Abstract: Concentrated alkali metal hydroxide substantially free of alkali metal halide and other impurities is produced by the electrolysis of an alkali metal halide solution in an electrolytic cell having a dimensionally stable anode and a metal cathode separated by an electrically conductive stable selectively permeable hydrated cation ion-exchange membrane film of a fluorinated copolymer having pendant sulfonic acid groups or derivatives of such groups. The membrane film is capable of use at high temperatures and under severely corrosive chemical conditions for extended periods without degradation.
Abstract: Ostomy collection pouch appliances suitable for operation in a first, non-vented, or second, vented but substantially leak-proof, mode and provided with a sealed port member including a heat seal configuration which provides the user with directional information concerning proper opening of the port.
Abstract: A chromium-containing treating composition, which is especially useful for rinsing phosphatized metal surfaces, contains hexavalent chromium-containing compound, methylene chloride and a substance that can be acetamide, N,N-dimethylformamide, acetone oxime and mixtures thereof. The composition is a homogeneous solution that is particularly useful where aqueous systems may create potential water pollution problems.
Abstract: Disclosed are methods for rejuvenation of oxygen electrodes which maximize the power efficiency available from such oxygen electrodes while minimizing the voltage necessary to operate such oxygen electrodes over extended periods of time. These methods include in situ and out of cell techniques using hot water washing followed by air drying and dilute acid washing followed by air drying.
Type:
Grant
Filed:
August 9, 1978
Date of Patent:
January 22, 1980
Assignee:
Diamond Shamrock Corporation
Inventors:
Frank Solomon, Donald F. Lieb, Ronald L. LaBarre
Abstract: Disclosed is a method for converting a diaphragm electrolytic cell to a membrane electrolytic cell by using the standard diaphragm cell equipment and applying a membrane over top of a matting material upon the cathode surface. This method permits a manufacturer having diaphragm electrolytic cells to convert those cells to membrane electrolytic cells without significant capital expenditure to achieve the desirable characteristics of a membrane electrolytic cell.
Abstract: Novel oxygen selective electrode comprising a coating on said anode consisting of delta manganese dioxide. This outer coating on the anode may be placed on the anode electrochemically by electrolyzing an acid saline solution having dissolved therein sufficient manganous chloride. Sufficient manganese dioxide is plated on said anode when the chlorine evolution essentially ceases during electrolysis.
Abstract: Addition of sodium naphthaleneformaldehyde sulfonate to phosphate rock slurry in manufacture of phosphoric acid by the wet process permits reduction of the viscosity and/or water content of the slurry so that increased pumpability of the slurry is obtained.
Abstract: More rapid curing of polyepoxide resins is achieved by use of a curing system composed of at least one polymercaptan, at least one catalyst which is a poly[(N,N-dimethylamino)alkyl]ether and/or organic non-quaternized salts thereof derived from organic compounds having at least one acidic group and having a pKa greater than about 3.5 and, optionally, organic sulfide, tertiary phosphine or a tertiary amine having no bridged atoms, having no ether oxygen and having at least one tertiary amine group.
Abstract: Steroidal acids of the formula ##STR1## are prepared from steroidal ketones of the formula ##STR2## wherein R.sub.1 is hydrogen; hydroxy; lower alkyloxy; tetrahydropyranyloxy; aryloxy; alkyl; alkanoyloxy or aroyloxy; R.sub.2 is hydrogen; hydroxy; lower alkyloxy; tetrahydropyranyloxy; aryloxy; alkyl; alkanoyloxy or aroyloxy; R.sub.3 is hydrogen; hydroxy; lower alkyloxy; tetrahydropyranyloxy; aryloxy; alkyl; alkanoyloxy or aroyloxy; with the proviso that R.sub.1 and R.sub.2 together or R.sub.2 and R.sub.3 together may form a carbon-carbon bond; R.sub.4 is --(CH.sub.2).sub.n CO(CH.sub.2).sub.m CH.sub.3 ; R.sub.5 is --(CH.sub.2).sub.n+m+1 COOH; R.sub.
