Abstract: An optical glass fiber coating composition comprising:
(A) a urethane (meth)acrylate polymer,
(B) a (meth)acrylate compound represented by the following formula (1),
go wherein R1 is a hydrogen or a methyl group
(C) a reaction diluent, and
(D) a polymerization initiator.
The composition has superior storage stability over a long period of time and, at a cured state, exhibits excellent UV resistance, heat resistance, yellowing resistance, and oil resistance.
Type:
Grant
Filed:
April 11, 1997
Date of Patent:
February 20, 2001
Assignees:
DSM N.V., JSR Corporation
Inventors:
Tetsuya Yamamura, Masakatsu Ukon, Zen Komiya, Takashi Ukachi
Abstract: Process to separate &egr;-caprolactam from an aqueous mixture containing &egr;-caprolactam and at least 0.5 wt % oligomers, wherein the separation is performed by extraction using an organic extraction agent. The aqueous mixture may be obtained in a process to prepare &egr;-caprolactam starting from 6-aminocapronitrile or in a process to prepare &egr;-caprolactam starting from 6-aminocaproic acid.
Type:
Grant
Filed:
August 17, 1998
Date of Patent:
February 20, 2001
Assignees:
DSM N.V., E.I. du Pont Nemous and Company
Abstract: Radiation-curable inner and outer primary optical fiber coatings are disclosed having both fast cure speed and reduced rates of yellowing. The compositions comprise particular photoinitiators and UV absorbers which are used in amounts to provide the combination of properties. The UV absorber can have ethylenic unsaturation. Outer primary coatings can be formulated to screen inner primary coatings and have fast cure speed.
Type:
Grant
Filed:
June 18, 1998
Date of Patent:
February 13, 2001
Assignee:
DSM N.V.
Inventors:
David M. Szum, Chander P. Chawla, Timothy E. Bishop
Abstract: The invention relates to a copolyether ester composition for products that show particularly good aging behaviour when exposed to dynamic deformation at elevated temperatures and in contact with greases. The copolyether ester composition comprises a mixture of at least 2 copolyether esters A and B, composed of hard segments derived from at least one alkylene diol and at least one aromatic dicarboxylic acid and soft segments derived from at least one polyalkylene oxide glycol and at least one aromatic dicarboxylic acid, in which the concentration of soft segments X in A and the concentration of soft segments Y in B lie between 30 and 65 wt. %, relative to the copolyether ester and the molecular weights of X and Y lie between 500 and 3000 and |Mx−My|≧400.
Type:
Grant
Filed:
December 4, 1998
Date of Patent:
February 13, 2001
Assignee:
DSM N.V.
Inventors:
Henk W. Berendse, Béla B. Fudala, Ivan Vulic
Abstract: The invention relates to a ballistic-resistant molded article containing a compressed stack of monolayers, with each monolayer containing unidirectionally oriented reinforcing fibers and at most 30 wt. % of a plastic matrix material and with the fiber direction in each monolayer being rotated with respect to the fiber direction in an adjacent monolayer, characterized in that the density (&rgr;P) of the compressed stack is at least 98.0% of the theoretical maximum density. The invention also relates to a process for manufacturing the molded article. The ballistic-resistant article may be used in, for instance, helmets, as inserts in bullet-proof vests, as armoring on military vehicles and in ballistic-resistant panels.
Abstract: A liquid curable resin composition exhibiting superior storing stability and suitable for use as a material for optical fiber ribbon matrix, a bundling material, and a material for up-jacketing fibers. The composition contains a first polydimethylsiloxane compound which contains (i) at least two urethane bonds, (ii) an unreactive organic group attached to at least one end of the first polydimethyl-siloxane, and (iii) a (meth)acrylol group attached to at least one end of the first polydimethylsiloxane, and a second polydimethylsiloxane compound which contains (i) at least two urethane bonds and (ii) an unreactive organic group attached to at least one end of the second polydimethylsiloxane, and optionally a third polysiloxane compound which does not contain urethane bonds.
