Abstract: Described is a process for lightening or partially decolorizing vat- or sulfur-dyed textile materials, which comprises treating the material with aminoalkanesulfinic acids in a neutral or weakly acidic medium, and preparations of the aminoalkanesulfinic acids for carrying out this process.
Type:
Grant
Filed:
August 23, 2000
Date of Patent:
May 10, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Reinhard Schneider, Peter Maier, Eberhard Beckmann, Ulrich Karl
Abstract: The present invention defines a one-component low color clearcoat curable under ultraviolet (UV) light, a method for obtaining low color and good weather durability in a clearcoat coating composition and a method for obtaining a coated substrate with a low color clearcoat. When the composition is applied and cured with sufficient exposure to UV radiation, a low color clearcoat providing a hard coating, resistant to chemicals and weathering is obtained.
Abstract: A process for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of propene to acrolein, in which the temperature of the fixed catalyst bed is increased over the time and the gas phase partial oxidation is interrupted at least once per calendar year and the gas mixture G consisting of molecular oxygen, inert gas and optionally steam is conducted through the fixed catalyst bed at a temperature of the fixed catalyst bed of from 250 to 550° C.
Type:
Application
Filed:
October 12, 2004
Publication date:
May 5, 2005
Applicant:
BASF Aktiengesellschaft
Inventors:
Martin Dieterle, Jochen Petzoldt, Klaus Muller-Engel
Abstract: A process for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of acrolein to acrylic acid, in which the temperature of the fixed catalyst bed is increased over time and partial oxidation is interrupted and an oxygen-containing gas is conducted through the fixed catalyst bed before the temperature increase is 8° C.
Type:
Application
Filed:
October 13, 2004
Publication date:
May 5, 2005
Applicant:
BASF Aktiengesellschaft
Inventors:
Martin Dieterle, Jochen Petzoldt, Klaus Muller-Engel
Abstract: The invention relates to the use of enaminotriazines of the formula I in which the radicals Y, independently of one another, are hydrogen, an optionally substituted aliphatic, cycloaliphatic, araliphatic or aromatic radical having in each case up to 18 carbon atoms, the radicals X are identical or different, where at least one of the radicals X is the ethenyl radical of the formula II and X may also have the meanings of Y, and where in the formula II the radicals R are identical or different and are cyano, optionally esterified carboxyl, substituted carbonyl, optionally substituted aminocarbonyl, optionally esterified sulfo, substituted sulfonyl or optionally esterified phosphono, and where two adjacent radicals R may optionally form a ring and the radicals R? are identical or different and are hydrogen, an optionally substituted aliphatic, cycloaliphatic or aromatic radical having in each case up to 18 carbon atoms, as UV filters in cosmetic or pharmaceutical preparations for protecting human skin or
Type:
Grant
Filed:
May 13, 2002
Date of Patent:
May 3, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Heidenfelder, Kristin Tiefensee, Thomas Wünsch
Abstract: Ethylene or propylene are copolymerized with one another or with other olefinically unsaturated compounds in the presence of a catalyst system comprising the following components: A) a complex of a transition metal with one or two substituted or unsubstituted 1,3,5-triazacyclohexane ligands or corresponding ligands in which one or more of the ring nitrogens are replaced by phosphorus or arsenic atoms, and B) if desired, one or more activator compounds.
Abstract: A process for preparing 7-(pyrazol-3-yl)benzoxazoles of the formula I in which the variables R1-R6 are as defined in claim 1, which process is characterized in that a 2-halo-3-(pyrazol-3-yl)anilide of the formula II, in which X is bromine or iodine is reacted with a base in the presence of a transition metal compound of subgroup VIIa, VIIIa or Ib of the Periodic Table of the Elements, is disclosed.
Type:
Grant
Filed:
March 15, 2001
Date of Patent:
May 3, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Cyrill Zagar, Robert Reinhard, Michael Puhl, Thorsten Volk, Norbert Götz, Gerhard Hamprecht, Olaf Menke, Ingo Sagasser
Abstract: The invention relates to a fuel cell having a moderate operating temperature which comprises a cathode, an anode and an electrolyte, where at least the cathode comprises a material having the composition (Sr1-xCax)1-yAyMn1-zBzO3-? and A is at least one element from the group consisting of Ba, Pb, Na, K, Y and the lanthanide group, B is at least one element from the group consisting of Mg, Al, Ga, In, Sn and sub-group elements from the 4th, 5th or 6th period, and x adopts values of from 0.2 to 0.8, y adopts values of from 0 to 0.4, z adopts values of from 0 to <1, and ? adopts values which arise taking into account the electroneutrality principle.
