Abstract: A system for cooling high-temperature gasifiers and method for its operation wherein cooling conduits extend vertically through the walls of the gasifier and are connected at their ends to a closed-water circulation system which incorporates heat exchangers for removing heat from the system. Boiling in the system is prevented, and good heat transfer characteristics are achieved, by maintaining a high pressure system, at least 40 bar, coupled with a flow velocity of between 5 and 7 meters per second at a maximum internal diameter of the cooling conduits of 51 millimeters. Means are provided for maintaining the temperature of the water exiting from the cooling conduits at least 10.degree. C below the boiling point at the pressure and flow rate of the system.

Abstract: Apparatus for cleaning incrusted deposits from the regions of coke oven doors between a central refractory sealing plug and a surrounding sealing edge or strip with the use of two pairs of nozzles carried on the upper and lower ends of a frame which can traverse the inner end of the door on which the sealing plug is carried. The frame has a length preferably one-half the height of the door such that the upper nozzles will clean the upper half of the door while the lower nozzles clean the lower half. The nozzles are pivotally carried on the frame such that they can be actuated to clean the horizontally-extending portions of the door between the sealing plug and the sealing strip at the upper and lower extremities of the door.

Abstract: In the cellar located below an underjet-type of battery of coke ovens are gas distribution pipes. A gas dispensing nozzle is located within each of the separate pipes which extend from a distribution pipe through the regenerators into the burners for a row of heating flues between two coking chambers. These nozzles are cleaned by injecting compressed air from a pipeline that extends parallel to the rich gas distribution pipe. A nipple opposite each nozzle interconnects the air pipeline and the gas pipe. The nipple receives a plug having either an orifice or a nozzle tube to direct compressed air toward the gas dispensing nozzle. A supply header for compressed air extends along the battery of coke ovens and this header is connected by a valve to each compressed air pipeline in the cellar. A controller responsive to a timer operates the valves during regenerative heating reversals for periodic cleaning of the gas dispensing nozzles with compressed air.

Abstract: A tube-type reactor includes a reactor shell surrounding a bundle of vertically-arranged jacketed tube assemblies. An equilateral triangle is formed by lines interconnecting the central axes of the three jacketed tube assemblies in mutual contact. Each jacketed tube assembly includes a reactor tube forming an annular space within a sheathing tube which includes six longitudinally-arranged slots uniformly distributed about its top end and into which connecting elements are received and welded to join together the sheathing tubes. In one form, the connector element includes spacer heads extending along a web to lie within the annular gap between the reactor tube and the sheathing tube and abut against the reactor tube. In a second embodiment, the connector element includes a web having three spider arms with longitudinal recesses, the width of which corresponds to the wall thickness of a sheathing tube.

Abstract: A process is provided for removing ammonia, hydrogen sulfide and hydrocyanic acid from gases such as coke oven gas. In carrying out the process, the gas to be cleaned is first washed with an alkaline solution to remove the hydrogen sulfide and hydrocyanic acid. The hydrogen sulfide is oxidized by air to produce elemental sulfur, which is removed, and the alkaline solution is recirculated for reuse, a portion of the solution carrying cyanide and other compounds being diverted for further treatment. The gas to be cleaned is subjected to a second washing operation with an inorganic acid solution which removes the ammonia from the gas by formation of an ammonia salt solution. The salt solution is regenerated to recover the acid which is recirculated for reuse.

Abstract: Flushing liquor from a gas main of a coke oven is fed into a preliminary gravity separator to provide an aqueous liquid phase substantially free of tar and solids for reuse as flushing liquid in the gas main. A tar phase obtained from the preliminary gravity separator is fed into a circuit including a centrifuge for three-phase clarification and separation. The circulation in the circuit being at quantities greater than the quantities of the tar phase introduced per unit of time from the gravity separator to obtain a tar surplus which is substantially free of aqueous liquid and thick tar. The tar surplus is removed from the circuit by feeding clean tar from the centrifuge into an overflow tank from where clean tar is reintroduced into the circuit and clean tar is returned to the preliminary gravity separator in controlled response to the tar level therein.

Abstract: Fine-grain fuel is delivered from pressure vessels with a vehicle gas as a fluidized flow into a reactor for gasification at an elevated pressure. A gaseous gasification agent is also fed into the reactor. A control system for the fine-grain fuel and gasification agent includes detectors to provide an electrical signal which varies during feeding of fuel from the pressure vessels into the reactor. Controllers produce a fuel rate control signal corresponding to a comparison between the electrical signal from the detectors and a predetermined reference value corresponding to the desired fuel supply rate. Control valves respond to the fuel rate control signal to adjust the supply of vehicle gas to transfer fuel from the pressure vessels into the reactor.

