Patents Assigned to Celgard LLC
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Patent number: 12278348Abstract: A system for differentiating short circuiting in a battery includes: a detector coupled to the battery; a monitor in communication with the detector, the monitor including a profile of a battery shorting behavior, and a comparator for matching data from the detector to the profile; and a controller for taking action based upon information from the detector. A method for detecting short circuiting in a battery includes the steps of: detecting a behavior of the battery; comparing the behavior of the battery to a predetermined battery behavior profile; determining the type of short based on the comparison; and taking mitigating action based on the determination. The system/method may monitor temperature of the battery, heat generation from the battery, current flow through the battery, voltage drop across the battery, and/or combinations thereof. The system/method discriminates between the various battery shorting behaviors for aggressive response or passive response.Type: GrantFiled: February 15, 2021Date of Patent: April 15, 2025Assignee: Celgard, LLCInventors: Zhengming Zhang, Weifeng Fang
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Patent number: 12263649Abstract: Improved battery separators, base films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of making and/or using such separators, films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of enhancing battery or cell charge rates, charge capacity, and/or discharge rates, and/or methods of improving batteries, systems including such batteries, vehicles including such batteries and/or systems, and/or the like; biaxially oriented porous membranes, composites including biaxially oriented porous membranes, biaxially oriented microporous membranes, biaxially oriented macroporous membranes, battery separators with improved charge capacities and the related methods and methods of manufacture, methods of use, and the like; flat sheet membranes, liquid retention media; dry process separators; biaxially stretched separators; dry process biaxially stretched separators having a thickness range between about 5 ?m and 50 ?m, preferably between about 10 ?m and 25 ?m, having impType: GrantFiled: December 4, 2023Date of Patent: April 1, 2025Assignee: Celgard, LLCInventors: Xiaomin Zhang, Gerald P. Rumierz, Karl F. Humiston, Charles E. Haire, Tyrone S. Fields, Michael A Braswell, Ronald A. Proctor, Ronnie E. Smith
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Patent number: 12246520Abstract: Microporous battery separator membranes, separators, batteries including such membranes, separators are provided. A battery separator for a secondary or rechargeable lithium battery may have low Electrical resistance of less than 0.95 ohm-cm2. The inventive battery separator membrane may provide a means to achieve an improved level of battery performance in a rechargeable or secondary lithium battery based on a possibly synergistic combination of low Electrical resistance, low Gurley, low tortuosity, and/or a unique trapezoid shaped pore. Certain multilayer embodiments (by way of example only, a trilayer membrane made of two polypropylene layers with a polyethylene layer in between), the inventive microporous membrane or battery separator may have excellent onset and rate of thermal shutdown performance.Type: GrantFiled: August 21, 2023Date of Patent: March 11, 2025Assignee: Celgard, LLCInventors: Xiaomin Zhang, Lie Shi
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Patent number: 12230760Abstract: A microporous film having at least one of the following properties: unrestrained MD shrinkage, when the film is baked unrestrained at 90° C. for 1 hour, of 2% or more; unrestrained MD shrinkage, when the film is baked unrestrained at 105° C. for 1 hour, of 2.5% or more; MD restrained growth, when measured using the MD restrained growth test, of less than or equal to 0.2%; rebound or recovery of 5% or greater when measured by the compressibility test; a max compression greater than or equal to 18% when measured by the compressibility test; swelling in DEC when measured according to the swelling in DEC test of 0.95% or less; the film exhibits a round-shaped, not a slit-shaped opening when subjected to the puncture test; the lamellae of the film have a thickness no greater than 250 nm; a normalized puncture strength above 350 g/16 micron; and having higher modulus and lower elongation before break of less than 40% in the machine direction.Type: GrantFiled: November 1, 2018Date of Patent: February 18, 2025Assignee: Celgard, LLCInventors: Changqing Adams, Geoffrey Allen Tice, Gary Michael Shirah
