Patents Assigned to Celgard LLC
  • Patent number: 11482759
    Abstract: A lithium ion rechargeable battery comprises: a negative electrode adapted to give up electrons during discharge, a positive electrode adapted to gain electrons during discharge, a microporous separator sandwiched between said positive electrode and said negative electrode, an organic electrolyte being contained within said separator and being in electrochemical communication with said positive electrode and said negative electrode, and an oxidative barrier interposed between said separator and said positive electrode, and thereby preventing oxidation of said separator.
    Type: Grant
    Filed: June 17, 2019
    Date of Patent: October 25, 2022
    Assignee: Celgard, LLC
    Inventors: Zhengming Zhang, Pankaj Arora
  • Patent number: 11437684
    Abstract: New and/or improved coatings for porous substrates, including battery separators or separator membranes, and/or coated porous substrates, including coated battery separators, and/or batteries or cells including such coatings or coated separators, and/or related methods including methods of manufacture and/or of use thereof are disclosed. Also, new or improved coatings for porous substrates, including battery separators, which comprise at least a polymeric binder and heat-resistant particles with or without additional additives, materials or components, and/or to new or improved coated porous substrates, including battery separators, where the coating comprises at least a polymeric binder and heat-resistant particles with or without additional additives, materials or components are disclosed.
    Type: Grant
    Filed: July 21, 2017
    Date of Patent: September 6, 2022
    Assignee: Celgard, LLC
    Inventors: Michael B. Lane, Insik Jeon, Edward Kruger, Xiang Yu, Ronnie E. Smith, Stefan Reinartz, Junqing Ma
  • Patent number: 11420416
    Abstract: A microporous membrane is made by a dry-stretch process and has substantially round shaped pores and a ratio of machine direction tensile strength to transverse direction tensile strength in the range of 0.5 to 5.0. The method of making the foregoing microporous membrane includes the steps of: extruding a polymer into a nonporous precursor, and biaxially stretching the nonporous precursor, the biaxial stretching including a machine direction stretching and a transverse direction stretching, the transverse direction stretching including a simultaneous controlled machine direction relax.
    Type: Grant
    Filed: June 20, 2014
    Date of Patent: August 23, 2022
    Assignee: Celgard, LLC
    Inventors: Xiangyun Wei, Charles Haire
  • Patent number: 11283135
    Abstract: A membrane includes a porous membrane or layer made of a polymeric material having a plurality of surface treated (or coated) particles (or ceramic particles) having an average particle size of less than about 1 micron dispersed therein. The polymeric material may be selected from the group consisting of polyolefins, polyamides, polyesters, co-polymers thereof, and combinations thereof. The particles may be selected from the group consisting of boehmite (AlOOH), SiO2, TiO2, Al2O3, BaSO4, CaCO3, BN, and combinations thereof, or the particles may be boehmite. The surface treatment (or coating) may be a molecule having a reactive end and a non-polar end. The particles may be pre-mixed in a low molecular weight wax before mixing with the polymeric material. The membrane may be used as a battery separator.
    Type: Grant
    Filed: April 1, 2019
    Date of Patent: March 22, 2022
    Assignee: Celgard, LLC
    Inventors: C. Glen Wensley, Lie Shi
  • Patent number: 11239532
    Abstract: Battery separators and methods are disclosed. The battery separator may be used in a lithium battery. The separator may include a microporous membrane laminated to a coated nonwoven. The coating may contain a polymer and optionally, a filler or particles. The methods may include the steps of: unwinding the microporous membrane and the nonwoven, laminating the nonwoven and microporous membrane, and coating the nonwoven before or after lamination.
    Type: Grant
    Filed: August 17, 2016
    Date of Patent: February 1, 2022
    Assignee: Celgard, LLC
    Inventors: Lie Shi, Christopher L. Cowger, Heba K. Botros
  • Patent number: 11196126
    Abstract: In accordance with at least selected embodiments, novel or improved separator membranes, separators, batteries including such separators, methods of making such membranes and/or separators, and/or methods of using such membranes and/or separators are disclosed or provided. In accordance with at least certain embodiments, an ionized radiation treated microporous polyolefin, polyethylene (PE), copolymer, and/or polymer blend (e.g., a copolymer or blend comprising PE and another polymer, such as polypropylene (PP)) battery separator for a secondary or rechargeable lithium battery and/or a method of making an ionized radiation treated microporous battery separator is disclosed.
