Abstract: The invention relates to the use of a slightly anionic and water-soluble copolymer, as a dispersing agent and/or an agent for assisting the grinding of pigments and/or mineral fillers in aqueous suspension giving on the one hand a low Zeta potential to the aqueous suspensions of the said fillers and/or pigments and on the other hand affording an electro-steric stabilisation of the said suspensions. The invention also relates to the said aqueous suspensions of mineral pigments and/or fillers and their uses in the fields of paper, such as the manufacture or coating of paper, and drilling muds used for petroleum prospecting or extraction. The invention also relates to the use of the said dispersing agents and/or agent for assisting the grinding in the field of paints and plastic materials such as thermoplastic or thermosetting resins.
Type:
Grant
Filed:
June 12, 2001
Date of Patent:
September 20, 2005
Assignee:
Coatex S.A.S
Inventors:
Jean-Marc Suau, Christian Jacquemet, Jacques Mongoin, Patrick A. C. Gane
Abstract: A method of obtaining homopolymers and/or copolymers in aqueous solution by the use of phosphorous acid and/or its salts or sodium hypophosphite and by neutralisation during the polymerisation of the ethylenically unsaturated monomers by the continuous addition, first of all, of bases such as sodium hydroxide, potassium hydroxide or lithium hydroxide and then bases of alkaline earths such as calcium hydroxide, magnesium hydroxide, calcium oxide or magnesium oxide. The polymers obtained by the said method and uses thereof.
Type:
Application
Filed:
March 16, 2005
Publication date:
July 21, 2005
Applicant:
Coatex S.A.
Inventors:
Jean-Marc Suau, Christian Jacquemet, Jean-Bernard Egraz, Jacques Mongoin
Abstract: The invention relates to the use of a slightly anionic and water-soluble copolymer, as a dispersing agent and/or an agent for assisting the grinding of pigments and/or mineral fillers in aqueous suspension giving on the one hand a low Zeta potential to the aqueous suspensions of the said fillers and/or pigments and on the other hand affording an electro-steric stabilization of the said suspensions. The invention also relates to the said aqueous suspensions of mineral pigments and/or fillers and their uses in the fields of paper, such as the manufacture or coating of paper, and drilling muds used for petroleum prospecting or extraction. The invention also relates to the use of the said dispersing agents and/or agent for assisting the grinding in the field of paints and plastic materials such as thermoplastic or thermosetting resins.
Type:
Application
Filed:
February 1, 2005
Publication date:
June 30, 2005
Applicant:
COATEX S.A.S.
Inventors:
Jean-Marc Suau, Christian Jacquemet, Jacques Mongon, Patrick Gane
Abstract: The invention relates to the use of homopolymers and/or water-soluble copolymers of acrylic acid with one or more acrylic, vinyl or allylic monomers as dispersing agents for aqueous suspensions of mineral particles issuing from a mechanical and/or thermal reconcentration step following upon a step of wet grinding without the use of a dispersant and at low concentration in terms of dry matter.
The invention also relates to the said aqueous suspensions and their uses in the fields of paper, paint, fillers for synthetic resins and rubbers, detergent and cleaning formulations, ceramics, drilling fluids, cements, plasters and other fields of application in civil engineering and the construction industry.
Type:
Grant
Filed:
June 21, 2002
Date of Patent:
July 27, 2004
Assignee:
Coatex S.A.S.
Inventors:
Jean-Marc Suau, Christian Jacquemet, Jacques Mongoin
Abstract: The mechanical property known as “strength at young ages” of cement matrices or hydraulic binders may be significantly improved by adding dispersions of mineral fillers and dispersing agents. The dispersing agents of the present invention comprise copolymers prepared by the radical copolymerization of at least one alkoxy-, aryloxy-, alkylaryloxy- or arylalkyloxy-polyalkylene glycol ethylenic urethane monomer with at least one anionic monomer and at least one non-ionic monomer, and optionally, an alkoxy-, aryloxy-, alkylaryloxy- or arylalkyloxy-polyalkylene glycol acrylate or methacrylate or an alkyloxy-, aryloxy-, alkylaryloxy- or arylalkyloxy-polyalkylene glycol allyl ether, and/or a crosslinking agent.
