Patents Assigned to Bostik, Inc.
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Patent number: 12247142Abstract: A hot melt adhesive composition comprises a polypropylene homopolymer having a DSC melting point of less than 100° C.; a butene-based copolymer; and a plasticizer. The butene-based copolymer may comprise a butene-rich amorphous poly-alpha olefin, such as a butene-propylene copolymer, or a semi-crystalline copolymer, such as a butene-ethylene copolymer. The hot melt adhesive is especially useful for bonding substrates which swell or elongate significantly in use. Such uses include adhering superabsorbent polymers to a substrate or adhering together two substrates at least one of which having superabsorbent polymers, such as the top and bottom layer of an absorbent core of a disposable hygiene article, such as a diaper, feminine sanitary napkin, and adult incontinence pad. The hot melt adhesive composition, which does not contain a tackifier, demonstrates suitable elongation at break and stress at yield, with a sufficiently low viscosity, to stabilize an absorbent core having superabsorbent polymers.Type: GrantFiled: July 10, 2020Date of Patent: March 11, 2025Assignees: Bostik Inc., Bostik SAInventors: Kimberly E. Secrist, Steven D. Gray, Naji Hussein
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Patent number: 12245922Abstract: A hot melt wetness indicator comprising an adhesive base composition utilizing a halogen-free species, namely nitrazine yellow, to trigger color change in hygiene articles, such as disposable diapers, to serve as moisture or wetness indicator upon insult. In some embodiments of the invention, the wetness indicator turns from yellow to purple.Type: GrantFiled: March 12, 2020Date of Patent: March 11, 2025Assignee: Bostik Inc.Inventors: Kimberly E. Secrist, Neil G. Janetski
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Patent number: 11945977Abstract: A hot melt adhesive comprises at least one polymer selected from the group consisting of polystyrene, polybutene, polyisobutene, linear low density polyethylene, polypropylene random copolymer, polypropylene, olefin block copolymer, polyolefins, styrene block copolymers, and ethyl vinyl acetate polymers; a tackifying resin; and at least one precisely end-capped polystyrene (PECPS). The use of the styrene-based oligomers and polymers with the precisely controlled end-groups in hot melt adhesive formulations to improve compatibility with polymers and block copolymers frequently used in such adhesives.Type: GrantFiled: February 20, 2018Date of Patent: April 2, 2024Assignee: Bostik, Inc.Inventors: Steven D. Gray, Darius K. Deak, Brian R. Minix, Edward P. Tomlinson
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Patent number: 11912906Abstract: A hot melt adhesive composed of an ethylene vinyl acetate copolymer, a hydrogenated styrenic block copolymer, a tackifying resin, and a liquid plasticizer. The preferred ethylene vinyl acetate copolymer has a vinyl acetate content between 8 and 28 percent by weight, and the preferred hydrogenated styrenic block copolymer is a styrene-ethylene-butylene-styrene having about 30% styrene content and essentially no diblock. The hot melt gives excellent peel strength when used as a construction adhesive for disposable nonwoven articles. It can also be formulated to exhibit very low bleed through and blocking characteristics when used on low basis weight nonwoven fabrics.Type: GrantFiled: July 11, 2014Date of Patent: February 27, 2024Assignee: Bostik, Inc.Inventors: Kevin Stafeil, Kathleen M Farris
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Patent number: 11851537Abstract: A method for making a plasticized polymer comprises polymerizing a polymerizable monomer, such as an ethylenically unsaturated monomer, in a plasticizer, such as mineral oil, and in the presence of a catalyst system. The plasticized polymer may be mixed with a tackifying resin in a method for making an adhesive. A composition, which may be useful as an adhesive, comprises a polymer system comprising a first polymer; a plasticized system comprising a first plasticizer that was in the presence of the first polymer during the polymerization step to make the first polymer; and a tackifier. The method can be used to make compositions having polymers with a low density or a low molecular weight or both. The final compositions made by methods of the invention include adhesives, sealants, coating, or lubricants.Type: GrantFiled: September 27, 2019Date of Patent: December 26, 2023Assignee: Bostik, Inc.Inventors: Steven D. Gray, Kimberly E. Secrist, Miao Hu
