Abstract: Propargyl furan- and thiophenecarboxylates of the formulae Ia and Ib ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, chlorine, bromine, nitro, C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -alkenyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkenyl, or phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 -alkyl, or C.sub.1 -C.sub.4 -alkoxy, X is oxygen or sulfur, n is the integer 0 or 1, and, if X is sulfur, R.sup.1, R.sup.2 and R.sup.3 may furthermore be fluorine, cyano, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.2 -C.sub.4 -alkenyloxy or C.sub.2 -C.sub.4 -haloalkenyloxy, processes for their manufacture, and their use for combating pests.
Type:
Grant
Filed:
April 14, 1989
Date of Patent:
April 24, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans-Jurgen Neubauer, Wolfgang Seppelt, Rainer Burstinghaus, Peter Hofmeister, Christoph Kuenast
Abstract: Radiation-curable contact adhesives containing (A) oligomeric or polymeric reaction products of (a) diisocyanates, (b) polyesterols and/or polyetherols, (c) optionally C.sub.2 -C.sub.50 -diols, (d) C.sub.2 -C.sub.20 -hydroxyalkyl (meth)acrylates and (e) monohydroxyalkylcarboxylic acids in defined weight proportions and (e) monovinyl compounds in an amount of 2-90% by weight, based on A+B, produce contact adhesive layers of particularly high surface tackiness and particularly high cohesion.
Type:
Grant
Filed:
March 15, 1988
Date of Patent:
April 24, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Guenther Schulz, Wolfgang Druschke, Helmut Jaeger
Abstract: An improved multifilamentary fibrous material is formed having solid particles of a matrix-forming thermosetting resin substantially uniformly dispersed among adjoining filaments in the absence of fusion bonding. The thermosetting resin particles initially are dispersed in an aqueous medium containing an effective amount of a dissolved polymeric binding agent and the viscosity of the medium subsequently is substantially increased to at least 50,000 cps. to form a gelled impregnation bath having a plastic flow characteristic with shear-thinning behavior wherein the thermosetting resin particles are substantially uniformly suspended. The resulting impregnation bath is caused to flow between the adjoining filaments of the multifilamentary fibrous material with a concomitant viscosity reduction which aids in the incorporation of the resin particles. The concentration of the aqueous medium in the product is controlled to yield a uniform, handleable, drapable, tacky, and highly stable product.
Type:
Grant
Filed:
March 3, 1988
Date of Patent:
April 24, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Robert Dyksterhouse, Joel A. Dyksterhouse, Alan C. Handermann, Edward D. Western
Abstract: In an improved process for the preparation of 2-n-propyl-4-amino-5-methoxymethyl-pyrimidine of the formula I ##STR1## by reacting butyramidine II ##STR2## with .alpha.-methoxymethyl-.beta.-methoxyacrylonitrile III ##STR3## the butyramidine II is reacted with a 0.4-5 molar excess of .alpha.-methoxymethyl-.beta.-methoxyacrylonitrile III at from -10.degree. to +20.degree. C.
Abstract: An optical recording medium contains a transparent base, a dye-containing layer which is sensitive to laser light and a reflector layer which contains a silicon-phthalocyanine derivative of the formula ##STR1## where R.sup.1 is hydrogen, alkyl, alkoxy, halogen or trialkylsilyl, n is 1, 2, 3 or 4 and A and B are identical or different and independently of one another are each alkyl, halogen or unsubstituted or substituted alkoxy or trialkylsilyloxy.
Type:
Grant
Filed:
May 17, 1988
Date of Patent:
April 17, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernhard Albert, Peter Hauser, Michael Acker, Wolfgang Schrott, Gerhard Wagenblast
Abstract: Alkylated dodecahydronaphtho[2,1-b]furans of the general formula I ##STR1## where R.sup.1 and R.sup.2 are identical and each is hydrogen or methyl are prepared by reacting alkylated 2-hydroxydecahydronaphthalene-1-ethanol of the formula II ##STR2## where R.sup.1 and R.sup.2 are as defined above, with a sulfonyl chloride in the presence of basic catalysts by performing the cyclization in the presence of concentrated aqueous alkali metal hydroxides and a phase transfer catalyst, preferably a tetra-substituted ammonium or phosphonium salt, the sulfonyl chloride used preferably comprising a sulfonyl chloride of the general formula IIIR.sub.3 -SO.sub.2 Clwhere R.sup.3 is C.sub.1 -C.sub.3 -alkyl or phenyl which may be substituted in the para position by methyl, chlorine, bromine or nitro.
Type:
Grant
Filed:
September 28, 1988
Date of Patent:
April 17, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Walter Gramlich, Eckhard Hickmann, Rainer Becker, Gerald Lauterbach
Abstract: Preparation of acetic acid and methyl acetate by gas-phase carbonylation of methanol in the presence of a nickel-containing catalyst and in the presence of chlorine, bromine or iodine or a volatile compound of one of these halogens as a promoter, wherein the active material of the catalyst used consists of not less than 40% by weight of nickel and the catalyst contains 0.001-1 part by weight of palladium per part by weight of nickel, as well as supported catalysts whose active material contains Ni and Pd in the above ratio.
