Patents Assigned to Beijing Research Institute of Chemical Industry China Petroleum & Chemical Corporation
  • Patent number: 9593185
    Abstract: The present disclosure provides a suspension of a solid catalyst component used in propylene polymerization and a method for preparing the same. The suspension includes the solid catalyst component and a liquid medium containing propylene and an alkane, and is preferably prepared by mixing the solid catalyst component and the alkane to obtain a mixed slurry, which is further mixed with liquid propylene. Using of a proper liquid dispersing agent at a proper proportion and amount enables the solid catalyst component to be more homogeneously dispersed, thus preventing the phenomenon of agglomeration in the polymerization process without using a large amount of the dispersing agent or any additional mixer. The present disclosure further provides a method of propylene polymerization, including feeding the suspension into a reaction system of propylene polymerization, wherein propylene polymerization is initiated under polymerization conditions.
    Type: Grant
    Filed: December 5, 2014
    Date of Patent: March 14, 2017
    Assignees: China Petroleum & Chemical Corporation, Sinopec Catalyst Co., Ltd., Beijing Research Institute Of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Jinlai Qin, Haixiang Cui, Xiaodong Wang, Mingzhi Gao, Cuiling Xiao, Yanju Sun, Liang Pan, Xin Chen, Ziqiang Wang
  • Patent number: 9592491
    Abstract: The present disclosure discloses an ?-alumina carrier, comprising the elements of lanthanum and silicon both dispersed in the interior and on the surface of the carrier. The mass ratio of the element of lanthanum to the element of silicon is in the range from 0.1:1 to 20:1. The inventors of the present disclosure have made extensive researches into the field of the silver catalyst and alumina carrier thereof, and added the elements of lanthanum and silicon (i.e., bulk phase addition) in preparing the alumina carrier used in the silver catalyst. The carrier thus obtained contains the elements of silicon and lanthanum both in the interior and on the surface thereof, and has improved specific surface area and strength. The silver catalyst prepared with the carrier can react in a low reaction temperature (has a high reaction activity) and has a high selectivity in producing ethylene oxide through oxidation of ethylene.
    Type: Grant
    Filed: October 28, 2014
    Date of Patent: March 14, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xianfeng Li, Jinbing Li, Xinxin Sun, Jianshe Chen, Shuyuan Cao, Lixin Gao, Hui Wang, Rujun Liang, Qian Xue, Zhixiang Zhang
  • Publication number: 20170058060
    Abstract: A magnesium halide solution is disclosed. The magnesium halide solution comprises a magnesium halide, an oxygen-containing organic titanium compound, a hydroxyl-containing compound, and an organic solvent. The magnesium halide solution further comprises an organic heterocyclic compound. The organic solvent is a hydrocarbon and/or a halogenated hydrocarbon. The organic heterocyclic compound is at least one selected from a group consisting of a sulphur-containing organic heterocyclic compound, a nitrogen-containing organic heterocyclic compound, and an organic epoxy compound. The magnesium halide solution has a good stability, and can be used for preparing a catalyst for olefin polymerization and copolymerization reactions. The raw material of the magnesium halide solution is cheap and easy to be obtained. The preparing method is easy to be performed and is environment-friendly.
    Type: Application
    Filed: April 29, 2015
    Publication date: March 2, 2017
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Shibo WANG, Junling ZHOU, Dongbing LIU, Lei ZHANG, Xinping LV, Bingquan MAO, Zhenjie LIU, Xin ZHOU, Changli ZHANG, Baoquan XING
  • Publication number: 20170051086
    Abstract: The present invention provides a preparation method of a catalyst component for olefin polymerization, comprising firstly dissolving an anhydrous magnesium halide into a mixed solvent which comprises an oxygen-containing organic titanium compound, an organic epoxy compound, a hydroxy-containing compound, and an inert solvent, and does not comprise a phosphate compound, so as to form a magnesium halide solution; then mixing the magnesium halide solution with a halogen-containing compound to precipitate a solid, so as to obtain the catalyst component, wherein the halogen-containing compound comprises at least one selected from a group consisting of halogen and titanium-containing compounds, halogenated organic hydrocarbon compounds, acyl halide compounds, halogen and phosphorus-containing compounds, halogen and boron-containing compounds, halogenated organic aluminium compounds, and halogen and silicon-containing compounds.
    Type: Application
    Filed: April 29, 2015
    Publication date: February 23, 2017
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Shibo WANG, Junling ZHOU, Dongbing LIU, Lei ZHANG, Xinping LV, Bingquan MAO, Zhenjie LIU, Xin ZHOU, Changli ZHANG, Baoquan Xing
  • Publication number: 20170044280
    Abstract: The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compounds as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C6-C30 heteroaryl, C7-C30 alkylaryl and C7-C30 arylalkyl; R1 and R2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C7-C30 alkylaryl and C7-C30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity.
