Patents Assigned to Diamond Shamrock Chemicals Company
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Patent number: 5292965Abstract: Radiation curable compositions containing outstanding reactive diluents have been developed. The diluents are lower alkyl ether acrylates and methacrylates of particular alkoxylated and non-alkoxylated polyols.Examples are mono-methoxy trimethylolpropane diacrylate, mono-methoxy neopentyl glycol monoacrylate and mono-methoxy, ethoxylated neopentyl glycol monoacrylate having an average of about two moles of ethylene oxide.Type: GrantFiled: June 14, 1993Date of Patent: March 8, 1994Assignee: Diamond Shamrock Chemicals CompanyInventors: Francis A. Higbie, Robert A. LieBerman, Rose Ira M.
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Patent number: 5159119Abstract: Radiation curable compositions containing outstanding reactive diluents have been developed. The diluents are lower alkyl ether acrylates and methacrylates of particular alkoxylated and non-alkoxylated polyols.Examples are mono-methoxy trimethylolpropane diacrylate, mono-methoxy neopentyl glycol monoacrylate and mono-methoxy, ethoxylated neopentyl glycol monoacrylate having an average of about two moles of ethylene oxide.Type: GrantFiled: May 6, 1991Date of Patent: October 27, 1992Assignee: Diamond Shamrock Chemicals CompanyInventors: Francis A. Higbie, Robert A. LieBerman, Ira M. Rose
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Patent number: 5053554Abstract: Radiation curable compositions containing outstanding reactive diluents have been developed. The diluents are lower alkyl ether acrylates and methacrylates of particular alkoxylated and non-alkoxylated polyols.Examples are mono-methoxy trimethylolpropane diacrylate, mono-methoxy neopentyl glycol monoacrylate and mono-methoxy, ethoxylated neopentyl glycol monoacrylate having an average of about two moles of ethylene oxide.Type: GrantFiled: January 30, 1990Date of Patent: October 1, 1991Assignee: Diamond Shamrock Chemical CompanyInventors: Francis A. Higbie, Robert A. LieBerman, Ira M. Rose
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Patent number: 4814389Abstract: An aqueous drilling fluid having present in an amount sufficient to disperse the fluid and to provide resistance to high temperatures and solids contamination of the drilling fluid, at least one salt of a polymer or copolymer of acrylic or methacrylic acid with alkanolamine, alkylamine, mixtures of alkanolamine and alkylamine, mixtures of lithium and alkanolamine, mixtures of lithium and alkylamine and mixtures of lithium, alkanolamine and alkylamine, the polymer having a weight average molecular weight of between about 2,000 and about 15,000 and a pH of from about 6 to about 8.5 and where mixtures of lithium and alkanolamine, lithium and alkylamine or mixtures of lithium, alkanolamine and alkylamine are used, the amount of lithium is present to give from about 30% to about 70% of the desired neutralization of the polymer and the alkanolamine and/or alkylamine is present to give from about 70% to about 30% of the desired neutralization of the polymer.Type: GrantFiled: July 8, 1987Date of Patent: March 21, 1989Assignee: Diamond Shamrock Chemicals CompanyInventors: Christopher M. Garvey, Arpad Savoly, Thomas M. Weatherford
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Patent number: 4810328Abstract: An improved method of brown stock washing is disclosed. A nonionic surfactant in combination with a polyelectrolyte dispersant, and preferably a solvent, are utilized in the washing step in the pulping of virgin cellulosic fiber. The methods of the invention provide for the enhanced removal and recovery of cooking chemicals and organics from the pulp.Type: GrantFiled: November 4, 1987Date of Patent: March 7, 1989Assignee: Diamond Shamrock Chemicals CompanyInventors: Richard E. Freis, James E. Maloney, Thomas R. Oakes
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Patent number: 4800229Abstract: Reactive dispersants for magnetic recording media are prepared by sequentially phosphating and esterifying or esterifying and phosphating alkoxylated alcohols having at least two carbon atoms and at least two hydroxyl groups. The phosphating agent can be phosphorus oxychloride while the esterifying agent can be acrylic acid.Type: GrantFiled: January 12, 1988Date of Patent: January 24, 1989Assignee: Diamond Shamrock Chemical CompanyInventor: John G. Papalos
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Patent number: 4770952Abstract: Reactive dispersants for magnetic recording media are prepared by sequentially phosphating and esterifying or esterifying and phosphating alkoxylated alcohols having at least two carbon atoms and at least two hydroxyl groups. The phosphating agent can be phosphorus oxychloride while the esterifying agent can be acrylic acid.Type: GrantFiled: July 10, 1987Date of Patent: September 13, 1988Assignee: Diamond Shamrock Chemicals CompanyInventor: John G. Papalos
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Patent number: 4744795Abstract: The present invention relates to coal water slurries containing about 0.01% to 1% by weight of a water soluble terpolymer of ethylacrylate/methacrylic acid/ unsaturated carboxylic acid ester of an ethoxylated or nonethoxylated alcohol or an ethoxylated carboxylic acid.The water soluble terpolymer functions as a stablizing agent for the coal water slurry to prevent sedimentation and provide ease of pumping the coal water slurry.The water soluble terpolymer may be used alone or in combination with anionic or nonionic dispersants.Type: GrantFiled: August 21, 1986Date of Patent: May 17, 1988Assignee: Diamond Shamrock Chemicals CompanyInventors: Arpad Savoly, Jose L. Villa, Reuben H. Grinstein, Solomon J. Nachfolger