Abstract: An ion exchange membrane of a fluorinated polymer which contains sulfonyl groups, wherein the sulfonyl groups on one surface of the membrane are in the form of N-monosubstituted sulfonamide groups formed from a di- or polyamine, is treated by heating at a temperature of 100.degree. to 160.degree. C. for a time of at least 15 minutes. The resulting membrane is useful as the membrane in a chloralkali electrolysis cell, and permits operation of such cells at high current efficiency over extended periods of time.
Type:
Grant
Filed:
September 27, 1978
Date of Patent:
September 18, 1979
Assignees:
Diamond Shamrock Corporation, E. I. Du Pont de Nemours and Company
Abstract: Addition of zinc naphthaleneformaldehyde sulfonate to concrete mix improves compressive strength. This sulfonate is effective in concrete mixes prepared with Type I, II and III cements.
Abstract: Certain imidazothiazoles and thiazolopyrimidines have been found to prevent and inhibit the formation of granuloma tissue in animals. This result is accomplished by administering to the animal subject a therapeutically effective amount of a compound having the formula: ##STR1## WHEREIN R is hydrogen or methyl, R' is hydrogen, lower alkyl or thioalkyl, carboxy methyl, or phenyl; R" is lower alkyl, 2-benzofuranyl, naphthyl, phenyl, or mono- or disubstituted phenyl. The hydrated precursors of certain of these compounds as well as the acid addition and quaternary salts of both the compounds and their hydrated precursors may be employed.
Type:
Grant
Filed:
March 2, 1978
Date of Patent:
July 10, 1979
Assignee:
Diamond Shamrock Corporation
Inventors:
Robert E. Moser, Larry J. Powers, Zaven S. Ariyan
Abstract: Disclosed is a cyclone for use in conjunction with electrolytic cells for separating a gas such as hydrogen from the electrolyte solution so as to significantly increase the efficiency of subsequent cells connected in series in a large bank of electrolytic cells. The subject cyclone is especially useful in a sea water hypochlorite electrolytic cell wherein the flow rate of electrolyte is in the range of 20 to 80 gallons per minute (75 to 300 liters per minute).
Abstract: Substituted 1,2,4-triazines, compositions thereof and methods of using same are described. The compounds of the invention exhibit a wide range of pharmacological activity including anti-inflammatory, analgesic, anti-pyretic, hypotensive and central nervous system effects.
Type:
Grant
Filed:
April 19, 1978
Date of Patent:
June 5, 1979
Assignee:
Diamond Shamrock Corporation
Inventors:
James M. Gullo, William P. Heilman, Robert J. Wayner, Robert E. Moser
Abstract: Disclosed is a method for converting box form dimensionally stable anodes to the more useful and energy-saving expandable type. In one embodiment, anode box plates are cut off the anode riser at the closest point thereto. Expander springs are then attached to the anode riser and the anode box plates which have been cut into quarter panels, sized and spliced together to form new anode plates are rewelded to the expander springs. Alternatively, the method comprises the steps of cutting away only the end portions of the box anode structure and bending remaining portions of the anode screens into a spring form similar to expander springs and attaching a new pair of anode plates or screens to adjacent pairs of these newly formed springs. The anodes may then be substituted in a diaphragm-type electrolytic cell for the production of alkali metal hydroxides and halogen and the energy savings associated with the use of expandable anodes may thereby be realized.
Abstract: Since primers can be applied to metal substrates prior to subsequent operation, including metal deformation, they are often applied in coil coating operation. The potential for the removal of primer coating during metal deformation is a drawback to early coating application. There is now provided a lubricant composition particularly adapted to meet this problem. The composition comprises metallic stearate, emulsifier, titanium dioxide and Xanthomonas hydrophilic colloid, all in aqueous medium.