Patents Assigned to BASF
  • Patent number: 4925972
    Abstract: Alkyl pentenoates are prepared by(a) reacting butadiene or a butadiene-containing hydrocarbon mixture with carbon monoxide and an alkanol in the presence of a tertiary aromatic heterocyclic nitrogen base and a cobalt carbonyl catalyst at from 80.degree. to 160.degree. C. under from 100 to 1,000 bar to obtain a reaction mixture which contains alkyl pentenoate, C.sub.6 -diester, tertiary nitrogen base, alkanol, butadiene, hydrocarbon and by-product,(b) substantially removing from the reaction mixture obtained any excess hydrocarbon, nitrogen base, alkanol and alkyl pentenoate by distillation to obtain a residue which contains cobalt carbonyl catalyst,(c) bringing the residue which contains cobalt carbonyl catalyst into contact with a mixture of carbon monoxide and hydrogen at elevated temperature and elevated pressure, and(d) recycling the residue which contains cobalt carbonyl catalyst into alkyl pentenoate synthesis stage (a).
    Type: Grant
    Filed: July 12, 1989
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Robert Maerkl, Wolfgang Harder
  • Patent number: 4925567
    Abstract: A stable baseline is achieved in a gradient ion chromatographic analysis by adding a nonionic modifier to the electrolytic eluent. The addition of the modifier may occur at any point upstream of the detector. The nonionic modifier has the effect of shifting the equilibrium of unsuppressed effluent electrolyte towards it nonionic form. For example, the addition of the nonionic modifier shifts both bicarbonate and carbonate towards the nonionic, nonconductive carbonic acid form.
    Type: Grant
    Filed: March 2, 1989
    Date of Patent: May 15, 1990
    Assignee: BASF Corporation
    Inventor: David L. McAleese
  • Patent number: 4925991
    Abstract: Dien-1-ols of the general formula I ##STR1## where the radicals R.sup.1 to R.sup.7 are identical to or different from one another and each is hydrogen or straight-chain or branched alkyl or 1-12 carbon atoms and n is 1-14, are prepared by dehydrating a hydroxylalkenyl tert-butyl ether of the formula II ##STR2## in the presence of an acidic catalyst at elevated tempertures and essentially at the same time splitting off the tert-butyl protective group, as is 9-hydroxydodec-10-enyl 1-tert-butyl ether which is useful as an intermediate for synthesizing 8,10-dodecadienol.
    Type: Grant
    Filed: August 24, 1988
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Mackenroth, Wolfgang Hoelderich, Rainer Becker, Walter Seufert
  • Patent number: 4925823
    Abstract: Oxidation catalysts of the general formulaMo.sub.12 P.sub.a W.sub.b Sb.sub.c As.sub.d Cu.sub.e X.sub.f O.sub.xwhereX is Nb, Fe, Mn, Sn and/or Cr,a is 0.1-3,b is 0.1-4,c is <0-2,d is 0-1,e is 0-1,d+e is <0-2,f is 0-1.5,e+f is 0-2 andx is the number of oxygen atoms formally required to saturate the valencies of the other catalyst components,may be used particularly advantageously for the preparation of methacrylic acid by gas phase oxidation of methacrolein.
    Type: Grant
    Filed: June 19, 1986
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Richard Krabetz, Gerd Duembgen, Friedbert Nees, Franz Merger, Gerd Fouquet
  • Patent number: 4925940
    Abstract: Cyclic N,N'-dimethylureas are prepared by catalytic hydrogenation of a cyclic urea which carries hydroxyl groups in the .alpha.-position to the two nitrogen atoms.
    Type: Grant
    Filed: January 4, 1989
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Lothar Franz, Manfred Eggersdorfer, Dieter Voges
  • Patent number: 4925954
    Abstract: A vat dye based on monobromofluoranthene is prepared by a process in which monobromofluoranthene which contains no more than 7% of dibromofluoranthene is reacted with 1-amino-4-benzoylaminoanthraquinone, the reaction product is condensed at from 50.degree. to 70.degree. C. in 83-88% strength sulfuric acid to give the carbazole compound, and the latter is then further brominated to a bromine content of from 20 to 23% by weight.The dyes obtained by the novel process are very useful for dyeing cotton.