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Patent number: 4742105Abstract: Binary mixtures of polyacrylates and sodium silicates are used as deflocculating agents for kaolin slurries to ensure pumpability and pourability of the slurry. An example of a binary mixture is a mixture of 67% by weight sodium polyacrylate having a weight average molecular weight of 4,200 and 33% by weight of sodium silicate on a dry solids basis.Type: GrantFiled: May 29, 1986Date of Patent: May 3, 1988Assignee: Diamond Shamrock Chemicals CompanyInventor: Edwin L. Kelley
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Patent number: 4711731Abstract: An aqueous drilling fluid having present in an amount sufficient to disperse the fluid and to provide resistance to high temperatures and solids contamination of the drilling fluid, at least one salt of a polymer or copolymer of acrylic or methacrylic acid with alkanolamine, alkylamine, mixtures of alkanolamine and alkylamine, mixtures of lithium and alkanolamine, mixtures of lithium and alkylamine and mixtures of lithium, alkanolamine and alkylamine, the polymer having a weight average molecular weight of between about 2,000 and about 15,000 and a pH of from about 6 to about 8.5 and where mixtures of lithium and alkanolamine, lithium and alkylamine or mixtures of lithium, alkanolamine and alkylamine are used, the amount of lithium is present to give from about 30% to about 70% of the desired neutralization of the polymer and the alkanolamine and/or alkylamine is present to give from about 70% to about 30% of the desired neutralization of the polymer.Type: GrantFiled: February 6, 1986Date of Patent: December 8, 1987Assignee: Diamond Shamrock Chemicals CompanyInventors: Christopher M. Garvey, Arpad Savoly, Thomas M. Weatherford
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Patent number: 4699225Abstract: Polymers of (1) from about 5% to about 50% by weight of 2-acrylamido-2-methylpropane sulfonic acid and (2) from about 95% to about 50% by weight of a second component, there being from 100% to about 80% by weight acrylic acid and from 0% to about 20% by weight of itaconic acid in the second component and having a weight average molecular weight of between about 50,000 to about 1,000,000 and which are at least water dispersible are used as fluid loss control additives for aqueous drilling fluids and are particularly advantageous when used with muds containing soluble calcium ions and muds containing chloride ions such as seawater muds. An example is a copolymer of 10% by weight 2-acrylamido-2-methylpropane sulfonic acid and 90% by weight acrylic acid in its sodium salt form.Type: GrantFiled: November 7, 1985Date of Patent: October 13, 1987Assignee: Diamond Shamrock Chemicals CompanyInventor: Dinshaw F. Bardoliwalla
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Patent number: 4696981Abstract: Homopolyamino acids and copolyamino acids are prepared by polycondensation of one kind or a mixture of two or more kinds of monoammonium, diammonium, monoamide, diamide or monoamideammonium salts of malic acid and/or maleic acid and/or fumaric acid, one kind or two or more kinds of amino acid being added to said raw materials, respectively, with application of microwaves, the resulting polyamino acids (imide type) being converted to peptide type, homopolyamino acids and copolyamino acids, respectively upon partial hydrolysis. The operation involved in the reaction is simple and the method permits the use of low cost reaction materials. As a result, imide type and also peptide type, homopolyamino and copolyamino acids are produced with uniform quality at a high rate of yield within an extremely short period of time. Accordingly, the method is incomparably superior to those which have been announced in the past.Type: GrantFiled: March 13, 1986Date of Patent: September 29, 1987Assignee: Diamond Shamrock Chemicals CompanyInventors: Kaoru Harada, Akira Shimoyama, Hiroji Mizumoto
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Patent number: 4676836Abstract: Aqueous lubricant dispersions having solids content of from about 50% by weight to about 75% by weight contain calcium stearate, dispersing agent, anionic lubricant and urea are characterized by increased solids content.Type: GrantFiled: September 11, 1986Date of Patent: June 30, 1987Assignee: Diamond Shamrock Chemicals CompanyInventors: John A. Hill, Gregory J. Flynn