    Type: Application
    Filed: April 24, 2015
    Publication date: February 16, 2017
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry China Petroleum & Chemical Corporation
    Inventors: Jun WANG, Mingzhi GAO, Haitao LIU, Jing MA, Jianhua CHEN, Xiaoxia CAI, Jixing MA, Changxiu LI, Jianjun HU, Xiaofan ZHANG, Xianzhong LI, Zhihui ZHANG, Ruilin DUAN, Linna YANG, Changyou MA
  • Patent number: 9505677
    Abstract: The present disclosure provides a steam cracking process, comprising heating a liquid feed stock in a convection section of a cracking furnace and subsequently conveying the material to a radiant section of the cracking furnace for cracking reaction therein, wherein a monoolefin-containing stream is conveyed to the cracking furnace for cracking reaction through at least one of modes A to C.
    Type: Grant
    Filed: October 28, 2013
    Date of Patent: November 29, 2016
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Guoqing Wang, Lijun Zhang, Yonggang Zhang, Junjie Liu, Zhiguo Du, Xianfeng Zhou, Wei Li, Cong Zhou
  • Patent number: 9499569
    Abstract: A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001 to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: November 22, 2016
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xianzhi Xia, Yuexiang Liu, Jigui Zhang, Xinsheng Wang, Ping Gao, Suzhen Qiao, Maoping Yin, Weili Li, Tianyi Zhang, Renqi Peng, Ying Chen, Zhihui Zhang
  • Patent number: 9453122
    Abstract: A rubber composition, preparation method and vulcanized rubber thereof are provided. The rubber composition comprises uncrosslinked rubber and rubber particles having crosslinked structure dispersed therein, wherein the rubber particles having crosslinked structure are synthetic rubber particles and/or natural rubber particles with an average particle size of 20 to 500 nm and a gel content of 60% by weight or higher, and the uncrosslinked rubber is styrene-butadiene rubber, and wherein the weight ratio of the rubber particles having crosslinked structure to the uncrosslinked rubber is 1:99-20:80.
    Type: Grant
    Filed: October 26, 2012
    Date of Patent: September 27, 2016
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Jinliang Qiao, Yuexin Cong, Xiaohong Zhang, Ying Li, Jianming Gao, Qianmin Zhang, Zhihai Song, Yanling Sun, Meifang Guo, Peijun Song, Chuanlun Cai, Guoxun Zhao, Hongwei Shi, Guicun Qi, Jinmei Lai, Hongbin Zhang, Ya Wang, Binghai Li, Xiang Wang
  • Patent number: 9424959
    Abstract: The invention provides a conductive full vulcanized thermoplastic elastomer and its preparation method, and relates to the technical field of full vulcanized thermoplastic elastomer. The full vulcanized thermoplastic elastomer is obtained by melt-blending components including rubber particles having crosslinking structure with mean particle diameter of 0.02 to 1 ?m, carbon nanotubes as conductive fillers and thermoplastic plastics once, wherein the weight ratio of the rubber particles and the thermoplastic plastics is from 30:70 to 75:25 and the content of conductive fillers is from 0.3 to 10 weight parts based on the total weight of rubber particles and thermoplastic plastics of 100 weight parts. The resulting conductive full vulcanized thermoplastic elastomers have low content of conductive fillers and excellent combination performances.
    Type: Grant
    Filed: March 2, 2012
    Date of Patent: August 23, 2016
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry China Petroleum & Chemical Corporation
    Inventors: Xiaohong Zhang, Jinliang Qiao, Guicun Qi, Zhihai Song, Chuanlun Cai, Ya Wang, Jianming Gao, Hongbin Zhang, Jinmei Lai, Binghai Li, Haosheng Wang, Yilei Zhu
  • Patent number: 9376513
    Abstract: Disclosed is a solid catalyst component for olefin polymerization. The catalyst component comprises a dialkoxy magnesium carrier, a titanium compound, and a product from an internal electron donor reacting in an inert solvent. The internal electron donor compound comprises a 2,3-di-non-linear-alkyl-2-cyano succinic acid diester compound as presented in formula I.