    Type: Grant
    Filed: November 23, 1988
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Patsch, Gerhard Epple, Helmut Flohr, Helmut Degen, Uwe Nahr
  • Patent number: 4925910
    Abstract: Copolycondensate molding materials are obtainable by polycondensation offrom 2 to 98 mol % of 2,2-di-(4'-hydroxyphenyl)-propane (A),from 2 to 98 mol % of 4,4'-dihydroxydiphenyl sulfone (B) andfrom 0 to 96 mol % of (C) ##STR1## where R.sup.1 and R.sup.2 are each H, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxy, X is a chemical bond, --S--, --O--, --CO--, CR.sup.3 R.sup.4 (where R.sup.3 and R.sup.4 are different when n and p are each 0), or SO.sub.2 -- only when n or p is 0), R.sup.3 and R.sup.4 are each H, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, aryl or halogen-substituted alkyl of 1 to 4 carbon atoms, m is 0 or 1, and n and p are each 0, 1, 2, 3, or 4,with from 1 to 100 mol % of (D) ##STR2## where R.sup.5 and R.sup.6 have the same meaning as R.sup.1 and R.sup.2, and v and w are each 0, 1, 2, 3 or 4, and from 0 to 99 mol % of (E) ##STR3## where R.sup.7 -R.sup.10 are each Cl or F or have the same meanings as R.sup.1 and R.sup.2, q is 0 or 1, r, s, t and n are each 0, 1, 2, 3 or 4, Z.sub.
    Type: Grant
    Filed: April 9, 1987
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventor: Gerhard Heinz
  • Patent number: 4925897
    Abstract: Polyacetylene which is modified by reaction with a dienophilic compound, preparation of the said polyacetylene and its use for the production of moldings by processing by a thermoplastic method.
    Type: Grant
    Filed: January 10, 1989
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Gernot Koehler
  • Patent number: 4925946
    Abstract: Pyrazolo[5,1-b]quinazolones are prepared by reacting isatoic anhydrides with 3-methylpyrazol-5-one in water as reaction medium at from 40.degree. to 150.degree. C. under from 1 to 5 bar.
    Type: Grant
    Filed: September 9, 1988
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Hartmut Kanter, Burkhard Ort
  • Patent number: 4925484
    Abstract: N-Phenyltetrahydrophtalimides of the general formula I ##STR1## where R.sup.1 is hydrogen or halogen, R.sup.2 is halogen, R.sup.3 is hydrogen or C.sub.1 -C.sub.4 -alkyl, R.sup.4 is unsubstituted or C.sub.1 -C.sub.3 -alkoxy-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.4 -alkenyl or C.sub.3 -C.sub.4 -alkynyl, and R.sup.5 is hydrogen or C.sub.1 -C.sub.4 - alkyl, methods for their manufacture, and their use as herbicides.
    Type: Grant
    Filed: December 5, 1988
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Lothar Rueb, Karl Eicken, Hans J. Pander, Peter Plath, Barbara Schwalge, Bruno Wuerzer, Norbert Meyer
  • Patent number: 4925905
    Abstract: Water-soluble copolymers having a K value of from 8 to 100 (determined on the Na salt of the copolymers according to H. Fikentscher in aqueous solution at 25.degree. C., at a pH of 7 and at a concentration of the Na salt of the polymer of 1% by weight) are prepared by copolymerization of monomer mixtures of(a) from 98.5 to 18.5 mol % of one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids,(b) from 1.5 to 20 mol % of one or more comonomers which contain two or more ethylenically unsaturated, nonconjugated double bonds which are separated from one another by one or more ester bonds,(c) from 0 to 80 mol % of one or more monoethylenically unsaturated C.sub.4 -C.sub.
    Type: Grant
    Filed: March 30, 1989
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Boeckh, Hans-Peter Seelmann-Eggebert, Heinrich Hartmann, Wolfgang Trieselt, Richard Baur
  • Patent number: 4925476
    Abstract: Nitrification inhibitors contain azole hemiaminal derivatives of the formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, alkyl, aryl or halogen, R.sup.3 is alkyl, cycloalkyl, alkoxy, alkenyl, alkynyl, styryl, aryl, hetaryl or aralkyl, where the aromatic radical may be substituted, or is hydroxyl, A and B are each N or CR.sup.4, and R.sup.4 is hydrogen, alkyl, aryl or halogen.
    Type: Grant
    Filed: February 5, 1988
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Wagner, Norbert Rieber, Ernst-Heinrich Pommer, Juergen Dressel
  • Patent number: 4925888
    Abstract: A mixture for stabilizing polyurethanes contains(a) an amine of the formula I ##STR1## (b) a mixture of the benzotriazoles II and III ##STR2## in which n is chosen so that the mean molecular weight of the mixture is greater than 600, and(c) .alpha.-tocopherol, if necessary mixed with tris-(nonylphenyl) phosphite, and polyurethanes contain from 0.005 to 5.0% by weight, based on the material to be stabilized, of this mixture.