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Patent number: 12218379Abstract: An improved multilayer laminated microporous battery separator for a lithium ion secondary battery, and/or a method of making or using this separator is provided. The preferred inventive dry process separator is a tri-layer laminated Polypropylene/Polyethylene/Polypropylene microporous membrane with a thickness range of 12 ?m to 30 ?m having improved puncture strength and low electrical resistance for improved cycling and charge performance in a lithium ion battery. In addition, the preferred inventive separator's or membrane's low Electrical Resistance and high porosity provides superior charge rate performance in a lithium battery for high power applications.Type: GrantFiled: September 19, 2023Date of Patent: February 4, 2025Assignee: Celgard, LLCInventors: Xiaomin Zhang, Lie Shi, William John Paulus
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Patent number: 12191441Abstract: In accordance with at least selected embodiments, a battery separator or separator membrane comprises one or more co-extruded multi-microlayer membranes optionally laminated or adhered to another polymer membrane. The separators described herein may provide improved strength, for example, improved puncture strength, particularly at a certain thickness, and may exhibit improved shutdown and/or a reduced propensity to split.Type: GrantFiled: August 29, 2023Date of Patent: January 7, 2025Assignee: Celgard, LLCInventors: Kang Karen Xiao, Eric Joseph Penegar, Takahiko Kondo, Robert Nark, Eric Robert White, Xiaomin Zhang, Kristoffer K. Stokes
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Patent number: 12179469Abstract: A microporous membrane is made by a dry-stretch process and has substantially round shaped pores and a ratio of machine direction tensile strength to transverse direction tensile strength in the range of 0.5 to 5.0. The method of making the foregoing microporous membrane includes the steps of: extruding a polymer into a nonporous precursor, and biaxially stretching the nonporous precursor, the biaxial stretching including a machine direction stretching and a transverse direction stretching, the transverse direction stretching including a simultaneous controlled machine direction relax.Type: GrantFiled: February 8, 2021Date of Patent: December 31, 2024Assignee: Celgard, LLCInventors: Xiangyun Wei, Charles Haire
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Patent number: 12166166Abstract: A membrane is a microporous sheet made of a blend of a first ultra high molecular weight polyolefin and a second ultra high molecular weight polyolefin. Each polyolefin has a molecular weight, both of those molecular weights are greater than 1 million, and one molecular weight is greater than the other. Additionally, the intrinsic viscosity (IV) of the membrane may be greater than or equal to 6.3.Type: GrantFiled: September 28, 2020Date of Patent: December 10, 2024Assignee: Celgard, LLCInventors: Donald K. Simmons, Joseph G. Yaritz
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Patent number: 12134259Abstract: Disclosed herein are novel or improved microporous battery separator membranes, separators, batteries including such separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries. Further disclosed are laminated multilayer polyolefin membranes with exterior layers comprising one or more polyethylenes, which exterior layers are designed to provide an exterior surface that has a low pin removal force. Further disclosed are battery separator membranes having increased electrolyte absorption capacity at the separator/electrode interface region, which may improve cycling. Further disclosed are battery separator membranes having improved adhesion to any number of coatings. Also described are battery separator membranes having a tunable thermal shutdown where the onset temperature of thermal shutdown may be raised or lowered and the rate of thermal shutdown may be changed or increased.Type: GrantFiled: August 23, 2021Date of Patent: November 5, 2024Assignee: Celgard, LLCInventors: Xiaomin Zhang, Eric Robert White, Kang Karen Xiao, Robert A Nark, Insik Jeon, Kristoffer K. Stokes, Paul Vido, Zhengming Zhang
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Patent number: 12122133Abstract: The present invention is directed to novel, improved, modified or treated microporous membranes for use in textile related applications and which are preferably composed of two or more dissimilar porous membrane or material layers laminated together using heat, compression and/or adhesives. The preferred inventive laminated composite microporous membrane is modified using a technique or treatment such as microcreping to introduce permanent small, regularly spaced, crepes, profiles, compactions, pleats, or wrinkles into the laminated composite microporous membrane for the purpose of improving mechanical strength, elasticity and/or resiliency. In addition, the inventive microcreped microporous laminated membrane more preferably has significantly improved ‘hand’ or softness, has ‘next-to-the-skin’ softness, and/or is quiet without crinkling noises during movement, which may be desired performance properties or characteristics of or in textile garments, materials or applications.Type: GrantFiled: July 23, 2018Date of Patent: October 22, 2024Assignee: Celgard, LLCInventors: Karl F. Humiston, Gerald P. Rumierz, Jr., Dickie J. Brewer
