Patents Assigned to Catalysts & Chemicals Industries Co., Ltd.
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Patent number: 7309457Abstract: A chain antimony oxide fine particle group comprising antimony oxide fine particles which have an average particle diameter of 5 to 50 nm, are connected in the form of a chain and have an average connection number of 2 to 30 and preferably used for forming a hard coating film. The fine particle group can be prepared by a process comprising treating an alkali antimonate aqueous solution with a cation exchange resin to prepare an antimonic acid (gel) dispersion and then treating the dispersion with an anion exchange resin and/or adding a base to the dispersion. Also provided is a substrate with a film comprising a substrate and a hard coating film. The hard coating film includes a chain inorganic oxide fine particle group, in which inorganic oxide fine particles of 2 to 30 on the average are connected in the form of a chain, and a matrix.Type: GrantFiled: November 5, 2004Date of Patent: December 18, 2007Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Ryo Muraguchi, Masayuki Matsuda, Hiroyasu Nishida, Toshiharu Hirai, Mitsuaki Kumazawa
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Publication number: 20070275257Abstract: To provide silica-based particles with a low refractive index, the hollow and spherical silica-based particles include porous materials or cavities inside an outer shell thereof by growing porous composite oxide particles (primary particles) adjusting a ratio of a quantity of added silica sources versus a quantity of added sources for an inorganic oxide other than silica and then removing the inorganic oxide other than silica. The dispersion liquid of silica-based particles is aged at a range from the room temperature to 300° C., cleaning is performed according to the necessity, and hydrothermal processing is performed at a temperature in the range from 50 to 300° C.Type: ApplicationFiled: July 19, 2005Publication date: November 29, 2007Applicant: Catalysts & Chemicals Industries Co., LtdInventors: Ryou Muraguchi, Mitsuaki Kumazawa, Toshiharu Hirai
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Publication number: 20070249736Abstract: It is an object of the present invention to provide a material which is applied to substrates by an easy and simple process, is applicable to substrates of a wide range and is capable of forming an antifouling film exhibiting excellent antifouling performance, and a substrate with an ink-receiving layer having excellent decoloring property. The titanium-containing silica sol of the invention includes (a) the following fine particles (a1) or the following fine particles (a2) and (b) a dispersion medium: (a1) titania fine particles having a mean particle diameter of 2 to 50 nm and porous silica fine particles having a mean particle diameter of 5 to 100 nm and a specific surface area, as determined by BET method, of not less than 300 m2/g, or (a2) porous silica fine particles obtained by surface-modifying surfaces of porous silica fine particles having a mean particle diameter of 5 to 100 nm and a specific surface area, as determined by BET method, of not less than 300 m2/g with a titanate compound.Type: ApplicationFiled: September 1, 2005Publication date: October 25, 2007Applicant: Catalysts & Chemicals Industries Co., Ltd.Inventors: Manabu Watanabe, Tatsuo Ogawa, Hiroyasu Nishida, Michio Komatsu
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Patent number: 7232769Abstract: The present invention relates to an amorphous silica-based coating film with a low specific dielectric constant of 2.5 or below and the Young's modulus of 6.0 GPa or more and having excellent hydrophobic property, and to a method of forming the same. A liquid composition containing a silicon compound obtained by hydrolyzing tetraalkyl ortho silicate (TAOS) and specific alkoxysilane (AS) in the presence of tetraalkyl ammonium hydroxide (TAAOH) is prepared. The liquid composition is then applied on a substrate, heated and cured to obtain a coating film. The coating film obtained as described has a smooth surface and also has specific micropores therein.Type: GrantFiled: October 27, 2003Date of Patent: June 19, 2007Assignees: Catalysts & Chemicals Industries Co., Ltd., Fujitsu LimitedInventors: Akira Nakashima, Miki Egami, Michio Komatsu, Yoshihiro Nakata, Ei Yano, Katsumi Suzuki
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Publication number: 20070119750Abstract: The desulfurization catalyst for catalytic cracked gasoline according to the present invention has high performance in removal of sulfur compounds in gasoline fractions. This catalyst contains particulate vanadium oxide having the average particle diameter in the range from 0.1 to 10 ?m at the content in the range from 0.3 to 3 weight % calculated as that of V2O5. The porous spherical particles of inorganic oxide are made of crystalline aluminosilicate zeolite and a porous inorganic oxide matrix, and furthermore contain antimony.Type: ApplicationFiled: November 21, 2006Publication date: May 31, 2007Applicant: CATALYSTS & CHEMICALS INDUSTRIES CO., LTD.Inventors: Seijiro Nonaka, Hiroshi Matsumoto, Yoshiaki Kato, Kazuo Shirozono
