Abstract: The reaction of sodium hypochlorite with sodium bromide is slow, and commonly only part of the bromide is converted to hypobromite. Methods to accelerate the reaction by adding a regulated amount of acid to a solution comprising bleach and bromide are provided, whereby the yield of hypobromite can be increased. The amount of acid added can be predetermined based on the content of a base in the bleach, and acid can be added to neutralize the base. The amount of acid added can be based on a measured parameter of the reaction that is indicative of reaction kinetics. For example, the amount of acid can be actively controlled by measuring pH, absorbance of visible or near Ultraviolet light, or temperature of the reacting solution and adjusting acid.

Abstract: Methods and compositions for generating stabilized oxidants using a stabilizer composition and an in situ generated oxidant in a water system. The method includes mixing the stabilizer composition and the in situ generated oxidant with water to form a liquid treatment composition, and then adding the liquid treatment composition to a water stream in the water system, the liquid treatment composition improving the efficacy of the in situ generated oxidant in the water stream.

Abstract: Non-triazole compounds are provided that can be effective to inhibit corrosion of a corrodible metal surface in an aqueous system. The non-triazole compounds show comparable or better corrosion inhibition as compared to conventional triazole corrosion inhibitors, and have low toxicity and good stability in the presence of halogens such as halogen-containing biocides or free chlorine.

Abstract: A method includes varying at least one condition of water in a water system while (i) measuring an amount of deposit control agent (DCA) in the water to detect a change in the amount of DCA in the water; and (ii) measuring scaling in the water system to detect a change in the amount of scaling; and correlating the detected change in the measured amount of DCA with the detected change in scaling in the water in order to predict and monitor the onset of scaling.

Abstract: Systems and methods are provided for evaluating performance of a heat exchanger, such as a condenser, using rules-based logic. A plurality of sensors can measure various operating properties of the heat exchanger and transmit corresponding measurement information to a controller. The controller can (i) evaluate the measurement information for a plurality of rules in which each rule considers an operating parameter of the heat exchanger that is based on the measurement information to provide a set of operating values; compare the set of operating values to a rules matrix in which each of a plurality of possible diagnoses for the heat exchanger are associated with a corresponding set of predetermined values from a set of the plurality of rules; and (iii) based on the comparison, determine at least one likely diagnosis for the heat exchanger from among the plurality of possible diagnoses.

Abstract: Methods are described that reduce the amount of organic matter in water, including reducing an amount of total organic carbon in water. The method includes adding powder activated carbon to the water; mixing the powder activated carbon in the water; and separating the powder activated carbon from the water. Also described are a method for reducing glycol content in water containing glycols, and a method for reducing glycol content in a steel mill wastewater stream containing glycols.

Abstract: The reaction of sodium hypochlorite with sodium bromide is slow, and commonly only part of the bromide is converted to hypobromite. Methods to accelerate the reaction by adding a regulated amount of acid to a solution comprising bleach and bromide are provided, whereby the yield of hypobromite can be increased. The amount of acid added can be predetermined based on the content of a base in the bleach, and acid can be added to neutralize the base. The amount of acid added can be based on a measured parameter of the reaction that is indicative of reaction kinetics. For example, the amount of acid can be actively controlled by measuring pH, absorbance of visible or near Ultraviolet light, or temperature of the reacting solution and adjusting acid.

Abstract: A method for determining the lignin or lignin by-product content of a process stream includes measuring the fluorescence parameter of a fluorescence spectra of the process stream, comparing the measured fluorescence parameter with predetermined a fluorescence parameter of lignin or lignin by-product reference samples, determining the amount of lignin or lignin by-product based on the comparison with the reference samples. Lignin or lignin by-products can then be removed from a process stream by adding a sufficient amount of a compound suitable for precipitating the lignin or lignin by-product to the process stream, and removing the precipitated lignin or lignin by-product from the process stream.

Abstract: Methods and compositions for suppressing corrosion of a corrodible metal surface that contacts a water stream in a water system. The method comprises introducing into the water stream a treatment composition, the treatment composition including a combination of passivators and a hydroxycarboxylic acid promoter.