Abstract: Phosphonic acid, phosphinic acid and phosphine oxide derivatives of the general formula ##STR1## where A, B and R.sup.1 to R.sup.5 have the meanings stated in the description, processes for their preparation, pharmaceutical agents containing them, and their use for the treatment of acne and psoriasis are described .
Abstract: The invention provides a novel photosensitive recording material in the shape of a multilayer element comprising(i) a photopolymerizable or photocrosslinkable relief-forming layer (RL) of a thickness from 0.1 to 6000 .mu.m and(ii) a dimensionally stable support layer.The said relief-forming layer (RL) consists essentially of an ionic polymer, of one or more photoinitiators and, if desired, of one or more photopolymerizable monomers.The said ionic polymer contains(A) from about 45 to 90% by weight, based on the ionic polymer, of a polymer main chain formed from an alkadiene polymer A',(B) from about 6 to about 45% by weight, based on the ionic polymer, of one or mored olefinically unsaturated side radicals having the structure (I), ##STR1## where R.sup.1 and R.sup.2 are different and are each H or a carbon atom of A',R.sup.3 is a polyvalent, straight-chain or branched C.sub.1 -C.sub.
Type:
Grant
Filed:
March 30, 1989
Date of Patent:
April 10, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Horst Koch, Wolfgang F. Mueller, Reiner Hofmann, Peter Richter
Abstract: A cassette incorporating a locking element, in particular for a hinged flap of the cassette, has mounting elements which are arranged so as not to turn in at least one retaining slit and a resiliently flexible integrated part which products a bending and torsional stress when the locking element is actuated.
Abstract: A catalytically active composition for the gas phase oxidation of propylene to acrolein and acrylic acid, of the general formulaMo.sub.12 Bi.sub.0.1-10 Fe.sub.0.8-12 [Co,Ni].sub.0.1-10 P.sub.0-2 A.sub.0-10 B.sub.0.001-1 O.sub.xwhere A is arsenic, antimony, tin, thallium, tungsten, an alkaline earth metal, zinc and/or chromium, B is at least one of the metals sodium, potassium, rubidium, cesium and/or indium and X is the number determined by the atomic valences of the individual elements, is prepared by introducing all or some of the iron and molybdenum in the form of dried pulverulent iron molybdate gel into an aqueous solution or suspension of the other constituents and gelating the mixture by stirring and possibly heating, then comminuting, drying at elevated temperatures and finally calcining.
Type:
Grant
Filed:
November 25, 1988
Date of Patent:
April 10, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans Martan, Matthias Schwarzmann, Karl-Heinz Boehning, Heinz Dreyer
Abstract: 1-Amino-2-(6'-hydroxyhexoxy)-4-hydroxyanthraquinone (I) is prepared from the corresponding 2-phenoxy- or 2-halo-anthraquinone compound and 1,6-hexanediol with or without a phenol in the presence of an alkaline agent at elevated temperatures by reacting, per mole of the anthraquinone compound, from 2 to 6 moles of 1,6-hexanediol in the presence of ethylene oxide adducts on phenols or alkanols and/or polyethylene glycols at from 125.degree. to 135.degree. C. and then heating the resulting reaction mixture at from 140.degree. to 150.degree. C., in the course of which the stage 1 byproducts, namely the 1',6'-bis(1-amino-4-hydroxyanthraquinonyloxy)hexane diether is cleaved into (I), leaving a diether level of .ltoreq.2% by weight in (I).
Abstract: Diamines of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, alkyl, aryl, alkoxy, aralkyl or cycloalkyl and X is a group of the formula(CR.sup.4 R.sup.5).sub.m (II)where R.sup.4 and R.sup.5 have the meanings given above for R.sup.1 and m is from 1 to 12, are prepared by a process in which a diamine of the formula ##STR2## where R.sup.1, R.sup.2 and X are the groups described above, is reacted with an olefin of the formula ##STR3## where R.sup.6 and R.sup.9 are each hydrogen or alkyl which is straight-chain in the .alpha.-position, in the presence of a zeolite as a catalyst.
Type:
Grant
Filed:
June 15, 1988
Date of Patent:
April 3, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Hesse, Wolfgang Hoelderich, Matthias Schwarzmann
Abstract: Basecoating compositions for preparing multilayered protective and/or decorative coatings comprise aqueous dispersions which contain(a) as film-forming material one or more polyurethane resins having an acid number of from 5 to 70, which has been prepared by preparing from(A) liner polyetherdiols and/or polyesterdiols having a molecular weight of from 400 to 3,000(B) diisocyanates and(C) compounds which contain two groups which are reactive toward isocyanate groups, one or more of the compounds used as component C having one or more groups capable of anion formation which have preferably been neutralized before the reaction with a tertiary amine,an intermediate which as terminal isocyanate groups and whose free isocyanate groups have subsequently been reacted with a polyol which contains three or more hydroxyl groups, preferably a triol,(b) pigments and(c) further customary additives.