    Type: Grant
    Filed: September 18, 2019
    Date of Patent: December 7, 2021
    Assignee: Celgard, LLC
    Inventors: Changqing Wang Adams, Michael Bielmann, Zhengming Zhang
  • Patent number: 11165121
    Abstract: Described herein, are battery separators, comprising the following: a microporous polymeric film; and an optional coating layer on at least one side of the microporous polymeric film, wherein at least one of the microporous polymeric film and the optional coating comprises an additive. The additive is selected from the group consisting of a lubricating agent, a plasticizing agent, a nucleating agent, a shrinkage reducing agent, a surfactant, an SEI improving agent, a cathode protection agent, a flame retardant additive, LiPF6 salt stabilizer, an overcharge protector, an aluminum corrosion inhibitor, a lithium deposition agent or improver, or a solvation enhancer, an aluminum corrosion inhibitor, a wetting agent, and a viscosity improver. Also, described herein are batteries, including lithium-ion batteries, comprising one or more of the described separators. Methods for making the battery separators are also described.
    Type: Grant
    Filed: November 7, 2017
    Date of Patent: November 2, 2021
    Assignee: Celgard, LLC
    Inventors: Changqing Wang Adams, Kang Karen Xiao, Stefan Reinartz, Masaaki Okada, Brian R. Stepp, Yao Lu, Eric Robert White, Katharine Chemelewski
  • Patent number: 11124622
    Abstract: A functionalized microporous, mesoporous, or nanoporous membrane, material, textile, composite, laminate, or the like, and/or a method of making or using such functionalized membranes. The functionalized porous membrane may be a functionalized microporous, mesoporous, or nanoporous membrane that has a functional molecule attached, such as a functional polymer, to the surface and/or internal fibrillar structure of the membrane.
    Type: Grant
    Filed: January 18, 2019
    Date of Patent: September 21, 2021
    Assignee: Celgard, LLC
    Inventors: Kristoffer K. Stokes, Karl F. Humiston
  • Patent number: 11114702
    Abstract: In accordance with at least selected aspects, objects or embodiments, optimized, novel or improved membranes, battery separators, batteries, and/or systems and/or related methods of manufacture, use and/or optimization are provided. In accordance with at least selected embodiments, the present invention is related to novel or improved battery separators that prevent dendrite growth, prevent internal shorts due to dendrite growth, or both, batteries incorporating such separators, systems incorporating such batteries, and/or related methods of manufacture, use and/or optimization thereof. In accordance with at least certain embodiments, the present invention is related to novel or improved ultra thin or super thin membranes or battery separators, and/or lithium primary batteries, cells or packs incorporating such separators, and/or systems incorporating such batteries, cells or packs.
    Type: Grant
    Filed: July 8, 2019
    Date of Patent: September 7, 2021
    Assignee: Celgard, LLC
    Inventors: Paul M. Halmo, Xiaomin Zhang, Paul D. Vido, Zhengming Zhang, Lie Shi, Daniel R. Alexander, Jill V. Watson
  • Patent number: 11101525
    Abstract: Disclosed herein are novel or improved microporous battery separator membranes, separators, batteries including such separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries. Further disclosed are laminated multilayer polyolefin membranes with exterior layers comprising one or more polyethylenes, which exterior layers are designed to provide an exterior surface that has a low pin removal force. Further disclosed are battery separator membranes having increased electrolyte absorption capacity at the separator/electrode interface region, which may improve cycling. Further disclosed are battery separator membranes having improved adhesion to any number of coatings. Also described are battery separator membranes having a tunable thermal shutdown where the onset temperature of thermal shutdown may be raised or lowered and the rate of thermal shutdown may be changed or increased.