Type:
Grant
Filed:
June 26, 2002
Date of Patent:
May 3, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Stefan Bitterlich, Hartwig Voss, Andreas Fischer, Werner Weppner, Ingolf Voigt
Abstract: The use of ?-lipoic acid or ?-dihydrolipoic acid for increasing the bioavailability of mineral salts, the use of ?-lipoic acid or ?-dihydrolipoic acid in combination with metal salts, in particular the use of metal ?-lipoates, metal ?-dihydrolipoates or metal-?-lipoic acid complexes, in particular in mineral preparations or drugs and the metal ?-lipoates, metal ?-dihydrolipoates or metal-?-lipoic acid complexes themselves are described.
Abstract: A hydrogenation catalyst which is suitable, in particular, for the hydrogenation of maleic anhydride and its derivatives to THF or its derivatives comprises copper oxide and at least one further metal or compound thereof, preferably an oxide, selected from the group consisting of Al, Si, Zn, La, Ce, the elements of groups IIIA to VIIIA and the elements of groups IA and IIA and having a pore volume of ?0.01 ml/g for pore diameters of >50 nm and a ratio of the pore volume of macropores having a diameter of >50 nm to the total pore volume for pores having a diameter of >4 nm of >10%.
Type:
Grant
Filed:
December 7, 2001
Date of Patent:
May 3, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Holger Borchert, Stephan Schlitter, Markus Rösch, Rolf-Hartmuth Fischer, Ralf-Thomas Rahn, Alexander Weck
Abstract: A process for working up residues from the preparation of pyrrolidone and/or N-vinylpyrrolidone comprises subjecting the residues to a thermolysis.
Type:
Grant
Filed:
May 10, 2001
Date of Patent:
May 3, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Herbert Helfert, Martin Schmidt-Radde, Gerhard Laqua, Ulrich Eiden, Stephan Scholl, Christoph Übler
Abstract: Propene and, if desired, 1-butene are prepared by a) reacting 1-butene and 2-butene to give propene and 2-pentene in the presence of a metathesis catalyst comprising at least one compound of a metal of transition group VIb, VIIb or VIII of the Periodic Table of the Elements, b) subsequently separating the propene and 2-pentene formed, c) subsequently reacting the 2-pentene with ethene to give propene and 1-butene in the presence of a metathesis catalyst comprising at least one compound of a metal of transition group VIb, VIIb or VIII of the Periodic Table of the Elements, d) subsequently separating the propene and 1-butene formed, e) discharging at least some of the 1-butene formed and/or at least partly isomerizing the 1-butene formed to give 2-butene in the presence of an isomerization catalyst and subsequently returning the undischarged 1-butene and the 2-butene formed together with a part of the C4 fraction not reacted in step a) to step a).
Type:
Grant
Filed:
August 6, 2002
Date of Patent:
May 3, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Schwab, Boris Breitscheidel, Carsten Oost, Ralf Schulz, Michael Schulz
Abstract: A process for producing plasticizers in which a phthalic acid having the CAS Nos. 111381-89-6, 111381-90-9, 111381-91-0, 68515-44-6, 68515-45-7 and 3648-20-7, the formed plasticizers and a method of increasing the plasticity of a plastic product.
Type:
Grant
Filed:
June 13, 2001
Date of Patent:
May 3, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Melanie Brunner, Arnd Böttcher, Boris Breitscheidel, Klaus Halbritter, Jochem Henkelmann, Lucien Thil, Rolf Pinkos
Abstract: A process for painting integrated automobile and commercial vehicle bodies or cabins which comprise plastic parts. The metal parts of the body/cabin are provided with an electrocoat and are integrated with the plastic parts. These plastic parts either already have an electrically conductive aqueous primer coat or an uncured electrically conductive aqueous primer film or are unpainted. Primers are applied to the metal and plastic parts. Atop the primers, a basecoat and a clearcoat are applied.