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Patent number: 7192986Abstract: An inorganic compound sol comprises a dispersion medium and, dispersed therein, inorganic compound particulates whose surface has been modified by an organic compound exhibiting a molecular polarizability of from 2×10?40 to 850×10?40C2m2J?2. The inorganic compound sol modified by an organic compound possesses a desirable affinity with the dispersion media, providing excellent dispersion stability in solvents while avoiding aggregation of particulates.Type: GrantFiled: March 11, 1998Date of Patent: March 20, 2007Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Tsuguo Koyanagi, Hiroyasu Nishida
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Patent number: 7163892Abstract: There is provided a process for producing an integrated circuit, wherein not only can conductive fine particles be deposited efficiently and densely in minute wiring channels and connecting holes but also a circuit of low wiring resistance and high density can be formed and wherein a high-degree integration can be achieved to thereby bring about an economic advantage. In particular, there is provided a process for producing an integrated circuit, comprising coating a substrate provided with wiring channels with a coating liquid for integrated circuit formation containing conductive fine particles to thereby form an integrated circuit on the substrate, wherein the coating liquid for integrated circuit formation while being exposed to ultrasonic waves is applied to the wiring channels.Type: GrantFiled: April 23, 2001Date of Patent: January 16, 2007Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Atsushi Tonai, Toshiharu Hirai, Tsuguo Koyanagi, Masayuki Matsuda, Michio Komatsu
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Publication number: 20060286051Abstract: Present invention provides an antibacterial deodorant with antibacterial characteristics and high deodorizing capability. The antibacterial deodorant is inorganic oxide particles comprising a metal component and an inorganic oxide other than the metal component, the inorganic oxide includes titanium oxide and silica and/or zirconia, and the titanium oxide is crystalline titanium oxide. A content of the metal component in the inorganic oxide particles is in a range from 0.1 to 30% by weight as converted to an oxide thereof, and an average particle diameter of the inorganic oxide particle is in a range from 2 to 500 nm.Type: ApplicationFiled: April 29, 2005Publication date: December 21, 2006Applicant: CATALYSTS & CHEMICALS INDUSTRIES CO., LTD.Inventors: Atsushi Tanaka, Tsuguo Koyanagi
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Publication number: 20060269733Abstract: There is provided an antireflective laminate having a low refractive index and excellent mechanical strength, which comprises a coating layer of an ionizing radiation curing-type resin composition comprising ionizing radiation curing group-containing hollow silica fine particles. The antireflective laminate comprises a light transparent base material and at least a low refractive index layer having a refractive index of not more than 1.45 provided on the light transparent base material, wherein the low refractive index layer comprises an ionizing radiation curing-type resin composition and silica fine particles having an outer shell layer with the interior of the silica fine particles being porous or void, and, for a part or all of the silica fine particles, at least a part of the surface of the silica fine particle has been treated with an ionizing radiation curing group-containing silane coupling agent.Type: ApplicationFiled: August 26, 2004Publication date: November 30, 2006Applicants: Dai Nippon Printing Co., Ltd., Catalysts & Chemicals Industries Co., Ltd.Inventors: Utako Mizuno, Midori Nakajo, Seiji Shinohara, Toshio Yoshihara, Hiroyasu Nishida, Ryo Muraguchi, Masafumi Hirai
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Publication number: 20060234087Abstract: A transparent film-forming coating liquid is provided which is capable of forming a transparent film that is excellent not only in scratch resistance, film hardness, scratch strength and adhesion to a substrate but also in haze and anti-glare properties. Also provided is a display device having a front panel constituted of a substrate with such a transparent film applied thereto. The transparent film-forming coating liquid comprises inorganic oxide particle groups, in each of which 2 to 10 inorganic oxide particles on an average are linked in the form of a chain, and a polar solvent. In the transparent film-forming coating liquid, the inorganic oxide particles have an average particle diameter of 4 to 200 nm. The inorganic oxide particles are silica particles, and the silica particles are porous particles and/or hollow particles each having a cavity inside.Type: ApplicationFiled: May 12, 2004Publication date: October 19, 2006Applicant: CATALYSTS & CHEMICALS INDUSTRIES CO., LTD.Inventors: Mitsuaki Kumazawa, Masayuki Matsuda, Toshiharu Hirai
