Abstract: The invention relates to an enamel-like mixture containing resin and inorganic particles for applying a polymeric, corrosion-proof, wear-resistant, deformable and electrically conductive covering to a substrate. Said mixture contains at least 10 wt. % of electrically conductive particles having an electrical conductivity better than that of zinc particles and having a Moh's hardness greater than 4 with regard to the solids contents of the mixture. These electrically conductive particles have a particle size distribution in which 3 to 22 vol. % of the electrically conductive particles, measured with a Mastersizer 2000 equipped with measuring head Hydro 2000S of the company Malvern Instruments, are, in a volume representation, larger than the average layer thickness of the dried and, optionally, also hardened covering determined on recordings made using a scanning electron microscope.
Abstract: A water based coating mixture for the application of a polymeric coating to a substrate mixture includes water and optionally an organic solvent, at least one free-radically polyerizable compound. Preferably the coating is weldable.
Abstract: A degreasing method for descaling or removing laser scales from iron-containing metal part surface by treating the iron-containing metal part surfaces that is optionally tainted with laser scales with an aqueous solution containing at least one type of highly water-soluble and complexed with Fe ions carboxylic acid, at least one type of salt of at least one type of carboxylic acid exhibiting the same action and at least one type of fatty amine ethoxylate, wherein the solution is buffered, the Fe ions are carried into the solution and at least partially complexed, increasing the pH value of the solution for descaling with respect to at least one type of carboxylic acid. The entire concentration of carboxylic acids and the salts thereof is increased for descaling by 2 to 20% by weight.
Abstract: A process for the treatment or pretreatment of containers made of aluminum, aluminum-containing alloys, magnesium-containing alloys, iron-containing materials such as steel, coated iron-containing materials such as galvanized steel, or aluminum alloys, tinplate, brass or bronze, in particular the treatment or pretreatment of bags, tubs, bottles, cans, canisters, casks or tubes, wherein the process steps for the treatment or pretreatment take place at the same time as the application of the lubricant, with the agent used for the pretreatment or treatment, which also contains or is a lubricant, not essentially consisting of titanium or zirconium with fluoride and polymer, the lubricant possibly being formed first in the agent for the pretreatment or treatment or in the formation of the coating produced therefrom.
Type:
Grant
Filed:
May 21, 2001
Date of Patent:
March 18, 2008
Assignee:
Chemetall GmbH
Inventors:
Karl-Heinz Bischoff, Mats Eriksson, Norbert Kliehm, Lars Sebralla, Markus Wahren, Manfred Walter
Abstract: A method for the production of alkyl lithium compounds is disclosed, in which metallic lithium is reacted with an alkyl halide in a solvent, whereby the metallic lithium is introduced in the form of lithium particles, generated by spraying molten lithium into an inert atmosphere or into a vacuum.
Abstract: The invention relates to a mixture for the application of a polymeric coating to a substrate. Said mixtures comprises water and optionally an organic solvent, at least one water-dispersible radically polymerizable compound, at least one water-dispersible polymerizable crosslinking compound and at least one water-dispersible compound which forms free radicals upon exposure to actinic radiation. The radically polymerizable compound cannot fully set with the free radicals formed on irradiation at room temperature, but rather comprises further reactive bonds, which lead to further or complete setting with the crosslinking compound. The invention further relates to a method for application of a non-adhesive corrosion protection layer to a substrate, by application of a mixture to the surface of a metallic or polymeric substrate, drying the mixture and irradiation of the applied coating with actinic radiation of such an intensity and for such a period that a solid, hard, tough coating is formed.
Abstract: A process for the preparation of lithium borohydride by reaction of lithium hydride with boron trifluoride is described, in which lithium hydride is reacted with boron trifluoride in a molar ratio LiH:BF3 of >4.1:1, the reaction being carried out in an ethereal solvent whose boiling point at normal pressure is at least 50° C., and at temperatures of at least 10° C.
Abstract: The invention relates to an aqueous concentrate which is stable with respect to freezing and defrosting and which contains at least one water-soluble or water-dispersible copper compound and, optionally, also a water-soluble or water-dispersible tin compound for use in a diluted state as a bath for the currentless copper plating or bronze plating of objects, especially metal objects such as iron or steel wires, characterized in that it contains at least one complexed water-soluble or water-dispersed copper compound. The invention also relates to an aqueous bath which contains at least one aqueous or water-dispersible copper compound and, optionally, a water-soluble or water-dispersible tin compound for the currentless copper plating of objects in addition to at least one brightening agent and which has an adjusted pH value of less than 2.5. The invention also relates to a method for currentless copper plating or bronze plating of an object, especially a metallic object.
