Patents Assigned to Chemische Werke Huels
  • Patent number: 4442245
    Abstract: Epoxy resin-diammonium salt emulsions are based on a liquid epoxy resin, a latent curing agent, and an emulsifier. The latent curing agent comprises diammonium oxalates and the emulsifiers are C.sub.8 - to C.sub.14 - alcohols and/or the adducts thereof with up to 10 ethylene oxide groups. A process for the production of such emulsions is provided. They are useful in epoxy resin mortars and epoxy resin-cement mortars, and for the sealing of concrete surfaces.
    Type: Grant
    Filed: June 16, 1983
    Date of Patent: April 10, 1984
    Assignee: Chemische Werke Huels, AG
    Inventors: Jorn-Volker Weiss, Heinz Riemer, Friedhelm Mutzberg
  • Patent number: 4440882
    Abstract: An epoxy resin-polyammonium salt emulsion is based on a liquid epoxy resin, a latent curing agent, an emulsifier, and water, wherein(a) the emulsifier is a primary aliphatic alcohol of 12-14 carbon atoms, an adduct thereof with up to 5 ethylene oxide groups, or a carboxylic acid polyglycol ester, and(b) the latent curing agent is the reaction product obtained by complete neutralization of oxalic acid with a polyamine of the formulaH.sub.2 N--CH.sub.2 --CH.sub.2 --NH--hd xHwherein X=2, 3, or 4or with a reaction product, containing amino groups, of a reaction of this polyamine with fatty acids.
    Type: Grant
    Filed: June 16, 1983
    Date of Patent: April 3, 1984
    Assignee: Chemische Werke Huels, AG
    Inventors: Joern-Volker Weiss, Heinz Riemer
  • Patent number: 4438244
    Abstract: Vinyl chloride is polymerized in suspension using as the suspension stabilizer a copolymer of 65-85 molar percent of 2-isopropyl-.DELTA..sup.2 -oxazoline and 35-15 molar percent of 2-methyl-.DELTA..sup.2 -oxazoline, having a viscosity number of 35-80 ml/g, measured at 25.degree. C. in an isopropanol/water mixture (50 volume percent of isopropanol) in a concentration of 0.5% (weight/volume of solution).
    Type: Grant
    Filed: May 24, 1982
    Date of Patent: March 20, 1984
    Assignee: Chemische Werke Huels, AG
    Inventors: Gilbert Sielfeld, Paul Sunder-Plassmann
  • Patent number: 4434276
    Abstract: A process for the post condensation of poly(alkylene terephthalate) in the solid phase is carried out in the presence of esters of phosphorous acid at 25.degree.-65.degree. C. below the melting point of the poly(alkylene terephthalate) while passing an inert gas stream through the reaction mixture.
    Type: Grant
    Filed: March 31, 1983
    Date of Patent: February 28, 1984
    Assignee: Chemische Werke Huels Aktiengesellschaft
    Inventors: Gernot Horlbeck, Horst Heuer
  • Patent number: 4434310
    Abstract: A process for the isomerization of isolated double bonds to conjugated double bonds in optionally substituted cyclooctadienes using alkali metal or alkaline earth metal amides, if desired in the presence of a solvent, requires that the alkali metal or alkaline earth metal amide be produced with exclusion of moisture and under a protective gas atmosphere in the presence of the cyclooctadiene to be isomerized; and that the isomerization be conducted at temperatures of 70.degree.-200.degree. C.
    Type: Grant
    Filed: January 13, 1983
    Date of Patent: February 28, 1984
    Assignee: Chemische Werke Huels Aktiengesellschaft
    Inventor: Wolfgang Kampf
  • Patent number: 4433175
    Abstract: For the production of neohexanol with a purity above 99%, a chlorine content of less than 10 ppm, and a sulfur content of less than 5 ppm, 3,3-dimethylbutyric acid with a chlorine content below 650 ppm, preferably below 100 ppm, is first esterified, optionally after distillatory separation into a portion richer in chlorine with a chlorine content above 650 ppm, preferably above 100 ppm, and into a portion low in chlorine with a chlorine content below 650 ppm, preferably below 100, with an alcohol boiling above 117.degree. C., preferably an octyl alcohol. The resultant ester is separated by distillation into fractions richer in chlorine with chlorine contents above 10 ppm and into fractions low in chlorine with chlorine contents below 10 ppm. The ester of low chlorine contents below 10 ppm is hydrogenated to neohexanol over a barium-activated copper chromite catalyst under a pressure of 200-300 bar, at 120.degree.-22.degree. C., and with catalyst loads of 0.05-1.
