Abstract: An improvement in the preparation of orthosilicic acid tetraalkyl esters by reaction of metallic silicon with alcohol in the presence of alkali alcoholate is disclosed, the improvement residing in carrying out the reaction in the co-presence of an ether alcohol or alkanolamine as cocatalyst.
Type:
Grant
Filed:
April 16, 1979
Date of Patent:
September 23, 1980
Assignee:
Dynamit Nobel Aktiengesellschaft
Inventors:
Wilhelm Flick, Hermann Richtzenhain, Volker Hunger, Wilhelm Joch
Abstract: A process for coating an inorganic silicatic substrate is described wherein the substrate is contacted with a copolymer of vinylacetate and a vinylalkoxysilane followed by water removal.
Abstract: A method has been invented for the preparation of phthalide which comprises chlorinating o-toluic acid at 30.degree.-260.degree. C. and recovering the phthalide obtained.
Abstract: Glycidyloxypropylalkoxysilanes are produced by thermal treatment of novel siliceous dioxolane derivatives of the formula: ##STR1## wherein a is 0 or 1 and R represents an oxygen radical or two hydrogen atoms and R' and R" each represents an alkyl radical, wherein the R" 's can be the same or different. The glycidyl products are useful as adhesives.
Abstract: Process for the side-chain chlorination of aromatic compounds completely halogenated in the nucleus, containing methyl groups, and having the general formulas: ##STR1## wherein y=1 or 2, z=0 to 1, x=6-(y+z), n=0 to 8 and k=(8-n) and the methyl groups are, respectively, in the ortho, meta or para position to one another and in the p-position to the oxygen bridge, by thermal chlorination in the liquid phase. The bis-monochloromethyl compounds of formula (II) are novel compounds. The chlorination products are useful as intermediates.
Type:
Grant
Filed:
May 15, 1978
Date of Patent:
July 15, 1980
Assignee:
Dynamit Nobel Aktiengesellschaft
Inventors:
Egon N. Petersen, Hermann Richtzenhain, Klaus Schrage
Abstract: A method has been invented for preparing phthalide by catalytic hydrogenation with a Periodic Table, Group VIII catalyst of a phthalide substituted in the 3-position by a hydroxyl, methoxy or acetoxy group.
Abstract: A polymer having as a component thereof a moiety corresponding to a monomer having the following formula ##STR1## wherein n=0 or 1, X is bromine, chlorine or a mixture thereof and R represents hydrogen or methyl, a method of preparing the same and the use of such a polymer, including a copolymer thereof in a plastic composition containing a normally flammable plastic.
Type:
Grant
Filed:
July 10, 1978
Date of Patent:
July 8, 1980
Assignee:
Dynamit Nobel Aktiengesellschaft
Inventors:
Norbert Vollkommer, Egon N. Petersen, Herbert Klinkenberg, Werner Schmidt
Abstract: A ceramic molding composition comprising an alcoholate of aluminum or a metal of the fourth sub-group of the Periodic System, a refractory metal oxide and a polyvalent alcohol, an improvement in the formation of a ceramic product wherein a ceramic molding composition is shaped and hardened, which improvement resides in employing the above defined ceramic molding composition.
Type:
Grant
Filed:
June 22, 1978
Date of Patent:
July 8, 1980
Assignee:
Dynamit Nobel Aktiengesellschaft
Inventors:
Werner Dittrich, Walter Josten, Heinz Nestler, Friedhelm Schnippering
Abstract: A projectile for training ammunition wherein the projectile body is joined at its front end to a dummy detonator. The dummy detonator is constructed as a hollow body and preferably a cap-shaped hollow body.
Abstract: A rocket fuel is formed by mixing a liquid prepolymer of butadiene having carboxyl groups with hexamethylene tetramine or a nitroso derivative thereof, shaping and hardening.
Abstract: A continuous composite sheet material is formed of a genuine wood sheet bonded by a layer of adhesive to a thermally weldable, thermoplastic synthetic resin carrier sheet. This composite sheet is especially useful as a covering for a profiled structure used in furniture construction or interior decoration.
Type:
Grant
Filed:
October 24, 1978
Date of Patent:
May 27, 1980
Assignee:
Dynamit Nobel Aktiengesellschaft
Inventors:
Hans Jaschke, Rudolf Kautz, Hermann Plate, Horst Ulb
Abstract: A process for producing elongated profile members made of thermoplastic synthetic resins having a coating over at least a portion of their circumference of at least one additional thermoplastic polymeric material which includes the steps of extruding a coating of a thermoplastic secondary material, simultaneously and continuously with the extrusion of the elongated profile member, onto said member while said member is still within the plastic temperature range, and subsequently sizing the resultant coated member.
Abstract: A composition comprising a polyvinylidene fluoride and a fluoroelastomer, especially a fluoroelastomer containing moieties of vinylidene fluoride and hexa- or pentafluoropropylene, and methods for the preparation of formed articles from such composition and formed articles thereof having improved notch impact toughness and elongation at rupture.This is a continuation, filed June 8, 1977, now abandoned, which in turn is a continuation of 609,870 filed Sept. 2, 1975 (now abandoned).
