Abstract: The invention relates to coating slip including latex comprising styrene and with a particle size centered around 100 nm, the use of latex as an agent for reducing the low shear gradient viscosity and increasing the low shear gradient viscosity, and methods thereof.
Abstract: The invention concerns the use of hydrosoluble homopolymers and/or copolymers of acrylic/or methacrylic acid with one or more acrylic, vinyl or ally monomers as an aid to the grinding of mineral particles in aqueous suspension, providing them by their use particular optical properties. The invention also concerns the said aqueous suspensions and their uses in the fields of paper and paint.
Type:
Grant
Filed:
March 6, 2006
Date of Patent:
September 13, 2011
Assignee:
Coatex S.A.S.
Inventors:
Xueping Qiu, Jacques Mongoin, Christian Jacquemet
Abstract: The present invention pertains to particular HASE rheology modifiers: they are aqueous emulsions whose solids content may reach about 25%, based on acrylic thickeners having an associative monomer functionalized by an oxo alcohol based hydrophobic group. Their method of synthesis, as well as a method for thickening an aqueous formulation containing them, also constitute objectives of the present invention.
Abstract: A HASE-type rheology modifier containing an associative monomer which is functionalised by a hydrophobic group of an oxo alcohol base is provided. A method to prepare the HASE rheology modifier and its use in a method to thicken and create a Newtonian rheological profile in an aqueous formulation such as a water based paint is also provided.
Abstract: The present invention pertains to an aqueous solution of comb-branched polymers, having a (meth)acrylic skeleton functionalized by side-chains with hydrophilic alcoxy- or hydroxy-polyalkylene glycol functions, said solution remaining stable and workable at dry solids content levels greater than 60% of its weight. The invention also pertains to a method for manufacturing such solutions, as well as their use as a plasticizing agent, and hydraulic binder-based compositions containing them.
Abstract: The present invention pertains to the use, in the manufacture of an aqueous formulation with a hydraulic binder base, of a combination of at least one comb-branched copolymer having a (meth)acrylic skeleton, onto which are grafted side-chains terminated by a hydrophilic group, and at least one ASE acrylic polymer. This results in improving the workability of said formulation, without causing a segregation phenomenon.
Type:
Application
Filed:
November 25, 2009
Publication date:
August 25, 2011
Applicant:
COATEX S.A.S.
Inventors:
David Platel, Jean Moro, Olivier Guerret
Abstract: The invention relates to novel sulphur compounds, to the production thereof by a method carried out in an aqueous medium and the use thereof in the form of transfer agents in a method for controlled radical polymerisation of acrylic acid and/or acrylic acid with water-soluble monomers in water. The thus obtained polymers are usable in the form of dispersing agents or grinding aid agents and/or aid agents for combined grinding of mineral materials in an aqueous suspension and in the form of dispersing agents directly incorporated into aqueous formulations containing mineral materials.
Abstract: The invention relates to the use, as a dispersant and/or a grinding aid agent for pigments and/or mineral fillers in aqueous suspension, of a water soluble polymer with a controlled structure obtained by a controlled free radical polymerization process putting into practice a particular alkoxyamine as a polymerization initiator.
Type:
Application
Filed:
November 3, 2010
Publication date:
June 30, 2011
Applicant:
COATEX S.A.S.
Inventors:
Jean-Marc Suau, Christian Jacquemet, Yves Kensicher
Abstract: The invention consists in the use, as a dry grinding aid agent of a mineral matter chosen from among the dolomites, talc, titanium dioxide, alumina, kaolin and calcium carbonate, the function of which is to reduce the specific grinding energy and to increase the grinding capacity, of formulations containing glycerol.
Type:
Application
Filed:
December 7, 2010
Publication date:
June 9, 2011
Applicant:
COATEX S.A.S.
Inventors:
Murielle GUILLOT, Jacques Mongoin, Olivier Guerret
Abstract: The invention consists in the use, in a method to manufacture a mineral matter, notably a precipitated calcium carbonate, of a polymer consisting of at least one vinylic monomer chosen from among acrylic or methacrylic acid, acrylamide, methacrylamide or a cationic monomer, or their blends, and at least one non-ionic monomer. The use of this polymer enables the carbonation time of the PCC to be reduced, without however impairing its crystallographic structure and its granulometric characteristics.
Abstract: The invention relates to novel sulphur compounds, to the production thereof by a method carried out in an aqueous medium and the use thereof in the form of transfer agents in a method for controlled radical polymerization of acrylic acid and/or acrylic acid with water-soluble monomers in water. The thus obtained polymers are usable in the form of dispersing agents or grinding aid agents and/or aid agents for combined grinding of mineral materials in an aqueous suspension and in the form of dispersing agents directly incorporated into aqueous formulations containing mineral materials.