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Patent number: 11806971Abstract: A semicrystalline copolyester resin composition formed by twin screw extrusion of various ingredients includes copolyester resins, antiblock, slip and antifog additives. This semicrystalline copolyester resin can be extruded on to PET film or coextruded with PET resin to form clear PET films with antifog properties. These films with antifog properties are produced in a single step without the use of solvent and does not involve any secondary step for coating a separate antifog layer. This minimizes the cost and time required by a converter to make such clear antifog films. These films containing the heat seal copolyester resin can be heat sealed to clear APET trays. Contents within the trays, such as food, can be seen without fogging on the inside of the film that is used to seal the tray. The seals are strong and the peels are smooth giving a very good packaging performance.Type: GrantFiled: February 7, 2022Date of Patent: November 7, 2023Assignee: Bostik, Inc.Inventor: Deepa Puthanparambil
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Publication number: 20230234341Abstract: A multilayer film comprising, in this order: (a) a biaxially oriented polyethylene terephthalate layer, (b) a pressure sensitive adhesive layer, (c) an elastic polyurethane dispersion, and (d) a biaxially oriented polyethylene terephthalate layer. Layer (d) preferably has the structure A:B:A:C; where A and B preferably comprise crystalline PET and antiblocking particles and C is preferably an amorphous, heat-sealable copolyester.Type: ApplicationFiled: April 14, 2021Publication date: July 27, 2023Applicants: BOSTIK, INC., TERPHANE LLCInventors: Kasra MIRMESDAGH, Ellen SMITH
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Patent number: 11661537Abstract: A hot melt adhesive comprises a polylactide homopolymer or copolymer, such as polylactic acid; sulfonated copolyester; and at least one plasticizer, and is compostable. The plasticizer may be a solid plasticizer, such as a benzoate, and a second plasticizer may also be used. The adhesive is suitable for use in a variety of applications, such as case and carton applications, use with burlap or other compostable substrates for tree bulbs or plant seeds, and use with other compostable films, and is especially appropriate for dual-walled paperboard beverage cups. The adhesive demonstrates good bond performance comparable to non-compostable adhesives over a range of temperatures, reflective of the temperatures of hot and cold beverages.Type: GrantFiled: September 6, 2019Date of Patent: May 30, 2023Assignee: Bostik, Inc.Inventors: Monina D. Kanderski, Michael D. Vitrano, David P. Keuler, Deepa Puthanparambil, Jacqueline M. Lambert, Brian J. Morrow
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Patent number: 11643578Abstract: A hot melt adhesive composed of a styrene-butadiene-styrene polymer having a relatively high diblock content and styrene content, a second styrenic block copolymer having a lower diblock content than the styrene-butadiene-styrene polymer, which is preferably a styrene-isoprene-styrene polymer, together with tackifying resin, and liquid plasticizer. The preferred styrene-butadiene-styrene polymer contains a styrene content of greater than 30 percent and a diblock content greater than 30 percent by weight. When used in conjunction with a styrene-isoprene-styrene polymer, the hot melt composition provides improved peel strength at 5° C., and when used as a pad attachment positioning adhesive, did not exhibit adhesive transfer at 40° C.Type: GrantFiled: January 16, 2015Date of Patent: May 9, 2023Assignee: BOSTIK, INC.Inventors: Kevin Stafeil, Kelley Gerschke, Kyle Gerarden
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Patent number: 11365329Abstract: A polymer composition for use in a hot melt adhesive comprises at least one semierystalline, low molecular weight (LMW) propylene-based polymer; at least one essentially amorphous, high molecular weight (HMW) propylene-based polymer; and at least one essentially amorphous, LMW propylene-based polymer. A hot melt adhesive composition further contains a tackifier, a plasticizer, an antioxidant, and optionally a wax, a filler, a colorant, a UV absorber, another polymer, or combinations thereof. The hot melt adhesive is useful for a variety of industrial applications where bonding of low surface energy substrates is encountered, including disposable nonwoven hygienic articles, labeling and other assembly applications.Type: GrantFiled: October 11, 2018Date of Patent: June 21, 2022Assignee: Bostik, Inc.Inventors: Baoyu Wang, Ronald F. Graf, Russell Stuczynski