    Type: Grant
    Filed: July 8, 2019
    Date of Patent: August 24, 2021
    Assignee: Celgard, LLC
    Inventors: Xiaomin Zhang, Eric Robert White, Kang Karen Xiao, Robert A. Nark, Insik Jeon, Kristoffer K. Stokes, Paul Vido, Zhengming Zhang
  • Patent number: 11094995
    Abstract: In accordance with at least selected embodiments, novel or improved porous membranes or substrates, separator membranes, separators, composites, electrochemical devices, batteries, methods of making such membranes or substrates, separators, and/or batteries, and/or methods of using such membranes or substrates, separators and/or batteries are disclosed. In accordance with at least certain embodiments, novel or improved microporous membranes, battery separator membranes, separators, energy storage devices, batteries including such separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries are disclosed. In accordance with at least certain selected embodiments, a separator for a battery which has an oxidation protective and binder-free deposition layer which is stable up to 5.2 volts or more, for example, up to 7 volts, in a battery is disclosed.
    Type: Grant
    Filed: July 22, 2016
    Date of Patent: August 17, 2021
    Assignee: Celgard, LLC
    Inventors: Lie Shi, C. Glen Wensley, Zhengming Zhang, Katharine Chemelewski, Junqing Ma, Ronnie E. Smith, Kwantai Cho, Weifeng Fang, Changqing Wang Adams, Ian McCallum, Jun Nada, Shante P. Williams, Jacob S. Mangum
  • Patent number: 11075429
    Abstract: Improved microporous battery separator membranes, separators, cells, batteries including such membranes, separators, cells, and/or methods of making such membranes and/or separators, and/or methods of using such membranes and/or separators are provided. In accordance with at least certain embodiments, an improved battery separator for a secondary or rechargeable lithium battery may have low electrical resistance of less than 0.95 ohm-cm2, or less than 0.8 ohm-cm2. The inventive battery separator membrane may provide a means to achieve an improved level of battery performance in a rechargeable or secondary lithium battery based on a possibly synergistic combination of low electrical resistance, low Gurley, low tortuosity, and/or a unique trapezoid shaped pore.
    Type: Grant
    Filed: July 21, 2020
    Date of Patent: July 27, 2021
    Assignee: Celgard, LLC
    Inventors: Xiaomin Zhang, Lie Shi
  • Patent number: 11056750
    Abstract: In accordance with at least selected embodiments, a battery separator or separator membrane comprises one or more co-extruded multi-microlayer membranes optionally laminated or adhered to another polymer membrane. The separators described herein may provide improved strength, for example, improved puncture strength, particularly at a certain thickness, and may exhibit improved shutdown and/or a reduced propensity to split.
    Type: Grant
    Filed: November 11, 2016
    Date of Patent: July 6, 2021
    Assignee: Celgard, LLC
    Inventors: Kang Karen Xiao, Eric Joseph Penegar, Takahiko Kondo, Robert Nark, Eric Robert White, Xiaomin Zhang, Kristoffer K. Stokes
  • Patent number: 10953591
    Abstract: An embossed porous membrane wipe and/or a method of making and/or using such embossed microporous membrane wipe. The preferred embossed microporous membrane wipe includes a microporous membrane embossed alone or with a polypropylene nonwoven. The nonwoven may be a spunbond, meltblown, and/or electrospun nonwoven. The microporous membrane may include a biaxially oriented microporous membrane. The biaxially oriented microporous membrane may be made from one or more block copolymers of polyethylene and/or polypropylene. A method of using such an embossed microporous membrane, composite or laminate wipe for skin oil blotting is also provided.
    Type: Grant
    Filed: March 19, 2015
    Date of Patent: March 23, 2021
    Assignee: Celgard, LLC
    Inventors: Karl F. Humiston, Kristoffer K. Stokes, Victor J. Lin, Jui-Hung Huang
  • Patent number: 10944087
    Abstract: Improved battery separators, base films or membranes and/or a method of making or using such separators, base films or membranes are provided. The preferred inventive separators, base films or membranes are made by a dry-stretch process and have improved strength, high porosity, high charge capacity and high porosity to provide excellent charge rate and/or charge capacity performance in a rechargeable battery.