Abstract: A method of preparing certain dihalogen vinyl cyclopropane carboxylic acid esters of the formula ##STR1## wherein R is an alkyl moiety and X is chlorine or bromine by exposing a dihalogen vinyl dihydrofuran of the formula ##STR2## to light, e.g., ultraviolet light. Also disclosed is a method for preparing such 2,4,4-trimethyl-3-carbalkoxy-5-(.beta.,.beta.-dihalogenvinyl)-4,5-dihydrof urans by reaction of a .beta.-alkoxycrotonic acid ester or 3,3-bisalkoxybutyric acid ester with a 1,1,1-trihalogen-4-methyl-3- or -4-pentene-2-ol in the presence of an acid catalyst. Also disclosed is a method of converting such 2,4,4-trimethyl-3-carbalkoxy-5-(.beta.,.beta.-dihalogenvinyl)-4,5-dihydrof uran by thermal rearrangement into 2,5,5-trimethyl-3-carbalkoxy-4-(.beta.,.beta.-dihalogenvinyl)-4,5-dihydrof urans. Such 2,4,4- and 2,5,5-trimethyl-3-carbalkoxy-5-(.beta.,.beta.-dihalogenvinyl)-4,5-dihydrof urans are new.
Abstract: A method of preparing certain dihalogen vinyl cyclopropane carboxylic acid esters of the formula ##STR1## wherein R is an alkyl moiety and X is chlorine or bromine by exposing a dihalogen vinyl dihydrofuran of the formula ##STR2## to light, e.g., ultraviolet light. Also disclosed is a method for preparing such 2,4,4-trimethyl-3-carbalkoxy-5-(.beta.,.beta.-dihalogenvinyl)-4,5-dihydrof urans by reaction of a .beta.-alkoxycrotonic acid ester or 3,3-bisalkoxybutyric acid ester with a 1,1,1-trihalogen-4-methyl-3- or -4-pentene-2-ol in the presence of an acid catalyst. Also disclosed is a method of converting such 2,4,4-trimethyl-3-carbalkoxy-5-(.beta., .beta.-dihalogenvinyl)-4,5-dihydrofuran by thermal rearrangement into 2,5,5-trimethyl-3-carbalkoxy-4-(.beta.,.beta.-dihalogenvinyl)-4,5-dihydrof urans. Such 2,4,4- and 2,5,5-trimethyl-3-carbalkoxy-5-(.beta.,.beta.-dihalogenvinyl)-4,5-dihydrof urans are new.
Abstract: A method of preparing certain dihalogen vinyl cyclopropane carboxylic acid esters of the formula ##STR1## wherein R is an alkyl moiety and X is chlorine or bromine by exposing a dihalogen vinyl dihydrofuran of the formula ##STR2## to light, e.g., ultraviolet light. Also disclosed is a method for preparing such 2,4,4-trimethyl-3-carbalkoxy-5-(.beta..beta.-dihalogenvinyl)-4,5-dihydrofu rans by reaction of a .beta.-alkoxycrotonic acid ester or 3,3-bisalkoxybutyric acid ester with a 1,1,1-trihalogen-4-methyl-3-or -4-pentene-2-ol in the presence of an acid catalyst. Also disclosed is a method of converting such 2,4,4-trimethyl-3-carbalkoxy-5-(.beta.,.beta.-dihalogenvinyl)-4,5-dihydrof uran by thermal rearrangement into 2,5,5-trimethyl-3-carbalkoxy-4-(.beta.,.beta.-dihalogenvinyl)-4,5-dihydrof urans. Such 2,4,4- and 2,5,5-trimethyl-3-carbalkoxy-5-(.beta.,.beta.-dihalogenvinyl)-4,5-dihydrof urans are new.
Abstract: A process for preparing an orthosilicic acid tetraester of a monoalkyl ether of an aliphatic glycol having 2 to 6 carbon atoms which comprises contacting silicon, iron silicide or ferrosilicon with a monoalkyl ether of an aliphatic glycol having 2 to 6 carbon atoms in the aliphatic chain in the presence of the corresponding orthosilicic acid tetraalkoxy alkyl ether at a temperature between 125 and 250.degree. C.
Type:
Grant
Filed:
October 30, 1974
Date of Patent:
April 8, 1980
Assignee:
Dynamit Nobel Aktiengesellschaft
Inventors:
Wilhelm Joch, Arnold Lenz, Walter Rogler
Abstract: A composition comprising a granular inorganic oxidic material other than glass powder and 1 to 30 weight percent, based on the weight of said material, of glass powder, especially a composition additionally containing a hardenable thermo- or cold-setting phenolic resin, which composition does not disintegrate at high temperatures and retains compressive strength.
Type:
Grant
Filed:
March 10, 1977
Date of Patent:
April 1, 1980
Assignee:
Dynamit Nobel Aktiengesellschaft
Inventors:
Walter Hoppe, Hans Junger, Franz Weissenfels