Type:
Grant
Filed:
August 22, 1988
Date of Patent:
April 3, 1990
Assignee:
BASF Lacke & Farben AG
Inventors:
Hans-Dieter Hille, Franz Ebner, Hermann-Josef Drexler
Abstract: Organic polyacids are prepared from monomeric monofunctional acids, such as acrylic acid or methacrylic acid and monomers without an acid group, with or without dicarboxylic acids or their anhydrides, by continuous free radical mass copolymerization under superatmospheric pressure at from 200.degree. to 400.degree. C., followed, if desired, by neutralization of the polyacids obtained. The polyacids obtained by the novel process are useful as phosphate substitutes and scale inhibitors in detergents and cleansers.
Type:
Grant
Filed:
July 8, 1985
Date of Patent:
April 3, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Juergen Hambrecht, Heinrich Hartmann, Walter Denzinger, Albert Hettche, Wolfgang Trieselt, Rolf Schneider
Abstract: Finely divided acicular and pore-free .alpha.-Fe.sub.2 O.sub.3 is prepared from an iron(III) salt in the presence of one or more organic substances which form complexes with iron(III) ions, in alkaline supension at from 80.degree. to 250.degree. C., and is used for the preparation of magnetic materials suitable for magnetic recording media.
Type:
Grant
Filed:
February 24, 1989
Date of Patent:
April 3, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Volker Arndt, Helmut Auweter, Rainer Feser, Ekkehard Schwab
Abstract: Water-soluble copolymers having a K value of from 8 to 100 (determined according to H. Fikentscher on sodium salt in aqueous solution at 25.degree. C., a pH of 7 and a polymer concentration of the Na salt of 1% by weight) contain, in polymerized form,(a) not less than 15 mol % of one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids,(b) from 0.5 to 84.5 mol % of one or more ethylenically unsaturated C.sub.4 -C.sub.6 -dicarboxylic acids,(c) from 0 to 20 mol % of one or more hydroxyalkyl esters, where hydroxyalkyl is of 2 to 6 carbon atoms, of monoethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids,(d) from 0 to 30 mol % of other water-soluble, monoethylenically unsaturated monomers copolymerizable with (a), (b) and (c),(e) from 0.
Type:
Grant
Filed:
April 8, 1988
Date of Patent:
April 3, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans-Peter Seelmann-Eggebert, Dieter Boeckh, Heinrich Hartmann, Wolfgang Trieselt
Abstract: Cleaning compositions, especially liquid detergent compositions containing chlorine bleach, are disclosed. The compositions include a chlorine bleach stable nonionic surfactant which is a mixture of the formulay[A.sub.1 O).sub.n (A.sub.2 O).sub.n' (A.sub.3 O).sub.n' H].sub.mwherein A.sub.1 and A.sub.2 are C.sub.2 -C.sub.4 alkylene groups, tetramethylene and mixtures thereof, A.sub.3 is a sterically hindered C.sub.4 -C.sub.30 alkylene group, C.sub.4 -C.sub.30 arylalkylene group, and mixtures thereof, n+n'=a value such that the total molecular weight of the uncapped portion of the molecule is about 500 to 25,000, n" is a number from 1 to 8, m is a number from 1 to 8, and Y is the residue of an organic compound having from about 1 to 30 carbon atoms and at least 1 reactive hydrogen atom. The surfactant has a hydrophilic content of from about 5 to 40 weight percent.
Type:
Grant
Filed:
June 9, 1988
Date of Patent:
April 3, 1990
Assignee:
BASF Corporation
Inventors:
Jay G. Otten, Michael G. Kinnaird, Ronald E. Greenough, Edward J. Parker
Abstract: Process for the preparation of the compounds of the formulae Ia and Ib ##STR1## wherein A. 2,4,4-trimethylcyclohex-2-en-1-one oxime of the formula IIb ##STR2## is treated with a strong aqueous acid at from 30.degree. to 80.degree. C., preferably from 40.degree. to 70.degree. C.,B. the resulting ketone of the formula IIIb ##STR3## is oxidized in a conventional manner, and C. if desired, the resulting compound Ib is isomerized in a conventional manner.Compounds of the formula A ##STR4## where R is one of the following radicals: --CH(OH)--CH.sub.2 --CH.dbd.CH.sub.2 (IIIb), --CH(OH)--CH.sub.3 (IIIc), --CH.sub.2 OH (IIId), --CH(OH)--CH.dbd.CH.sub.2 (IIIe), --CH(OCOCH.sub.3)--CH.sub.3 (IIIf), --CH.sub.2 --OCOCH.sub.3 (IIIg), --CO--CH.sub.2 --CH.dbd.CH.sub.2 (Ib), --CO--CH.sub.3 (Ic), and --CO--CH.dbd.CH.sub.2 (Ie).The compounds IIIb to IIIg, Ib, Ic and Ie are useful scents and aromas, and furthermore may become important intermediates for novel carotenoids.