Abstract: Transparent, impact-resistant thermoplastic molding materials produced from a rigid methylmethacrylate polymer A, a rigid styrene-acrylonitrile polymer B and a flexible graft copolymer C, made from grafting an alkylmethacrylate and optionally styrene onto a rubber grafting base.
Type:
Grant
Filed:
March 26, 1982
Date of Patent:
July 12, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Graham E. McKee, Franz Haaf, Juergen Hambrecht, Klaus Benker, Rudolf Stephan, Hans Breuer
Abstract: New 1-acyl- and 1-hydroxymethyl-cyclododecanes and -cyclododecenes. The new 1-acyl-cyclododecenes and -cyclododecanes are obtained by a Rupe or Meyer-Schuster rearrangement, with or without subsequent hydrogenation in the presence of Ni, Pd and Pt catalysts. The 1-acyl-cyclododecenes and -cyclododecanes are valuable scents of the basic type of the sought-after macrocyclic musk scents. Furthermore, they are used for the manufacture of numerous other new 1-substituted or 1-and 2-substituted cyclododecenes and cyclododecanes having good scent characteristics.
Type:
Grant
Filed:
December 2, 1981
Date of Patent:
July 12, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Werner Hoffman, Karl von Fraunberg, Manfred Baumann
Abstract: Hydrogenation catalysts which are prepared from mixed crystals of copper-zinc compounds, obtained by precipitation, of the formulaCu.sub.1.5-3 Zn.sub.1-2.5 (CO.sub.3).sub.1-2 (OH).sub.4-6.(H.sub.2 O).sub.0-1by decomposition at 200.degree.-500.degree. C., and are used for the catalytic preparation of propanediols of the formula ##STR1## where the R's may be identical or different and each is an aliphatic, araliphatic or aromatic radical, or the two R's together with the adjacent carbon atom are members of an alicyclic ring, by hydrogenating hydroxypropionaldehydes of the formula ##STR2## where R has the above meanings, and to processes for the preparation of propanediols, using such catalysts. The propane-1,3-diols obtainable by the novel process are valuable starting materials for the preparation of lubricants, plastics, surface coatings and synthetic resins, for example of polyesters derived from the propanediols.
Type:
Grant
Filed:
February 10, 1982
Date of Patent:
July 12, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Franz J. Broecker, Leopold Hupfer, Franz Merger, Ernest Miesen, Juergen Paetsch, Guenter Zirker
Abstract: A synthetic resin is in the form of a metal complex compound. The resin is the reaction product of:(a) Mannich bases which are free from epoxide groups; with(b) epoxide resins;wherein aliphatic hydroxyl groups originating from (a), (b), or a mixture thereof, are at least partially converted into urethane groups by reaction with partially blocked isocyanate, said Mannich bases (a) formed from components selected from:(a.sub.1) condensed phenols which are free from ether groups and contain at least two aromatic rings and at least two phenolic hydroxyl groups;(a.sub.2) condensed phenols which contain ether groups and contain at least two aromatic rings and at least two phenolic hydroxyl groups;(a.sub.5) formaldehyde or compounds which split off formaldehyde;(a.sub.3) secondary amines having at least one hydroxyalkyl group; and(a.sub.4) dialkylamines or dialkoxyalkylamines which do not contain free hydroxyl groups; or from the components:(a.sub.1) and (a.sub.2) with (a.sub.5) and (a.sub.3);(a.sub.1) with (a.sub.
Abstract: In accordance with the instant invention, a water-based hydraulic fluid, having improved low foaming properties can be obtained by blending 2-ethylhexanol with a conventional water-based hydraulic fluid composition.
Type:
Grant
Filed:
April 13, 1981
Date of Patent:
July 5, 1983
Assignee:
BASF Wyandotte Corporation
Inventors:
Ellen S. Schwartz, Cline A. Tincher, Jerrold F. Maxwell
Abstract: A process for the preparation of polyisobutylene by polymerizing isobutylene in a polymerization zone which is at from 0.degree. to -130.degree. C., by means of from 0.01 to 1.0 percent by weight of boron trifluoride catalyst, in the presence of a primary or secondary alcohol as polymerization accelerator and in the presence of from 30 to 90% by weight of a low-boiling solvent which is inert under the reaction conditions, wherein the solvent vaporized during the polymerization is continuously drawn off, liquefied and recycled, in the liquid state, to the polymerization zone, and wherein the boron trifluoride catalyst used contains less than 0.3, in particular less than 0.01, percent by volume of silicon tetrafluoride and the solvent, which is preferably ethylene, is recycled not less than twice but not more than 36 times during the continuous polymerization.