Type:
Grant
Filed:
August 25, 2000
Date of Patent:
May 3, 2005
Assignee:
BASF Coatings AG
Inventors:
Klaus Arlt, Bernd Mayer, Franz-Josef Wylegalla, Norbert Zdahl
Abstract: In a process for heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid, the starting reaction gas mixture is oxidized at a propene loading of <160 l(STP)/l·h in a first reaction stage over a fixed catalyst bed 1 which is accommodated in two successive reaction zones A, B, and the acrolein-containing product gas mixture of the first reaction stage is subsequently oxidized in a second reaction stage over a fixed catalyst bed 2 which is a accommodated in two successive reaction zones C, D, the highest temperature of the reaction gas mixture within reaction zone A being above the highest temperature of the reaction gas mixture within reaction zone B and the highest temperature of the reaction gas mixture within reaction zone C being above the highest temperature of the reaction gas mixture within reaction zone D.
Type:
Grant
Filed:
March 15, 2004
Date of Patent:
May 3, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Martin Dieterle, Jochen Petzoldt, Klaus Joachim Müller-Engel, Heiko Arnold
Abstract: A thermal separating process for removing a stream containing enriched (meth)acrylic monomers from a mixture containing (meth)acrylic monomers, in which the liquid phases retained in the separating space at high temperature and high (meth)acrylic monomer content are minimized.
Type:
Application
Filed:
July 12, 2004
Publication date:
April 28, 2005
Applicant:
BASF Akiengesellschaft
Inventors:
Bernd Eck, Ulrich Hammon, Klaus Mueller-Engel, Juergen Schroeder, Joachim Thiel, Hans Martan
Abstract: The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF3 and n is 1 or 2.
Type:
Application
Filed:
October 4, 2002
Publication date:
April 28, 2005
Applicant:
BASF Aktiengesellschaft
Inventors:
Michael Bartsch, Robert Baumann, Dagmar Kunsmann-Keitel, Gerd Haderlein, Tim Jungkamp, Marco Altmayer, Wolfgang Siegel, Ferenc Molnar
Abstract: Phosphinites I of the formula 1, 2 or 3 where R1, R2, R4 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that at least one of the groups R1, R2, R4 is not H, R3 is H or methyl X is F, Cl or CF3 n is 0, 1 or 2 can be used as catalysts.
Type:
Application
Filed:
October 4, 2002
Publication date:
April 28, 2005
Applicant:
BASF Aktiengesellschaft
Inventors:
Michael Bartsch, Robert Baumann, Dagmar Kunsmann-Keitel, Gerd Haderlein, Tim Jungkamp, Marco Altmayer, Wolfgang Siegel, Ferenc Molnar
Abstract: Styrene is recovered continuously from a styrene-containing mixture by distillation of the mixture in a cascade of n distillation columns, where (i) a feed stream comprising a stabilizer system is fed into the first column and/or a stabilizer system is introduced into at least one distillation column upstream of the nth distillation column, where the stabiliser system comprises N-oxyl radicals; (ii) a high boiler fraction having a boiling point higher than that of styrene and comprising the stabilizer system accumulates in the bottom of the nth distillation column; (iii) a substream of the high boiler fraction is recirculated and introduced into at least one distillation column upstream of the nth distillation column; (iv) the remainder of the high boiler fraction is discharged from the process.
Abstract: A method comprising: (I) providing a composition; (II) applying the composition to a paper substrate; and (III) forming a paper coating on the paper substrate; wherein the composition comprises a blend of polymers, wherein the blend of polymers comprises a vinyl aromatic-acrylic polymer and a vinyl aromatic-diene polymer, wherein the vinyl aromatic-acrylic polymer comprises a reaction product of vinyl aromatic and an alkyl (meth)acrylate, and the vinyl aromatic-diene polymer comprises a reaction product of vinyl aromatic and a conjugated diene, wherein, based on a solids weight of all polymers in the blend of polymers, the vinyl aromatic-acrylic polymer is present in the blend of polymers in an amount from 50% to about 95% and the vinyl aromatic-diene polymer is present in an amount from about 5% to 50%.
Type:
Grant
Filed:
October 27, 2003
Date of Patent:
April 26, 2005
Assignee:
BASF AG
Inventors:
David L. Abundis, Peter C. Hayes, Ronald E. Hostetler