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Patent number: 11338565Abstract: A method and system of using a polyolefin-based, hot melt adhesive improves creep performance of elastic strands adhered to another substrate. Some deflection, greater than 1°, of the exit angle formed by a line normal to the axis of a neutrally-positioned applicator and the elastic strand extending from the applicator is introduced. Preferably, deflection of the entrance angle is also introduced and a head tilt angle is also provided. The use of deflection improves creep performance or allows for a reduced amount of adhesive to be used to achieve the same or similar creep performance. The elastic strands may be used to form a leg cuff in personal care products, such as diapers, and the substrate to which they are applied could be a polyethylene film or non-woven materials.Type: GrantFiled: May 4, 2017Date of Patent: May 24, 2022Assignee: Bostik, Inc.Inventors: Kimberly E. Secrist, Ronald F. Graf
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Patent number: 11299657Abstract: A hot melt adhesive composition made from polypropylene copolymer or polypropylene impact copolymer, a polyolefin elastomer, a low density polyethylene, a tackifying resin, a plasticizer, and a nucleating agent. These adhesives are fast setting yet show an improved balance of mechanical properties making them useful for hygiene, construction, and packaging applications.Type: GrantFiled: April 16, 2015Date of Patent: April 12, 2022Assignee: BOSTIK, INC.Inventors: Steven Daniel Gray, Miao Hu
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Patent number: 11273627Abstract: A semicrystalline copolyester resin composition formed by twin screw extrusion of various ingredients includes copolyester resins, antiblock, slip and antifog additives. This semicrystalline copolyester resin can be extruded on to PET film or coextruded with PET resin to form clear PET films with antifog properties. These films with antifog properties are produced in a single step without the use of solvent and does not involve any secondary step for coating a separate antifog layer. This minimizes the cost and time required by a converter to make such clear antifog films. These films containing the heat seal copolyester resin can be heat sealed to clear APET trays. Contents within the trays, such as food, can be seen without fogging on the inside of the film that is used to seal the tray. The seals are strong and the peels are smooth giving a very good packaging performance.Type: GrantFiled: January 10, 2018Date of Patent: March 15, 2022Assignee: Bostik, Inc.Inventor: Deepa Puthanparambil
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Patent number: 11268001Abstract: An adhesive composition for adhesively bonding floor coverings to a variety of substrates. The composition includes 0.2 to 10 weight percent of a plurality of irregularly shaped spacer particles of size 0.5 mm to 10 mm; 10 to 50 weight percent of a moisture curable polymer system; and 40 to 90 weight percent of additives for modifying physical properties of the composition. The adhesive has a composition such that, when cured, results in an elastomeric film of uniform thickness that exhibits controlled moisture vapor transmission and sound abatement properties. A floor structure and a method for constructing the floor structure using the adhesive composition are also provided.Type: GrantFiled: April 20, 2018Date of Patent: March 8, 2022Assignee: Bostik, Inc.Inventors: Michael S. Lontchar, Michael A. Chronister, Kristin J. Ryan
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Patent number: 11261355Abstract: A hot melt adhesive composition, which may be used as a construction adhesive in hygiene articles, comprises a first polymer comprising a unimodal copolymer of propylene and ethylene and having a weight average molecular weight of between about 5,000 and 60,000 daltons; a second polymer comprising a copolymer of propylene and ethylene and having a weight average molecular weight of at least 100,000 daltons; a tackifying resin having a Ring & Ball softening point of at most 115° C.; and a plasticizer. The composition demonstrates good peel strength and good shear resistance and is sprayable, with a sufficiently low viscosity, at low application temperatures, such as at about 121° C.Type: GrantFiled: January 29, 2019Date of Patent: March 1, 2022Assignee: Bostik, Inc.Inventors: Jill Marie Scheu, Kimberly Eileen Secrist, Kathleen M. Farris