Abstract: Methods are described that reduce the amount of organic matter in water, including reducing an amount of total organic carbon in water. The method includes adding powder activated carbon to the water; mixing the powder activated carbon in the water; and separating the powder activated carbon from the water. Also described are a method for reducing glycol content in water containing glycols, and a method for reducing glycol content in a steel mill wastewater stream containing glycols.

Abstract: A method for applying a chemical treatment solution to a process stream in an industrial processing system while the system is online. The method includes measuring a mineral hardness and alkalinity of the process stream, determining a dosage of the chemical treatment solution based on a relationship between the dosage and a scale saturation parameter that is calculated based on the mineral hardness and the alkalinity of the process stream, and controlling application of the chemical treatment solution to the process stream based on the determined dosage.

Abstract: Methods and compositions for inhibiting corrosion of a corrodible metal surface that contact a nitrogen-containing solution. The method comprises adding a chemical treatment composition to the nitrogen-containing solution that includes an organic filmer and a passivator. The organic filmer may be a hydroxycarboxylic acid. The chemical treatment composition may further include a surface-active compound.

Abstract: A method for forming a protective antioxidative barrier on the furnace electrodes using a chemically altered cooling liquid containing an antioxidant additive. This method can be applied to electrodes used in electric arc furnaces and ladle metallurgy furnaces. The method can involve spraying the cooling liquid onto the electrode, thereby forming the protective antioxidative barrier and reducing the oxidation of the electrode.

Abstract: The amount of sulfite in water can be determined using fluorescence by adding to the water a fluorophore compound, measuring a fluorescence signal of the water, and determining the amount of the sulfite in the water based on the measured fluorescence signal. This method can be used in a water treatment system in which a sulfite solution is added to treat the water, and the amount of sulfite that is added can be controlled based on the measured fluorescence of the water.

Abstract: Systems and methods for applying a volatized chemical treatment solution to a combustion chamber in a boiler system while the system is online. The method includes measuring a combustion parameter, determining in real time a dosage of the volatized chemical treatment solution based on the measured combustion parameter, and applying the volatized chemical treatment solution to the combustion chamber based on the determined dosage.

Abstract: A method for forming a protective antioxidative barrier on the furnace electrodes using a chemically altered cooling liquid containing an antioxidant additive. This method can be applied to electrodes used in electric arc furnaces and ladle metallurgy furnaces. The method can involve spraying the cooling liquid onto the electrode, thereby forming the protective antioxidative barrier and reducing the oxidation of the electrode.

Abstract: A method for applying a chemical treatment to a cooling medium in an evaporative cooling system. The method includes applying the chemical treatment to the cooling medium, and the chemical treatment includes at least one of a phosphonate and a dispersant polymer.

Abstract: Methods and compositions for inhibiting corrosion of a metal product are provided. The metal product can be contacted with water that includes at least one carbonate and/or bicarbonate salt, or otherwise has components that increase the alkalinity of the water. In addition, or as an alternative, the water can include a stannous corrosion inhibitor. The water can be evaporated off of a surface of the metal product to provide a residual of the salt on the surface and/or a protective stannous film on the surface.

Abstract: Methods and compositions for inhibiting corrosion of a corrodible metal surface that contact a nitrogen-containing solution. The method comprises adding a chemical treatment composition to the nitrogen-containing solution that includes an organic filmer and a passivator. The organic filmer may be a hydroxycarboxylic acid. The chemical treatment composition may further include a surface-active compound.

Abstract: The reaction of sodium hypochlorite with sodium bromide is slow, and commonly only part of the bromide is converted to hypobromite. Methods to accelerate the reaction by adding a regulated amount of acid to a solution comprising bleach and bromide are provided, whereby the yield of hypobromite can be increased. The amount of acid added can be predetermined based on the content of a base in the bleach, and acid can be added to neutralize the base. The amount of acid added can be based on a measured parameter of the reaction that is indicative of reaction kinetics. For example, the amount of acid can be actively controlled by measuring pH, absorbance of visible or near Ultraviolet light, or temperature of the reacting solution and adjusting acid.