Abstract: A process for gasification of pulverized or fine-grain coal is characterized by using a portion of the combustible gas generated at a temperature between 1500.degree. and 2200.degree. C in a slag bath generator as a gaseous agent that is mixed with the coal and then introduced under pressure into the slag bath generator. The portion of the combustible gas to be used for this purpose undergoes processing which includes extracting dust, cooling and drying before the gas is combined with the fuel. According to a different embodiment, the combustible gas produced in the generator is used in the reduction process by feeding the gas into a reduction shaft furnace. The top gas from the shaft furnace is processed by extracting dust, cooling, drying and normalizing the acidity of the top gas before the top gas is combined with fuel for introduction as a mixture into the slag bath generator.

Abstract: A damaged part of a coke oven such as a heating wall is restored by selecting masonry bridging material with an essentially low thermal expansion property to close the heating flue and support the heating wall. The selected masonry bridging material may take the form of bridging bricks or castable concrete material. Such masonry bridging material is arranged to close and support the existing masonry which is to remain as part of the heating wall for continued use. The masonry bridging material forms flat connecting surfaces used to provide lateral expansion joints which are aligned from course-to-course. The expansion joint compensates for length changes of the renewed part of the heating wall formed by stretcher bricks having the usual relatively high thermal expansion property. The masonry bridging material reforms an internal crosswall that defines part of a heating flue chamber within a heating wall.

Abstract: The high temperature gasification of solid fuel or mixtures of solid and liquid fuels is carried out by a method and apparatus wherein the gasified product from a high temperature gasification chamber having a slag bath therein is fed into a first dust collector. Gases, including vapors or aerosols, are fed from the dust collector into a waste heat boiler to reduce the temperature of the gases down to about 250.degree. C. The solids which essentially include flue coke are discharged from the dust collector into a separate heat exchanger wherein the temperature of the solids is reduced down to about 200.degree. C. The cooled solids and the cooled gases are fed into an absorption chamber wherein for a period of 1 to 10 seconds, the aerosols are absorbed into the flue coke. The absorption chamber is connected to a second dust collector that separates the gases from the flue coke having the absorbed aerosols.

Abstract: A control system maintains a predetermined volumetric ratio between fine-particle fuel and a gasification agent which are fed separately into a reactor wherein the fuel is gasified under pressure. The control system includes a first measuring means responsive to the absorption of electromagnetic radiation by the fine-particle fuel in a fuel-feed line for producing a fuel-feed signal corresponding to the volumetric amount of fuel conducted by the line. A vehicle gas-feed signal is produced by a second measuring means in response to the volumetric amount of vehicle gas conducted by a line into the fuel-feed line for admixture with the fuel therein. Computing means is responsive to the fuel-feed signal and the vehicle gas-feed signal to produce a control signal according the expression:U.sub.1 . (U.sub.2 - U.sub.v)for all values of U.sub.2 greater than U.sub.v where U.sub.1 corresponds to the reciprocal of the fuel-feed signal, U.sub.2 corresponds to the vehicle gas-feed signal and U.sub.

Abstract: A process and apparatus for the regeneration of washing oil which has been spent to recover naphthalene and/or benzol from coke oven gas. The spent washing oil is stripped by steam in a bubble column arranged as an integral part of a single main column that includes first, second and third exchange column sections disposed in a superimposed relation one above the other to receive the stripped vapors from the bubble column. The first exchange column section is fed with a mixture of toluene, xylene and naphthalene as a reflux, the second exchange column section is fed with water as the reflux and the third exchange column section is fed with benzol as the reflux. The head product from the column is condensed and passed through a first-phase separator to obtain a substantially anhydrous benzol fraction and a water fraction. These fractions are separately used as a reflux for the second and third exchange column sections.

Abstract: Nozzles introduce jet streams of fine-grain fuel and a gasification medium downwardly toward the surface of a slag bath at the bottom of a cylindrical reactor shaft within a vessel to impinge upon the surface of liquid slag which is discharged through a centrally-arranged overflow in the bottom of the vessel. The nozzles are arranged at an angle within a range of 35.degree. to 40.degree. with respect to the horizontal and positioned so that the jet streams impinge upon the surface of the slag at points defined by a plurality of concentric circles with respect to the overflow to circulate and produce a resulting movement of the liquid slag toward the overflow while maintaining a high temperature and homogeneous slag bath. The nozzles are further positioned so that an angle of about 10.degree. is defined between each jet stream and a vertical tangential plane to the concentric circle at the point where the jet stream impinges.