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Publication number: 20060084277Abstract: The present invention relates to an amorphous silica-based coating film with a low specific dielectric constant of 2.5 or below and the Young's modulus of 6.0 GPa or more and having excellent hydrophobic property, and to a method of forming the same. A liquid composition containing a silicon compound obtained by hydrolyzing tetraalkyl ortho silicate (TAOS) and specific alkoxysilane (AS) in the presence of tetraalkyl ammonium hydroxide (TAAOH) is prepared. The liquid composition is then applied on a substrate, heated and cured to obtain a coating film. The coating film obtained as described has a smooth surface and also has specific micropores therein.Type: ApplicationFiled: October 27, 2003Publication date: April 20, 2006Applicants: Catalysts & Chemicals Industries Co., Ltd, Fujitsu LimitedInventors: Akira Nakashima, Miki Egami, Michio Komatsu, Yoshihiro Nakata, Ei Yano, Katsumi Suzuki
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Publication number: 20060046000Abstract: A recording sheet with an ink-receptive layer which can be used not only for dye type inks but also for pigment type inks. The sheet has excellent printing properties such that a print free from ink blotting is obtainable and clear printing with uniform density is feasible, is excellent in water resistance, weathering resistance and fading resistance and has sufficiently high strength. Also provided is a coating liquid for forming an ink-receptive layer. The recording sheet with an ink-receptive layer is a recording sheet including a substrate sheet and an ink-receptive layer formed thereon, wherein the ink-receptive layer comprises (i) fibrous crystalline particles on surfaces of which a cationic hydrated metal compound is supported and (ii) a binder. In the recording sheet with an ink-receptive layer, the fibrous crystalline particles have an average fiber diameter (D) of 0.Type: ApplicationFiled: November 20, 2003Publication date: March 2, 2006Applicant: Catalysts & Chemicals Industries Co., Ltd.Inventors: Manabu Watanabe, Hiroyasu Nishida
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Publication number: 20060034879Abstract: Scale-like composite particles having oily feel as well as soft and smooth feel are provided. The scale-like composite particles include inorganic oxide particles having an average diameter in a range from 0.1 to 3.0 ?m and adhered in a single layer to a surface of resin-coated scale-like inorganic particles. The scale-like inorganic particles may include natural minerals such as mica, talc and sericite, synthetic mica, synthetic sericite, plate-like titanium oxide, and resin may include resin having rubber-like elasticity such as polyurethane, styrene-butadiene copolymer, acrylonitrile-butadiene copolymer, silicone rubber, crude rubber and nylon-based elastomer.Type: ApplicationFiled: August 10, 2005Publication date: February 16, 2006Applicant: CATALYSTS& CHEMICALS INDUSTRIES CO., LTDInventors: Takumi Miyazaki, Hirokazu Tanaka, Shuji Akeda
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Publication number: 20060009575Abstract: The present invention relates to a coating liquid for forming an amorphous silica-based coating film with a low dielectric constant of 2.5 or below and the Young's modulus of 6.0 GPa or more and having excellent hydrophobic property, and to a method of preparing the same. The coating liquid may contain a silicon compound obtained by hydrolyzing tetraalkyl ortho silicate (TAOS) and specific alkoxysilane (AS) in the presence of tetraalkyl ammonium hydroxide (TAAOH), or may contain a silicon compound obtained by hydrolyzing or partially hydrolyzing tetraalkyl ortho silicate (TAOS) in the presence of tetraalkyl ammonium hydroxide (TAAOH), mixing the reaction product with specific alkoxysilane or a hydrolysate or a partial hydrolysate thereof, and hydrolyzing all or a portion of the mixture according to the necessity. In addition, the coating liquid is prepared by mixing components described above at a specific ratio and under specific process conditions.Type: ApplicationFiled: October 27, 2003Publication date: January 12, 2006Applicants: CATALYSTS & CHEMICALS INDUSTRIES CO., LTD., FUJITSU LIMITEDInventor: Akira Nakashima
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Patent number: 6923974Abstract: A flaky, fine powder comprising a flaky substance as the base and silica particles covering the surface of the base, aimed at reducing the glossiness of the base caused by the irregular reflection of light on its surface and improving the slipperiness. In particular, the powder comprises a flaky base substance such as natural mica and silica particles deposited on the base surface, wherein the silica particles may be optionally further immobilized by the hydrolysate of alkoxysilane or silica gel. The flaky fine powder is produced either by the adding alkoxysilane to a dispersion containing a flaky substance and silica particles and hydrolyzing it, by adding a silicic acid solution to the dispersion and gelling it, or by adding a combination of alkoxysilane and silicic acid solution. The powder can be compounded with various ingredients and is particularly useful with cosmetics.Type: GrantFiled: March 28, 2001Date of Patent: August 2, 2005Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Hirokazu Tanaka, Naoyuki Enomoto