Type:
Grant
Filed:
October 7, 1999
Date of Patent:
January 30, 2001
Assignees:
DSM N.V., JSR Corporation
Inventors:
Yoshikazu Yamaguchi, Zen Komiya, Takashi Ukachi
Abstract: A solid imaging apparatus and method produces an integral three-dimensional object from a multiplicity of cross sectional portions of the object by selectively exposing successive layers of a liquid photoformable composition to actinic radiation. The apparatus includes a vessel for containing the composition so as to present a free surface, and a movable platform disposed within the vessel below the free surface. Part of the composition is transferred above the free surface by lowering and raising a dispenser at predetermined positions located away from the platform. A doctor blade contacts the composition transferred above the free surface, and then moves over the platform to form a substantially uniform layer of the composition.
Type:
Grant
Filed:
February 21, 1997
Date of Patent:
January 16, 2001
Assignee:
DSM N.V.
Inventors:
Brian Gregory Chapman, Christian Henning Clausen, Daniel James Mickish, Eustathios Vassiliou
Abstract: The present invention provides an improved hydroformylation process in which the catalyst system is composed of a Group VIII metal and organic phosphite ligand having the structure P(OR)2-OR′O—P(OR)2 or P(OR)3, where R and R′ are organic residues which may be the same or different and where the R or R′ contain at least one C9 to C40 aliphatic group positioned as a tail extending away from the primary ligand structure rendering the ligand lipophilic.
Type:
Grant
Filed:
December 11, 1998
Date of Patent:
January 16, 2001
Assignees:
E. I. du Pont de Nemours and Company, DSM N.V.
Abstract: Process for the preparation of an alkyl pentenoate respectively an aryl pentenoate by contacting an alkoxy-butene respectively an aryloxy-butene compound with carbon monoxide in the presence of a catalyst system comprising palladium, a phosphorus ligand and an acid promotor, wherein the molar ratio of 3-alkoxy-1-butene to 1-alkoxy-2-butene, respectively the molar ratio of 3-aryloxy-1-butene to 1-aryloxy-2-butene, is higher than 4.
Type:
Grant
Filed:
August 26, 1999
Date of Patent:
January 16, 2001
Assignee:
DSM N.V.
Inventors:
Henk Oevering, Patrick M Burke, Otto E Sielcken
Abstract: Car part made from a polyamide composition wherein the polyamide substantially consists of 60-99 wt. % units derived from aliphatic dicarboxylic acids and diamines and the remaining chain units are derived from cycloaliphatic dicarboxylic acid(s) and an aliphatic diamine or cycloaliphatic diamine(s) and an aliphatic dicarboxylic acid.
Abstract: Optical fiber primary coating systems are disclosed having excellent ribbon stripping and adhesion behavior. The coatings are radiation-curable. The excellent stripping and adhesion behavior can be inner primary coating composition having a slip enhancing component and a high modulus outer primary coating composition. Combination of means can be employed. Stripping behavior can be measured by crack propagation and fiber friction measurements.
Type:
Grant
Filed:
July 15, 1999
Date of Patent:
January 2, 2001
Assignee:
DSM N.V.
Inventors:
David M. Szum, Chander P. Chawla, James R. Petisce, George Pasternack, Timothy E. Bishop, Paul E. Snowwhite, Edward P. Zahora
Abstract: The invention relates to a plastic sheeting which is suitable, in particular, for application in the construction industry.
It is obtained by employing polyetherester block copolymers and has good humidity-regulating properties and water impermeability. Flame retardancy in accordance with DIN 4102 B2 is obtained by employing melamine, melamine compounds or melamine condensates in the polyetherester composition for the sheeting.
Type:
Grant
Filed:
June 22, 1998
Date of Patent:
January 2, 2001
Assignee:
DSM N.V.
Inventors:
Henricus J. J. Goertz, Richerdes J. M. Hulskotte, Reinoldus J. M. Borggreve
Abstract: A reactor for the synthesis of urea from ammonia and carbon dioxide at elevated temperature and pressure is provided with perforated reactor trays in which at least a pair of spaced part perforated reactor trays each have at least one opening at least a distance closer towards the periphery than the center, such as on or near the edge of a perforated reactor tray, and each of such pair perforated reactor trays is provided with a tube with a height of 50-500 mm located on and depending from an underside, e.g. bottom side in a column reactor, of each of such pair perforated reactor tray. The tubes extend to no more than 1/3 of the distance between two adjacent reactor trays.