    Type: Grant
    Filed: October 21, 1988
    Date of Patent: May 15, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Alexander Aumueller, Peter Neumann, Peter Spang, Guenter Matzke, Hubert Trauth
  • Patent number: 4923503
    Abstract: Agents for influencing plant growth, containing as active ingredient an azolylacetophenone oxime ether of the formula ##STR1## where R and R.sup.1 independently of one another are each hydrogen, halogen, alkyl, cycloakyl, alkoxy, alkylthio, alkylsulfonyl, haloalkyl, nitro, cyano, phenyl or phenoxy, R.sup.2 is hydrogen, alkyl, aralkyl, allyl or propargyl, R.sup.3 is a divalent radical of the formula --(CH.sub.2).sub.m --, --(CH.sub.2 CH.sub.2 O--).sub.u CH.sub.2 CH.sub.2 --, --(CH.sub.2).sub.v CH.dbd.CH--(CH.sub.2).sub.t -- or --(CH.sub.2).sub.v --C.tbd.C--(CH.sub.2).sub.t --, n, p, u, v and t independently of one another are each 1, 2 or 3, m is an integer from 2 to 10, and Az is 1,2,4-triazol-1-yl, pyrazol-1-yl or imidazol-1-yl, or a salt or metal complex thereof, and a method of influencing plant growth or of destroying unwanted plants with these active ingredients.
    Type: Grant
    Filed: November 30, 1984
    Date of Patent: May 8, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Guenter Schulz, Ernst Buschmann, Hubert Sauter, Bernd Zeeh, Bruno Wuerzer, Johann Jung, Guenter Retzlaff
  • Patent number: 4923988
    Abstract: Triphendioxazines are prepared by cyclizing benzoquinone derivatives in oleum in the presence of an organic iodine compound.
    Type: Grant
    Filed: October 14, 1988
    Date of Patent: May 8, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Uwe Nahr, Manfred Pastsch
  • Patent number: 4924000
    Abstract: Acylated imidazoles of the formula ##STR1## where R.sup.1 and R.sup.3 are each H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, R.sup.4 is H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, and R.sup.5 is alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl, alkylaryl or carboxyl, are prepared by reacting imidazoles of the formula ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, at least one of the radicals R.sup.1, R.sup.2 and R.sup.3 being hydrogen, and R.sup.4 is H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, with widely used acylating agents of the formula ##STR3## where R.sup.
    Type: Grant
    Filed: March 9, 1989
    Date of Patent: May 8, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Hesse, Wolfgang Hoelderich, Toni Dockner, Hermann Koehler
  • Patent number: 4924003
    Abstract: An electrophotographic recording element comprising(A) an electrically conducting base and(B) at least one photoconductive layer consisting essentially of(b.sub.1) at least one binder,(b.sub.2) at least one sensitizer which on exposure of layer (B) generates charge carriers and which is selected from the group of the isoindolenine dyes of the general structure I ##STR1## where the index and the variables have specified meanings, (b.sub.3) at least one photoconductor which transports the generated charge carriers and optionally(b.sub.4) additives,is useful for reprographic purposes, for producing printing plates, in particular offset plates, and for producing photoresists.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: May 8, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhold J. Leyrer, Peter Neumann
  • Patent number: 4923928
    Abstract: Prereact modifiers prepared by reacting a propenylphenol with an epoxy resin are useful in toughening heat curable bismaleimide resin systems so as to minimize impact produced damage, and which have exceptional gel times.
    Type: Grant
    Filed: February 18, 1988
    Date of Patent: May 8, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Jack D. Boyd, Hong-Son Ryang
  • Patent number: 4923972
    Abstract: Liquid formulations of basic azo dyes are prepared from unsubstituted or C.sub.1 -C.sub.4 -alkyl- or C.sub.1 -C.sub.4 -alkoxy-substituted m-phenylenediamine by diazotizing and coupling in carboxylic acid solution, which comprises performing the reaction with 0.76 to 0.95 mole of nitrile, calculated as nitrous acid and based on 1 mole of m-phenylenediamine, and then heating the resulting reaction mixture at from 60.degree. C. to the boiling point of the reaction mixture.
    Type: Grant
    Filed: April 14, 1988
    Date of Patent: May 8, 1990
    Assignee: BASF Aktiengesellschaft
    Inventor: Karl Schmeidl
  • Patent number: 4923811
    Abstract: A process for carrying out enzymatic oxidations is described.
    Type: Grant
    Filed: August 28, 1987
    Date of Patent: May 8, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Helmut Simon, Helmut Guenther