Abstract: The present invention to a process for preparing 2-alkenals of the formula I in which R1 is selected from hydrogen and C1-C4-alkyl; and R2 is selected from hydrogen, C1-C12-alkyl, C2-C12-alkenyl, C4-C8-cycloalkyl and C6-C10-aryl, wherein C1-C12-alkyl and C1-C12-alkenyl may be substituted with C5-C7-cycloalkyl or C5-C7-cylcoalkenyl; comprising dehydrogenating an alkenol of the formula II, an alkenol of the formula III or a mixture thereof, wherein R1 and R2 are each as defined above, wherein the alkenol II, the alkenol III or a mixture thereof is brought into contact with a catalytic system comprising at least one ligand and a metal compound selected from ruthenium(II) compounds and iridium(I) compounds, and wherein the hydrogen formed during the dehydrogenation is removed from the reaction mixture by: v) reaction with a reoxidant selected from C3-C12-alkanones, C4-C9-cycoalkanones, benzaldehyde and mixtures thereof; and/or vi) purely physical means.
Type:
Grant
Filed:
November 23, 2012
Date of Patent:
April 7, 2015
Assignee:
BASF SE
Inventors:
Thomas Schaub, Bernhard Brunner, Klaus Ebel, Rocco Paciello
Abstract: The present invention relates to separators for electrochemical cells comprising (A) at least one layer comprising (a) crosslinked polyvinylpyrrolidone in the form of particles, (b) at least one binder, and (c) optionally a base structure, where the mass ratio of the crosslinked polyvinylpyrrolidone in the form of particles (a) to the sum of the mass of the binders (b) in the layer (A) has a value in the range from 99.9:0.1 to 50:50. The present invention further relates to the use of inventive separators and to apparatuses, especially electrochemical cells, comprising inventive separators.
Type:
Grant
Filed:
February 25, 2013
Date of Patent:
April 7, 2015
Assignees:
BASF SE, Carl Freudenberg KG
Inventors:
Oliver Gronwald, Klaus Leitner, Nicole Janssen, Christoph J. Weber, Michael Roth, Gunter Hauber, Sandra Falusi, Sigrid Geiger, Margitta Berg
Abstract: A process for producing porous structures from polyamide by dissolving the polyamide in an ionic liquid and precipitating or coagulating the dissolved polyamide by contacting the solution with a liquid precipitant medium. Fibers are produced from the dissolved polyamide in a wet-spinning process by precipitation in protic solvents, in particular water, a C1-4-alkanol or mixtures thereof, and subsequent freeze-drying. Foils, films or coatings are produced by blade coating the dissolved polyamide onto a substrate surface, optionally spraying with protic solvent, in particular water, a C1-4-alcohol or mixtures thereof, dipping into a precipitation or coagulation bath, freeze-drying of the resulting foil, of the film or of the coated substrate. Molded parts are prepared by extracting the dissolved polyamide with protic solvents, preferably water, a C1-4-alcohol or mixtures thereof, wherein the dissolved polymer is transformed to a solid or wax-like state by cooling and extracted after subsequent molding.
Type:
Grant
Filed:
February 11, 2009
Date of Patent:
April 7, 2015
Assignee:
BASF SE
Inventors:
Stefan Schwiegk, Axel Wilms, Ronald Frans Maria Lange, Michael Siemer, Giovanni D'Andola, Volker Rauschenberger, Frank Hermanutz, Frank Gaehr, Julien Courtois, Dirk Gerhard
Abstract: The present invention relates to aqueous insecticidal preparations in the form of an aqueous dispersion of finely divided polymer particles which comprise at least one insecticidal organic active ingredient with a solubility in water of not more than 5 g/l at 25° C. at 1013 mbar and which have a mean particle size, determined by dynamic light scattering, of not more than 300 nm, where the polymer particles which comprise the at least one insecticidal active ingredient of a cationic surface charge and where the aqueous dispersion of the active-ingredient-comprising polymer particles is obtainable by subjecting a monomer composition of ethylenically unsaturated monomers M, in which the ethylenically unsaturated monomers M comprise the at least one insecticidal active ingredient in dissolved form, to radical aqueous emulsion polymerization.
Type:
Grant
Filed:
March 8, 2006
Date of Patent:
April 7, 2015
Assignee:
BASF Aktiengesellschaft
Inventors:
Patrick Amrhein, Gunnar Kleist, Dirk Haentzschel, Joerg Habicht, Holger Schöpke
Abstract: The use of a composition which is liquid under standard conditions (20° C., 1 bar) as a coating material, wherein the composition comprises a) an unsaturated polyester resin composed of ?-olefinically unsaturated polycarboxylic acids, polyols, and optionally further compounds, b) compounds with vinyl ether groups (vinyl ethers for short), and c) optionally ?-olefinically unsaturated polycarboxylic acids or their monoesters or diesters, where the sum of the double bonds of the ?-olefinically unsaturated polycarboxylic acids from a) and optionally of the compounds c) to the double bonds of the vinyl ethers b) is in a molar ratio of 1.3:1 to 0.8:1.
