Abstract: Stable materials, such as films of fluorinated ethylene-propylene copolymers, are bonded to synthetic resinous cell frames with a cyanoacrylate adhesive. The so-covered frames are optimally employed in bipolar electrolytic filter press cells.
Abstract: A process for the continuous manufacture of vinylpyrrolidone polymers of low K values, wherein vinylpyrrolidone, with or without comonomers copolymerizable therewith, is polymerized in organic solvents at elevated temperatures and superatmospheric pressures in the presence of a source of free radicals.
Type:
Grant
Filed:
November 17, 1975
Date of Patent:
October 11, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Karl Herrle, Hermann Gausepohl, Wolfgang Schwarz
Abstract: Liquid and solid compositions are provided for souring and imparting softness to freshly laundered textile meterials. When in the form of a stable homogeneous liquid, the composition may contain (a) a quaternized fatty amide, an aqueous emulsion of partially oxidized polyethylene or a fatty amphoteric compound as the siftening agent, (b) hydrofluorosilicic acid, ammonium silicofluoride, zinc silicofluoride, ammonium acid fluoride, potassium acid fluoride, or orthophosphoric acid as the souring agent, and (c) water. When in the form of a stable dry solid, the composition may contain (a) a quaternized fatty amide or fatty amphoteric compound as the softening agent, and (b) ammonium silicofluoride, potassium silicofluoride, sodium silicofluoride, zinc silicofluroide, ammonium acid fluoride, sodium acid fluoride or potassium acid fluoride. A method of preparing the liquid composition is provided which insures that it remains stable and homogeneous while awaiting use.
Type:
Grant
Filed:
January 30, 1975
Date of Patent:
October 11, 1977
Assignee:
BASF Wyandotte Corporation
Inventors:
John D. Ciko, John J. Cramer, Geoffrey A. Jamieson
Abstract: An oxyalkylated product useful for making polyurethane foams is prepared by reacting an alkylene oxide with a heated mixture of a phenol and a non-phenolic active hydrogen compound, at least one of which can be halogenated, in the presence of a catalyst complex of a phenol and an iron or aluminum substance. The mixture can also include a neutral phosphorus compound and/or acid anhydrides to enhance flame retardant properties. Optionally, also, the oxyalkylation reaction can be terminated by adding a tri (lower alkyl) amine and alkylene oxide to react with residual phenolic hydrogen in the mixture.
Type:
Grant
Filed:
June 25, 1975
Date of Patent:
October 4, 1977
Assignee:
BASF Wyandotte Corporation
Inventors:
Arthur L. Austin, William W. Levis, Jr., Louis C. Pizzini, Robert J. Hartman
Abstract: A monoazo dye or pigment of the formula: ##STR1## in which D is the radical of the diazo component, preferably a diazotized compound of the aminoanthraquinone, aminophthalimide or aniline series;X is --NH or a direct bond; andY is --NH, --CONH, --NHCO or a direct bond; andWherein the rings A and B may contain from one to three substituents such as chloro, bromo, methyl, ethyl, methoxy, ethoxy, cyano, nitro, alkoxycarbonyl, trifluoromethyl, methylsulfonyl and optionally N-substituted carbamoyl or sulfamoyl radicals. The dyes or pigments are eminently suitable for coloring for example printing inks, surface coatings and resins because of their color strength and very good fastness properties.
Abstract: The azo dye of the formula ##STR1## is a brilliantly red pigment which imparts lightfast and migration resistant color to printing inks, plastics, and the like.
Type:
Grant
Filed:
January 21, 1976
Date of Patent:
October 4, 1977
Assignee:
BASF Farben + Fasern AG
Inventors:
Leonhard Heckl, Egon Liedek, Wolfgang Ruff
Abstract: In the oxidation of .alpha.-olefins in the gas phase to .alpha.,.beta.-olefinically unsaturated aldehydes and carboxylic acids with molecular oxygen in the presence of an inert gas using a catalyst containing molybdenum and bismuth with elements as oxides or mixed oxides at from 280.degree. to 450.degree. C a content of indium and/or aluminum and/or lanthanum and/or gallium as oxide or mixed oxide results in an improvement in the conversion and/or activity and/or life of the catalyst.
