl and R.sup.2 and R.sup.3 are each alkoxy, aryloxy or substituted aryloxy.
Abstract: Abstract of the Disclosure: Crosslinked acrylic or methacrylic acid copolymers with crosslinkable groups that are useful as thickeners for textile print pastes are obtainable by copolymerization of(a) from 50 to 99 parts by weight of acrylic acid and/or methacrylic acid,(b) from 1 to 50 parts by weight of at least one N-methylol (meth)acrylamide or derivatives thereof,(c) from 50 to 10,000 ppm, based on the monomers (a) and (b), of an at least bifunctional crosslinker, and(d) from 0 to 49 parts by weight of other monoethylenically unsaturated monomersin the presence of a free radical polymerization initiator in the aqueous phase of a water-in-oil emulsion.
Abstract: Thermoplastic molding materials based on a mixture of polybutylene terephthalate and polyethylene terephthalate (a.sub.1), graft polymers having acrylate rubbers as the grafting base (a.sub.2), copolymers of vinylaromatic monomers and acrylonitrile or methacrylonitrile (a.sub.3) and glass fibers (B) have a balanced property spectrum.
Type:
Grant
Filed:
September 20, 1991
Date of Patent:
June 15, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Graham E. McKee, Manfred Knoll, Peter Kolm, Dietrich Lausberg
Abstract: An exhaust system for exhausting fumes released from a melt spinning process has a housing defining an exhaust system, a nozzle assembly extending partially from the housing toward the fume source with a nozzle tip disposed sufficiently close to the fume source to collect the fumes, a duct in communication with the exhaust chamber and having an outlet for exhausting the fumes, a driving force moving the fumes through the system from the nozzle to the outlet, and a method for automatically purging the exhaust system of condensed fume deposits.
Abstract: Magnetic recording media consisting of a nonmagnetic substrate and at least one magnetizable layer which is firmly applied thereon and is based on a magnetic material which essentially consists of ferromagnetic chromium dioxide and is finely dispersed in a polymer binder and further conventional additives are distinguished by a particular stability to the chemical decomposition due to moisture and oxidizable compounds and hence particular stability to the deterioration in the magnetic properties, as a result of the addition of from 0.1 to 8% by weight, based on the amount of chromium dioxide, of a monomeric, polyunsaturated, organic compound to the magnetic layer.
Type:
Grant
Filed:
March 19, 1992
Date of Patent:
June 8, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
August Lehner, Rudolf Suettinger, Michael Bobrich, Hermann Dikow, Hermann Roller, Werner Lenz, Ludwig Kreitner, Werner Loch, Norbert Schneider