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Patent number: 12119513Abstract: Problem: The invention provides a separator for a lithium-ion secondary battery exhibiting excellent strength, wettability with nonaqueous electrolyte solutions, voltage endurance and cycle characteristics in lithium-ion secondary batteries, and a method of increasing the puncture depth of the separator. Solution: A separator for a lithium-ion secondary battery is formed of a microporous film comprising a polyolefin resin (A) as a major component, and a resin (B), at least portions of the surfaces of the micropores in the microporous film being coated with resin (B).Type: GrantFiled: April 3, 2018Date of Patent: October 15, 2024Assignees: Asahi Kasei Kabushiki Kaisha, Celgard, LLCInventors: Takahiko Kondo, Kazunori Uchida, Shinya Hamasaki
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Patent number: 12100548Abstract: Disclosed or provided are non-shutdown high melt temperature or ultra high melt temperature microporous battery separators, high melt temperature separators, battery separators, membranes, composites, and the like that preferably prevent contact between the anode and cathode when the battery is maintained at elevated temperatures for a period of time and preferably continue to provide a substantial level of battery function (ionic transfer, discharge) when the battery is maintained at elevated temperatures for a period of time, methods of making, testing and/or using such separators, membranes, composites, and the like, and/or batteries, high temperature batteries, and/or Lithium-ion rechargeable batteries including one or more such separators, membranes, composites, and the like.Type: GrantFiled: July 21, 2020Date of Patent: September 24, 2024Assignee: Celgard, LLCInventors: Lie Shi, C. Glen Wensley, Jill W. Watson
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Patent number: 12040456Abstract: Novel or improved microporous single or multilayer battery separator membranes, separators, batteries including such membranes or separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries are provided. In accordance with at least certain embodiments, a multilayer dry process polyethylene/polypropylene/polyethylene microporous separator which is manufactured using the inventive process which includes machine direction stretching followed by transverse direction stretching and a subsequent calendering step as a means to reduce the thickness of the multilayer microporous membrane, to reduce the percent porosity of the multilayer microporous membrane in a controlled manner and/or to improve transverse direction tensile strength.Type: GrantFiled: January 27, 2023Date of Patent: July 16, 2024Assignee: Celgard, LLCInventors: Kristoffer K. Stokes, William John Mason, Kang Karen Xiao, Xiaomin Zhang, Barry J. Summey, Robert Moran, Jeffrey Gordon Poley, Brian R. Stepp, Changqing Wang Adams, Daniel R. Alexander, Shante P. Williams, Andrew Edward Voss, Douglas George Robertson
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Patent number: 11990639Abstract: The present invention is preferably directed to a polylactam ceramic coating for a microporous battery separator for a lithium ion secondary battery and a method of making this formulation and application of this formulation to make a coated microporous battery separator. The preferred inventive coating has excellent thermal and chemical stability, excellent adhesion to microporous base substrate, membrane, and/or electrode, improved binding properties to ceramic particles and/or has improved or excellent resistance to thermal shrinkage, dimensional integrity, and/or oxidation stability when used in a rechargeable lithium ion battery.Type: GrantFiled: October 12, 2021Date of Patent: May 21, 2024Assignee: Celgard, LLCInventor: Insik Jeon
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Patent number: 11969929Abstract: Described herein is a multilayer microporous film or membrane that may exhibit improved properties, including improved dielectric break down and strength, compared to prior monolayer or tri-layer microporous membranes of the same thickness. The preferred multilayer microporous membrane comprises microlayers and one or more lamination interfaces or barriers. Also disclosed is a battery separator or battery comprising one or more of the multilayer microporous films or membranes. The inventive battery and battery separator is preferably safer and more robust than batteries and battery separators using prior monolayer and tri-layer microporous membranes. Also, described herein is a method for making the multilayer microporous separators, membranes or films described herein.Type: GrantFiled: May 10, 2019Date of Patent: April 30, 2024Assignee: Celgard, LLCInventors: Kang Karen Xiao, Stefan Reinartz, Takahiko Kondo, Hisaki Ikebata, Eric J. Penegar, Robert Nark, Changqing Wang Adams, Masaaki Okada, Brian R. Stepp, Eric Robert White, Allen M. Donn, Katharine Chemelewski