    Type: Grant
    Filed: January 27, 2017
    Date of Patent: March 9, 2021
    Assignee: Celgard, LLC
    Inventors: Xiaomin Zhang, Gerald P. Rumierz, Karl F. Humiston, Charles E. Haire, Tyrone S. Fields, Michael A. Braswell, Ronald A. Proctor, Ronnie E. Smith
  • Patent number: 10938011
    Abstract: An improved multilayer laminated microporous battery separator for a lithium ion secondary battery, and/or a method of making or using this separator is provided. The preferred inventive dry process separator is a tri-layer laminated Polypropylene/Polyethylene/Polypropylene microporous membrane with a thickness range of 12 ?m to 30 ?m having improved puncture strength and low electrical resistance for improved cycling and charge performance in a lithium ion battery. In addition, the preferred inventive separator's or membrane's low Electrical Resistance and high porosity provides superior charge rate performance in a lithium battery for high power applications.
    Type: Grant
    Filed: June 24, 2019
    Date of Patent: March 2, 2021
    Assignee: Celgard, LLC
    Inventors: Xiaomin Zhang, Lie Shi, William John Paulus
  • Patent number: 10934440
    Abstract: In one aspect, microporous membranes are described herein demonstrating composite architectures and properties suitable for electronic and/or optical applications. In some embodiments, a composite membrane described herein includes a microporous polymeric matrix or substrate having an interconnected pore structure and an index of refraction and an electrically conductive coating deposited over one or more surfaces of the microporous polymeric matrix. In other embodiments, the pores are filled and the membranes are substantially transparent.
    Type: Grant
    Filed: July 10, 2018
    Date of Patent: March 2, 2021
    Assignee: Celgard, LLC
    Inventors: Karl F. Humiston, Kristoffer K. Stokes
  • Patent number: 10921385
    Abstract: A system for differentiating short circuiting in a battery includes: a detector coupled to the battery; a monitor in communication with the detector, the monitor including a profile of a battery shorting behavior, and a comparator for matching data from the detector to the profile; and a controller for taking action based upon information from the detector. A method for detecting short circuiting in a battery includes the steps of: detecting a behavior of the battery; comparing the behavior of the battery to a predetermined battery behavior profile; determining the type of short based on the comparison; and taking mitigating action based on the determination. The system/method may monitor: temperature of the battery, heat generation from the battery, current flow through the battery, voltage drop across the battery, and/or combinations thereof. The system/method discriminates between the various battery shorting behaviors for aggressive response or passive response.
    Type: Grant
    Filed: May 19, 2020
    Date of Patent: February 16, 2021
    Assignee: Celgard, LLC
    Inventors: Zhengming Zhang, Weifeng Fang
  • Patent number: 10913237
    Abstract: A microporous membrane is made by a dry-stretch process and has substantially round shaped pores and a ratio of machine direction tensile strength to transverse direction tensile strength in the range of 0.5 to 5.0. The method of making the foregoing microporous membrane includes the steps of: extruding a polymer into a nonporous precursor, and biaxially stretching the nonporous precursor, the biaxial stretching including a machine direction stretching and a transverse direction stretching, the transverse direction stretching including a simultaneous controlled machine direction relax.
    Type: Grant
    Filed: June 6, 2014
    Date of Patent: February 9, 2021
    Assignee: Celgard, LLC
    Inventors: Xiangyun Wei, Charles Haire
  • Patent number: 10899898
    Abstract: Provided herein are seam tapes and related methods. The seam tapes can be compatible with polyolefin-based waterproof/breathable (w/b) membranes, including polypropylene (PP) w/b membranes and/or polyethylene (PE) w/b membranes. Also provided are seams sealed by means of these seam tapes, as well as materials, fabrics, and garments including one or more of these sealed seams.
    Type: Grant
    Filed: October 4, 2017
    Date of Patent: January 26, 2021
    Assignee: Celgard, LLC
    Inventors: Karl F. Humiston, Kristoffer K. Stokes, Perry K. Hancock