Patents Assigned to Beijing Research Institute of Chemical Industry China Petroleum & Chemical Corporation
  • Publication number: 20200246781
    Abstract: Disclosed is a composite catalyst, comprising carbon in a continuous phase and Raney alloy particles in a dispersed phase. The Raney alloy particles are dispersed evenly or unevenly in the carbon in a continuous phase, and the carbon in a continuous phase is obtained by carbonizing at least one carbonizable organic substance. The catalyst has good particle strength, high catalytic activity, and good selectivity.
    Type: Application
    Filed: April 20, 2020
    Publication date: August 6, 2020
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute Of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Wei Dai, Shuliang Lu, Haibin Jiang, Guoqing Wang, Xiaohong Zhang, Hui Peng, Jinliang Qiao
  • Patent number: 10662268
    Abstract: Disclosed is a catalyst component for olefin polymerization. The catalyst component comprises magnesium, titanium, halogen and an internal electron donor. The internal electron donor includes an imine compound with a ketone group as shown in Formula I. Disclosed further is a method of preparing the catalyst component, and a catalyst for olefin polymerization containing the catalyst component. When the catalyst is used in olefin polymerization reaction especially propene polymerization reaction, the catalyst has a high long-term activity and good hydrogen response, and the obtained polymer has characteristics of an adjustable isotactic index and a relatively wide molecular weight distribution.
    Type: Grant
    Filed: September 22, 2017
    Date of Patent: May 26, 2020
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Jun Wang, Mingzhi Gao, Jing Ma, Haitao Liu, Jianhua Chen, Xiaoxia Cai, Jixing Ma, Jianjun Hu, Changxiu Li, Zhihui Zhang, Changyou Ma
  • Patent number: 10662308
    Abstract: The invention relates to a flame-retardant thermoplastic material, comprising thermoplastic base resin, a flame retardant, and an optional antioxidant, wherein the flame retardant comprises a complex of phosphine oxide and a transition metal salt. The invention also relates to flame-retardant thermoplastic expanded beads. A foam molding prepared from the flame-retardant thermoplastic expanded beads has good flame-retardant and antistatic properties, has excellent mechanical properties and is widely used.
    Type: Grant
    Filed: April 28, 2017
    Date of Patent: May 26, 2020
    Assignees: China Petroleum & Chamical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Peng Guo, Mingfu Lyu, Yaohui Xu, Shijun Zhang, Hui Quan, Kai Xu, Fuyong Bi, Wenbo Song
  • Patent number: 10661254
    Abstract: Disclosed is a composite catalyst, comprising carbon in a continuous phase and Raney alloy particles in a dispersed phase. The Raney alloy particles are dispersed evenly or unevenly in the carbon in a continuous phase, and the carbon in a continuous phase is obtained by carbonizing at least one carbonizable organic substance. The catalyst has good particle strength, high catalytic activity, and good selectivity.
    Type: Grant
    Filed: September 6, 2016
    Date of Patent: May 26, 2020
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Wei Dai, Shuliang Lu, Haibin Jiang, Guoqing Wang, Xiaohong Zhang, Hui Peng, Jinliang Qiao
  • Publication number: 20190270882
    Abstract: A polyester composition includes a first polyester selected from one or more of aliphatic-aromatic copolyesters, which is a copolymer comprising repeating units A as shown in formula (I) and repeating units B as shown in formula (II), in which m is an integer of 2 to 10 and n is an integer of 2 to 8; p is an integer of 2 to 10; and m, n and p are the same or different from each other. Optionally, the polyester composition has a second polyester. The polyester composition includes at least two polyesters. The polyester composition can be used in shape memory materials, 3D print wires, heat shrinkable sleeves, functional layers, medical limb immobilization braces, heat shrinkable thin films, nonwoven fabrics, elastic fibers, etc.
    Type: Application
    Filed: October 20, 2017
    Publication date: September 5, 2019
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Cui ZHENG, Guixiang ZHU, Lizhi LIU, Wei ZHANG, Xuerong YAO, Minqiao REN, Ling HAN, Yi REN, Nan CHEN, Ying SHI
  • Publication number: 20190264022
    Abstract: A polyester composition includes polybutylene terephthalate and an aliphatic-aromatic copolyester. Based on the total weight of the polybutylene terephthalate and the aliphatic-aromatic copolyester, the content of the polybutylene terephthalate is from 50 to 99% by weight, and the content of the aliphatic-aromatic copolyester is from 1 to 50% by weight. Further, a method for preparing such a polyester composition and a toughened composite material prepared therefrom. The polyester composition has an elongation at break of up to 230% or more, and an improved toughness without substantial loss of strength.