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Patent number: 10815398Abstract: A hot melt adhesive that is composed of a metallocene catalyzed polyethylene polymer, a hydrogenated styrenic block copolymer, a tackifying resin, and a solid plasticizer. The preferred polyethylene polymer is an ethylene-octene copolymer, and the preferred styrenic block copolymer is a styrene-ethylene-butylene-styrene having less than 30% styrene content. The preferred solid plasticizer is either glycerol tribenzoate or 1,4-cyclohexane dimethanol dibenzoate.Type: GrantFiled: April 9, 2012Date of Patent: October 27, 2020Assignee: BOSTIK, INC.Inventors: Michael D. Vitrano, Kevin Stafeil, Tsebaot Hailemichael
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Patent number: 10779995Abstract: The present invention is directed to a novel process for dosing super absorbent polymer particles into a plurality of particles flows, comprising the steps of: (i) providing super absorbent polymer particles; (ii) imparting a rotation to said particles; and (iii) collecting separate flows of particles, wherein the step (ii) is performed with a rotating mobile (11) provided into a housing (12). Use for manufacturing absorbent article and article thus obtained.Type: GrantFiled: December 20, 2013Date of Patent: September 22, 2020Assignees: BASF SE, BOSTIK INC.Inventor: Jean Francois Chartrel
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Patent number: 10759978Abstract: A hot melt adhesive made from a blend of a polypropylene-based polymer, a polyolefin elastomer, and an amorphous polyolefin. These adhesives exhibit excellent molten and pre-set flow allowing them to wet out substrates yet develop properties needed to form and maintain strong bonds making them useful for hygiene, construction, and packaging applications.Type: GrantFiled: October 13, 2015Date of Patent: September 1, 2020Assignee: BOSTIK, INC.Inventors: Steven Daniel Gray, David Frederic Freund, Richard Edward Hamann, Miao Hu, Fabrice Nicolas-Henri Flores
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Patent number: 10597563Abstract: A laminate comprises a primary substrate and a secondary substrate mated with the primary substrate through contact with a hot melt adhesive. The hot melt adhesive comprises a polymer blend based on a low molecular weight semicrystalline propylene based polymer and a high molecular weight essentially amorphous propylene based polymer, both of which are prepared by using single-site catalysts. The composition further contains a compatible tackifier, a plasticizer, an antioxidant, and optionally a wax, a filler, a colorant, a UV absorber, another polymer, or combinations thereof. Particularly preferred applications include nonwoven disposable diaper and feminine sanitary napkin construction, diaper and adult incontinent brief elastic attachment, diaper and napkin core stabilization, diaper backsheet lamination, industrial filter material conversion, and surgical gown and surgical drape assemblies.Type: GrantFiled: January 9, 2019Date of Patent: March 24, 2020Assignee: BOSTIK, INC.Inventors: Baoyu Wang, Kelley Gerschke, Terhi I. Hawkins, Charley Paul, Kimberly E. Secrist
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Patent number: 10563086Abstract: A low temperature heat seal coating solution which contains an amorphous or semi-crystalline polyester or co-polyester resin, tackifier, anti-blocking agent, and solvent. The coating solution can be applied to a packaging web such as a foil or film by converters using conventional methods such as gravure, rod, slot die, or printing process. The heal seal coating can be sealed to itself or another substrate to manufacture food packaging bags or pharmaceutical blister packaging. The heat seal temperature can be as low as 70° C. under conventional equipment and conditions in the industry.Type: GrantFiled: March 27, 2017Date of Patent: February 18, 2020Assignee: Bostik, Inc.Inventors: Darius K. Deak, Thomas L. Ruppert, Elaine Lo