Patents Assigned to BASF
  • Patent number: 4405330
    Abstract: Navy mixtures which contain dyes of the formula I ##STR1## where X is chlorine or bromine,Y is hydrogen, methoxy or ethoxy andR is N(C.sub.2 H.sub.5).sub.2, N(CH.sub.2 CH.dbd.CH.sub.2).sub.2 or N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2,the mixtures being composed of 10-70% of dyes with Y.dbd.H and R=N(C.sub.2 H.sub.5).sub.2, 5-40% of dyes with Y=OCH.sub.3 or OC.sub.2 H.sub.5 and R.dbd.N(CH.sub.2 --CH.dbd.CH.sub.2).sub.2 and 5-80% of dyes with Y=OCH.sub.3 or OC.sub.2 H.sub.5 and R=N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2.The novel mixtures have excellent tinctorial properties and give very fast dyeings on synthetic polyesters.
    Type: Grant
    Filed: October 8, 1982
    Date of Patent: September 20, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Udo Bergmann, Helmut Degen, Guenter Hansen, Reinhold Krallmann, Wolf-Dieter Kermer
  • Patent number: 4405765
    Abstract: A curable resin is composed ofA. an epoxy resin andB. a pyrylium salt as a catalyst, with or withoutC. a metal chelate or metal salt as a co-catalyst.Preferred pyrylium salts are those of the formula ##STR1## Preferred co-catalysts are acetylacetonates, stearates, benzoates, naphthenates, octoates or phthalates of Cu.sup.++, Co.sup.++, Co.sup.+++, Fe.sup.+++ or Al.sup.+++. The resin compositions may be used to produce coatings and moldings.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: September 20, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Kurt Demmler, Wolfram Ochs
  • Patent number: 4405494
    Abstract: Polyhydroxy-polyalkylene-polyamine salts of maleic amide acids are useful metal corrosion inhibitors for use in water-in-oil emulsions.
    Type: Grant
    Filed: December 10, 1981
    Date of Patent: September 20, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Knut Oppenlaender, Erich Schwartz, Klaus Barthold, Wilhelmus Slotman
  • Patent number: 4405614
    Abstract: N-sulfonylated thiolphosphoric ester amides of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3, X and n have the meanings given in the description, and their use for controlling insects, arachnida and nematodes.
    Type: Grant
    Filed: March 10, 1982
    Date of Patent: September 20, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Peter Loeffler, Walter Seufert, Heinrich Adolphi
  • Patent number: 4404176
    Abstract: A process for the preparation of hydroxylammonium salts by catalytic reduction of nitric oxide with hydrogen in a dilute aqueous solution of a mineral acid, in the presence of a suspended supported platinum catalyst, at elevated temperatures, wherein the reaction is carried out in a conventional manner, in one or more reaction zones, under superatmospheric pressure, and the exit gases produced are let down to a lower pressure, and are reacted, in a downstream reaction zone, with the reaction mixture, containing hydroxylammonium salt, the ammonium salt, the supported platinum catalyst and residual mineral acid, from the upstream reaction zone or zones, or with a fresh aqueous solution of the mineral acid, which contains the supported platinum catalyst in suspension.
    Type: Grant
    Filed: February 1, 1982
    Date of Patent: September 13, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Otto-Alfred Grosskinsky, Elmar Frommer, Gunther Rapp, deceased, Erwin Thomas
  • Patent number: 4404175
    Abstract: A process for the preparation of zeolites of the ZSM-5 structural type from a mixture of SiO.sub.2 and Al(OH).sub.3 by hydrothermal crystallization in an aqueous amine solution, in the absence of alkali, at from 100.degree. to 200.degree. C., wherein the crystallization is carried out in the presence of a triamine, tetraamine and/or higher amine and the reaction mixture is formulated to have an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio defined by an equation which involves the chain length and number of amine groups of the amine employed, as well as to have certain molar ratios of H.sub.2 O/amine and amine/Al.sub.2 O.sub.
    Type: Grant
    Filed: May 29, 1981
    Date of Patent: September 13, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Laszlo Marosi, Hans-Ulrich Schlimper, Matthias Schwarzmann, Joachim Stabenow
  • Patent number: 4404036
    Abstract: Copper phthalocyanine blue pigments are produced by(A) grinding,1. copper phthalocyanine blue crystals with2. an inorganic salt and digesting the ground copper phthalocyanine blue inwater containinga strong mineral acid.(B) separately preparing an emulsion by dissolving1. a resin in2. an organic solvent,3. an emulsifying agent and4. water(C) mixing1. the emulsified resin with2. the digested ground copper phthalocyanine pigment and(D) separating the pigment from the other materials.
