Abstract: The present application relates to a modified rubber masterbatch and preparation method thereof, rubber composition prepared therewith and vulcanized rubber and preparation method thereof. The modified rubber component comprises uncrosslinked rubber and rubber particles having crosslinked structure dispersed therein, wherein the rubber particles having crosslinked structure are synthetic rubber particles and/or natural rubber particles, have an average particle size of 20-500 nm and a gel content of 60% by weight or higher, and wherein the uncrosslinked rubber is styrene-butadiene rubber. The weight ratio of the rubber particles having crosslinked structure to the uncrosslinked rubber is greater than 20:80 and less than or equal to 80:20. The rubber composition comprises a blend of modified rubber component and base rubber, in which the modified rubber masterbatch is present in an amount of 1 to 70 parts by weight, relative to per 100 parts by weight of the base rubber.

Abstract: A catalyst component for olefin polymerization comprising magnesium, titanium, halogen and electron donor, wherein the electron donor is selected from at least one of the diol diester compounds, when the diol diester comprised contains a certain amount of isomer with Fischer projection formula as shown in Formula (II), the activity and stereospecificity of the catalyst are greatly improved, especially in the production of polymers with high melt index, the isotactic index of the obtained polymers is improved substantially.

Abstract: The present invention discloses an alumina carrier for a silver catalyst, a process for preparing the alumina carrier, a silver catalyst made from the alumina carrier, and a use of the silver catalyst in the production of ethylene oxide by the oxidization of ethylene. The alumina carrier comprises alumina and promoters, as well as titanium silicate molecular sieve(s); and therefore, has an improved catalytic activity.

Abstract: Provided is a copolymer rubber, comprising a copolymer having a star-shaped block structure (SIB-PA)n-X, wherein SIB is a block comprising styrene, butadiene, and isoprene as constituent monomers; PA is a block comprising butadiene or isoprene as a constituent monomer; X is the residue of at least one coupling agent; and n=2-4. Also provided is a process for preparing the copolymer rubber and use thereof.

Abstract: The present invention relates to a catalyst component for olefin polymerization, which comprises the reaction product of at least one organo-magnesium compound, at least one titanium-containing compound, at least one hydroxyl group-containing compound, at least one chlorine-containing organo-aluminum, boron, phosphorus or silicon compound, and at least one polybutadiene block copolymer. The catalyst component of the present invention has well-shaped particles, and a narrow particle size distribution; a polymerization reaction of olefins with the catalyst component produces well-shaped polymer particles with a high bulk density (BD) and an excellent comprehensive catalytic performance. The present invention also relates to a preparation method for said catalyst component and the application thereof, particularly in the homopolymerization and copolymerization of olefins such as ethylene, propylene, butene, hexene and octene.

Abstract: The present invention provides a process for preparing high melt strength propylene polymer by direct polymerization, comprising that a propylene polymer with wide molecular weight distribution and containing “very high molecular weight fraction” can be prepared by controlling the species and ratios of the external electron donors in the Ziegler-Natta catalyst system at different reaction stages according to the requirement for different molecular weight fractions in the different propylene polymerization stage of the series operation, and said polymer has excellent mechanical properties, especially with very high melt strength. The present invention also provides a propylene homopolymer with high melt strength, comprising the following features: (1) the MFR is 0.2-10 g/10 min at 230° C. with a load of 2.16 kg; (2) the molecular weight distribution Mw/Mn is 6-20; (3) the content of the fraction with a molecular weight higher than 5,000,000 is higher than or equal to 0.

Abstract: A magnesium halide adduct is provided, comprising at least one compound of the formula MgXY, at least one compound of the formula ROH, methanol, at least one modifying agent chosen from DOE and o-hydroxy benzoates, and optionally water. Also provided herein are a catalyst component comprising the magnesium halide adduct, a catalyst for olefin polymerization comprising the catalyst component; the respective processes for preparing the magnesium halide adduct and the catalyst component; use of the magnesium halide adduct for preparing the catalyst component, use of the catalyst component in a catalyst for olefin polymerization and use of the catalyst in olefin polymerization; and a process of olefin polymerization.