Type:
Grant
Filed:
January 22, 1982
Date of Patent:
July 5, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Karl-Heinz Fauth, Heinrich Mohr, Wolfgang Immel
Abstract: The subject invention relates to polyol compositions comprising the reaction product prepared by reacting from 4 to 9 moles of propylene oxide per mole of toluenediamine by weight at temperatures greater than 140.degree. C. in the presence of at least 0.6 parts of alkali metal hydroxide per 100 parts by weight of toluenediamine, with the proviso that at least 0.8 part by weight of alkali metal hydroxide is used if the toluenediamine is 2,4-toluenediamine, or 2,6-toluenediamine, or mixtures thereof.
Type:
Grant
Filed:
December 1, 1981
Date of Patent:
July 5, 1983
Assignee:
BASF Wyandotte Corporation
Inventors:
Alexander Korczak, William W. Levis, Jr.
Abstract: In accordance with the instant invention, a water-based hydraulic fluid, having improved anti-wear and corrosion inhibition properties can be obtained by blending neodecanoic acid with a conventional water-based hydraulic fluid composition.
Abstract: Spray paint lines, in particular the spray sites in spray booths of auto assembly lines, are provided with the paint material by means of a pump delivering the paint material into the main ring. The pressure level required for spraying the paint is adjusted by means of a pressurized vessel and a pressurized gas above the liquid level. A second pump conveys fresh paint material into the pressurized vessel.
Type:
Grant
Filed:
May 30, 1980
Date of Patent:
June 28, 1983
Assignee:
BASF Farben & Fasern A.G.
Inventors:
Hagen Buchholz, Hans-Dieter Johannsmeier, Friedrich Vock
Abstract: Mineral tanned leather is frequently retanned with synthetic tanning agents to improve the fullness and softness, but leather retanned by the prior art methods is difficult to dye in full shades with anionic dyes. According to the invention, condensation products of C.sub.1-4 aldehydes with certain aromatic sulfonic acids or carboxylic acids containing amino groups are employed for retanning, thereby improving the receptivity of the leather for anionic dyes. These acids have the general formula ##STR1## where X and X' are independently H, --CH.sub.2 --SO.sub.3 H or --CH.sub.2 --OH, A is a benzene radical, Y and Z are independently H, --SO.sub.3 H or --CO.sub.2 H, R is H or C.sub.1-4 -alkyl and n is from 0 to 10, with the proviso that at least one sulfonic acid or carboxyl group is present in the molecule.
Abstract: In accordance with the instant invention, a water-based hydraulic fluid, having improved viscosity can be obtained by blending a carboxylic acid with a thickened hydraulic fluid composition employing a thickener obtained by modifying a conventional polyether polyol thickening agent with an alpha-olefin epoxide or glycidyl ether having about 10 to 24 carbon atoms or mixtures thereof. Small amounts of higher molecular weight glycols may also be incorporated into the chain.
Abstract: Corrosion inhibited alcohol compositions can be prepared which are suitable for use as anti-freeze compositions in the cooling systems of internal combustion engines. The alcohol is selected from at least one of the group consisting of methanol, ethanol, propanol, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol and glycerol. The corrosion inhibitor comprises an effective amount of a conventional corrosion inhibitor selected from the group consisting of the alkali metal carbonates, borax, the alkali metal dichromates, the alkali metal silicates, phosphorous acid, phosphoric acid, an alkali metal tungstate, benzotriazole, tolyltriazole, an alkali metal salt of benzoic or toluic acid, an alkali metal salt of a phenol, an alkanolamine and an organo-silicone compound in addition to an alkanolamine phosphate and a heterocyclic nitrogen-containing compound. The phosphate is the reaction product of an alkanolamine and phosphoric acid.
Type:
Grant
Filed:
July 8, 1981
Date of Patent:
June 21, 1983
Assignee:
BASF Wyandotte Corporation
Inventors:
Joe C. Wilson, Stephen E. Eisenstein, Jerrold F. Maxwell, Stanley T. Hirozawa
Abstract: Navy dye mixtures which contain, as essential components, compounds of the general formula I ##STR1## in the following amounts, based on the total weight of the mixture:______________________________________ X = Br R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = CH.sub.2 CHCH.sub.2 39-49%, X = Br R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = H 1-10%, X = Br R.sup.1 = H R.sup.2 = CH.sub.2 CHCH.sub.2 4-16%, X = Cl R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = H 15-25%, X = Cl R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = CH.sub.2 CHCH.sub.2 4-9%, and X = Cl ##STR2## R.sup.2 = H 4-10%. ______________________________________The novel mixtures are very useful for dyeing synthetic polyesters.