Abstract: A boiler has an outer wall of weldable material and an inner chamber including a high temperature heat exchanger which is connected by pipes passing through openings in the outer boiler wall for the supply and discharge of a heat exchange medium. Each pipe for the heat exchange medium is spaced from and passes through a sleeve-like jacket that is welded to the outer boiler wall and projects outwardly therefrom. A cooling gas is fed into the sleeve-like jacket to pass along an annular space between the jacket and the pipe. The cooling gas flows into an annular chamber between the outer boiler wall and the inner chamber. According to a second embodiment, concentric sleeves are provided in the annular space between the jacket and pipe to pass the cooling gas to and fro within this space.

Abstract: A carriage movable along the coke side of a coke oven battery and carrying a coke guide, a door extractor, a frame cleaner and a door cleaner. These elements can be manipulated on the carriage so as to effect door extraction, coke pushing, door cleaning and frame cleaning in a minimum amount of time and without the necessity for moving the carriage itself along the coke oven battery while servicing any one coke oven chamber.

Abstract: This disclosure relates to reinforced support walls arranged to extend transversely of the length of a battery of coke ovens in a cellar for supporting battery decking of underjet coke ovens. Ducts extend in the cellar for supplying gaseous combustion media to the heating flues of the heating walls and control members are arranged in the cellar to control the flow of the combustion media in the individual ducts. A foundation slab includes reinforcement members bonded to reinforcement members within the support walls. Expansion joints, including slip plates, are arranged between the support walls and the battery decking. The decking may include a projection extending downwardly along the center line of the battery for bonding engagement with the support walls.

Abstract: A method and apparatus for gasifying fine-grained fuel, e.g., coal and a gasifying medium, e.g., oxygen in a slag bath generator. The fine-grained fuel and gasifying medium are injected at a downwardly-inclined angle to tangentially impinge with a turbulent rotary motion upon a slag bath in the lower end of a vertically-extending reactor shaft within a pressure vessel. A desired slag bath level is maintained in the bottom of the vessel by using an overflow to discharge slag from the bath through the bottom of the vessel. A first treatment zone for the high temperature gasification of the fuel is formed between the slag bath and a circular constriction to the reactor shaft. A second treatment zone for the final gasification of the fuel at a lower temperature as compared with the temperature in the first treatment zone extends above the circumferential constriction along the reactor shaft. Fuel and gases passing through the circumferential constriction are essentially free of a turbulent rotary motion.

Abstract: In the process disclosed, gas from a coke plant is washed with an aqueous metallic salt solution including sulfureous and sulfuric acid to absorb the ammonia, hydrogen sulfide and hydrogen cyanide from the gas. The washing solution is then oxidized in an aerating tank to recover elementary sulfur. A portion of the washing fluid from the oxidizer is returned for continued washing of gas and a portion of the fluid is heated in the presence of a catalyst to yield products of combustion including an acid anhydride and a metal or metal oxide. After processing the combustion products through a heat recovering system, the acid anhydride and metal oxides are combined and react to form renewed aqueous metal salt solution that is combined with the oxidized washing solution to wash additional quantities of gas.

Abstract: A process for carrying out an endothermic chemical reaction, such as the water-gas reaction, wherein heat is supplied to the reaction from nuclear reactor cooling gases. The invention is characterized in that water vapor and fuel, for example, are passed through a series of heat exchangers and reaction chambers in series, the heat exchangers being disposed within a conduit through which cooling gases from a nuclear reactor flow. When a fuel such as methane, for example, is being dissociated in the endothermic reaction, additional fuel is added to each reaction chamber where heat is supplied from the nuclear reactor cooling medium via a separate heat exchanger for that chamber.

Abstract: The heating walls for a battery of coke oven chambers are formed by rows of twin heating flues. Each heating flue includes a crosswall having an internal passageway with exit ports at graduated elevation to form a header flue. The header flues in two adjacent heating walls are connected by a first series of ducts to regenerators that supply preheated air during the heating half-cycle. A second series of ducts extend between other regenerators and exit ports on the sole of the heating flues for conducting preheated lean gas or, optionally, preheated air when heating with rich gas. The ducts of each series alternate from heating wall to heating wall so that the sequence of upgoing and downgoing flues alternates from heating wall to heating wall.