    Type: Grant
    Filed: January 19, 2012
    Date of Patent: June 28, 2016
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Zhong Tan, Lunjia Xie, Xiudong Xu, Yu Tian, Qilong Zhou, Zaixing Feng, Li'an Yan, Siyuan Zhao, Jinhua Yu, Zhufang Sun, Fengkui Li, Shanshan Yin, Weiwei Song
  • Patent number: 9359560
    Abstract: The present disclosure relates to a heat transfer tube and a cracking furnace using the heat transfer tube. The heat transfer tube comprises a twisted baffle arranged in an inner wall of the tube, said twisted baffle extending spirally along an axial direction of the heat transfer tube. The twisted baffle defines a closed circle viewed from an end of the heat transfer tube. Along the trajectory of the circle a casing is arranged, which is fixedly connected to a radial inner end of the twisted baffle. The twisted baffle is provided with a plurality of holes. The heat transfer tube according to the present disclosure has a good heat transfer effect and small pressure loss.
    Type: Grant
    Filed: October 29, 2013
    Date of Patent: June 7, 2016
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Guoqing Wang, Lijun Zhang, Xianfeng Zhou, Junjie Liu, Zhiguo Du, Yonggang Zhang, Zhaobin Zhang, Cong Zhou
  • Patent number: 9353197
    Abstract: A catalyst component for olefin polymerization is disclosed, which comprises at least one diol ester type electron donor compound (a) and at least one diether type electron donor compound (b) among others, wherein the molar ratio of a to b is 0.55-50. A preparation method of the catalyst component, a catalyst comprising the catalyst component, and an olefin polymerization method using the catalyst which can especially be used for preparation of polypropylenes of low ash contents are also disclosed.
    Type: Grant
    Filed: April 19, 2010
    Date of Patent: May 31, 2016
    Assignees: China Petroleum and Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum and Chemical Corporation
    Inventors: Xianzhi Xia, Jin Zhao, Yuexiang Liu, Jigui Zhang, Weili Li, Yang Tan, Suzhen Qiao, Renqi Peng, Ping Gao, Maoping Yin, Tianyi Zhang
  • Publication number: 20160136635
    Abstract: A metal loaded catalyst comprises a support and main active metal components and optional auxiliary active metal components, wherein the main active metal components are elementary substances and obtained by ionizing radiation reducing precursors of main active metal components. The catalyst can be widely used in the catalytic reactions of petrochemistry industry with high activity and selectivity. The catalyst can be used directly without being reduced preliminarily by hydrogen.
    Type: Application
    Filed: October 16, 2015
    Publication date: May 19, 2016
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Wei DAI, Jing PENG, Haibo YU, Hui PENG, Genshuan WEI, Maolin ZHAI, Zuwang MAO, Yi LE, Wei MU, Haijiang LIU, Yunxian ZHU
  • Patent number: 9321857
    Abstract: A spheric magnesium compound comprises a reaction product of at least the following components: (a) a magnesium halide having a formula of MgX2-nRn, wherein X is independently chloride or bromide, R is a C1-C14 alkyl, a C6-C14 aryl, a C1-C14 alkoxy, or a C6-C14 aryloxy, and n is 0 or 1; (b) an alcohol compound; and (c) an epoxy compound having a general formula (I), wherein R2 and R3 are independently hydrogen, a C1-C5 linear or branched alkyl, or a C1-C5 linear or branched haloalkyl. The magnesium compound has characteristic DSC curve and X-ray diffraction pattern, and can be used as a carrier for olefin polymerization catalyst. stereoregularity of polymer having high melt index, and low content of polymer fines.
    Type: Grant
    Filed: October 18, 2010
    Date of Patent: April 26, 2016
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Weili Li, Xianzhi Xia, Yuexiang Liu, Jigui Zhang, Suzhen Qiao, Jin Zhao, Ping Gao, Xinsheng Wang, Yang Tan, Zhihui Zhang, Linna Yang, Ruilin Duan, Renqi Peng
  • Patent number: 9303108
    Abstract: The present invention relates to a propylene-butene-1 random copolymer which has a butene-1 content of 1-6 mol % and a relative dispersity of butene-1, as determined according to NMR method, of greater than 98.5%. The propylene-butene-1 random copolymer of the present invention has a high relative dispersity of butene-1, as well as better transparency and heat resistance, so that it is more suitable for packaging food that may be edible after heating. Moreover, the copolymer has a lower xylene solubles content at room temperature. In addition, the present invention further relates to a method for preparing the copolymer and to a composition and an article comprising the copolymer.