    Type: Grant
    Filed: November 24, 1982
    Date of Patent: February 21, 1984
    Assignee: Chemische Werke Huels, A.G.
    Inventor: Manfred Kaufhold
  • Patent number: 4430474
    Abstract: A stoving enamel comprising (a) 30-70% by weight of a mixture of a polymer containing hydroxyl groups having a hydroxyl number between 40 and 240 mg KOH/g with an isocyanurate-free derivative of isophorone diisocyanate containing uretidinedione groups and blocked isocyanate groups, (b) 0-3% by weight of a cross-linking catalyst, (c) 30-60% by weight of an organic solvent, (d) 0-65% by weight of a filler or pigment, (e) 0-5% by weight of a dye, and (f) optionally 0.1-3% by weight of leveling agents, gloss improvers, antioxidants, and/or stabilizers, has improved storage stability, reduced curing time and reduced liberation of blocking agent during cure.
    Type: Grant
    Filed: August 13, 1981
    Date of Patent: February 7, 1984
    Assignee: Chemische Werke Huels AG
    Inventors: Horst Schnurbusch, Rainer Gras, Elmar Wolf, Josef Disteldorf, Werner Hubel
  • Patent number: 4429106
    Abstract: A high molecular-weight polyphenylene oxide is produced by the oxidative coupling of a diortho-substituted phenol in the presence of a copper amine complex and an activator of morpholinium bromide and an alkali metal hydroxide or alkaline earth hydroxide.
    Type: Grant
    Filed: May 23, 1983
    Date of Patent: January 31, 1984
    Assignee: Chemische Werke Huels AG
    Inventors: Klaus Burzin, Martin Bartmann, Hanns-Jorg Bax, Wilfried Ribbing
  • Patent number: 4425266
    Abstract: N-oxalkylated derivatives of aniline of the formula ##STR1## wherein R.sub.1 and R.sub.2 each independently is hydrogen, NH.sub.2, or lower alkyl;R.sub.3 is hydrogen or lower alkyl,R.sub.4 is hydrogen or methyl, andn is a number from 1.0 to 5.0,are useful as polymer-dissolving components in floor cleaners.
    Type: Grant
    Filed: February 22, 1982
    Date of Patent: January 10, 1984
    Assignee: Chemische Werke Huels Aktiengesellschaft
    Inventors: Rudolf Beck, Sigrid Scholz-Weigl
  • Patent number: 4414125
    Abstract: A corrosion inhibited composition comprises an aqueous drilling, cutting, or polishing agent, an aqueous hydraulic fluid or an aqueous antifreeze compound; and an alkali metal salt, or an aliphatic amine salt of a mixture of 2- and 3-C.sub.6-12 -alkyladipic acids, the amount of this acid component being effective as a corrosion inhibitor.
    Type: Grant
    Filed: December 1, 1980
    Date of Patent: November 8, 1983
    Assignee: Chemische Werke Huels Aktiengesellschaft
    Inventors: Hans S. H. Keil, deceased, Helmut Alfs, Klaus Schulze
  • Patent number: 4412038
    Abstract: Silyl-group-containing 1,3-butadiene polymers are stabilized against self crosslinking by addition of epoxides having an epoxy oxygen content of 2-17% by weight.