Abstract: The present disclosure provides a suspension of a solid catalyst component used in propylene polymerization and a method for preparing the same. The suspension includes the solid catalyst component and a liquid medium containing propylene and an alkane, and is preferably prepared by mixing the solid catalyst component and the alkane to obtain a mixed slurry, which is further mixed with liquid propylene. Using of a proper liquid dispersing agent at a proper proportion and amount enables the solid catalyst component to be more homogeneously dispersed, thus preventing the phenomenon of agglomeration in the polymerization process without using a large amount of the dispersing agent or any additional mixer. The present disclosure further provides a method of propylene polymerization, including feeding the suspension into a reaction system of propylene polymerization, wherein propylene polymerization is initiated under polymerization conditions.

Abstract: Disclosed herein are polybutadiene grafted isoprene rubber, processes for preparing polybutadiene grafted isoprene rubber, mixed compositions and vulcanized forms thereof.

Abstract: The present disclosure provides catalysts for olefin polymerization comprising titanium, silicon, magnesium, phosphorus, at least one internal electron donor compound, and at least one halogen, processes for preparing the catalysts for olefin polymerization, and processes for olefin polymerization using the catalysts for olefin polymerization.

Abstract: The present invention discloses a process for producing olefins from petroleum saturated hydrocarbons. The process of the present invention comprises: contacting a preheated petroleum saturated hydrocarbons feedstock with a dehydrogenation catalyst in a dehydrogenation reaction zone of a reaction system to obtain a petroleum hydrocarbon stream containing unsaturated hydrocarbon compounds, in which the dehydrogenation reaction has a conversion rate of at least 20%; and contacting the obtained petroleum hydrocarbon stream containing the unsaturated hydrocarbon compounds with olefins cracking catalyst in an olefin cracking zone of the reaction system to obtain a product stream containing olefins with a reduced number of carbon atoms.

Abstract: The present invention provides a functional diene polymer, a preparation method thereof and a rubber composition comprising the functional diene polymer. The functional diene polymer comprises at least one type of conjugated diene structural units and silane coupler functional units represented by formula (I) in its molecular chain, and the number-average molecular weight of the functional diene polymer is 50,000˜1,000,000; R1-R4 are C1-C20 linear or branched alkyl or heteroatom-containing C1-C20 linear or branched alkyl, and the heteroatom is selected from one or more of halogen, oxygen, sulfur, silicon, and phosphorus. Not only the relationship between the wet slip resistance and the rolling resistance of the functional diene polymer is effectively improved, but also the offensive odor produced in the rubber mixing process owing to the addition of the silane coupler is reduced.

Abstract: The present invention relates to a support for silver catalyst used in the ethylene oxide production, a preparation method for the same, a silver catalyst prepared from the same, and its use in the ethylene oxide production. The silver catalyst produced from the silver catalyst support has an improved activity, stability and/or selectivity in the production of ethylene oxide by epoxidation of ethylene.

Abstract: The method for preparation of polyisoprene includes conducting polymerization reaction of isoprene in a first organic solvent under the presence of rare earth catalyst I and rare earth catalyst II, to obtain polyisoprene with bimodal molecular weight distribution, wherein the polymerization reaction conditions are controlled to ensure the peak molecular weight of the high molecular weight component fraction in the polyisoprene is 1×106-2×106 and the peak molecular weight of the low molecular weight component fraction is 2×105-4×105, and the weight ratio of content of the high molecular weight component fraction to the low molecular weight component fraction is 1-25:1. The molecular weight distribution of the polyisoprene obtained with the method provided is bimodal distribution; therefore, the polyisoprene not only has the mechanical properties of polyisoprene with high molecular weight, but also has the processability of polyisoprene with low molecular weight.

