Abstract: A process to form coated polymer particles comprising polymer particles formed from a polymer composition comprising an olefin-based polymer, and a coating formed from a coating composition comprising an aqueous metal acid dispersion and an aqueous polysiloxane emulsion, said process comprising the following: mixing together the aqueous metal acid dispersion and the aqueous polysiloxane emulsion to form a dispersion/emulsion mixture; applying the dispersion/emulsion mixture to a portion of the surfaces of the polymer particles to form wet-coated polymer particles; drying the wet-coated polymer particles to form the coated polymer particles. The aqueous metal acid dispersion and the aqueous polysiloxane emulsion may also be applied, individually, in separate steps.

Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.

Abstract: A composition comprises (A) an ethylene/alpha-olefin/diene interpolymer; (B) a peroxide comprising at least one peroxide bond; and (C) a bis-TEMPO compound having the Structure (I), wherein R1-4 are each independently H or a C1-C6 alkyl group; X is S, O, N, P, Se, a carbonyl group, a carboxyl group, an amide group, an azo group, an imino group, a carbamate group, a peroxy group, a phosphono group, a phosphate group, a sulfonyl group, a sulfinyl group, a sulfonate ester group, a sulfonate ester group, or combinations thereof; Y is a substitute or unsubstituted aliphatic alkyl group or aromatic alkyl group, a heterocyclic group, a siloxane group, an ethylene glycol group, an imide group, or combinations thereof; and n is greater than 1. The ratio of the molar amount of nitroxide groups of component (C) to the molar amount of the peroxide bonds of component (B) is from 0.100:1.000 to 2.000:1.000.

Abstract: The present disclosure relates to an olefin polymerization catalyst system for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the catalyst system comprises: (A) a first olefin polymerization procatalyst, (B) a second olefin polymerization procatalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by procatalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

Abstract: Polyolefin photovoltaic (PV) backsheets comprise a polypropylene layer stabilized with (A) at least one hindered amine with 2,2,6,6-tetraalkylpiperdine or 2,2,6,6 -tetraakylpiperazinone, either or both in combination with a triazine moiety, (B) a thioester, and, optionally, (C) at least one hindered hydroxybenzoate, and/or (D) an ortho hydroxyl triazine compound. These PV backsheets exhibit a low flame spread index of <100 without the use of FR agents, and the polypropylene layer exhibits good weatherability while providing the required long term heat aging performance necessary for PV modules.

Abstract: An ethylene-based polymer formed from reacting at least the following: ethylene and at least one asymmetrical polyene, of Structure 1, as described herein.

Abstract: A compound of formula (1) as drawn in the description, wherein M is a Group 4 metal, one R is a silicon-containing organic solubilizing group, and the other R is a silicon-containing organic solubilizing group or a silicon-free organic solubilizing group. A method of synthesizing the compound (1). A solution of compound (1) in alkane solvent. A catalyst system comprising or made from compound (1) and an activator. A method of polymerizing an olefin monomer with the catalyst system.

Abstract: Embodiments of the present disclosure are directed to laminates comprising a uniaxially oriented first multilayer film comprising ethylene-based polymer, wherein the uniaxially oriented first multilayer film has a ratio of percent elongation at break in the cross direction to percent elongation at break in the machine direction of at least 2 to 1; a biaxially oriented second multilayer film adhered to the uniaxially oriented first multilayer film and comprising an ethylene-based polymer, wherein the biaxially oriented second multilayer film has a ratio of percent elongation at break in the machine direction to percent elongation at break in the cross direction of at least 2 to 1; and a third film adhered to the biaxially oriented second multilayer film such that the biaxially oriented second multilayer film is disposed between the uniaxially oriented first multilayer film and the third film, wherein the third film comprises an ethylene-based polymer.

Abstract: According to one or more embodiments, olefins may be produced by contacting a hydrocarbon feed stream with a particulate solid in a reaction vessel. The reaction vessel may be connected to a riser. The riser may extend through a riser port of an outer shell of a particulate solid separation section such that the riser may comprise an interior riser segment and an exterior riser segment. The particulate solid separation section may include a gas outlet port, a riser port, and a particulate solid outlet port. The particulate solid separation section may house a gas/solids separation device and a solid particulate collection area. The riser port may be positioned on a sidewall of the outer shell such that it is not located on a central vertical axis of the particulate solid separation section. The particulate solid may be separated from an olefin-containing product stream in the gas/solids separation device.

Abstract: According to one or more embodiments, particulate solids may be regenerated in a particulate solid treatment vessel. The particulate solid treatment vessel may be connected to a riser. The riser may extend through a riser port of an outer shell of a particulate solid separation section such that the riser may comprise an interior riser segment and an exterior riser segment. The particulate solid separation section may include a gas outlet port, a riser port, and a particulate solid collection area. The riser port may be positioned on a sidewall of the outer shell such that it is not located on a central vertical axis of the particulate solid separation section. The particulate solids may be separated from gasses in the particulate solid separation section.