Type:
Grant
Filed:
October 25, 2001
Date of Patent:
June 22, 2004
Assignee:
Coatex, S.A.S.
Inventors:
Pascal Gonnon, Yves Kensicher, Christian Jacquemet
Abstract: The mechanical property known as “strength at young ages” of cement matrices or hydraulic binders may be significantly improved by adding dispersions of mineral fillers and dispersing agents. The dispersing agents of the present invention comprise copolymers prepared by the radical copolymerization of at least one alkoxy-, aryloxy-, alkylaryloxy- or arylalkyloxy-polyalkylene glycol ethylenic urethane monomer with at least one anionic monomer and at least one non-ionic monomer, and optionally, an alkoxy-, aryloxy-, alkylaryloxy- or arylalkyloxy-polyalkylene glycol acrylate or methacrylate or an alkyloxy-, aryloxy-, alkylaryloxy- or arylalkyloxy-polyalkylene glycol allyl ether, and/or a crosslinking agent.
Type:
Application
Filed:
September 26, 2003
Publication date:
June 17, 2004
Applicant:
COATEX S.A.S.
Inventors:
Pascal Gonnon, Yves Kensicher, Christian Jacquemet
Abstract: Cements or hydraulic binders may be prepared by adding an aqueous suspension comprising a ground mineral filler and at least one grinding aid agent to a cement or hydraulic binder. The resulting cement or hydraulic binder has very appreciably improved mechanical properties, particularly the property of “strength at young ages.” The grinding aid agent may be a natural or synthetic homopolymer and/or copolymer.
Type:
Grant
Filed:
October 25, 2001
Date of Patent:
March 30, 2004
Assignee:
Coatex S.A.S.
Inventors:
Pascal Gonnon, Yves Kensicher, Christian Jacquemet
Abstract: The invention relates to the technical field of mortars, concretes, and other compositions based on cement, and in particular to agents capable of modifying their rheological characteristics, in particular workability.
Abstract: The invention relates to the technical field of mortars, concretes, and other compositions based on cement, and in particular to agents capable of modifying their rheological characteristics, in particular workability. Workability may be defined as the property of a hydraulic binder to remain workable during as long a time as possible. The invention relates to novel agents of the acrylic copolymer type having urethane functions for improving the workability of hydraulic binders, to a method of preparing such novel agents, to binders containing them, and to uses for them. Such agents have the advantageous property of not retarding the setting time.
Abstract: Cements or hydraulic binders may be prepared by adding an aqueous suspension comprising a ground mineral filler and at least one grinding aid agent to a cement or hydraulic binder. The resulting cement or hydraulic binder has very appreciably improved mechanical properties, particularly the property of “strength at young ages.” The grinding aid agent may be a natural or synthetic homopolymer and/or copolymer.
Type:
Application
Filed:
June 3, 2003
Publication date:
October 30, 2003
Applicant:
COATEX S.A.S.
Inventors:
Pascal Gonnon, Yves Kensicher, Christian Jacquemet
Abstract: A stable aqueous liquid polymer composition, which comprises:
(i) at least one polyvinyl alcohol (PVA) which has an Ostwald viscosity less than 5 mPa·s corresponding to a degree of polymerization less than 600 and a molar percentage of hydrolysis ranging from 70 to 100 measured from the ester value (DIN 53401), corresponding to a molar percentage of vinyl acetate units from 30 to 0, and
(ii) at least one water-soluble polymer at neutral or alkaline pH, the composition controlling the activation of optical brighteners, water retention and viscosities of paper coating colors.
Type:
Grant
Filed:
July 9, 2001
Date of Patent:
February 18, 2003
Assignee:
Coatex S.A.S.
Inventors:
Jean-Bernard Egraz, Georges Ravet, Jean-Marc Suau, Isabelle Capra-Ogier, Henri Grondin
Abstract: Cements or hydraulic binders may be prepared by adding an aqueous suspension comprising a ground mineral filler and at least one grinding aid agent to a cement or hydraulic binder. The resulting cement or hydraulic binder has very appreciably improved mechanical properties, particularly the property of “strength at young ages.” The grinding aid agent may be a natural or synthetic homopolymer and/or copolymer.