Abstract: The invention consists in the use, as a thickening agent of an aqueous formulation which is, notably, salt-rich, of a water-soluble or alkali-soluble copolymer consisting of (by weight): a) 30% to 45% of (meth)acrylic acid, b) 50% to 60% of acrylamide and/or of N-methylol and/or of an acrylic ester, c) 2% to 10% of a hydrophobic monomer of formula R1—(R2O)m—R3, in which: R1 designates a polymerisable unsaturated group, R2O designates an alkylene oxide group having 1 to 6 carbon atoms, m is an integer of between 20 and 50, R3 designates a linear alkyl chain comprising at least 16 and at most 26 carbon atoms, d) 0.1% to 4% of at least one cross-linking agent, which is preferentially ethyleneglycoldimethacrylate (EDMA).
Abstract: A method including first step grinding, in aqueous media of natural calcium carbonate, an acrylic polymer having a molecular weight of between 8,000 g/mole and 15,000 g/mole and a molar content of less than 20% of polymeric chains of molecular weight less than 3,000 g/mole and second, optionally concentrating, leading to an aqueous suspension with an increased slope factor, which improves the opacity of the coated paper produced from such a suspension.
Type:
Application
Filed:
June 16, 2009
Publication date:
April 21, 2011
Applicant:
COATEX S.A.S.
Inventors:
Jacques Mongoin, Christian Jacquemet, Jean-Marc Suau
Abstract: The invention consists of a process for manufacturing ashes from the combustion of coal, this process comprising at least one step of bringing the coal into contact with an absorbent agent on the one hand, this absorbent agent being, on the other hand, contained in an aqueous phase in the presence of a (meth)acrylic dispersant, preferably a (meth)acrylic comb polymer. Thus the emissions of carbon dioxide and likewise the compounds based on sulphur, nitrogen or mercury which result from the combustion of coal are effectively combated.
Abstract: The object of the invention is the use, as a thickening agent for a water-based paint, of an aqueous solution of a polyether of at least one polyoxyalkylene and at least one alpha-olefin epoxy, and/or at least one aliphatic or aromatic glycidyl ether, and at least one surface active agent whose chemical formula is CxH2x+1—(OX)y—OH where OX designates an oxylakylated unit, and characterized in that: for the polyether, the molar ratio (polyoxyalkylene:alpha-olefin epoxy or aliphatic or aromatic glycidyl ether) is between (1:4) and (1:10), for the surface active agent, 6?x?12 and 5?y?12, said solution exhibits a mass ratio (polyether/surface active agent) of between 2.0 and 0.5, and exhibits a water content of 30% to 75% of its total weight. Another object is the paint containing such a thickening system.
Abstract: The present invention relates to new associative monomers, terminated by a hydrophobic chain with a base of polycosanols, which can be bio-resourced raw materials, and notably of octacosanol. It also concerns the HASE-type associative copolymers manufactured from these monomers, from (meth)acrylic acid and from an ester of one of these acids. The invention also concerns the use of these copolymers as thickening agents for water-based formulations.
Abstract: New associative polyurethanes which are manufactured with cardanol which is potentially oxyethylated. Use of these polyurethanes as thickening agents for aqueous formulations.
Abstract: The invention consists of the use, in an alkide resin formulation in an aqueous phase, of a dispersing agent/thickener pair: the dispersing agent is a copolymer of (meth)acrylic acid with an oxyalkylated monomer possessing a polymerizable function and terminated by hydrogen or an alkyl group having from 1 to 4 carbon atoms, the thickener is an associative thickener containing at least one hydrophobic group which is a polystyrylphanyl, preferentially chosen from among distyrylphenyl, tristyrylphenyl, and mixtures thereof, and which is very preferentially tristyrylphenyl. This combination makes it possible to improve the brightness level retention of the paint film over time, while ensuring that the aqueous formulation has the desired rheology.
Abstract: The invention concerns the polymers obtained by the use of sulphur compounds in a process for controlled radical polymerisation in water of acrylic acid and/or acrylic acid with hydrosoluble monomers. It concerns also their uses as dispersant agents or agents to aid grinding and/or co-grinding of mineral matters in aqueous suspensions, and as dispersant agents incorporated directly in aqueous formulations containing mineral matters. Finally, the invention concerns the formulations of mineral matters obtained in this manner.
Abstract: A method for manufacturing a sheet of paper from a pulp and a sheet of paper obtained by the present method, wherein said pulp comprises a mixture of natural and/or synthetic fibers, water, and at least one aqueous suspension and/or dispersion comprising at least one mineral material, wherein said dispersion or suspension comprises, as a steric dispersing agent of at least one mineral material, at least one copolymer comprising at least one vinylic monomer, at least one non-ionic monomer, or a mixture of several monomers having formula (I) in the present method, wherein said agent limits the presence of divalent ions in the aqueous phase and said agent is not a chelating agent.
Type:
Application
Filed:
October 10, 2007
Publication date:
December 16, 2010
Applicant:
COATEX S.A.S.
Inventors:
Olivier Guerret, Francois Dupont, Jacques Mongoin