Type:
Grant
Filed:
March 5, 1982
Date of Patent:
June 21, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Udo Bergmann, Helmut Degen, Guenter Hansen, Reinhold Krallmann, Wolf-Dieter Kermer
Abstract: An electrophotographic recording medium which consists essentially of an electrically conductive base and a photosemiconductive double layer which comprises a first layer containing charge carrier-producing dyes, and a second layer containing one or more compounds which are charge carrier-transporting when exposed to light, wherein the charge carrier-producing dyes are those of the general formula ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each hydrogen or a non-ionic substituent, X is the radical of a methyleneactive compound, or of an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic amine or hydrazine, and Z is hydrogen, methyl or phenyl, and the production of this recording medium.
Abstract: The invention relates to the preparation of molded polyurethane parts having a lightfast polyurethane skin. The skin is formed by applying a reaction mixture comprising an organic polyisocyanate, a polyol, a chain extender, an aliphatic primary or secondary aliphatic diamine, and a catalyst, by a one-shot process in the absence of solvents, to the inside wall of the molding tool.The molded parts produced in accordance with this invention are used, for instance, in the automobile industry for the inside equipment of vehicles. Specifically, they may be used as cover plates for steering wheels and for lining doors. They may also be used for external equipment such as bumpers, headlight housings, and may be used in the electrical industry as housing elements.
Type:
Grant
Filed:
April 8, 1981
Date of Patent:
June 21, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Heinrich Horacek, Matthias Marx, Dietmar Hobein
Abstract: 1-Aroyl-2-phenylamino-2-imidazolines of the general formula ##STR1## where R.sup.1 and R.sup.2 are identical or different and each is chlorine, bromine, fluorine, methyl, ethyl, methoxy, trifluoromethyl or cyano,R.sup.3 has the meanings given for R.sup.1 and R.sup.2 or is hydrogen andAr is an unsubstituted or substituted monocyclic or bicyclic heteroaromatic radical containing 1, 2 or 3 nitrogen and/or oxygen and/or sulfur atoms, their salts with physiologically tolerated acids, their preparation, and drugs containing these compounds.The compounds have, inter alia, a blood pressure-reducing action.
Type:
Grant
Filed:
March 3, 1981
Date of Patent:
June 21, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans-Joachim May, Dieter Lenke, Josef Gries, Hans-Juergen Teschendorf, Wolfgang Worstmann
Abstract: The subject invention relates to corrosion inhibitors prepared by reacting certain imidazolines or precursors thereof with sulfur. The corrosion inhibitors are particularly useful in inhibiting corrosion of metal tanks caused by CO.sub.2 and H.sub.2 S ("acid gas") during the transport and storage of crude oils.
Type:
Grant
Filed:
February 26, 1982
Date of Patent:
June 14, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Knut Oppenlaender, Karl Stork, Klaus Barthold
Abstract: There is provided a process for preparing a microcellular foam with improved green strength properties comprising the step of reacting an organic polyisocyanate with polyalkylene ether polyol and from 1 to about 35 parts (by weight, per hundred parts of said polyol) of a chain extender in the presence of from about 0.1 to about 10.0 parts (by weight, per hundred parts of said polyol) of a compound selected from the group consisting of: ##STR1## wherein: (a) said polyol has an average functionality of from about 2 to about 8 and an average equivalent weight of from about 1000 to about 2700, and from about 0.8 to about 1.2 equivalents of said polyol are reacted per equivalent of isocyanate;(b) R is a divalent alkylene radical containing from about 1 to about 4 carbon atoms; and(c) R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently selected from the group consisting of hydroxyalkyl containing from about 1 to about 4 carbon atoms and from about 1 to about 2 hydroxyl groups.
Abstract: Concentrates of from 20 to 50% by weight of titanium dioxide in polycaprolactam are produced by a process in which a 5-15% strength by weight aqueous suspension of titanium dioxide is metered into a solution of caprolactam in water at from 100.degree. to 150.degree. C. at the same rate at which water is distilled off, and after the water has been distilled off the resulting mixture is polymerized at from 240.degree. to 280.degree. C.
Type:
Grant
Filed:
June 4, 1982
Date of Patent:
June 14, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Hugo Strehler, Werner Hoerauf, Guenter Valentin
Abstract: The invention relates to corrosion inhibitors which are amides of cyclic amidines. The inhibitors are particularly useful for preventing the corrosion of metals caused by H.sub.2 S and CO.sub.2 in water-in-oil, particularly in saltwater-in-oil emulsions.
Type:
Grant
Filed:
February 26, 1982
Date of Patent:
June 14, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Knut Oppenlaender, Karl Stork, Klaus Barthold