Type:
Application
Filed:
October 25, 2001
Publication date:
July 11, 2002
Applicant:
COATEX S.A.S.
Inventors:
Pascal Gonnon, Yves Kensicher, Christian Jacquemet
Abstract: The mechanical property known as “strength at young ages” of cement matrices or hydraulic binders may be significantly improved by adding dispersions of mineral fillers and dispersing agents. The dispersing agents of the present invention comprise copolymers prepared by the radical copolymerization of at least one alkoxy-, aryloxy-, alkylaryloxy- or arylalkyloxy-polyalkylene glycol ethylenic urethane monomer with at least one anionic monomer and at least one non-ionic monomer, and optionally, an alkoxy-, aryloxy-, alkylaryloxy- or arylalkyloxy-polyalkylene glycol acrylate or methacrylate or an alkyloxy-, aryloxy-, alkylaryloxy- or arylalkyloxy-polyalkylene glycol allyl ether, and/or a crosslinking agent.
Type:
Application
Filed:
October 25, 2001
Publication date:
June 20, 2002
Applicant:
COATEX S.A.S.
Inventors:
Pascal Gonnon, Yves Kensicher, Christian Jacquemet
Abstract: A stable aqueous liquid polymer composition, which comprises:
(i) at least one polyvinyl alcohol (PVA) which has an Ostwald viscosity less than 5 mPa·s corresponding to a degree of polymerization less than 600 and a molar percentage of hydrolysis ranging from 70 to 100 measured from the ester value (DIN 53401), corresponding to a molar percentage of vinyl acetate units from 30 to 0, and
(ii) at least one water-soluble polymer at neutral or alkaline pH, the composition controlling the activation of optical brighteners, water retention and viscosities of paper coating colors.
Type:
Grant
Filed:
November 10, 1999
Date of Patent:
October 2, 2001
Assignee:
Coatex S.A.
Inventors:
Jean-Bernard Egraz, Georges Ravet, Jean-Marc Suau, Isabelle Capra-Ogier, Henri Grondin
Abstract: Homopolymers and/or copolymers are manufactured by polymerizing ethylenically monounsaturated monomer(s) in an aqueous solution in a reaction vessel containing compounds which contain a phosphorus atom of degree of oxidation less than 5, phosphorous compounds being introduced in amounts of 0.005-0.49 gram-atom phosphorus per mol of unsaturation in said ethylenically unsaturated monomer(s) in the presence of hydrogen peroxide and in the absence of any agent(s) which decomposes hydrogen peroxide thereby forming free radicals, in the absence of any other generator of free radicals, and in the absence of any per salt and/or any other transfer agent.
Abstract: A method of producing milling adjuvants and/or dispersing agents, with the use of a separation apparatus which is comprised of one or more organic and/or mineral membranes; a milling adjuvant and/or dispersing agent produced by said method; and use of said adjuvant/agent in preparing an aqueous suspension of mineral particles; and the use of the aqueous suspension in applications involving pigments.
Type:
Grant
Filed:
May 14, 1996
Date of Patent:
October 17, 2000
Assignee:
Coatex S. A.
Inventors:
Jean-Bernard Egraz, Georges Ravet, Matthias Buri, Rene Blum
Abstract: The present invention relates to a method of dispersing or treating a mineral filler into a thermoplastic resin; the dispersing agent or agent for treatment of a mineral filler is a styrene-maleic anhydride copolymer, having an weight average molecular weight preferably between 1000 to 3000; the thermoplastic resin is selected from (a) a hydrocarbon homopolymer without an aryl group, (b) a copolymer without an aryl group, and with a molecule comprised of carbon, hydrogen and oxygen in which the content of oxygen atoms does not exceed 22% by weight or (c) a mixture of the above described homopolymer and copolymer; the mineral fillers are basic or have surfaces that have free hydroxyl groups. The present invention relates also to thermoplastic compounds which are highly filled, stable, fluid and homogeneous and which contain mineral agents; further these compositions are useful in the fabrication of plastic products.