Abstract: The invention provides a process for the preparation of valerolactone, said process comprising reacting levulinic acid with hydrogen by using a solid Ru catalyst, characterized in that the process is carried out in the presence of at least 0.08% (w/w) water relative to the amount of levulinic acid. Said process may be faster and more selective. This process advantageously allows the production of valerolactone from renewable sources. The valerolactone may be used in the preparation of methylpentenoate, adipic acid dimethylester, adipic acid, hexamethylenediamine, and polyamide 6,6 (all claimed).
Type:
Grant
Filed:
June 20, 2012
Date of Patent:
December 3, 2013
Assignee:
DSM IP Assets B.V.
Inventors:
Anna Maria Cornelia Francisca Castelijns, Michele Catherine Christianne Janssen, Henricus Wilhemus Leonardus Marie Vaessen
Abstract: The present invention relates to a resin composition comprising (a) from 30 to 70 wt. % of a vinyl ester resin, (b) from 30 to 70 wt. % of reactive diluent, wherein the resin composition comprises methacrylate containing compound and an itaconate ester as reactive diluent.
Type:
Grant
Filed:
March 24, 2010
Date of Patent:
December 3, 2013
Assignee:
DSM IP Assets B.V.
Inventors:
Marian Henryk Szkudlarek, Johan Franz Gradius Antonius Jansen
Abstract: The invention relates to aqueous compositions comprising an anionic surfactant and a hyperbranched polyesteramide comprising at least one secondary amide bond and having at least one quarternized amine end-group. The compositions, in particular in the form of shampoo preparations are suited for increasing the volume of hair treated therewith. Furthermore, such compositions provide styling attributes and increase the wet-combability of hair.
Type:
Grant
Filed:
June 19, 2009
Date of Patent:
December 3, 2013
Assignee:
DSM IP Assets B.V.
Inventors:
Franciscus Derks, Stephen Foster, Robert Lochhead, Adarsh Maini, Dirk Weber
Abstract: The present invention is directed to a formulation of a lipophilic health ingredient comprising a lipophilic health ingredient, a protective colloid comprising a modified starch and an emulsifier. The present invention is further directed to a formulation of (a) lipophilic health ingredient(s) comprising (a) lipophilic health ingredient(s) and a protective colloid, wherein said protective colloid is a modified starch, characterized in that the formulation has a residual moisture content ?6.5 weight-%, based on the total weight of the formulation, as well as to a process for their manufacture. The latter formulations are especially suitable for the preparation of stable tablets of these lipophilic health ingredients.
Type:
Grant
Filed:
July 21, 2008
Date of Patent:
December 3, 2013
Assignee:
DSM IP Assets B.V.
Inventors:
Sylvain Diguet, Bruno H. Leuenberger, Bernd Schlegel, Johann Ulm
Abstract: The present invention describes a process comprising a) subjecting a microorganism to autolysis under conditions at which a substantial part of the RNA remains in a form degradable into 5?-ribonucleotides; b) subjecting the autolysate to solid/liquid separation and recovering the RNA-containing cell wall fraction; and c) converting the RNA in the recovered RNA-containing cell wall fraction into 5?-ribonucleotides, whereby the solid/liquid separation in step b) is done at a pH of lower than 5.1. Said process is simple and allows for the production of a very pure composition of 5?-ribonucleotides. It also allows for the production of a very clear yeast extract.
Abstract: Animal feed with 25-hydroxy vitamin D3 added, optionally in combination with vitamin D3, improves bone strength in animals, particularly pigs.
Abstract: A polymer composition containing a polymer, which polymer contains a residue of a dimerised fatty acid and/or a derivative thereof, which polymer composition contains an epoxidized plasticizer.
Type:
Application
Filed:
December 12, 2011
Publication date:
November 28, 2013
Applicant:
DSM IP Assets B.V.
Inventors:
Zeynep Özyürek, Atze Jan Nijenhuis, Paul Willem Jan Van Den Heuvel, Francois Antoine Marie Buijsch Op Den
Abstract: A photocurable resin composition for three-dimensional photofabrication operations, including stereolithography, comprising (A) a cationically polymerizable compound having two or more bisphenol structures and one or more hydroxyl groups, (B) a cationically polymerizable compound other than the component (A), (C) a cationic photoinitiator, (D) a radically polymerizable compound, (E) a radical photoinitiator, and (F) multilayer polymer particles having a core and a shell layer, the shell layer containing functional group-modified rubber polymer particles having at least one reactive functional group.
Type:
Application
Filed:
May 21, 2013
Publication date:
November 28, 2013
Applicants:
DSM IP Assets B.V., Japan Fine Coatings Co., Ltd., JSR Corporation
Abstract: The present invention relates to polyethylene material that has a plurality of unidirectionally oriented polyethylene monolayers cross-plied and compressed at an angle to one another, each polyethylene monolayer composed of ultra high molecular weight polyethylene and essentially devoid of resins. The present invention further relates to ballistic resistant articles that include or incorporate the inventive polyethylene material and to methods of preparing the material and articles incorporating same.