    Type: Application
    Filed: October 20, 2017
    Publication date: August 29, 2019
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Cui ZHENG, Guixiang ZHU, Lizhi LIU, Wei ZHANG
  • Patent number: 10239969
    Abstract: A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001 to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.
    Type: Grant
    Filed: October 13, 2016
    Date of Patent: March 26, 2019
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xianzhi Xia, Yuexiang Liu, Jigui Zhang, Xinsheng Wang, Ping Gao, Suzhen Qiao, Maoping Yin, Weili Li, Tianyi Zhang, Renqi Peng, Ying Chen, Zhihui Zhang
  • Patent number: 10184017
    Abstract: The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compounds as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C6-C30 heteroaryl, C7-C30 alkylaryl and C7-C30 arylalkyl; R1 and R2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C7-C30 alkylaryl and C7-C30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity.
    Type: Grant
    Filed: April 24, 2015
    Date of Patent: January 22, 2019
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Jun Wang, Mingzhi Gao, Haitao Liu, Jing Ma, Jianhua Chen, Xiaoxia Cai, Jixing Ma, Changxiu Li, Jianjun Hu, Xiaofan Zhang, Xianzhong Li, Zhihui Zhang, Ruilin Duan, Linna Yang, Changyou Ma
  • Patent number: 10174141
    Abstract: The present invention provides a preparation method of a catalyst component for olefin polymerization, comprising firstly dissolving an anhydrous magnesium halide into a mixed solvent which comprises an oxygen-containing organic titanium compound, an organic epoxy compound, a hydroxy-containing compound, and an inert solvent, and does not comprise a phosphate compound, so as to form a magnesium halide solution; then mixing the magnesium halide solution with a halogen-containing compound to precipitate a solid, so as to obtain the catalyst component, wherein the halogen-containing compound comprises at least one selected from a group consisting of halogen and titanium-containing compounds, halogenated organic hydrocarbon compounds, acyl halide compounds, halogen and phosphorus-containing compounds, halogen and boron-containing compounds, halogenated organic aluminum compounds, and halogen and silicon-containing compounds.
    Type: Grant
    Filed: April 29, 2015
    Date of Patent: January 8, 2019
    Assignee: China Petroleum & Chemical Corporation Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Shibo Wang, Junling Zhou, Dongbing Liu, Lei Zhang, Xinping Lv, Bingquan Mao, Zhenjie Liu, Xin Zhou, Changli Zhang, Baoquan Xing
  • Patent number: 10150822
    Abstract: A catalyst component (A) for olefin polymerization is prepared by contacting a solid component (a) containing magnesium, titanium, halogen and an internal electron donor compound with an organosilicon compound (b), wherein the organosilicon compound (b) is one or more selected from a Si—H functional group containing chainlike polysiloxane (b1) represented by formula (Ix), a cyclic polysiloxane (b2) represented by formula (Iy) and a Si—H functional group containing organosilicon compound (b3) represented by formula (Iz). In addition, a process for preparing the catalyst component and the corresponding catalyst is described. The catalyst component and its catalyst have high catalytic activity, good hydrogen response, and good stereospecificity, the catalyst can release its activity more evenly, and the obtained polymer has significantly increased bulk density. The definitions of R1 to R10, n and z in the formulae (Ix), (ly) and (Iz) are as described in the specification.
    Type: Grant
    Filed: July 24, 2012
    Date of Patent: December 11, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Qilong Zhou, Zhong Tan, Xiudong Xu, Li'an Yan, Weiwei Song, Fengkui Li, Shanshan Yin, Jinhua Yu
  • Patent number: 10087264
    Abstract: A magnesium halide solution is disclosed. The magnesium halide solution comprises a magnesium halide, an oxygen-containing organic titanium compound, a hydroxyl-containing compound, and an organic solvent. The magnesium halide solution further comprises an organic heterocyclic compound. The organic solvent is a hydrocarbon and/or a halogenated hydrocarbon. The organic heterocyclic compound is at least one selected from a group consisting of a sulphur-containing organic heterocyclic compound, a nitrogen-containing organic heterocyclic compound, and an organic epoxy compound. The magnesium halide solution has a good stability, and can be used for preparing a catalyst for olefin polymerization and copolymerization reactions. The raw material of the magnesium halide solution is cheap and easy to be obtained. The preparing method is easy to be performed and is environment-friendly.