    Type: Grant
    Filed: August 4, 1982
    Date of Patent: October 25, 1983
    Assignee: Chemische Werke Huels AG
    Inventors: Dieter Zerpner, Roland Streck
  • Patent number: 4396776
    Abstract: A process for preparing a methyl-blocked ethoxylate comprises heating at 180.degree.-320.degree. C., in the presence of a catalytically effective amount of a noble metal catalyst, an unsubstituted ethoxylate of 3 or more ethoxy units, or a monoalkyl-, monoaryl-, mono- or di-alkylamino- or mono- or di-arylamino ethoxylate of 2 or more ethoxy units, or a monoalkyl- or monoaryl-N,N-bis(ethoxylate) of 2 or more ethoxy units, all of which are derived from vicinal glycols, whereby there is prepared a corresponding methyl-blocked ethoxylate product which, for an unsubstituted ethoxylate starting material is a dimethylethoxylate having two fewer ethoxy units than the starting ethoxylate, and for the other ethoxylate starting materials, is a methylethoxylate having one less ethoxy unit in each ethoxylate group of the starting material.
    Type: Grant
    Filed: July 2, 1981
    Date of Patent: August 2, 1983
    Assignee: Chemische Werke Huels, Aktiengesellschaft
    Inventors: Rudolf Brockhaus, Hans-Jurgen Franke
  • Patent number: 4396751
    Abstract: A homo- or copolymer of a 1,3-diene having reactive silyl groups bound thereto, and containing 0.4-12% by weight of bound silicon, prepared by reacting at a temperature of 150.degree.-300.degree. C., a 1,3-diene homo- or copolymer, having less than 1% of its aliphatic double bonds conjugated and having a molecular weight (M.sub.n) of 400-8,000, with a silicon compound of the formula ##STR1## wherein R is an unsaturated aliphatic hydrocarbon residue of 2-20 carbon atoms,X is halogen, C.sub.1-6 alkoxy, C.sub.1-6 alkoxyalkoxy, C.sub.6-12 aryloxy, C.sub.1-8 alkanoyloxy, C.sub.1-6 ketoximato or C.sub.1-8 hydrocarbylamido,Y and Z independently are one of the X groups, hydrogen, alkyl of 1-8 carbon atoms, cycloalkyl of 5-12 carbon atoms, or optionally substituted phenyl.
    Type: Grant
    Filed: June 15, 1981
    Date of Patent: August 2, 1983
    Assignee: Chemische Werke Huels Aktiengesellschaft
    Inventors: Wolfgang Kampf, Roland Streck, Horst G. Haag
  • Patent number: 4390654
    Abstract: A polyvinyl chloride blend contains, as a smoke-reducing additive, a copper (II) hydroxide phosphate of the composition Cu.sub.3 (PO.sub.4).sub.2.Cu(OH).sub.2 in amounts from about 0.1 to 20 parts by weight per 100 parts by weight of polyvinyl chloride. The thus-treated polyvinyl chloride is not discolored by the addition of this copper compound a significant advantage when compared to conventional copper compound additives.
    Type: Grant
    Filed: April 28, 1982
    Date of Patent: June 28, 1983
    Assignee: Chemische Werke Huels, A.G.
    Inventors: Ralf Schuler, Gunther Maahs
  • Patent number: 4387213
    Abstract: A process for condensing a linear polyalkylene terephthalate having a viscosity number of at least 60 cc/g in two stages, at an elevated temperature, in the solid phase, and in the presence of an alkanediol, comprises, in a first stage, treating the polyalkylene terephthalate in an inert gas stream at a reaction temperature 30.degree.-80.degree. C. below its melting point, with 0.2-3.5% by weight, based on the weight of the polyalkylene terephthalate, of an alkanediol whose boiling point under normal pressure is 20.degree.-70.degree. C. above the reaction temperature, wherein the amount of inert gas passed through per hour, measured under standard conditions, corresponds to 0.3 to 2 times the gross reactor volume; and, in a second stage, condensing the polyalkylene terephthalate in an inert gas stream at a temperature 5.degree.-25.degree. C. below its melting point, wherein the amount of inert gas passed through per hour, measured under standard conditions, corresponds to 2.