Abstract: The present invention describes a process to produce a yeast extract comprising a) subjecting yeast to autolysis; and b) subjecting the autolysate to solid/liquid separation and recovering the soluble fraction, whereby the solid/liquid separation in step b) is done at a pH of less than 5.1. The process of the invention is simple, has a high yield, and results in a yeast extract having low turbidity.
Abstract: Ballistic resistant sheets and molded articles formed thereof are disclosed, wherein a ballistic resistant sheet includes a stack of at least 4 monolayers, each monolayer containing unidirectionally oriented reinforcing fibers with a tensile strength of between 3.5 and 4.5 GPa, and at most 20 mass % of a matrix material, the areal density of a monolayer is at least 25 g/m2 and with the fiber direction in each monolayer being rotated with respect to the fiber direction in an adjacent monolayer. When a plurality of the ballistic resistant sheets are formed into a pile and subjected to curved molding conditions, a homogenous curved ballistic resistant molded article is formed without irregular folding of the ballistic resistant sheets in the pile.
Type:
Grant
Filed:
December 21, 2007
Date of Patent:
November 26, 2013
Assignee:
DSM IP Assets B.V.
Inventors:
Martin Antonius M. A. Es Van, Marcel M. Jongedijk, Roelof R. Marissen, Hen H. Hoefnagels
Abstract: The present invention relates to a process of reacting specific compounds, which are defined below with hydrogen in the presence of a structured catalyst based on sintered metal fibers (SMF) coated by a ZnO layer with Pd-nanoparticles, to reactions of these specific compounds with hydrogen in the presence of said catalyst and an organic base as well as to vitamins, carotinoids, perfume ingredients, and/or food or feed ingredients prepared by using this reaction.
Type:
Grant
Filed:
January 28, 2011
Date of Patent:
November 26, 2013
Assignee:
DSM IP Assets B.V.
Inventors:
Werner Bonrath, Thomas Mueller, Lioubov Kiwi-Minsker, Albert Renken, Igor Iouranov
Abstract: The invention relates to Mutant cellobiohydrolase, being a mutant of SEQ ID NO:1, having a substitution at position N247(I,F,H,W) of SEQ ID NO: 1, wherein the mutant cellobiohydrolase has at least 50% sequence identity with SEQ ID NO: 1, and wherein the mutant cellobiohydrolase has CBHI activity.
Type:
Application
Filed:
January 30, 2012
Publication date:
November 21, 2013
Applicant:
DSM IP ASSETS B.V.
Inventors:
Jan Metske Van Der Laan, Margot Elisabeth Francoise Schooneveld-Bergmans, Denise Ilse Jacobs
Abstract: Described is a method for the preparation of renin inhibitors such as aliskiren, and intermediates useful therein. The method introduces a nitrogen-containing intermediate such as a lactone of formula (8). with R4 being a branched C3-6 alkyl. In the preparation of the lactone, or related intermediates, a desired stereochemical configuration can be controlled by starting from a chiral aldehyde satisfying formula (10).
Type:
Application
Filed:
July 11, 2013
Publication date:
November 21, 2013
Applicant:
DSM IP ASSETS B.V.
Inventors:
Ben DE LANGE, Anna Maria Cornelia Francisca CASTELIJNS, Johannes Gerardus DE VRIES, Andreas Hendrikus Maria DE VRIES, Jeroen Antonius Franciscus BOOGERS
Abstract: Use of pure lanthanum oxide which is obtained by calcination of oxygen-containing lanthanum salts at temperatures of at least 700° C. as heterogeneous catalyst in the aldol condensation of citral and acetone to give pseudoionone, and process for the preparation of pseudoionone by aldol condensation of citral and acetone in the liquid phase using pure lanthanum oxide.
Type:
Application
Filed:
July 19, 2011
Publication date:
November 21, 2013
Applicant:
DSM IP ASSETS B.V.
Inventors:
Wolfgang Hölderich, Verena Ritzerfeld, Bernhard Markus Ernst Russbüldt, Erhard Henning Fleischhauer, Werner Bonrath, Reinhard Karge, Jan Schütz
Abstract: The present invention describes a mannoprotein solution which has a turbidity, when measured by nephelometry at a concentration of 200 g/l of mannoprotein and at a pH in the range of pH 4 to pH 8 lower than 70 NTU, preferably lower than 60 NTU, more preferably lower than 50 NTU, most preferably lower than 40 NTU. This solution can be advantageously used in the stabilisation of wine against tartrate salt precipitation because it is very clear and can be added directly to the wine without causing any turbidity.
Type:
Application
Filed:
July 23, 2013
Publication date:
November 21, 2013
Applicant:
DSM IP ASSETS B.V.
Inventors:
Peter Philip Lankhorst, Hendrik Louis Bijl, Ibrahim Oezkan