Type:
Grant
Filed:
August 16, 2010
Date of Patent:
April 7, 2015
Assignee:
BASF SE
Inventors:
Matthias Fies, Ulrich Poth, Oliver Seewald, Wolfgang Bremser
Abstract: A process for coproducing di- and/or polyisocyanates and glycols, comprising process stages A, B, C and E for preparing glycols and process stages A, C, D, E, F and G for preparing di- and/or polyisocyanates, which comprises accomplishing the material coupling via the separation of the reaction mixture obtained in process stage A into process stages B and C, by in process stage A, reacting an aqueous alkylene oxide with carbon dioxide to give a reaction mixture comprising alkylene carbonate, hydrolyzing a portion of the alkylene carbonate-comprising reaction mixture obtained in process stage A to glycol in process stage B, dewatering the remaining alkylene carbonate-comprising stream of the reaction mixture from process stage A in process stage C, in process stage D, synthesizing amine by hydrogenating an aromatic nitro compound or a nitrile, in process stage E, transesterifying the dewatered alkylene carbonate-comprising mixture from process stage C with a monohydroxy alcohol to give the corresponding dia
Type:
Grant
Filed:
October 27, 2010
Date of Patent:
April 7, 2015
Assignee:
BASF SE
Inventors:
Michael Bock, Robert Baumann, Axel Franzke, Eckhard Stroefer, Gerhard Theis
Abstract: The present application relates to a process for preparing secondary amines by aminating excess primary or secondary alcohols with primary amines in the liquid phase in the presence of copper-comprising catalysts.
Type:
Grant
Filed:
January 9, 2013
Date of Patent:
April 7, 2015
Assignee:
BASF SE
Inventors:
Christof Wilhelm Wigbers, Johann-Peter Melder, Bernd Stein
Abstract: The present invention relates to new condensation resins formed from urea, formaldehyde and CH-acidic aldehydes, to processes for preparing them, and to use thereof.
Type:
Grant
Filed:
July 13, 2010
Date of Patent:
April 7, 2015
Assignee:
BASF SE
Inventors:
Stefan Meuer, Klaus Menzel, Guenter Scherr
Abstract: The present invention relates to odor-inhibiting compositions comprising water-absorbing polymer particles and metal peroxides, and to the production thereof.
Type:
Application
Filed:
December 8, 2014
Publication date:
April 2, 2015
Applicant:
BASF SE
Inventors:
Volker Braig, Thomas Daniel, Rupert Kohradi, Herbert Platsch, Bettina Sobotka, Axel Jentzsch
Abstract: The present application relates to a process for the preparation of compounds of general formula (I) Lia?bM1bFe1?cM2cPd?eM3eOx??(I), wherein M1, M2, M3, a, b, c, d, e and x: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, a: 0.8-1.9, b: 0-0.3, c: 0-0.9, d: 0.8-1.9, e: 0-0.5, x: 1.
Type:
Application
Filed:
December 8, 2014
Publication date:
April 2, 2015
Applicant:
BASF SE
Inventors:
Hartmut HIBST, Brian Roberts, Jordan Keith Lampert, Kirill Bramnik
Abstract: The present invention relates to encapsulated phthalocyanine particles, to a process for the preparation thereof, compositions comprising such particles and washing agent formulations. The encapsulated phthalocyanine particles comprise a) at least one water-soluble phthalocyanine compound, and b) gelatine having a bloom strength of 2 to 80 as encapsulating material.
Type:
Application
Filed:
April 24, 2013
Publication date:
April 2, 2015
Applicant:
BASF SE
Inventors:
Stefan Bruhns, Gunther Schlingloff, Ullrich Menge, Frank Bachmann, Andreas Lindenmaier
Abstract: The present invention relates to a method for extracting buds 8 from a stalk 1 of a graminaceous plant. The method comprises the steps of obtaining at least one stalk half 7 by cutting the stalk 1 in longitudinal direction L of the stalk 1, automatically detecting a bud 8 on the stalk half 7 and cutting out a vegetal tissue comprising the bud 8 based on the detected position of the bud 8. Furthermore, the invention relates to a system for carrying out this method as well as the use of this system for extracting buds 8 from a stalk 1 of a graminaceous plant.