Abstract: The invention relates to a sealing mass with low density and improved tensile strength on the basis of sulfur-containing polymers such as on the basis of polysulfide, polyether or/and polytioether that has a density of not more than 1.3 g/cm3 according to ISO 2781 and a tensile strength of at least 1.9 N/mm2 according to ISO 37 after curing. The invention further relates to a ground mass based on sulfur-containing polymers for producing a sealing mass that comprises at least one long-chain linear polymer and at least one short-chain branched polymer having a content in trifunctional molecules, or/and at least one multifunctional cross-linker with a number of functional groups n?3.
Type:
Grant
Filed:
April 5, 2002
Date of Patent:
August 28, 2007
Assignee:
Chemetall GmbH
Inventors:
Peter Bons, Heinz Burock, Francisco Diez, Andrea Paul, Heiko Diehl
Abstract: Electrolytes containing lithium-bis(oxalato)borate, a cyclic carbonate, one or more compounds selected from acrylic carbonates, aliphatic esters, alicyclic ethers and aliphatic, difunctional ethers, one or more compounds selected from lactones, dinitriles, compounds that contain at least one carboxylic acid ester group and an ether group, compounds that contain at least one carbonic acid group and an ether group, compounds that contain at least one nitrile group and an ether group, trialkyl phosphoric acid esters and trialkyl boric acids.
Type:
Grant
Filed:
March 5, 2002
Date of Patent:
June 5, 2007
Assignee:
Chemetall GmbH
Inventors:
Jan-Christoph Panitz, Ulrich Wietelmann, Markus Scholl
Abstract: Methods are described for the production of hydrogen-bis(chelato)borates of the general formula H[BL1L2] and of alkali metal-bis(chelato)borates of the general formula M[BL1L2] where M=Li, Na, K, Rb, Cs L1=—OC(O)—(CR1R2)n—C(O)O— or —OC(O)—(CR3R4)—O— where n=0 or 1, R1, R2, R3, R4 independently of one another denote H, alkyl, aryl or silyl, L2=—OC(O)—(CR5R6)n—C(O)O— or —OC(O)—(CR7R8)—O— where n=0 or 1, R5, R6, R7, R8 independently of one another denote H, alkyl, aryl or silyl, wherein the respective raw materials are mixed in solid form without the addition of solvents and are reacted. Lithium-bis(oxalato)borate, lithium-bis(malonato)borate, caesium-bis-(oxalato)borate, caesium-bis-(malonato)borate and the mixed salts lithium(lactato,oxalato)borate and lithium(glycolato,oxalato)borate for example may be produced in this way.
Type:
Grant
Filed:
February 15, 2002
Date of Patent:
April 24, 2007
Assignee:
Chemetall GmbH
Inventors:
Ulrich Wietelmann, Uwe Lischka, Klaus Schade, Jan-Christoph Panitz
Abstract: Metallic surfaces are coated with an aqueous, acidic phosphate solution containing 10 to 60 g/l zinc, 0.5 to 40 g/l manganese, 50 to 300 g/l phosphate ions calculated as P2O5, and optionally other components.
Type:
Grant
Filed:
March 6, 2001
Date of Patent:
April 24, 2007
Assignee:
Chemetall GmbH
Inventors:
Hardy Wietzoreck, Klaus Bittner, Thomas Kolberg, Marion Wegner, Thomas Wendel, Gerrit Schüllermann
Abstract: Disclosed is a method for producing Alkyllithium compounds by reacting metallic lithium with an Alkyl halide in a solvent. The reaction is performed at a reduced pressure at the boiling point of the solvent.
Abstract: The inventive aqueous pickling agent on the basis of sulfuric acid or phosphoric acid and hydrogen fluoride for stainless steels, which pickling agent is free of wetting and emulsifying agents, contains (each as 100 wt-% substance) 1.5 to 16 wt-% sulfuric acid or 2.0 to 30 wt-% phosphoric acid as well as 0.5 to 14 wt-% hydrogen fluoride and 0.5 to 15.5 wt-% acid-soluble aromatic nitro compound. An iron(III) compound is not supplied to said pickling agent. Merely in the starting phase, an oxidizing agent can be supplied, which oxidizes iron(II) to form iron(III). As acid-soluble aromatic nitro compound m-nitrobenzene sulfonate and/or 3-nitrophthalate are particularly advantageous. The inventive pickling agent can be used as bath pickle and —when adding 2.5 to 5.5 wt-% magnesium and/or magnesium compound (calculated as Mg)—also as spraying pickle or brush pickle.