Abstract: An alumina support comprises alpha-alumina as the main crystal phase of its backbone, and having a specific surface area of no higher than 3.0 m2/g, a pore volume ranging from 0.3 ml/g to 0.8 ml/g, an alkaline earth metal content ranging from 0.05% to 2.0% by weight of the support, wherein the support has such properties that treating the support with an aqueous oxalic acid solution having a concentration ranging from 0.4% to 2.0% by weight and having twice the weight of the support for 30 minutes can produce a leach liquor having an aluminum content of no higher than 60 ?g/mL, a sodium content of no higher than 20 ?g/mL, and a silicon content of no higher than 40 ?g/mL. Processes for preparing the alumina support, silver catalysts comprising the alumina support, and methods of preparing ethylene oxide by ethylene oxidation using the silver catalyst are also disclosed herein.

Abstract: The present disclosure provides a catalyst composition for ethylene oligomerization including an imino ferrous complex shown in Formula (I) as the main catalyst, an aluminum-containing cocatalyst, water, and an organic solvent: According to the present disclosure, a higher oligomerization activity can be obtained with the catalyst composition than with a catalyst composition system in the prior art which contains no water. Moreover, when the catalyst composition according to the present disclosure is used, a high selectivity of ?-olefins is obtainable. Besides, the catalyst composition according to the present disclosure can enable rapid initiation, stable operation, and good repeatability of the oligomerization reaction. According to the present disclosure, a high oligomerization activity can be obtained even at a rather low ratio of Al/Fe, or at a low reaction temperature.

Abstract: The present invention relates to a biodegradable composite and its preparation process, which composite is prepared by mixing feed stocks comprising a polylactic acid, an aliphatic-aromatic copolyester A, an aliphatic-aromatic copolyester B and an organic peroxide at a temperature between about 100 and about 200° C. The present invention also relates to a disposable article, which is prepared from said biodegradable composite.

Abstract: The present application relates to a modified rubber masterbatch and preparation method thereof, rubber composition prepared therewith and vulcanized rubber and preparation method thereof. The modified rubber component comprises uncrosslinked rubber and rubber particles having crosslinked structure dispersed therein, wherein the rubber particles having crosslinked structure are synthetic rubber particles and/or natural rubber particles, have an average particle size of 20-500 nm and a gel content of 60% by weight or higher, and wherein the uncrosslinked rubber is styrene-butadiene rubber. The weight ratio of the rubber particles having crosslinked structure to the uncrosslinked rubber is greater than 20:80 and less than or equal to 80:20. The rubber composition comprises a blend of modified rubber component and base rubber, in which the modified rubber masterbatch is present in an amount of 1 to 70 parts by weight, relative to per 100 parts by weight of the base rubber.

Abstract: A catalyst component (A) for olefin polymerization is prepared by contacting a solid component (a) containing magnesium, titanium, halogen and an internal electron donor compound with an organosilicon compound (b), wherein the organosilicon compound (b) is one or more selected from a Si—H functional group containing chainlike polysiloxane (b1) represented by formula (Ix), a cyclic polysiloxane (b2) represented by formula (Iy) and a Si—H functional group containing organosilicon compound (b3) represented by formula (Iz). In addition, a process for preparing the catalyst component and the corresponding catalyst is described. The catalyst component and its catalyst have high catalytic activity, good hydrogen response, and good stereospecificity, the catalyst can release its activity more evenly, and the obtained polymer has significantly increased bulk density. The definitions of R1 to R10, n and z in the formulae (Ix), (ly) and (Iz) are as described in the specification.

Abstract: A process for preparing 2,3-di(non-linear-alkyl)-2-cyanosuccinate compounds, especially 2,3-diisopropyl-2-cyanosuccinate compounds, and processes for preparing 2,3-di(non-linear-alkyl)succinic acids and esters thereof by using the 2,3-di-non-linear propyl-2-cyanosuccinate compounds as intermediates are disclosed.