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Publication number: 20050118220Abstract: Cosmetics comprising spherical and nonporous particles with a pore volume of substantially zero and having a blurring effect is provided. The cosmetics comprise spherical and nonporous particles by 0.1 to 70% by weight, a liquid component, and the balance of solid components other than the spherical and nonporous particles, and the spherical and nonporous particles each comprise aggregate of inorganic oxide particles having an average particle diameter in a range from 1 to 100 ?m comprising fine particles of inorganic oxide having an average diameter in a range from 2 to 250 nm and a silica-based layer coating the aggregate.Type: ApplicationFiled: January 11, 2005Publication date: June 2, 2005Applicant: CATALYSTS& CHEMICALS INDUSTRIES CO., LTDInventors: Takumi Miyazaki, Hirokazu Tanaka
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Patent number: 6893726Abstract: A coating liquid for forming a silica-containing film with a low-dielectric constant which enables formation of low-density film having a dielectric constant as low as 3 or less and having excellent resistance to oxygen plasma and process adaptation but also in the adhesion to a substrate and film strength. A substrate coated with the silica-containing film having the above characteristics, obtained by the use of the above coating liquid.Type: GrantFiled: August 26, 2003Date of Patent: May 17, 2005Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Akira Nakashima, Michio Komatsu
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Patent number: 6890647Abstract: Highly transparent alumina hydrate particles having a large pore volume, having a pore diameter which falls in a specified range and, when formed into a high-concentration dispersion sol, exhibiting a low viscosity are provided. Alumina hydrate particles having a composition represented by the general formula xM2O.y(NH4)2O.Al2O3.zH2O (2×10?4?x?25×10?4, 0.1×10?4?y?20×10?4, 0.6?z?2.5, M represents an alkali metal; when the alkali metal is in the form of M2O, x is the number of moles thereof per mol of Al2O3; when ammonia is in the form of (NH4)2O, y is the number of moles thereof per mol of Al2O3; and z is the number of moles of hydration water (H2O) per mol of Al2O3), the alumina hydrate particles having an average particle diameter of 0.02 to 0.2 ?m, a total pore volume of 0.5 to 1.5 ml/g, and a volume of pores whose diameter is from 15 to 30 nm ranging from 0.3 to 1.0 ml/g.Type: GrantFiled: August 9, 2000Date of Patent: May 10, 2005Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Hiroyasu Nishida, Naoyuki Enomoto, Michio Komatsu
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Patent number: 6864415Abstract: A photoelectric cell that includes a first insulating base, having on its surface a first electrode layer, which has on its surface a metal oxide semiconductor film, which includes anatase titanium oxide particles, on which a photosensitizer is absorbed and a second insulating base having on its surface a second electrode layer and an electrolyte sealed between the metal oxide semiconductor film and the second electrode layer. The first electrode layer and the second electrode layer are arranged opposite from each other. At least one of the first and second insulating bases with an electrode layer is transparent.Type: GrantFiled: February 6, 2003Date of Patent: March 8, 2005Assignee: Catalysts & Chemicals Industries Co., Ltd.Inventors: Tsuguo Koyanagi, Michio Komatsu, Hirokazu Tanaka, Katsuhiro Shirono
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Patent number: 6858294Abstract: A coating liquid for forming on a substrate surface a hard coat film which exhibits a high refractive index, being excellent in resistance to hot water, weather resistance, scuffing resistance, attrition resistance and dye affinity, and which does not exhibit photochromism, is provided. A coating liquid for forming a hard coat film, comprises a matrix-forming component and composite metal oxide particles of 1 to 100 nm average particle size, composed either of an iron oxide component and a titanium oxide component used at a specified ratio or an iron oxide component, a titanium oxide component and a silica component used at a specified ratio. A substrate coated with a hard coat film is formed by applying the above coating liquid to the substrate surface and effecting drying.Type: GrantFiled: December 14, 1998Date of Patent: February 22, 2005Assignee: Catalyst & Chemicals Industries Co., Ltd.Inventors: Hirokazu Tanaka, Masafumi Hirai, Chiemi Murakami