Type:
Application
Filed:
April 22, 2013
Publication date:
April 2, 2015
Applicant:
BASF SE
Inventors:
Harald Rödel, Cassio da Silva Cardoso Teixeira, Antonio Cesar Azenha, Efraim Albrecht Neto, Domingos Guilherme Pellegrino Cerri
Abstract: A method and an apparatus for forming a surface relief microstructure, especially an optically variable image on a paper substrate are provided, the method comprising the steps of: A) applying a curable composition to at least a portion of the frontside of the paper substrate; B) contacting at least a portion of the curable composition with surface relief microstructure, especially optically variable image forming means; C) curing the composition by using at least one UV lamp (1, 2, 3) which is arranged on the backside of the paper substrate; D) optionally depositing a layer of a transparent high refractive index material and/or a metallic layer on at least a portion of the cured composition, wherein the lamp (1, 2, 3) having emission peak(s) in the UV-A and near VIS range and the curable composition comprises at least a photoinitiator which absorbs in the UV-A region and preferably in the near VIS range.
Type:
Grant
Filed:
June 20, 2012
Date of Patent:
March 31, 2015
Assignee:
BASF SE
Inventors:
Michelle Richert, Thomas Bolle, Roland Fleury
Abstract: A method for preparing a layered oxide cathode using a two step calcination procedure, wherein the first step includes pre-calcination utilizing a rotary calciner.
Type:
Grant
Filed:
June 24, 2011
Date of Patent:
March 31, 2015
Assignee:
BASF Corporation
Inventors:
Ivan Petrovic, Anthony Thurston, Stephen Sheargold
Abstract: A process for preparing phosgene by reaction of a feed stream (1) obtained by combining and mixing a chlorine feed stream (2) and a carbon monoxide feed stream (3), with the carbon monoxide being introduced in a stoichiometric excess over chlorine, in catalyst tubes filled with beds of activated carbon in a reactor R having a bundle of catalyst tubes, to give a product gas mixture (4) which is separated into a liquid, phosgene-comprising product stream (5) and an offgas stream (6) comprising carbon monoxide which is discharged via a pressure-regulating valve, where the reaction of the feed stream (1) in the reactor R and the separation of the product gas mixture (4) are carried out under a pressure in the range from 2.0 to 6.
Type:
Grant
Filed:
March 10, 2010
Date of Patent:
March 31, 2015
Assignee:
BASF SE
Inventors:
Gerhard Olbert, Kai Thiele, Byoung-Yeon Kim, Heiner Schelling
Abstract: The invention relates to a copolymer of (a) 5 to 40% by weight of isoprenol, (b) 5 to 93% by weight of at least one monoethylenically unsaturated C3 to C8 monocarboxylic acid, an anhydride or salt of same, (c) 2 to 90% by weight of one or more sulfonic acid group-comprising monomers.
Type:
Grant
Filed:
July 10, 2012
Date of Patent:
March 31, 2015
Assignee:
BASF SE
Inventors:
Torben Gädt, Jürgen Detering, Stephan Nied
Abstract: A color filter comprising a cured layer of a photosensitive resist composition comprising a highly reactive polyacrylate monomer and an alkali soluble binder having a side chain containing an ethylenically unsaturated bond in the side chain and a process for the preparation thereof are provided. The color filter is especially useful for low temperature applications such as electrophoretic displays, polymer dispersed liquid crystal displays, OLED devices and the like.
Type:
Grant
Filed:
May 2, 2011
Date of Patent:
March 31, 2015
Assignee:
BASF SE
Inventors:
Gerardus De Keyzer, Liliana Craciun, Michael Kuepfert, Frank Oliver Heinrich Pirrung
Abstract: A transgenic crop plant transformed by a Serine Hydroxymethyltransferase-Like Stress-Related Polypeptide (SHSRP) coding nucleic acid, wherein expression of the nucleic acid sequence in the crop plant results in the plant's increased root growth, and/or increased yield, and/or increased tolerance to environmental stress as compared to a wild type variety of the plant. Also provided are agricultural products, including seeds, produced by the transgenic crop plants. Also provided are isolated novel SHSRPs, and isolated novel nucleic acids encoding SHSRPs, and vectors and transgenic plant containing the same.
Type:
Grant
Filed:
September 28, 2012
Date of Patent:
March 31, 2015
Assignee:
BASF Plant Science GmbH
Inventors:
Rodrigo Sarria-Millan, Eric Garr, Jamie Susan Haertel, Damian Allen, Bryan D. McKersie
Abstract: The invention relates to a method for producing and using a solid sodium diformate having a high formic acid content, to the use thereof in animal foods in the form of an acidifier, preservatives, ensilage auxiliary agents, fertilizers, and a growth and productivity-stimulating agent and the inventive animal food additives containing sodium diformate.
Type:
Grant
Filed:
June 20, 2013
Date of Patent:
March 31, 2015
Assignee:
BASF SE
Inventors:
Robert Heinz, Otto Machhammer, Stefan Gropp, Alexander Hauk, Gerd Diebold, Anna Valeska Lohmann, Dieter Feuerstein, Robert Rühle, Rüdiger Schmitt