Abstract: Multicrystalline melamine powder having the following properties:specific surface area: 0.7-5 m.sup.2 /glevel of oxygen-containing components <0.7 wt %color APHA less than 17melamine: >98.5 wt %melam: <1.3 wt %Multicrystalline melamine powder obtainable via a high-pressure process in which solid melamine is obtained by the melamine melt being transferred to a vessel where the melamine melt is cooled with an evaporating cooling medium, the melamine melt having a temperature between the melting point of melamine and 450.degree. C. being treated with 0.1-15 mol of ammonia per mole of melamine and then being sprayed via spraying means and cooled with an evaporating cooling medium within a vessel in an ammonia environment at an ammonia pressure of 0.1-25 MPa, the melamine melt being converted into melamine powder having a temperature between 200.degree. C. and the solidification point of melamine, the melamine powder then being cooled to a temperature below 50.degree. C.
Abstract: A fermentation process is disclosed for producing an HMG-CoA reductase inhibitor such as lovastatin or compactin. In particular, it relates to a process wherein at least part of the assimilable nitrogen source and, optionally, the carbon source is provided continuously or intermittently to the culture.
Abstract: Reactive silica particles capable of producing coatings exhibiting excellent scratch resistance, weather resistance, adhesiveness, and curability, while satisfying a wide spectrum of performances from transparency to semi-transparency and providing a glossy surface as well as a frosty surface.
Type:
Grant
Filed:
April 2, 1998
Date of Patent:
December 12, 2000
Assignees:
DSM N.V., JSR Corporation, Japan Fine Coatings
Abstract: Process for the preparation of an aldehyde through hydroformylation of an unsaturated organic compound in the presence of a catalyst system comprising rhodium of iridium and a multidentate organic phosphite ligand, wherein a monodentate phosphine is present.The process according to the invention can advantageously be carried out for the preparation of methyl-5-formylvalerate, which is an intermediate product in the preparation of a caprolactam or adipic acid, which are in turn raw materials for the preparation of nylon-6 and nylon-6,6, respectively.
Type:
Grant
Filed:
May 3, 1999
Date of Patent:
November 28, 2000
Assignees:
DSM N.V., E.I. du Pont de Nemours and Company
Inventors:
Onko J. Gelling, Peter C. Borman, Petrus W. N. M. Van Leeuwen
Abstract: The invention relates to a catalyst system and a process suited for the preparation of a rubbery copolymer of ethylene, one or more .alpha.-olefins and optionally one or more polyunsaturated compounds, in which the catalyst system comprises a vanadium compound, an organometal compound and optionally a promoter, characterized in that the organometal complex in the catalyst system is an imido complex that satisfies the general formula(R.sub.u -X.sup.1.sub.v -Me.sup.1).sub.n =NR.sup.1 (I)where each individual Me.sup.1 is a metal chosen from group 1, 2, 12 or 13 of the Periodic System of Elements, each individual R is hydrogen or a hydrocarbon group having 1-20 C atoms, N--R.sup.1 is an imido group where R.sup.1 is hydrogen or a hydrocarbon group having 1-20 C atoms or a group with the general formula MR.sup.3.sub.3, where M is an element chosen from group 14 of the Periodic System of Elements, each individual R.sup.3 is hydrogen, a hydrocarbon group having 1-20 C atoms or a heteroatom-containing group, X.sup.
Abstract: The present invention discloses that topically occurring microbial growth is inhibited by applying a topical composition comprising a sphingoid base. Specifically, said sphingoid base is effectively formulated in combination with a surfactant.
Type:
Grant
Filed:
December 29, 1998
Date of Patent:
November 14, 2000
Assignee:
DSM N.V.
Inventors:
Johannes Wilhelmus Jacobus Lambers, Hugo Streekstra
Abstract: The invention relates to a process for preparing a conductive curable moulding compound with reduced electrical surface resistance, comprising mixing together an unsaturated polyester resin, a thermoplastic polymer, a conductive paste and optionally a filler, and is characterized in that the conductive paste is obtained by dispersing conductive pigment particles in a solution of a thermoplastic polymer in a suitable solvent. The invention further relates to the conductive paste itself and to mouldings having reduced surface resistance, obtained therefrom.
Type:
Grant
Filed:
March 24, 1999
Date of Patent:
November 7, 2000
Assignee:
DSM N.V.
Inventors:
Dieter Buhl, Heinz Fuerst, Harald Schneider, Jan Visser, Joachim Zwecker