    Type: Grant
    Filed: October 15, 1981
    Date of Patent: September 13, 1983
    Assignee: BASF Wyandotte Corporation
    Inventor: Thomas E. Donegan
  • Patent number: 4404359
    Abstract: A process for the preparation of high molecular weight polyphenylene ethers from monohydric phenols which have alkyl substituents in both ortho-positions and may additionally have an alkyl substituent in one meta-position but not in the para-position, by an oxidative coupling reaction, employing oxygen, at from 10.degree. to 25.degree. C., in the presence of a catalyst complex comprising a copper salt and an N-substituted imidazole, in the presence of an aromatic C.sub.8 -C.sub.10 -hydrocarbon solvent.N-Methylimidazole, N-ethylimidazole, N-isopropylimidazole, N-n-butylimidazole, N-cyclohexylimidazole, N-octylimidazole and N-phenylimidazole are preferably used as the imidazole, advantageously in amounts of from 0.5 to 5 percent by weight.
    Type: Grant
    Filed: July 19, 1982
    Date of Patent: September 13, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Juergen Hambrecht, Norbert Rieber
  • Patent number: 4404389
    Abstract: Compounds of the general formula I ##STR1## where B.sup.2 and B.sup.2 independently of one another are hydrogen, C.sub.1 -C.sub.6 -alkyl which may or may not be interrupted by oxygen or sulfur and is unsubstituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylmercapto, cyano, phenylmercapto (which is unsubstituted by chorine or methyl), unsubstituted or substituted carbamoyl or a carboxylic acid ester group, benzyl or phenylethyl which are unsubstituted or substituted in the ring by chlorine, bromine, methyl, ethyl, methoxy or ethoxy, phenyl which is unsubstituted or substituted by chlorine, bromine, hydroxyl, methoxy, ethoxy, methyl, C.sub.1 -C.sub.4 -alkylmercapto, C.sub.1 -C.sub.4 -alkanoylamino or amino, unsubstituted or substituted carbamoyl or a carboxylic acid ester group,B.sup.2 may in addition be cyano, C.sub.2 -C.sub.4 -alkanoyl, benzoyl which is unsubstituted or substituted by chlorine, methyl, methoxy or ethoxy, C.sub.1 -C.sub.
    Type: Grant
    Filed: July 29, 1982
    Date of Patent: September 13, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Christos Vamvakaris, Manfred Patsch, Wolfgang Mach
  • Patent number: 4403993
    Abstract: Water-soluble or self-dispersing resin tanning agents are prepared by heating from 5 to 30% by weight of melamine, from 15 to 45% by weight of urea, from 20 to 35% by weight (calculated as anhydrous material) of formaldehyde and from 15 to 55% by weight of sodium bisulfite or of a corresponding amount of some other salt of sulfurous acid for from two to twelve hours in aqueous solution at 40.degree.-120.degree. C. and a pH of from 5 to 9.
    Type: Grant
    Filed: April 9, 1982
    Date of Patent: September 13, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Dietrich Lach, Rolf Streicher, Gerhard Bolz
  • Patent number: 4404344
    Abstract: The invention relates to a method for preparing polymers of ethylene and propylene, or of copolymers of ethylene and alpha olefins such as propylene 1-butene and 1-hexene or alpha omega dienes such as alpha omega octadiene, respectively, by polymerization within a temperature range from -80.degree. to 150.degree. C. in the presence of a halogen free Ziegler type catalyst system consisting of a cyclopentadienyl compound containing a transition metal and of an aluminum alkyl compound, whereby the polymerization is made in the presence of catalyst system consisting of the following components:(1) a compound containing a transition metal and having the general formula (cyclopentadienyl).sub.n MeY.sub.n, in which n is an integer from 1 to 4, Me is a transition metal, preferably zirconium, and Y being selected from the group of hydrogen, a C.sub.1 -C.sub.5 alkyl group or C.sub.1 -C.sub.5 metal alkyl group or of a compound of the following general formula ##STR1## in which R is a C.sub.1 -C.sub.5 alkyl group or C.
    Type: Grant
    Filed: February 27, 1981
    Date of Patent: September 13, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Hansjorg W. Sinn, Walter O. Kaminsky, Hans-Jurgen C. Vollmer, Rudiger O. H. H. Woldt
  • Patent number: 4404304
    Abstract: Novel chroman derivatives ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each H or C.sub.1 -C.sub.4 -alkyl, R.sup.6 and R.sup.7 are each H, C.sub.1 -C.sub.4 -alkyl or aryl, m is 1, 2 or 3, and R.sup.8 is alkyl or alkenyl of up to 30 carbon atoms, the preparation of these compounds, and their use as stabilizers for organic materials.