Type:
Grant
Filed:
August 26, 2003
Date of Patent:
May 9, 2006
Assignee:
Chemetall GmbH
Inventors:
Eckart Schonfelder, Gunther Schwane, Harald Werner
Abstract: A process is described for the preparation of LiAlH4 solutions, in which lithium hydride reacts with an aluminium halide in diethyl ether to give lithium aluminium hydride, the lithium halide which arises is separated off, and wherein a solvent the complexing energy of which with LiAlH4 is greater than the complexing energy of diethyl ether with LiAlH4 is then added, and the diethyl ether is removed by distillation.
Type:
Grant
Filed:
July 25, 2003
Date of Patent:
February 7, 2006
Assignee:
Chemetall GmbH
Inventors:
Dirk Dawidowski, Bernhard Debbeler, Ute Emmel, Walter Pleyer, Wilfried Weiss
Abstract: A process is described for the preparation of lithium iodide solutions by reacting a lithium-containing substance with elemental iodine, the lithium iodide being prepared in an aprotic solvent that can be used as a solvent in a liquid electrolyte solution.
Abstract: The invention relates to a method for coating metallic surfaces by wetting one such surface with an aqueous dispersion containing, in addition to water, at least one UV-cross-linkable, water-soluble and/or water-dispersible resin, at least one wax as a deforming additive, at least one photoinitiator and at least one corrosion inhibitor. The coating is dried and hardened after being formed on the metallic surface. The invention is characterised in that the coating that is formed is up to 10 ?m thick when hard, and in that during a condensation water test according to DIN 50017 KFW carried out directly after over 240 hours, said coating shows no signs of corrosion >5% on a test surface having been deformed by a mandrel with a diameter of 3.2 mm to 38 mm during a mandrel bending test according to DIN ISO 6860 without cracking the test surface.
Abstract: The invention relates to a method for coating a metal surface with an aqueous composition, characterized in that the composition contains, in addition to water: a) at least one organic film former that contains at least one water-soluble or water-dispersible polymer with an acid number ranging from 5 to 200, b) at least one particulate inorganic compound with an average particle diameter measured by a scanning electron microscope in the range of from 0.005 to 0.3?, c) at least one slip additive and/or at least one corrosion inhibitor, d) optionally at least one organic solvent, e) optionally at least one silane and/or siloxane, f) optionally at least one cross-linking agent, and g) optionally at least one chromium (VI) compound. The clean metal surface is contacted with the aqueous composition and a particle-containing film is formed on the metal surface which is then dried. The dried and optionally also cured film has a layer thickness ranging from 0.01 to 10 ?m.
Type:
Grant
Filed:
October 11, 2001
Date of Patent:
April 5, 2005
Assignee:
Chemetall GmbH
Inventors:
Christian Jung, Toshiaki Shimakura, Norbert Maurus, Heribert Domes
Abstract: A method for preparing lithium amide is described in which in a first method step lithium metal is reacted with ammonia to form lithium bronze and in a second method step the lithium bronze is reacted with a 1,3-diene or an arylolefin in the presence of a solvent.
Abstract: The invention relates to a method for producing compounds of general formula (A) by reacting an alkali metal hydride with a compound (B) during which the reaction is carried out in the presence of a catalyst that contains boron, whereby: M represents Li, Na, K, Rb or Cs; E represents B or Al, and; X1, X2, X3, independent of one another, represent a secondary or tertiary alkyl group, which is comprised of 2 to 10 atoms, or represent a phenyl group which itself can be alkyl-substituted or they represent an alkoxy group, and the catalyst, which contains boron, or the conversion product thereof with MH is capable of acting as a hydride transfer agent.
Type:
Grant
Filed:
February 25, 2003
Date of Patent:
March 30, 2004
Assignee:
Chemetall GmbH
Inventors:
Ulrich Wietelmann, Dieter Hauk, Andre Majdalani, Uwe Lischka