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Patent number: 4674574Abstract: Cementing compositions and methods of using such compositions in oil, gas and water well cementing operations to reduce fluid loss from the composition to the formation are disclosed. Such compositions incorporate a terpolymer formed from (a) an acid monomer selected from the group consisting of 2-acrylamido, 2-methyl propane sulfonic acid (AMPS), sodium vinyl sulfonate or vinyl benzene sulfonate, and metal salts thereof at about 10 to 75 weight percent in the polymer; (b) an unsaturated polybasic acid such as itaconic acid at about 1 to 60 weight percent; and metal salts thereof and (c) a nonionic monomer selected from the group consisting of acrylamide, N, N dimethylacrylamide, N-vinyl pyrrolidone, N-vinyl acetamide, or dimethylamino ethyl methacrylate and metal salts thereof at about 10 to 76 weight percent. The terpolymer should have a molecular weight between 200,000 to 1,000,000. The preferred terpolymer comprise AMPS, acrylamide and itaconic acid.Type: GrantFiled: September 26, 1986Date of Patent: June 23, 1987Assignee: Diamond Shamrock Chemicals CompanyInventors: Arpad Savoly, Jose L. Villa, Christopher M. Garvey, Albert L. Resnick
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Patent number: 4659489Abstract: Aqueous lubricant dispersions having solids content of from about 50% by weight to about 75% by weight contain calcium stearate, dispersing agent, nonionic lubricant and urea are characterized by increased solids content.Type: GrantFiled: June 22, 1984Date of Patent: April 21, 1987Assignee: Diamond Shamrock Chemicals CompanyInventors: John A. Hill, Gregory J. Flynn
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Patent number: 4647384Abstract: Copolymers of (1) from about 80% to about 98% by weight of acrylic acid and (2) from about 2% to about 20% by weight of itaconic acid and having a weight average molecular weight of between about 50,000 to about 1,000,000, preferably between about 100,000 to about 500,000, and which are at least water dispersible, are used as fluid loss control additives for aqueous drilling fluids and are particularly advantageous when used with muds containing soluble calcium and muds containing chloride ions such as seawater muds. An example is a copolymer of 95% by weight acrylic acid and 5% by weight itaconic acid in its sodium salt form.Type: GrantFiled: November 12, 1985Date of Patent: March 3, 1987Assignee: Diamond Shamrock Chemicals CompanyInventors: Dinshaw F. Bardoliwalla, Jose L. Villa
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Patent number: 4643800Abstract: The method of substantially removing and dispersing resinous or waxy contaminants from contaminant-containing secondary fiber during repulping, is disclosed. The method includes combining the contaminant-containing secondary fiber in an aqueous repulping medium with a substituted oxyethylene glycol nonionic surfactant, and a water soluble, low molecular weight polyelectrolyte dispersant, at an elevated temperature.Type: GrantFiled: June 7, 1985Date of Patent: February 17, 1987Assignee: Diamond Shamrock Chemicals CompanyInventors: James F. Maloney, Richard E. Freis, Thomas R. Oakes
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Patent number: 4634451Abstract: Aqueous carbonaceous mixtures such as water slurries of solid particulate carbonaceous materials having reduced viscosity, a stabilized network of carbonaceous materials in water and improved pumpability are obtained by using a condensation product of an aldehyde in aldehyde liberating composition, ketone and sulfur dioxide in a sulfur dioxide liberating composition as dispersant, the dispersant being present in an amount sufficient to reduce viscosity of the slurry, stabilize the network of carbonaceous materials in water and improve pumpability. An improved process for the condensation product is disclosed.Type: GrantFiled: May 10, 1985Date of Patent: January 6, 1987Assignee: Diamond Shamrock Chemicals CompanyInventors: Stanley A. Lipowski, Jose L. Villa, John J. Miskel, Jr., Reuben H. Grinstein
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Patent number: 4622373Abstract: Polymers of (1) from about 5% to about 50% by weight of 2-acrylamido-2-methylpropane sulfonic acid and (2) from about 95% to about 50% by weight of a second component, there being from 100% to about 80% by weight acrylic acid and from 0% to about 20% by weight of itaconic acid in the second component and having a weight average molecular weight of between about 50,000 to about 1,000,000 and which are at least water dispersible are used as fluid loss control additives for aqueous drilling fluids and are particularly advantageous when used with muds containing soluble calcium ions and muds containing chloride ions such as seawater muds. An example is a copolymer of 10% by weight 2-acrylamido-2-methylpropane sulfonic acid and 90% by weight acrylic acid in its sodium salt form.Type: GrantFiled: May 10, 1984Date of Patent: November 11, 1986Assignee: Diamond Shamrock Chemicals CompanyInventor: Dinshaw F. Bardoliwalla
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Patent number: 4622370Abstract: Copolymers of (1) from about 80% to about 98% by weight of acrylic acid and (2) from about 2% to about 20% by weight of itaconic acid and having a weight average molecular weight of between about 50,000 to about 1,000,000, preferably between about 100,000 to about 500,000, and which are at least water dispersible, are used as fluid loss control additives for aqueous drilling fluids and are particularly advantageous when used with muds containing soluble calcium and muds containing chloride ions such as seawater muds. An example is a copolymer of 95% by weight acrylic acid and 5% by weight itaconic acid in its sodium salt form.Type: GrantFiled: May 1, 1984Date of Patent: November 11, 1986Assignee: Diamond Shamrock Chemicals CompanyInventors: Dinshaw F. Bardoliwalla, Jose L. Villa