Type:
Grant
Filed:
October 10, 1973
Date of Patent:
October 4, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Richard Krabetz, Heinz Engelbach, Ulrich Lebert, Walter Frey, Gerd Duembgen, Fritz Thiessen, Carl-Heinz Willersinn
Abstract: Special quaternary ammonium salts derived from triaminoalkyl derivatives of hexahydrotriazine for use as retarders in the dyeing of anionic polyacrylonitrile fibers with basic dyes.
Type:
Grant
Filed:
July 6, 1976
Date of Patent:
October 4, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Ernst Fuerst, Jozsef Gerendas, Rudolf Rokohl, Rolf Fikentscher, Herbert Helfert
Abstract: Compounds of the formula: ##STR1## WHICH ARE EMINENTLY SUITABLE FOR DYEING NATURAL AND SYNTHETIC POLYAMIDES AND FOR COLORING SURFACE COATINGS. Dyeings on textile material are distinguished by very good lightfastness and very good fastness to wet treatments, for example fastness to water, perspiration, sea water and washing.
Abstract: New diazarhodamine-lactones of the formula ##STR1## where R.sup.1 is hydrogen or alkyl of 1 to 4 carbon atoms, R.sup.2 is alkyl of 1 to 4 carbon atoms, unsubstituted phenyl or phenyl substituted by one or two alkyls of 1 to 3 carbon atoms, chlorine and/or bromine, R.sup.3 and R.sup.4 independently of one another are hydrogen, alkyl of 1 to 7 carbon atoms, cycloalkyl of 5 to 7 carbon atoms, phenylalkyl of 7 to 10 carbon atoms or alkoxyalkyl of a total of 3 to 8 carbon atoms, or the group ##STR2## is a 5-membered, 6-membered or 7-membered saturated heterocyclic ring or a 6-membered saturated heterocyclic ring which additionally contains an --O--, --S-- or --N--group, wherein R.sup.6 is hydrogen, methyl or ethyl and R.sup.5 is unsubstituted phenyl or phenyl substituted by alkyl of 1 to 3 carbon atoms, methoxy, chlorine or bromine.The lactones (I) exhibit improved stability and therefore do not stain coated paper.
Abstract: Aziridinocarboxylic acid esters of polyols are manufactured by trans-esterification of the corresponding esters of lower alcohols, using magnesium oxide or calcium oxide as the trans-esterification catalyst; this method gives a higher yield and a purer product.
Type:
Grant
Filed:
April 13, 1976
Date of Patent:
October 4, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Toni Dockner, Albrecht Wallis, Rolf Fikentscher, Rainer Thomas, Reinhard Herzog
Abstract: A process for the manufacture of ##STR1## where R and A are identical or different and each is alky of 1 to 4 carbon atoms, by oxidation of ##STR2## with air, oxygen or mixtures thereof, in an acid medium at a pH of from 1.5 to 5.5, at from 30.degree. to 150.degree. C. The reaction takes place rapidly and gives a good yield of the lactone (I), which can be freed from residual (II) by a treatment with alkali. The compound (I) is used as a dye intermediate in no-carbon copying systems.
Abstract: A process for the manufacture of acicular .gamma.-iron(III) oxide of improved crystallinity and high coercive force by heating goethite or acicular alpha-iron(III) oxide particles at temperatures of from 500.degree. to 800.degree. C, reduction of the resulting product at temperatures of from 280.degree. to 600.degree. C and subsequent oxidation of the magnetite to .gamma.-iron(III) oxide of improved crystallinity and high coercive force.
