Patents Assigned to Cree Research, Inc.
  • Patent number: 5155062
    Abstract: A method and apparatus for substantially preventing undesired residual dopants or other impurities from becoming incorporated in growing epitaxial layers of silicon carbide during CVD by avoiding the use of a susceptor for CVD epitaxial growth is disclosed. During the CVD process, the substrate is suspended substantially out of physical contact with any other solid object while a suitable surface of the semiconductor substrate is contacted with source gases that will form epitaxial layers of silicon carbide thereon. Heating during the CVD process is performed, according to the present invention, by inductively heating the substrate using an induction frequency to which the substrate material is sufficiently responsive to heat the substrate to the temperatures required for CVD of silicon carbide.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: October 13, 1992
    Assignee: Cree Research, Inc.
    Inventor: Thomas G. Coleman
  • Patent number: 5119540
    Abstract: The invention is a method, and associated apparatus and product, of forming extremely pure epitaxial layers of silicon carbide by reducing the carrier concentration of residual nitrogen in silicon carbide formed by chemical vapor deposition processes. The method comprises placing a substrate upon which an epitaxial layer of silicon carbide will form upon a susceptor, and in which the susceptor is formed of a material that will not generate undesired nitrogen-containing out gases at the temperatures at which chemical vapor deposition of silicon carbide will take place from appropriate source gases. The substrate is heated to a temperature at which chemical vapor deposition of silicon carbide will take place from appropriate source gases by inductively heating the susceptor using an induction frequency that heats the susceptor material. Silicon-containing and carbon-containing source gases are then introduced that will form an epitaxial layer of silicon carbide upon the heated substrate.
    Type: Grant
    Filed: July 24, 1990
    Date of Patent: June 9, 1992
    Assignee: Cree Research, Inc.
    Inventors: Hua-Shuang Kong, Thomas G. Coleman, Calvin H. Carter, Jr.
  • Patent number: 5061972
    Abstract: The invention is a ultra-fast, high frequency, high temperature rectifying diode formed in silicon carbide that comprises a monocrystalline silicon carbide substrate having a sufficient carrier concentration to give the substrate a first conductivity type, a first monocrystalline epitaxial layer of silicon carbide upon the substrate and having the same conductivity type as the substrate, and a second monocrystalline epitaxial layer of silicon carbide upon the first epitaxial layer and having the opposite conductivity type from the first epitaxial layer. One of the epitaxial layers has a carrier concentration greater than the carrier concentration of the other epitaxial layer, so that the layer with the lesser concentration is predominantly depleted at reverse bias. The first and second epitaxial layers form an abrupt p-n junction.
    Type: Grant
    Filed: September 13, 1990
    Date of Patent: October 29, 1991
    Assignee: Cree Research, Inc.
    Inventor: John A. Edmond
  • Patent number: 5027168
    Abstract: The present invention comprises a light emitting diode formed in silicon carbide and that emits visible light having a wavelength of between about 465-470 nanometers, or between about 455-460 nanometers, or between about 424-428 nanometers. The diode comprises a substrate of alpha silicon carbide having a first conductivity type and a first epitaxial layer of alpha silicon carbide upon the substrate having the same conductivity type as the substrate. A second epitaxial layer of alpha silicon carbide is upon the first epitaxial layer, has the opposite conductivity type from the first layer, and forms a p-n junction with the first epitaxial layer. In preferred embodiments, the first and second epitaxial layers have carrier concentrations sufficiently different from one another so that the amount of hole current and electron current that flow across the junction under biased conditions are different from one another and so that the majority of recombination events take place in the desired epitaxial layer.
    Type: Grant
    Filed: August 28, 1989
    Date of Patent: June 25, 1991
    Assignee: Cree Research, Inc.
    Inventor: John A. Edmond
  • Patent number: 5008735
    Abstract: The invention is a packaged diode suitable for operation at temperatures above 200.degree. C. and during temperature excursions between -65.degree. C. and at least 350.degree. C. The invention comprises a diode having respective p-n portions with a p-n junction therebetween, and formed of a semiconductor material that is stable and will exhibit satisfactory diode characteristics at such temperatures. Ohmic contacts are made to the opposite sides of the junction diode and to the respective p and n portions of the diode. An electrode adjacent each of the ohmic contacts is formed of an electrically conductive material that has a coefficient of thermal expansion similar to the coefficient of thermal expansion of the semiconductor material for providing structural support to the junction diode and electrical contact therewith. A lead contacts each of the electrodes opposite each electrode's contact with the diode.
    Type: Grant
    Filed: December 7, 1989
    Date of Patent: April 16, 1991
    Assignees: General Instrument Corporation, Cree Research, Inc.
    Inventors: John A. Edmond, Douglas G. Waltz, Muni M. Mitchell, Mohammad Sedigh, Roman Hamerski
  • Patent number: 4966862
    Abstract: The invention is a method for preparing a plurality of light emitting diodes on a single substrate of a semiconductor material. The method is used for structures where the substrate includes an epitaxial layer of the same semiconductor material that in turn comprises layers of p-type and n-type material that define a p-n junction therebetween. The epitaxial layer and the substrate are etched in a predetermined pattern to define individual diode precursors, and deeply enough to form mesas in the epitaxial layer that delineate the p-n junctions in each diode precursor from one another. The substrate is then grooved from the side of the epitaxial layer and between the mesas to a predetermined depth to define side portions of diode precursors in the substrate while retaining enough of the substrate beneath the grooves to maintain its mechanical stability. Ohmic contacts are added to the epitaxial layer and to the substrate and a layer of insulating material is formed on the diode precursor.
    Type: Grant
    Filed: August 28, 1989
    Date of Patent: October 30, 1990
    Assignee: Cree Research, Inc.
    Inventor: John A. Edmond
  • Patent number: 4946547
    Abstract: The invention is a method of forming a substantially planar surface on a monocrystalline silicon carbide crystal by exposing the substantially planar surface to an etching plasma until any surface or subsurface damage caused by any mechanical preparation of the surface is substantially removed. The etch is limited, however, to a time period less than that over which the plasma etch will develop new defects in the surface or aggravate existing ones, and while using a plasma gas and electrode system that do not themselves aggravate or cause substantial defects in the surface.
    Type: Grant
    Filed: October 13, 1989
    Date of Patent: August 7, 1990
    Assignee: Cree Research, Inc.
    Inventors: John W. Palmour, Hua-Shuang Kong, John A. Edmond
  • Patent number: 4918497
    Abstract: The present invention comprises a light emitting diode formed in silicon carbide and that emits visible light having a wavelength of between about 475-480 nanometers, or between about 455-460 nanometers, or between about 424-428 nanometers. The diode comprises a substrate of alpha silicon carbide having a first conductivity type and a first epitaxial layer of alpha silicon carbide upon the substrate having the same conductivity type as the substrate. A second epitaxial layer of alpha silicon carbide is upon the first epitaxial layer, has the opposite conductivity type from the first layer, and forms a p-n junction with the first epitaxial layer. In preferred embodiments, the first and second epitaxial layers have carrier concentrations sufficiently different from one another so that the amount of hole current and electron current that flow across the junction under biased conditions are different from one another and so that the majority of recombination events take place in the desired epitaxial layer.
    Type: Grant
    Filed: December 14, 1988
    Date of Patent: April 17, 1990
    Assignee: Cree Research, Inc.
    Inventor: John A. Edmond