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Patent number: 11955662Abstract: The present invention provides (I) a dry-stretched microporous membrane and a separator for an electric storage device excellent in balance among the required performances such as product safety, charge/discharge characteristics, dimension stability, energy cost, consideration to the environment, etc., (II) a separator for an electric storage device superior in product safety obtained by controlling a puncture depth of a microporous membrane comprised in the separator for an electric storage device, or/and (III) a dry-stretched microporous membrane and a separator for an electric power storage device excellent in product safety realized by controlling a porosity and a puncture strength of a thin microporous membrane.Type: GrantFiled: November 19, 2018Date of Patent: April 9, 2024Assignees: Asahi Kasei Kabushiki Kaisha, Celgard, LLCInventors: Shinya Hamasaki, Masaki Takahashi, Shohei Mori, Yoshiyuki Ishii, Kenji Ebara, Changqing Adams
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Patent number: 11952475Abstract: A novel or improved base film for impregnation, impregnated base film, product incorporating the impregnated base film, and/or related methods as shown, claimed or described herein.Type: GrantFiled: September 12, 2018Date of Patent: April 9, 2024Assignee: Celgard, LLCInventors: Takahiko Kondo, Masaaki Okada, Stefan Reinartz, Daniel R. Alexander
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Patent number: 11949124Abstract: New and/or improved coatings, layers or treatments for porous substrates, including battery separators or separator membranes, and/or coated or treated porous substrates, including coated battery separators, and/or batteries or cells including such coatings or coated separators, and/or related methods including methods of manufacture and/or of use thereof are disclosed. Also, new or improved coatings for porous substrates, including battery separators, which comprise at least a matrix material or a polymeric binder, and heat-resistant particles with additional additives, materials or components, and/or to new or improved coated or treated porous substrates, including battery separators, where the coating comprises at least a matrix material or a polymeric binder, and heat-resistant particles with additional additives, materials or components are disclosed.Type: GrantFiled: January 4, 2019Date of Patent: April 2, 2024Assignee: Celgard, LLCInventors: Zhengming Zhang, Michael B. Lane, Insik Jeon, Edward Kruger, Xiang Yu, Ronnie E. Smith, Stefan Reinartz, Junqing Ma, Daniel R. Alexander
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Patent number: 11923497Abstract: Described herein, are battery separators, comprising the following: a microporous polymeric film; and an optional coating layer on at least one side of the microporous polymeric film, wherein at least one of the microporous polymeric film and the optional coating comprises an additive. The additive is selected from the group consisting of a lubricating agent, a plasticizing agent, a nucleating agent, a shrinkage reducing agent, a surfactant, an SEI improving agent, a cathode protection agent, a flame retardant additive, LiPF6 salt stabilizer, an overcharge protector, an aluminum corrosion inhibitor, a lithium deposition agent or improver, or a solvation enhancer, an aluminum corrosion inhibitor, a wetting agent, and a viscosity improver. Also, described herein are batteries, including lithium-ion batteries, comprising one or more of the described separators. Methods for making the battery separators are also described.Type: GrantFiled: November 1, 2021Date of Patent: March 5, 2024Assignee: Celgard, LLCInventors: Changqing Wang Adams, Kang Karen Xiao, Stefan Reinartz, Masaaki Okada, Brian R. Stepp, Yao Lu, Eric Robert White, Katharine Chemelewski
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Patent number: 11909006Abstract: In accordance with at least selected aspects, objects or embodiments, optimized, novel or improved membranes, battery separators, batteries, and/or systems and/or related methods of manufacture, use and/or optimization are provided. In accordance with at least selected embodiments, the present invention is related to novel or improved battery separators that prevent dendrite growth, prevent internal shorts due to dendrite growth, or both, batteries incorporating such separators, systems incorporating such batteries, and/or related methods of manufacture, use and/or optimization thereof. In accordance with at least certain embodiments, the present invention is related to novel or improved ultra thin or super thin membranes or battery separators, and/or lithium primary batteries, cells or packs incorporating such separators, and/or systems incorporating such batteries, cells or packs.Type: GrantFiled: February 24, 2023Date of Patent: February 20, 2024Assignee: Celgard, LLCInventors: Paul M. Halmo, Xiaomin Zhang, Paul D. Vido, Zhengming Zhang, Lie Shi, Daniel R. Alexander, Jill V. Watson