Abstract: Dyes of the formula: ##STR1## in which D is the radical of a diazo component;R.sup.1 is hydrogen, chloro, bromo, methoxy or ethoxy;R.sup.2 and R.sup.3 independently of one another are hydrogen, chloro, bromo, methyl, ethyl, trifluoromethyl, nitro, methylsulfonyl, ethylsulfonyl, phenylsulfonyl, unsubstituted or N-substituted carbamoyl or sulfamoyl, carboxylic ester, unsubstituted or substituted C-acylamino or phthalimidyl; orR.sup.2 and R.sup.3 together form a radical of the formula: ##STR2## The dyes are eminently suitable for coloring printing inks, surface coatings and resins with excellent fastness properties.
Abstract: Rigid cellular foams are prepared by catalytically condensing an organic polyisocyanate in the presence of (a) a carbodiimide-promoting catalyst, (b) a trimerization catalyst, (c) a urethane catalyst, and (d) from 10 parts to 40 parts per 100 parts of polyisocyanate of a polyol mixture comprising (1) from 5 parts to 30 parts of a polyoxyethylated polyhydric alcohol and (2) from 5 parts to 25 parts of a polyoxyethylated phosphate polyol.
Abstract: Mixtures based on vinyl chloride polymers and small amounts of a copolymer of an ester of acrylic acid or methacrylic acid. The said copolymer contains acrylic acid ester or methacrylic acid ester units, units which contain a lactone ring structure, and, optionally, units of other copolymerizable monomers. The mixtures exhibit improved processability and may in particular be used for the manufacture of films, sheets and the like.
Type:
Grant
Filed:
July 6, 1976
Date of Patent:
September 27, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Petr Simak, Karl Herrle, Franz Haaf, Guenter Hatzmann
Abstract: Shear-resistant aqueous copolymer emulsions which can be used for sizing paper are manufactured by first copolymerizing, in the aqueous phase of an aqueous emulsion, using conventional polymerization initiators which form free radicals, (A) from 0.5 to 15 per cent by weight of monomers containing a polymerizable C.dbd.C bond and at least one carboxyl and/or sulfonic acid or phosphate or phosphite group with (B) from 5 to 30 per cent by weight of monomers containing a C.dbd.C bond and a tertiary or quaternary amino group, or a nitrogen-containing heterocyclic group, and then adding, while continuing the copolymerization, (C) from 0 to 94.5 per cent by weight of styrene and/or acrylonitrile and (D) from 0 to 94.
Type:
Grant
Filed:
October 29, 1975
Date of Patent:
September 27, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Kurt Wendel, Fritz Reichel, Christof Taubitz
Abstract: A cell frame for a bipolar electrolytic filter press cell includes an electrolysis-associated lower section and a gas disengagement or diverting upper section. A pressure bar extends across the cell frame immediately above the lower section to prevent distortion of the separator by cathode generated gases, and to promote disengagement of the gases. The frame, also, includes external headers in the upper section for collection of the gases evolved by the electrolysis of the electrolytic solutions.
Type:
Grant
Filed:
May 19, 1975
Date of Patent:
September 27, 1977
Assignee:
BASF Wyandotte Corporation
Inventors:
Albert John Schweickart, Stephen Michael Collins, John Joseph Bortak
Abstract: A method and circuits for encoding a color video signal for processing, preferably recording and/or playback of said signal within a limited bandwidth of not more than 3MHz without a separate channel for color information such that one half the sum of two sequential horizontal scan lines of information equals the luminance information of the color video signal and one half of the difference of the said two sequential horizontal scan lines of information equals the chrominance information of the color video signal, wherein a first chrominance signal and a second chrominance signal are contained in two non-overlapping frequency regions.
Abstract: A process for the manufacture of acicular ferromagnetic metal pigments containing iron, having a reduced field strength distribution and a steeper residual magnetization curve, by applying equivalent amounts of an alkaline earth metal cation and of a monobasic, dibasic or tribasic aliphatic carboxylic acid of up to 6 carbon atoms onto appropriate acicular iron oxides and then reducing the treated oxides.
Type:
Grant
Filed:
July 14, 1975
Date of Patent:
September 27, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Eberhard Koester, Gerd Wunsch, Eduard Schoenafinger, Henning Schneehage