    Type: Grant
    Filed: October 29, 2012
    Date of Patent: April 5, 2016
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Meifang Guo, Wenbo Song, Liying Zhang, Liping Hou, Wenjun Wei, Hao Zhang, Yujing Tang, Huijie Hu
  • Patent number: 9296840
    Abstract: The present invention provides a functional diene polymer, a preparation method thereof and a rubber composition comprising the functional diene polymer. The functional diene polymer comprises at least one type of conjugated diene structural units and silane coupler functional units represented by formula (I) in its molecular chain, and the number-average molecular weight of the functional diene polymer is 50,000˜1,000,000; R1-R4 are C1-C20 linear or branched alkyl or heteroatom-containing C1-C20 linear or branched alkyl, and the heteroatom is selected from one or more of halogen, oxygen, sulfur, silicon, and phosphorus. Not only the relationship between the wet slip resistance and the rolling resistance of the functional diene polymer is effectively improved, but also the offensive odor produced in the rubber mixing process owing to the addition of the silane coupler is reduced.
    Type: Grant
    Filed: October 24, 2014
    Date of Patent: March 29, 2016
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Aimin Liang, Lin Xu, Nini Wang, Xinhe Kang, Liangliang Qu, Ke Jiang, Chuanqing Li, Ximing Xie, Hui Liu, Wenjuan Sun
  • Patent number: 9290643
    Abstract: The present application relates to a modified rubber masterbatch and preparation method thereof, rubber composition prepared therewith and vulcanized rubber and preparation method thereof. The modified rubber component comprises uncrosslinked rubber and rubber particles having crosslinked structure dispersed therein, wherein the rubber particles having crosslinked structure are synthetic rubber particles and/or natural rubber particles, have an average particle size of 20-500 nm and a gel content of 60% by weight or higher, and wherein the uncrosslinked rubber is styrene-butadiene rubber. The weight ratio of the rubber particles having crosslinked structure to the uncrosslinked rubber is greater than 20:80 and less than or equal to 80:20. The rubber composition comprises a blend of modified rubber component and base rubber, in which the modified rubber masterbatch is present in an amount of 1 to 70 parts by weight, relative to per 100 parts by weight of the base rubber.
    Type: Grant
    Filed: October 26, 2012
    Date of Patent: March 22, 2016
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Jinliang Qiao, Yuexin Cong, Xiaohong Zhang, Ying Li, Jianming Gao, Qianmin Zhang, Zhihai Song, Yanling Sun, Jinmei Lai, Peijun Song, Chuanlun Cai, Guoxun Zhao, Hongbin Zhang, Guicun Qi, Ya Wang, Binghai Li
  • Patent number: 9266983
    Abstract: The present disclosure provides a catalyst composition for ethylene oligomerization including an imino ferrous complex shown in Formula (I) as the main catalyst, an aluminum-containing cocatalyst, water, and an organic solvent: According to the present disclosure, a higher oligomerization activity can be obtained with the catalyst composition than with a catalyst composition system in the prior art which contains no water. Moreover, when the catalyst composition according to the present disclosure is used, a high selectivity of ?-olefins is obtainable. Besides, the catalyst composition according to the present disclosure can enable rapid initiation, stable operation, and good repeatability of the oligomerization reaction. According to the present disclosure, a high oligomerization activity can be obtained even at a rather low ratio of Al/Fe, or at a low reaction temperature.
    Type: Grant
    Filed: April 16, 2014
    Date of Patent: February 23, 2016
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Tonglin Li, Mingfang Zheng, Jun Liu, Huaijie Wang, Haiying Zhang, Weizhen Li, Jilong Wang, Yuling Piao
  • Publication number: 20160023168
    Abstract: A complex nanofiltration membrane comprising a substrate and a separating layer, wherein the separating layer is an oxidant-treated, crosslinked network structure formed from a hydroxyl-containing polymer, a thiol-containing silane coupling agent and a crosslinking agent, is disclosed. Also disclosed are a process for preparing the complex nanofiltration membrane and use of the complex nanofiltration membrane in water treatment.
    Type: Application
    Filed: July 22, 2015
    Publication date: January 28, 2016
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Yang ZHANG, Yiqun LIU, Guoyuan PAN, Hao YAN, Jian XU, Min GUO
  • Patent number: 9233942
    Abstract: The present invention relates to an alumina support for silver catalyst, a process for preparing said alumina support, a silver catalyst made from said alumina support, and a use of said silver catalyst in the production of ethylene oxide by the oxidization of ethylene. According to the present invention, the silver catalyst made from the support prepared by potassium melt technology can have a high selectivity.
    Type: Grant
    Filed: September 30, 2011
    Date of Patent: January 12, 2016
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Wei Lin, Jinbing Li, Jianshe Chen, Zhixiang Zhang, Qiang Lin, Jun Jiang, Shuyuan Cao, Qian Xue, Shujuan Wang, Zhiqiang Tang