    Type: Grant
    Filed: January 28, 1982
    Date of Patent: September 13, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Horner, Dieter Horn, Erik Lueddecke, Gernot Teege
  • Patent number: 4404126
    Abstract: A process for the preparation of electrically conductive polymers, having conductivities greater than 10.sup.-2 S/cm, wherein from 0.1 to 95% by weight of black phosphorus and from 0.5 to 25% by weight of sodium, potassium, rubidium or cesium or of an amide of these, preferably in tetrahydrofuran, dimethoxyglycol, nitromethane or methylene chloride (the molar ratio of alkali metal or amide to organic compound preferably being from 1:1 to 1:5) are added to an organic polymer chosen from the group comprising the polyphenylenes, heteropolyphenylenes and polyacetylenes, in the absence of moisture and of oxygen. The electrically conductive polymers obtained can be used in the electrical industry for the production of solar cells, for conversion and fixing of radiation and for the production of electrical and magnetic switches, and can also be used for the antistatic treatment of plastics.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: September 13, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Muench, Herbert Naarmann, Klaus Penzien
  • Patent number: 4402349
    Abstract: A mechanical process for filling the tubes (3) of tubular reactors with granular solids, e.g. catalysts, wherein two or more streams of material, e.g. of different catalytic activity, can be introduced in a controlled manner into each tube (3) which is to be filled, from two or more stock vessels (1,2) via two or more dispensing devices (MI, MZ) mounted above the upper tube end plate (13). By this process, different thermal/catalytic reaction profiles can be achieved over the length of the tube, or in certain groups of tubes within the tubular reactor, with substantially less time being required for filling the tubes (3).
    Type: Grant
    Filed: November 12, 1981
    Date of Patent: September 6, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd-Juergen Engert, Klaus de Haas, Rudolf Magin, Franz Nenninger, Horst Schauer
  • Patent number: 4402991
    Abstract: Process for electrostatically coating objects with a fluid, for instance liquid paint, by applying a high voltage to a spray bell and by feeding the fluid to a revolving, driven spray bell. The flow-rate of the fluid supplied to the center of the spray bell is decelerated nearly to zero when it enters the bell, then the rate of the fluid is increased by being accelerated by the bell to 15,000 to 60,000 rpm, and the fluid thereupon is centrifuged off the spray rim of the bell and is guided to the object to be coated.
    Type: Grant
    Filed: August 20, 1982
    Date of Patent: September 6, 1983
    Assignee: BASF Farben & Fasern A.G.
    Inventor: Roland A. Meisner
  • Patent number: 4402847
    Abstract: Compositions and method of using said compositions for inhibiting mineral scale and the corrosion of high lead solder and the cavitation-erosion corrosion of aluminum in aqueous systems are disclosed. Unexpectedly, a mixture of a siloxane-silicate copolymer with an azole is effective in reducing the corrosion of high lead solder and aluminum, particularly the cavitation-erosion corrosion of aluminum in contact with aqueous liquids, such as aqueous alcohol solutions used as heat transfer media. Antifreeze concentrates and a process for inhibiting corrosion are also disclosed.
    Type: Grant
    Filed: May 19, 1982
    Date of Patent: September 6, 1983
    Assignee: BASF Wyandotte Corporation
    Inventors: Joe C. Wilson, Stanley T. Hirozawa
  • Patent number: 4402937
    Abstract: A process for the preparation of PVP-iodine having an iodine:iodide ratio of about 2:1 and a partition coefficient of 180-250, by reacting PVP with elementary iodine in the presence of formic acid, oxalic acid or an ammonium salt or amide of carbonic acid, formic acid or oxalic acid, in aqueous solution.
    Type: Grant
    Filed: September 19, 1980
    Date of Patent: September 6, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Denzinger, Heinrich Hartmann, Wolfgang Schwarz
  • Patent number: 4403060
    Abstract: The subject invention relates to the use of certain iron oxide spinels to color plastics. The iron oxide spinels are acicular particles having an average length of less than 0.1 micron and are represented by the formulae XFe.sub.2 O.sub.4 or YFe.sub.5 O.sub.8 in which X is a metal selected from the group consisting of Zn, Sn, Cu, Ca, Cd, Co, Ba, Sr, Mg, Al, and Mn, and Y is Li. The spinels are incorporated into plastics by methods which are known to those of ordinary skill in the art. The resulting plastics can be made with a wide variety of colors and can be used to coat surfaces without hiding the underlying surface.
    Type: Grant
    Filed: August 24, 1981
    Date of Patent: September 6, 1983
    Assignee: BASF Wyandotte Corporation
    Inventors: Lowell E. Netherton, Arvind S. Patil
  • Patent number: 4401643
    Abstract: A process for the preparation of barium ferrite of the formula BaFe.sub.12 O.sub.19 by reacting an aqueous solution or suspension of a barium salt and an aqueous solution of an iron(III) salt with an aqueous sodium carbonate solution, removing the solvent, heating the dry salt mixture to below the melting point of the sodium salt present, but to not less than 680.degree. C., and isolating the resulting finely divided, platelet-like barium ferrite from the barium ferrite/sodium salt mixture by leaching with water.
    Type: Grant
    Filed: October 20, 1981
    Date of Patent: August 30, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Hartmut Hibst, Helmut Jakusch
  • Patent number: 4401545
    Abstract: Electrically conductive complexes of polypyrroles with nitroaromatic anions are prepared by polymerizing pyrrole, an N-alkylpyrrole and/or an N-arylpyrrole by anodic oxidation in a polar solvent, in the presence of a salt of an acidic nitroaromatic compound.
    Type: Grant
    Filed: December 21, 1981
    Date of Patent: August 30, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Dieter Naegele, Klaus Penzien, Johannes Schlag, Volker Kiener, Hugo Boehm