Abstract: A composition and a method for preparing a polymer composite article. The composition comprises (A) a filler in an amount of from 10 to 90 wt. The composition also comprises (B) a polymer in an amount of from 10 to 90 wt. %, wherein the (B) polymer is selected from polyolefins, polyamides, polyesters, or combinations thereof. Further, the composition comprises (C) an organopolysiloxane in an amount of from greater than 0 to 10 wt. %; the (C) organopolysiloxane having at least one silicon-bonded hydroxyl group and a viscosity of from 1,000 to 60,000 mPa·s at 25° C. The ranges for components (A)-(C) are based on the total weight of components (A), (B) and (C) in the composition.

Abstract: A hybrid catalyst including a metal oxide catalyst component comprising chromium, zinc, and at least one additional metal selected from the group consisting of aluminum and gallium, and a microporous catalyst component that is a molecular sieve having 8-MR pore openings. The metal oxide catalyst component includes anatomic ratio of chromium:zinc (Cr:Zn) from 0.35 to 1.00, and the at least one additional metal is present in an amount from 25.0 at % to 40.0 at %. A process for preparing C2 and C3 olefins comprising: a) introducing a feed stream comprising hydrogen gas and a carbon-containing gas selected from the group consisting of carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor; and b) converting the feed stream into a product stream comprising C2 and C3 olefins in the reaction zone in the presence of said hybrid catalyst.

Abstract: A method for making a solventless polyorganosiloxane pellet is disclosed. The pellet is comprised of a polyorganosilicate resin and a polyorganosiloxane gum. The pellet is useful for making silicone pressure sensitive adhesive compositions.

Abstract: A nylon composition comprising a blend, wherein the blend includes: (a) at least one polyamide; and (b) at least one modifier, wherein the modifier includes a substantially linear functionalized ethylene/alpha-olefin copolymer having at least one side chain furan moiety crosslinked with at least one maleimide structure; a process for making the composition; and an article made from the composition.

Abstract: A supported riser apparatus may be housed at least partially within a vessel. The supported riser apparatus may include a riser including a non-vertical riser segment, a non-linear riser segment, and a vertical riser segment. The supported riser apparatus may further include a support member comprising a proximal end and a distal end. The proximal end of the support member may be connected to the non-vertical riser segment and the angle between the support member and the non-vertical riser segment may be from 15 to 75. The supported riser apparatus may include a support structure connected to the riser and the support member and an expansion guide connected to an interior surface of the vessel. The expansion guide may be shaped and positioned such that the support member slides across the expansion guide as the support member undergoes thermal expansion or thermal contraction.

Abstract: According to one or more embodiments of the present disclosure, a riser may include a lower riser portion, where the lower riser portion terminates at an upper end of the vertical riser segment, and an upper riser portion including a lower end, where the lower end of the upper riser portion may be positioned around the upper end of the vertical riser segment of the lower riser portion. The riser may also include a first guide and a second guide each positioned on opposite sides of the interior of the lower end of the upper riser portion. The vertical riser segment of the lower riser portion may be guided in a direction substantially parallel with the outer surface of the first guide and the outer surface of the second guide when the lower riser portion expands or contracts due to changes in temperature.

Abstract: According to one or more embodiments presently disclosed herein, a multilayer structure may include an oriented film and a sealant layer. The oriented film may include at least 90% by weight polyethylene. The sealant layer may include from 15 wt. % to 40 wt. % of a low density polyethylene based on the total weight of the sealant layer. The sealant layer may further include (a) from 60 wt. % to 85 wt. % of an ethylene-based elastomer based on the total weight of the sealant layer, or (b) from 60 wt. % to 85 wt. % of a propylene-based plastomer based on the total weight of the sealant layer.

Abstract: A process for separating a catalyst component from a catalyst-containing slurry by centrifugation including separating the catalyst component from the mother liquor of the catalyst-containing slurry using a stacked disc centrifuge equipped with an auto-discharging functionality. The solids discharge from the stacked disc centrifuge is enhanced by adding a washing solution to the bowl and the solids discharge chute of the stacked disc centrifuge.

Abstract: The present disclosure provides a composition. The composition contains (A) an ethylene-based polymer; and (B) a slip agent blend, the slip agent blend containing (i) from greater than 50 wt % to 99 wt % of a first polydimethylsiloxane having a number average molecular weight (Mn) from 30,000 g/mol to less than 300,000 g/mol; and (ii) from 1 wt % to less than 50 wt % of a second polydimethylsiloxane having a number average molecular weight (Mn) from 300,000 g/mol to 2,000,000 g/mol, based on the total weight of the slip agent blend. The present disclosure also provides a film with a layer containing said composition.

Abstract: According to one or more embodiments presently disclosed herein, a multilayer structure may include a biaxially oriented film and a sealant layer. The biaxially oriented film may include at least 90% by weight of polypropylene. The sealant layer may be on the biaxially oriented polypropylene film. The sealant layer may include from 15 to 40 percent by weight of a low density polyethylene based on the total weight of the sealant layer. The sealant layer may additionally include from 60 to 85 percent by weight of a propylene-based plastomer based on the total weight of the sealant layer. The propylene-based plastomer may have a density of 0.890 g/cm3 or less and a melt flow rate (at 230° C. and 2.16 kg) of at least 8 g/10 minutes.