    Type: Grant
    Filed: April 29, 2015
    Date of Patent: October 2, 2018
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Shibo Wang, Junling Zhou, Dongbing Liu, Lei Zhang, Xinping Lv, Bingquan Mao, Zhenjie Liu, Xin Zhou, Changli Zhang, Baoquan Xing
  • Patent number: 10040032
    Abstract: A complex nanofiltration membrane comprising a substrate and a separating layer, wherein the separating layer is an oxidant-treated, crosslinked network structure formed from a hydroxyl-containing polymer, a thiol-containing silane coupling agent and a crosslinking agent, is disclosed. Also disclosed are a process for preparing the complex nanofiltration membrane and use of the complex nanofiltration membrane in water treatment.
    Type: Grant
    Filed: July 22, 2015
    Date of Patent: August 7, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Yang Zhang, Yiqun Liu, Guoyuan Pan, Hao Yan, Jian Xu, Min Guo
  • Patent number: 9988505
    Abstract: A polyethylene composition comprising an ethylene/?-olefin copolymerized linear low density polyethylene, wherein the polyethylene composition has a Mw of from 100,000 g/mol to 200,000 g/mol, a Mw/Mn of from 4.0 to 9.0, a Mz/Mw of from 4.0 to 7.0, and a Mz+1/Mw of from 4.5 to 13.5, is provided. A film formed of the polyethylene composition is also provided.
    Type: Grant
    Filed: October 27, 2015
    Date of Patent: June 5, 2018
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum and Chemical Corporation
    Inventors: Dali Gao, Hongwei Shi, Shijun Zhang, Meifang Guo, Luqiang Yu, Jinliang Qiao, Ruxian Li, Yujing Tang, Jianjun Yin, Liangshi Wang, Honghong Huang, Qingquan Yang, Hao Zou, Jie Li, Liying Zhang, Hua Yin, Jianye Liu, Jingbo Shao, Mingfu Lyu, Liqiu Chu, Meng Xu, Hui Quan, Kai Xu, Mu Dong, Yun Lyu, Yihui Xu, Yaohui Xu, Peng Guo, Yiqing Bai
  • Patent number: 9951157
    Abstract: Spherical carriers for an olefin polymerization catalyst, catalyst components, catalysts, and preparation methods therefor are disclosed. The method for preparing the spherical carriers comprises the following steps: (1) reacting, in the presence of at least one polymeric dispersion stabilizer, a magnesium halide with an organic compound containing active hydrogen to form a complex solution; (2) reacting said complex solution with an alkylene oxide-type compound to directly precipitate solid particles; and (3) recovering the solid particles to obtain spherical carriers. When a catalyst prepared by using the present spherical carrier is used in propylene polymerization, said catalyst exhibits high polymerization activity and high stereo-directing ability.
    Type: Grant
    Filed: October 17, 2014
    Date of Patent: April 24, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Weili Li, Xianzhi Xia, Yuexiang Liu, Yongtai Ling, Jin Zhao, Jigui Zhang, Futang Gao, Ping Gao, Yang Tan, Renqi Peng, Zhihui Zhang, Jie Lin, Ruilin Duan, Changyou Ma
  • Patent number: 9944883
    Abstract: The present invention relates to the field of lubricant, and specifically provides a lubricant composition and its preparation method and use. The lubricant composition comprises a base oil and rubber particles having radiation crosslinked structure dispersed therein, wherein the base oil is continuous phase and the rubber particles are dispersed phase. The viscosity of the lubricant composition of the present invention can be effectively adjusted as temperature changes. As compared with the lubricant composition comprising chemically crosslinked rubber particles, it has a lower viscosity at low temperatures and a higher viscosity at high temperatures, and has a relatively high viscosity index, which can meet the application requirements at the temperature above 200° C. In addition, the lubricant composition of the present invention also has excellent antiwear and friction-reducing properties.