    Type: Grant
    Filed: December 22, 1980
    Date of Patent: June 7, 1983
    Assignee: Chemische Werke Huels AG
    Inventors: Gernot Horlbeck, Horst Heuer, Hanns-Jorg Bax, Hans Jadamus
  • Patent number: 4381377
    Abstract: A homo- or copolymer of a 1,3-diene bound to reactive silyl groups, whereby it contains 0.4-12% by weight of bound silicon, is prepared by reacting, at a temperature of 190.degree.-300.degree. C., a 1,3-diene homo- or copolymer, with more than 1% of its aliphatic double bonds in conjugation and having a molecular weight (Mn) of 400-6,000, with a silane of the formula ##STR1## wherein R is an unsaturated aliphatic hydrocarbon radical of 2-20 carbon atoms,X is halogen, C.sub.1-6 alkoxy, C.sub.1-6 alkoxyalkoxy, C.sub.6-12 aryloxy, C.sub.1-8 alkanoyloxy, C.sub.1-6 ketoximato or C.sub.1-10 hydrocarbylamido, andY and Z are independently one of the X groups, hydrogen, alkyl of 1-8 carbon atoms, cycloalkyl of 5-12 carbon atoms, or optionally substituted phenyl.
    Type: Grant
    Filed: February 2, 1981
    Date of Patent: April 26, 1983
    Assignee: Chemische Werke Huels, AG
    Inventors: Wolfgang Kampf, Roland Streck, Horst-guenter Haag
  • Patent number: 4379890
    Abstract: A water-soluble polymer having quaternary ammonium groups, is prepared by reacting(a) a low molecular weight alkylating agent with(b) a corresponding polymer carrying tertiary, quaternizable amino groups.
    Type: Grant
    Filed: July 9, 1981
    Date of Patent: April 12, 1983
    Assignee: Chemische Werke Huels, Aktiengesellschaft
    Inventors: Alfred Konietzny, Wilfried Bartz
  • Patent number: 4368291
    Abstract: In a low pressure process for polymerizing ethene using a Ziegler mixed catalyst comprising (a) a titanium compound, a vanadium compound or a mixture thereof and (b) an aluminum-organic compound or a mixture thereof, an improvement is provided wherein the process is carried out in multi-stages comprising:polymerizing, in a first polymerization stage, in the liquid phase in a dispersion medium of a C.sub.3 - to C.sub.6 -hydrocarbon, andpolymerizing, in a last polymerization stage, in the gas phase.
    Type: Grant
    Filed: January 26, 1979
    Date of Patent: January 11, 1983
    Assignee: Chemische Werke Huels, A.G.
    Inventors: Albert Frese, Fritz Baxmann
  • Patent number: 4367362
    Abstract: A process for the catalytic skeleton isomerization of n-alkenes to isoalkenes comprises contacting the n-alkene with a fluorinated aluminum oxide as the catalyst at temperatures of 250.degree.-550.degree. C., in the presence of 0.5-150% by weight of water, based on the weight of the alkene employed and replenishing the fluorine discharged from the catalyst in metered amounts, continuously or discontinuously, using, e.g., a volatile fluorine compound. The catalyst, partially deactivated by coking, is regenerated by burning it off with an oxygen-containing gas in the presence of steam.
    Type: Grant
    Filed: January 12, 1981
    Date of Patent: January 4, 1983
    Assignee: Chemische Werke Huels, Aktiengesellschaft
    Inventors: Gerhard Franz, Friedrich Heinrich, Hans-Josef Ratajczak
  • Patent number: 4361686
    Abstract: A process for preparing a copolymer by copolymerizing ethylene and at least one other 1-monoolefin and, optionally, and unconjugated diene in the presence of a mixed catalyst of (1) a compound of a metal of main Groups I-III of the periodic table having at least one hydrogen atom or an alkyl or aryl group bound to the metal atom, and (2) a compound of a metal of Subgroups IV-VI of the periodic table, comprises performing the copolymerization in the presence of an amount effective as an activator of a 2, 3,4,4-tetrachloro-2-butenoic acid ester of the fromulaHCCl.sub.2 --CCl=CCl--COORwherein R is an optionally halogenated alkyl, cycloalkyl, aryl, alkaryl or aralkyl group, and wherein the cycloalkyl, aryl, alkaryl or aralkyl groups are optionally substituted by one or more alkyl groups.
    Type: Grant
    Filed: August 21, 1980
    Date of Patent: November 30, 1982
    Assignee: Chemische Werke Huels, Aktiengesellschaft
    Inventors: Wolfgang Zaar, Manfred Schroeder, Gunther Maahs