    Type: Grant
    Filed: April 19, 2016
    Date of Patent: April 17, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xiaohong Zhang, Chuanlun Cai, Jinmei Lai, Jinliang Qiao, Zhihai Song, Guicun Qi, Binghai Li, Xiang Wang, Jianming Gao, Hongbin Zhang, Haibin Jiang, Gu He, Yue Ru
  • Patent number: 9834675
    Abstract: The present invention relates to a resin composition having an improved haze effect and light transmittance and a process for preparing the same. The resin composition comprises blended components: a) a matrix resin; and b) crosslinked copolymer microspheres; wherein the crosslinked copolymer microspheres are alternating copolymers formed from monomers having anhydride, amide and/or imide groups, with olefin monomers and/or furan and its derivatives and optionally crosslinked with a crosslinking agent; preferably, the resin composition has a haze of not less than 92%, and a light transmittance of not less than 55%, preferably a haze of not less than 92%, and a light transmittance of not less than 59%, and more preferably a haze of not less than 95%, and a light transmittance of not less than 59%. The resin composition is energy efficient in use, provides excellent light diffusing effect, and, at the same time reduces the material cost.
    Type: Grant
    Filed: April 8, 2016
    Date of Patent: December 5, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Jinliang Qiao, Yue Ru, Xiaohong Zhang, Wantai Yang, Guicun Qi, Chuanlun Cai, Jinmei Lai, Binghai Li, Xiang Wang, Zhihai Song, Jianming Gao, Hongbin Zhang, Haibin Jiang, Gu He
  • Patent number: 9822196
    Abstract: The present disclosure discloses a catalyst composition for olefin polymerization, comprising the following components: a): a solid catalyst component containing magnesium, titanium, halogens, and at least one internal electron donor having a lone pair of electrons; b): an aluminum alkyl compound; and c): an external electron donor containing a first external electron donor C1, which is a malonate compound. In the present disclosure, a catalyst composition having an external electron donor that contains a malonate compound is used in olefin polymerization, in particular propene polymerization, and can significantly improve catalytic activity and hydrogen response of the catalyst and expand molecular weight distribution of polymers, which facilitates development of different polymers.
    Type: Grant
    Filed: September 28, 2014
    Date of Patent: November 21, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Changxiu Li, Mingzhi Gao, Haitao Liu, Jing Ma, Jianhua Chen, Xianzhong Li, Xiaoxia Cai, Jixing Ma, Jun Wang, Jianjun Hu
  • Patent number: 9751965
    Abstract: Disclosed herein is a polymerization method of propylene, which can prepare a propylene homopolymer with both high fluidity and high rigidity as well as a propylene/?-define copolymer having both high fluidity and a good rigidity-toughness balance by, for example, control of polymerization steps and elevation of polymerization temperature, while the catalyst still maintains a relatively high polymerization activity.
    Type: Grant
    Filed: October 30, 2013
    Date of Patent: September 5, 2017
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Luqiang Yu, Zhichao Yang, Jiangbo Chen, Jianxin Zhang, Yafeng Du, Qinyu Tong, Kang Sun, Yang Liu, Jie Zou, Lusheng Wang, Zengyue Dai, Zhong Tan
  • Patent number: 9751960
    Abstract: The present disclosure provides a solid catalyst component for olefin polymerization, comprising magnesium, titanium, a halogen, and an electron donor, wherein the electron donor is at least one selected from the group consisting of diol diester compounds as shown in Formula (I). The catalyst according to the present disclosure has significantly improved polymerization activity, hydrogen response, and stereoselectivity. According to the present disclosure, when the catalyst system containing a diol diester compound as shown in Formula (I) of the present disclosure is used in olefin polymerization, the catalyst shows good comprehensive performance, including high catalytic activity. In particular, in the presence of highly concentrated hydrogen, the catalyst has an improved hydrogen response and/or isotacticity of the polymers obtained can be significantly improved.
    Type: Grant
    Filed: May 21, 2014
    Date of Patent: September 5, 2017
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Changxiu Li, Mingzhi Gao, Haitao Liu, Jianhua Chen, Jing Ma, Jixing Ma, Xiaoxia Cai, Jun Wang, Xiaofan Zhang, Jianjun Hu
  • Publication number: 20170101486
    Abstract: A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.
    Type: Application
    Filed: October 13, 2016
    Publication date: April 13, 2017
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xianzhi XIA, Yuexiang LIU, Jigui ZHANG, Xinsheng WANG, Ping GAO, Suzhen QIAO, Maoping YIN, Weili LI, Tianyi ZHANG, Renqi PENG, Ying CHEN, Zhihui ZHANG